CN1587145A - Method for forming natural relief on ceramic glaze and its used ceramic glaze - Google Patents
Method for forming natural relief on ceramic glaze and its used ceramic glaze Download PDFInfo
- Publication number
- CN1587145A CN1587145A CN 200410050968 CN200410050968A CN1587145A CN 1587145 A CN1587145 A CN 1587145A CN 200410050968 CN200410050968 CN 200410050968 CN 200410050968 A CN200410050968 A CN 200410050968A CN 1587145 A CN1587145 A CN 1587145A
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- CN
- China
- Prior art keywords
- glaze
- ceramic
- ceramic glaze
- weight percent
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/08—Frit compositions, i.e. in a powdered or comminuted form containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/22—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions containing two or more distinct frits having different compositions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Glass Compositions (AREA)
Abstract
The ceramic glaze of the present invention contains K2O, Al2O3, SiO2, CaO, MgO, P2O5, impurity, and components decomposed and volatized at glaze sintering temperature. The use method of the ceramic glaze includes wet ball milling, applying glaze, drying to form 0.4-1 mm thick glaze layer, sintering at 1160-1250 deg.c to obtain the relief product with discrete glaze blocks or sheets, which are smooth, fine, naturally beautiful. The present invention may be used in producing daily used ceramic product, artistic work, ceramic work, building ceramic product, etc.
Description
Technical field
The present invention relates to the manufacture method of ceramic and the material of use, particularly on Ceramic glaze, form the method and the employed ceramic glaze thereof of concavo-convex anaglyph.
Background technology
Form concavo-convex embossment at ceramic surface and have its special cubic appearance, in household china and bone china, be favourably welcome.Prior art with the engraving, heap is filled out or printing transferring method is processed the embossment shape on biscuit of ceramics, glazing again, glaze firing is formed with the pottery of plastic relief sensation, this way needs a lot of artificial and dies, complex process, the tooling cost height, and gather more glaze but concave-convex effect is clear inadequately at recess, thereby the pottery of making is only applicable to rough products such as wall floor tile usually, can not be suitable for as fields such as household china, artistic porcelains.
The innovation and creation content
Thereby the purpose of this invention is to provide a kind of making and form the ceramic glaze that natural particle shape projection forms the simple and easy method of concavo-convex anaglyph and can form natural particle shape projection after glaze firing on the Ceramic glaze.
The present invention is by executing certain thickness ceramic glaze on ceramic green or biscuit, this glaze in drying process owing to shrinking dry and cracked cracking, make the glaze vitrifying through glaze firing, the control temperature of glaze firing makes glaze have adequate liquidity, because also being gathered into separately in the cracks disjunction, glaze self surface tension drips, thus the raised emboss effect of generation nature.
Ceramic glaze of the present invention contains following component and weight percent: K
2O:6.2～9.5%, Al
2O
3: 9.6～18.7%, SiO
2: 33.0～58.4%, CaO:14.2～30.1%, MgO:2.9～6.0%, P
2O
5: 2.1～5.4%, and the impurity and the temperature of glaze firing of content easily decompose down or volatile component usually.
The preferred weight percent of said components is: K
2O:7.0～8.6%, Al
2O
3: 11.9～16.4%, SiO
2: 39.3～52.0%, CaO:18.1～26.0%, MgO:3.7～5.2%, P
2O
5: 3.1～4.4%.
K in the said components
2O, CaO, MgO can use one or more in respective metal oxide compound, carbonate and the silicate, Al
2O
3Can use in respective metal oxide compound and the silicate one or more, P
2O
5Can use calcium phosphate, trimagnesium phosphate or potassiumphosphate.
Said components also can be used ore, compound or the composition that becomes said components after temperature of glaze firing decomposes down or volatilizees.
Easy down decomposition of described temperature of glaze firing or volatile component be CO preferably
2And H
2Among the O one or both.
Among the present invention, it is raw material that described ceramic glaze adopts following ore or compound, and its composition and weight percent are: potassium felspar sand 32～48%, marble 18～36%, talcum 8～16%, kaolin or clay 6～18%, calcium phosphate 4～10%.Preferred weight percent is: potassium felspar sand 32～48%, marble 18～36%, talcum 8～16%, kaolin 2～6%, clay 4～12%, calcium phosphate 4～10%.More preferably: potassium felspar sand 38～42%, marble 26～30%, talcum 10～15%, kaolin 3～5%, clay 6～10%, calcium phosphate 6～8%.
Can also add the color base material that uses in the ceramic industry in the above-mentioned ceramic glaze so that product shows the color of color base material after the glaze firing.
Use can be on the glaze of the ceramic whole or local nature embossment that produces of above-mentioned ceramic glaze, its method comprises following steps:
A. the component of the described ceramic glaze of the arbitrary claim of claim 1～5 is pressed described percentage mix, pulverize, add water for ball milling, make the solid particulate fineness for passing through 260 mesh sieves by 1: 1 weight ratio;
B. the whole or a certain requirement that above-mentioned ceramic glaze is imposed on ceramic green or biscuit produces on the part of nature embossment, and the dry back of formation thickness is 0.4～1 millimeter glaze layer;
C. after the glaze layer drying, 1160～1250 ℃ of following glaze firing, cooling obtains executing the ceramic that bulk or sheet nature embossment appear in above-mentioned ceramic glaze zone.
Above-mentioned glaze layer thickness is preferably 0.5～0.8 millimeter, is more preferably 0.6～0.8 millimeter.Among the step C, temperature of glaze firing is preferably 1190～1220 ℃.
The present invention is simple to operate, grasp easily and control in the production, the ceramic cost of making is low, the zone of ceramic glaze of the present invention produces the embossment of natural particle shape on executing, the smooth exquisiteness of glaze, isolate mutually between the projection particle, has unique natural aesthetic feeling, intergranular recess does not adhere to ceramic glaze, form groove clearly, the present invention can require to make protruding particle height reach 1～1.8 millimeter according to products appearance, spraying color base material on green compact that can be before glazing or the biscuit, perhaps on the glaze layer, spray the color base material after the glazing, perhaps in ceramic glaze, add the color base material and make goods form the color of color base material.The present invention can be used for making domestic ceramics, bone china, ceramics and building ceramic such as anti-skidding ceramic tile, decoration ceramic tile etc.
Embodiment
Get 4 kilograms of potassium felspar sands, 2.8 kilograms in marble, 1.3 kilograms in talcum, 0.4 kilogram of kaolin, originate in 0.7 kilogram of mixing of 0.8 kilogram of clay, calcium phosphate of Chaozhou flying apsaras swallow, ball milling 52 hours behind 260 mesh sieves, adds 10 kg water excessively, mixing and ball milling 50 hours, the gained slurry is a ceramic glaze of the present invention.
Ceramic green or biscuit are cleaned out, execute normally used transparent or various color glaze at the zone such as the vessel inwall that need glaze but do not need to form embossment, and the marble paper transfer printing printing technology that carries out usually being done operation, so that the product after the glaze firing forms pattern and smooth smooth glaze in this zone.Execute ceramic glaze of the present invention at the zone such as the vessel outer wall of needs formation embossment then, the mode glazing that the glazing mode can adopt spraying, brushing or get with the immersion libation at an ancient wedding ceremony, dry then, dry back glaze layer thickness is that 0.6～0.8 millimeter person is that glazing is qualified.For a ceramic, the glaze layer thickness is preferably even.The meeting nature is dry and cracked after the glaze layer drying, produces a large amount of crackles, and the glaze layer is become countless fritters by crack segmentation.
After glazing was finished, loading of kiln glaze firing adopted oxidation to burn till.As marble paper is arranged in the fruit product, arrange film down at 850～900 ℃ earlier.Kiln temperature rise to 1210 ℃ then is incubated 5～10 minutes so that kiln temperature is even, annealing cooling then.The ceramic product that obtains is being executed the smooth and gloss that conventional glaze position shows conventional glaze, execute that ceramic glaze of the present invention position forms a large amount of bulks, the top is the protruding naturally transparent embossment of cambered surface, middle a little more than periphery, original crack position becomes groove, and width enlarges, and can see does not have adhering to of glaze.
In the production, best temperature of glaze firing can change slightly because of the variation of the composition of ceramic glaze, but should be higher than the second-order transition temperature of ceramic glaze, and temperature of glaze firing too high as be higher than 1350 ℃ can be too little because of the viscosity of ceramic glaze, mobile excessive, the glaze laminar flow is put down and the anaglyph variation.
Among the present invention, the color base material that uses in the ceramic industry can be joined and form coloured ceramic glaze in the ceramic glaze, perhaps form and color base material that proportioning is constituted joins in the ceramic glaze of the present invention by following, the ceramic raised emboss made thus shows the color of color base material, is more suitable in as the technology exhibit:
Constitute white color base material by zirconium silicate 52～72% and zinc oxide 28～48% (weight percent), in color base material and 13: 100 ratio of ceramic glaze weight ratio of the present invention white color base material is added in the ceramic glaze of the present invention, the raised emboss of processing back ceramic is a white;
Constitute black color base material by red iron oxide 65～85%, cobalt oxide 9～29%, chromoxide green 2～10% (weight percent), in color base material and 5.3: 100 ratio of ceramic glaze weight ratio of the present invention black color base material is added in the ceramic glaze of the present invention, the raised emboss of processing back ceramic is a black;
Constitute brown color base material by red iron oxide 6～26%, chromoxide green 4～24%, zinc oxide 39～59%, aluminum oxide 10～30% (weight percent), in color base material and 1.96: 100 ratio of ceramic glaze weight ratio of the present invention brown color base material is added in the ceramic glaze of the present invention, the raised emboss of processing back ceramic is brown;
The red color base material that constitutes by red iron oxide, zircon, Cadmium oxide, potassiumchromate, stannic oxide, magnesium oxide and dispersion agent, ratio in color base material and ceramic glaze weight ratio of the present invention 2～6: 100 is added to red color base material in the ceramic glaze of the present invention, and the raised emboss of processing back ceramic is red;
Constitute blue color base material by Vanadium Pentoxide in FLAKES, zirconium white, cobalt oxide, zinc oxide, ratio in color base material and ceramic glaze weight ratio of the present invention 2～5: 100 is added to blue color base material in the ceramic glaze of the present invention, and the raised emboss of processing back ceramic is blue.
Among the present invention, can also be on ceramic green or biscuit the color paint that uses of coated ceramic industry, execute ceramic glaze of the present invention then, be formed with the embossment pottery of color background.The present invention can also be sprayed at the color base material that uses in the ceramic industry on the glaze layer after the glazing, forms coloured block-shaped protrusion embossment after the glaze firing.
Claims (10)
1. the ceramic glaze that can form the nature embossment on the glaze of ceramic is characterized in that, contains following component and weight percent: K
2O:6.2～9.5%, Al
2O
3: 9.6～18.7%, SiO
2: 33.0～58.4%, CaO:14.2～30.1%, MgO:2.9～6.0%, P
2O
5: 2.1～5.4%, and the impurity and the temperature of glaze firing of content easily decompose down or volatile component usually, described temperature of glaze firing easily decomposes down or volatile component is CO
2And H
2Among the O one or both.
2. according to the described ceramic glaze of claim 1, it is characterized in that the weight percent of described component is: K
2O:7.0～8.6%, Al
2O
3: 11.9～16.4%, SiO
2: 39.3～52.0%, CaO:18.1～26.0%, MgO:3.7～5.2%, P
2O
5: 3.1～4.4%.
3. according to the described ceramic glaze of claim 1, it is characterized in that adopting following ore or compound is raw material, its composition and weight percent are: potassium felspar sand 32～48%, marble 18～36%, talcum 8～16%, kaolin or clay 6～18%, calcium phosphate 4～10%.
4. according to the described ceramic glaze of claim 3, it is characterized in that adopting following ore or compound is raw material, its composition and weight percent are: potassium felspar sand 32～48%, marble 18～36%, talcum 8～16%, kaolin 2～6%, clay 4～12%, calcium phosphate 4～10%.
5. according to the described ceramic glaze of claim 4, it is characterized in that described ore or compound weight percent are: potassium felspar sand 38～42%, marble 26～30%, talcum 10～15%, kaolin 3～5%, clay 6～10%, calcium phosphate 6～8%.
6. according to claim 1 or 3 described ceramic glazes, it is characterized in that, also add the color base material in the described ceramic glaze so that product shows the color of color base material after the glaze firing.
7. the whole or local method that produces the nature embossment on the glaze of ceramic is characterized in that, comprises following steps:
A. the component of the described ceramic glaze of the arbitrary claim of claim 1～5 is pressed described percentage mix, pulverize, add water for ball milling, make the solid particulate fineness for passing through 260 mesh sieves by 1: 1 weight ratio;
B. the whole or a certain requirement that above-mentioned ceramic glaze is imposed on ceramic green or biscuit produces on the part of nature embossment, and the dry back of formation thickness is 0.4～1 millimeter glaze layer;
C. after the glaze layer drying, 1160～1250 ℃ of following glaze firing, cooling obtains executing the ceramic that bulk or sheet raised emboss appear in above-mentioned ceramic glaze zone.
8. according to the described method of claim 7, it is characterized in that among the described step B, the glaze layer thickness is 0.5～0.8 millimeter.
9. described according to Claim 8 method is characterized in that described glaze layer thickness is 0.6～0.8 millimeter.
10. according to the described method of claim 7, it is characterized in that among the described step C, temperature of glaze firing is 1190～1220 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410050968 CN1288104C (en) | 2004-07-30 | 2004-07-30 | Method for forming natural relief on ceramic glaze and its used ceramic glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410050968 CN1288104C (en) | 2004-07-30 | 2004-07-30 | Method for forming natural relief on ceramic glaze and its used ceramic glaze |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1587145A true CN1587145A (en) | 2005-03-02 |
| CN1288104C CN1288104C (en) | 2006-12-06 |
Family
ID=34602326
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410050968 Expired - Fee Related CN1288104C (en) | 2004-07-30 | 2004-07-30 | Method for forming natural relief on ceramic glaze and its used ceramic glaze |
Country Status (1)
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|---|---|
| CN (1) | CN1288104C (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007048890A1 (en) * | 2005-10-27 | 2007-05-03 | Commissariat A L'energie Atomique | Method and device for determining at least one dynamic property of a deformable fluid or solid material |
| CN102049958A (en) * | 2010-10-25 | 2011-05-11 | 深圳市祥钰精品制造有限公司 | Processing technique for colored carved dark-red enameled pottery |
| CN102731158A (en) * | 2012-06-19 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Ceramic glaze surface having three-dimensional effect |
| CN101648485B (en) * | 2009-08-28 | 2013-01-02 | 黄淦生 | Method for producing sculpturing landscape relief crafts |
| CN103980007A (en) * | 2014-06-04 | 2014-08-13 | 福建省德化铭丰金花纸有限公司 | Preparation process of overglazed famille-rose embossed printing product |
| CN104230379A (en) * | 2013-06-24 | 2014-12-24 | 魏红霞 | Preparation method of relief glaze |
| CN104230380A (en) * | 2013-06-24 | 2014-12-24 | 魏红霞 | Manufacturing method of relief glaze |
| CN107963813A (en) * | 2017-12-18 | 2018-04-27 | 广东永航新材料实业股份有限公司 | A kind of preparation method of the candy glaze being tuned into by raw glaze and candy glaze Ceramic Tiles |
| CN109369015A (en) * | 2018-12-10 | 2019-02-22 | 九牧厨卫股份有限公司 | A kind of high relief glaze compound powder, the preparation method of high relief powdered frit and the preparation method of sanitary ceramics high relief |
| CN110981201A (en) * | 2019-12-31 | 2020-04-10 | 湖南省醴陵市楚华陶瓷实业有限公司 | Imitation leather grain glaze material and preparation method of imitation leather grain glaze |
| CN111533581A (en) * | 2020-05-26 | 2020-08-14 | 广东清远蒙娜丽莎建陶有限公司 | Colored leather-feeling convex marble-imitated ceramic tile and preparation method thereof |
| CN114505944A (en) * | 2020-11-16 | 2022-05-17 | 禹州市华龙钧窑有限公司 | Method for manufacturing convex lines on Jun porcelain craft disc |
-
2004
- 2004-07-30 CN CN 200410050968 patent/CN1288104C/en not_active Expired - Fee Related
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007048890A1 (en) * | 2005-10-27 | 2007-05-03 | Commissariat A L'energie Atomique | Method and device for determining at least one dynamic property of a deformable fluid or solid material |
| FR2892814A1 (en) * | 2005-10-27 | 2007-05-04 | Commissariat Energie Atomique | METHOD AND DEVICE FOR DETERMINING AT LEAST ONE DYNAMIC PROPERTY OF A DEFORMABLE FLUID OR SOLID MATERIAL |
| US7484403B2 (en) | 2005-10-27 | 2009-02-03 | Commissariat A L'energie Atomique | Method and device for determining at least one dynamic property of a deformable solid or fluid material |
| CN101648485B (en) * | 2009-08-28 | 2013-01-02 | 黄淦生 | Method for producing sculpturing landscape relief crafts |
| CN102049958A (en) * | 2010-10-25 | 2011-05-11 | 深圳市祥钰精品制造有限公司 | Processing technique for colored carved dark-red enameled pottery |
| CN102731158A (en) * | 2012-06-19 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Ceramic glaze surface having three-dimensional effect |
| CN104230380A (en) * | 2013-06-24 | 2014-12-24 | 魏红霞 | Manufacturing method of relief glaze |
| CN104230379A (en) * | 2013-06-24 | 2014-12-24 | 魏红霞 | Preparation method of relief glaze |
| CN103980007A (en) * | 2014-06-04 | 2014-08-13 | 福建省德化铭丰金花纸有限公司 | Preparation process of overglazed famille-rose embossed printing product |
| CN103980007B (en) * | 2014-06-04 | 2015-12-09 | 福建省德化铭丰金花纸有限公司 | The manufacture craft of famille-rose embossment printed matter on glaze |
| CN107963813A (en) * | 2017-12-18 | 2018-04-27 | 广东永航新材料实业股份有限公司 | A kind of preparation method of the candy glaze being tuned into by raw glaze and candy glaze Ceramic Tiles |
| CN107963813B (en) * | 2017-12-18 | 2021-03-30 | 广东永航新材料实业股份有限公司 | Preparation method of candy glaze and candy glaze ceramic tile prepared from raw glaze |
| CN109369015A (en) * | 2018-12-10 | 2019-02-22 | 九牧厨卫股份有限公司 | A kind of high relief glaze compound powder, the preparation method of high relief powdered frit and the preparation method of sanitary ceramics high relief |
| CN109369015B (en) * | 2018-12-10 | 2022-03-25 | 九牧厨卫股份有限公司 | Preparation method of sanitary ceramic high relief |
| CN110981201A (en) * | 2019-12-31 | 2020-04-10 | 湖南省醴陵市楚华陶瓷实业有限公司 | Imitation leather grain glaze material and preparation method of imitation leather grain glaze |
| CN110981201B (en) * | 2019-12-31 | 2022-05-03 | 湖南省醴陵市楚华陶瓷实业有限公司 | Imitation leather grain glaze material and preparation method of imitation leather grain glaze |
| CN111533581A (en) * | 2020-05-26 | 2020-08-14 | 广东清远蒙娜丽莎建陶有限公司 | Colored leather-feeling convex marble-imitated ceramic tile and preparation method thereof |
| CN114505944A (en) * | 2020-11-16 | 2022-05-17 | 禹州市华龙钧窑有限公司 | Method for manufacturing convex lines on Jun porcelain craft disc |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1288104C (en) | 2006-12-06 |
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Granted publication date: 20061206 |