CN1583633A - Anionic enamel and manufacturing method thereof - Google Patents
Anionic enamel and manufacturing method thereof Download PDFInfo
- Publication number
- CN1583633A CN1583633A CN 200410024769 CN200410024769A CN1583633A CN 1583633 A CN1583633 A CN 1583633A CN 200410024769 CN200410024769 CN 200410024769 CN 200410024769 A CN200410024769 A CN 200410024769A CN 1583633 A CN1583633 A CN 1583633A
- Authority
- CN
- China
- Prior art keywords
- enamel
- tourmalinite
- negative ion
- base
- tourmaline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Cosmetics (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
Percents of negative ion vitrified enamel in the total weight is as follow. Vitrified enamel basic material is 80-90%. Tourmaline is 5-20%. The invention adopts vitrified enamel to be as carrier of tourmaline micromeritic and can improve the function of producing negative ion as possible. When the enamelware mixing tourmaline micromeritic is made to products, bathtub, basin, tea mug et, it will slow different functions. The vitrified enamel is prepared simply with low cost and is secure.
Description
Technical field
The present invention relates to a kind of enamel and preparation method thereof, relate in particular to enamel of a kind of functionalization and preparation method thereof.
Background technology
Enamel is a kind of application material very widely, has important purposes in chemical industry, medicine and daily life product.
Present enamel property is more single, does not have the effect of functionalization, therefore, how to improve its performance, thereby further expands its purposes, be people the problem very paid close attention to.
Summary of the invention
The technical issues that need to address of the present invention are to disclose a kind of negative ion enamel and preparation method thereof, satisfy the needs of people's daily life.
Negative ion enamelled component of the present invention and weight percent content comprise:
Enamel base-material 80～95%
Tourmalinite 5-20%
Said enamel base-material can adopt conventional prescription, as " the disclosed technology of Chinese enamel handbook, preferred weight percent content is as follows:
Quartz 20～30, borax 25～35, feldspar 5～10, soda ash 2～4, nitre sodium 1～2, weisspiessglanz 6～9, ice crystal 6～9, Calcium Fluoride (Fluorspan) 2～3, barium carbonate 1～2, zinc oxide 8～10.
Said tourmalinite is the very complicated natural mineral of a kind of chemical ingredients, is the ring texture silicate minerals of boracic, and mineral crystal is irregular hexagonal columnar.The present invention can adopt cheap aphrizite, and the place of production is not limit.The best country rock of tourmalinite and the impurity that adopt are few, and crystalline form is more complete, are convenient to clean.
The color of tourmalinite is very abundant, and the beautiful tourmalinite of color is used for jewel usually, is referred to as tourmaline.But the tourmalinite of natural output major part is a black, because color is bad, and poor transparency, the less jewel that is used for.Aphrizite has very unique character, and it is a kind of polar mineral, and its surface is electronegative, can react with airborne water generating electrodes, produces hydroxide ion, again with near water molecules formation hydroxyl ion OH
-(H
2O)
n, be a kind of negative aeroion to the human body beneficial.
Studies show that the biological effect of negative ion has three importances, does not poison even free radical has; Make body fluid be weakly alkaline; Air quality is improved.Tourmalinite also has the effect that makes water weak baseization, and the alkaline anion water that is produced is highly profitable to HUMAN HEALTH.It makes human body fluid be weakly alkaline, and health is adjusted to optimum regime; Active oxygen is not had poison, guarantee healthy internal environment; Purify the blood, guarantee metabolic ten large effects that normally wait.The functional tourmaline product of exploitation has health-care textile class, building material, household electrical appliances industry, makeup, papermaking etc. at present.
With making clothes behind the fiber weaving cloth that adds tourmaline powder, can prevent and treat diseases such as cardiovascular disorder, neurodynia, sacroiliitis.The ceramic that contains tourmaline powder under the effect of water, can discharge negative ion, the activated cell activity, and life-time service changes ceramic, and human body is benefited from it.Tourmaline powder also is applied in the cosmetics, and human body skin is had certain beautification function.In fact, add the beneficial effect that the enamel product of tourmaline powder can maximum possible performance tourmalinite.Tourmalinite has only after effective ingress of air and the water, could produce the negative ion to the human body beneficial.Tourmaline powder is added in the cover-coat enamel as mill addition in enamel making processes, and sintering is on the metal idiosome surface of enamel ccating ground-coat enamel then.Because cover-coat enamel is planar spread in the metallic surface, thereby make the tourmaline powder can maximum possible ingress of air and water.And other products such as fiber, pottery can only make a small amount of tourmalinite be in the vector product surface, have limited the effect that tourmalinite produces negative ion.Thus, enamel is most possibly to bring into play a kind of carrier substance that tourmalinite produces the negative ion effect.
Enamelled preparation method of the present invention comprises the steps:
At first natural tourmalinite is cleaned, remove country rock and impurity on the mineral, oven dry then, being crushed to mean particle size is 0.5-5um;
Above-mentioned tourmaline powder and enamel base-material frit ball milling were crushed to 100～140 orders in 1-2 hour, and the enamel powder that obtains is sprinkled upon the base surface, the end of preheating, just begin fusing and produce adherence when enamel touches scorching hot metal, place 800-850 ℃ of firing furnace sintering then.
Advantage of the present invention is:
(1) tourmalinite is a kind of polarization mineral, behind its ingress of air and water because generating electrodes reaction causes the generation of negative aeroion, particularly be processed into superfine powder after, its polarizability strengthens greatly, the ability that produces negative ion is also strengthened greatly.Negative aeroion is a kind of material that HUMAN HEALTH is highly profitable.
(2) tourmalinite also has the effect that makes water weak baseization, and the alkaline anion water of generation is highly profitable to HUMAN HEALTH.
(3) the present invention adopts the carrier of enamel as tourmaline powder, can maximum possible bring into play the function that tourmalinite produces negative ion, because tourmalinite has only abundant contact water and air, could effectively produce negative aeroion.Tourmalinite is joined in the enamel face uranium, and tourmaline particle is positioned at the enamel surface, and effectively ingress of air and water possess the objective condition that makes tourmalinite produce electrode reaction, cause the generation of negative aeroion.When this enamel during as certain aquamanile, the tourmalinite that is in the enamel surface with make water weak baseization after water contacts, thereby produce alkaline anion water.Negative aeroion and alkaline anion water all are the materials that human body is highly profitable.Enamel is the best carrier that tourmalinite is brought into play its beneficial functional thus.
(4) after the enamel that will add tourmaline powder is made into various products,, can produce different effects as bathtub, washbasin, mug etc.After in adding the bathtub of tourmaline powder, injecting hot water, can produce a large amount of water vapors, because temperature is than the normal temperature height, the polarizability of tourmalinite is strengthened, a large amount of negative aeroions of easier generation, human body is stayed wherein, just as placing oneself in the midst of the fountain limit, feels very pure and fresh.Tourmalinite also has the effect that makes water weak baseization simultaneously, and bathing also is highly profitable to human body skin in this alkalescence anion water, has beautification function.And for example, soaked with the enamel mug that adds tourmalinite, the weakly alkaline anion water that is produced, the intravital acid free radical that can neutralize after drinking, the activated cell activity impels human body to keep fit.
(5) manufacture craft of the present invention is simple, and is with low cost, safe and reliable, can produce in batches.
Embodiment
Embodiment 1
Adopting the place of production is the aphrizite in Xinjiang, at first the tourmalinite of choosing is cleaned, and removes country rock and impurity on the mineral, dries under 600 ℃ of temperature, carries out superfine grinding with pulverizer, reaches about 2.5um until granularity.
Get the cast iron of thick 2mm diameter 60mm, eliminate rust with the NaOH solution of 10% HCl and 1% respectively and decontamination is handled, pull dry for standby out.
At the Cast Iron Surface spraying ground-coat enamel of handling well, burn till after the drying earlier.Make cover-coat enamel (being the enamel base-material) frit again, it is filled a prescription as table 1:
Table 1 cover-coat enamel frit prescription (%)
| The quartzy borax feldspar of raw material soda ash nitre sodium weisspiessglanz ice crystal Calcium Fluoride (Fluorspan) barium carbonate zinc oxide |
| Form 26.2 31.3 8.8 3.1 1.6 8.1 8.0 2.4 1.0 9.5 |
Form according to this cover-coat enamel prescription, various composition weighings are mixed, put into crucible, melt under 1200 ℃, quenching in the water is dropped in the good back of fusing, pulls oven dry out.Then frit is dropped in the ball grinder, the tourmaline powder of weighing 10% simultaneously adds in the ball grinder simultaneously, grinds 2 hours, crosses 120 mesh sieves at last, pours dry for standby in the enamelled vessel into.
This cover-coat enamel powder that obtains is sprinkled upon the base surface, the end of preheating, and the metal idiosome that touches the scorching hot ground-coat enamel of enamel ccating when enamel just begins fusing and produces adherence, places 800～850 ℃ to burn till kiln roasting and get final product then.
Produce ITC-201A type anion test instrument with Japan this negative ion enamel sheet is tested, the result shows that it produces the negative ion ability and reaches as high as 28000/cm
3, the mean value that produces anion number in 1 minute is 160/cm
3, and the negative ion concentration in suburb, wilderness or park is 500～1000/cm
3
Embodiment 2
Adopting the place of production is the aphrizite in Xinjiang, at first the tourmalinite of choosing is cleaned, and removes country rock and impurity on the mineral, dries under 600 ℃ of temperature, carries out superfine grinding with pulverizer, reaches about 2.5um until granularity.
Get the cast iron of thick 2mm diameter 60mm, eliminate rust with the NaOH solution of 10% HCl and 1% respectively and decontamination is handled, pull dry for standby out.
At the Cast Iron Surface spraying ground-coat enamel of handling well, burn till after the drying earlier.Make cover-coat enamel (being the enamel base-material) frit again, it is filled a prescription as table 2:
Table 2 cover-coat enamel frit prescription (%)
| The quartzy borax feldspar of raw material soda ash nitre sodium weisspiessglanz ice crystal Calcium Fluoride (Fluorspan) barium carbonate zinc oxide |
| Form 25 31 8.8 3.1 1.5 6.9 8.0 2.5 1.0 9.5 |
Adopt the identical method of embodiment 1, form according to this cover-coat enamel prescription, various composition weighings are mixed, put into crucible, melt under 1200 ℃, quenching in the water is dropped in the good back of fusing, pulls oven dry out.Then frit is dropped in the ball grinder, the tourmaline powder of weighing 20% simultaneously adds in the ball grinder simultaneously, grinds 2 hours, crosses 120 mesh sieves at last, pours dry for standby in the enamelled vessel into.
This cover-coat enamel powder that obtains is sprinkled upon the base surface, the end of preheating, and the metal idiosome that touches the scorching hot ground-coat enamel of enamel ccating when enamel just begins fusing and produces adherence, places 840 ℃ to burn till kiln roasting and get final product then.
Produce ITC-201A type anion test instrument with Japan this negative ion enamel sheet is tested, the result shows that it produces the negative ion ability and reaches as high as 30000/cm
3, the mean value that produces anion number in 1 minute is 1200/cm
3, and the negative ion concentration in suburb, wilderness or park is 500～1000/cm
3
Claims (5)
1. a negative ion enamel is characterized in that, component and weight percent content comprise:
Enamel base-material 80-95%
Tourmalinite 5-20%.
2. negative ion enamel according to claim 1 is characterized in that, the weight percent content of said enamel base-material is as follows:
Quartz 20～30, borax 25～35, feldspar 5～10, soda ash 2～4, nitre sodium 1～2,
Weisspiessglanz 6～9, ice crystal 6～9, Calcium Fluoride (Fluorspan) 2～3, barium carbonate 1～2, zinc oxide 8～10.
3. enamelled preparation method according to claim 1 and 2 is characterized in that comprising the steps:
With tourmalinite and the ball mill pulverizing of enamel base-material frit, and the enamel powder that obtains is sprinkled upon the base surface, the end of preheating, places 800-850 ℃ of firing furnace sintering.
4. method according to claim 3 is characterized in that, at first natural tourmalinite is cleaned and oven dry, and being crushed to mean particle size is 0.5-5um.
5. method according to claim 3 is characterized in that, with tourmalinite and enamel base-material frit ball mill pulverizing to 100～140 orders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410024769 CN1256291C (en) | 2004-05-28 | 2004-05-28 | Anionic enamel and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410024769 CN1256291C (en) | 2004-05-28 | 2004-05-28 | Anionic enamel and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1583633A true CN1583633A (en) | 2005-02-23 |
| CN1256291C CN1256291C (en) | 2006-05-17 |
Family
ID=34600973
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410024769 Expired - Fee Related CN1256291C (en) | 2004-05-28 | 2004-05-28 | Anionic enamel and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1256291C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875198A (en) * | 2012-09-13 | 2013-01-16 | 何光辉 | Multifunctional tourmaline composite porcelain film, as well as preparation process and application thereof |
| CN103936288A (en) * | 2014-04-16 | 2014-07-23 | 河北工业大学 | Tourmaline/silicate glass composite material and preparation method thereof |
| CN106477892A (en) * | 2016-10-21 | 2017-03-08 | 青岛首创嘉业工贸有限公司 | A kind of active ceramic cup and preparation method thereof |
| CN107032615A (en) * | 2016-02-03 | 2017-08-11 | 潮州市兴业陶瓷有限公司 | New bio ceramic glaze and its production method with good biocompatibility and bioactivity |
| CN109592189A (en) * | 2017-09-30 | 2019-04-09 | 上海住邦电器有限公司 | Nano-silver anion restraining and sterilizing bacteria liner enamelled vessel |
| CN110372208A (en) * | 2019-07-02 | 2019-10-25 | 浙江开尔新材料股份有限公司 | The method for discharging the enamel glaze slip of anion and preparing anion enamel plate using it |
-
2004
- 2004-05-28 CN CN 200410024769 patent/CN1256291C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875198A (en) * | 2012-09-13 | 2013-01-16 | 何光辉 | Multifunctional tourmaline composite porcelain film, as well as preparation process and application thereof |
| CN103936288A (en) * | 2014-04-16 | 2014-07-23 | 河北工业大学 | Tourmaline/silicate glass composite material and preparation method thereof |
| CN107032615A (en) * | 2016-02-03 | 2017-08-11 | 潮州市兴业陶瓷有限公司 | New bio ceramic glaze and its production method with good biocompatibility and bioactivity |
| CN107032615B (en) * | 2016-02-03 | 2020-03-20 | 潮州市兴业陶瓷有限公司 | Biological ceramic glaze with good biocompatibility and bioactivity and production method thereof |
| CN106477892A (en) * | 2016-10-21 | 2017-03-08 | 青岛首创嘉业工贸有限公司 | A kind of active ceramic cup and preparation method thereof |
| CN109592189A (en) * | 2017-09-30 | 2019-04-09 | 上海住邦电器有限公司 | Nano-silver anion restraining and sterilizing bacteria liner enamelled vessel |
| CN109592189B (en) * | 2017-09-30 | 2021-04-30 | 上海住邦电器有限公司 | Nano-silver negative ion bacteriostatic and bactericidal inner container enamel container |
| CN110372208A (en) * | 2019-07-02 | 2019-10-25 | 浙江开尔新材料股份有限公司 | The method for discharging the enamel glaze slip of anion and preparing anion enamel plate using it |
| CN110372208B (en) * | 2019-07-02 | 2021-12-31 | 浙江开尔新材料股份有限公司 | Enamel glaze slip capable of releasing negative ions and method for preparing negative ion enamel plate by using enamel glaze slip |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1256291C (en) | 2006-05-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111646700B (en) | Fly ash-based antibacterial glaze powder | |
| CN100351202C (en) | Method for producing health ceramic brick capable of releasing negative ion | |
| CN101475364B (en) | Antistatic powder for antistatic ceramic tile | |
| CN108129027B (en) | Devitrified glazed tile with surface having golden star stone effect, base glaze and preparation method thereof | |
| CN106986541A (en) | A kind of easy clean antibacterial functions shellfish glaze and preparation method thereof | |
| CN101439990A (en) | Negative ion pseudo-classic ecological brick and technique for producing the same | |
| CN1298844A (en) | Lead-free fritting enamel for high-grade porcelain | |
| CN1256291C (en) | Anionic enamel and manufacturing method thereof | |
| CN102079556A (en) | Energy running water ball and preparation method thereof | |
| KR20180079493A (en) | Manufacturing method for emitter having far-infrared radiation thermal effect and an anion generating function and the emitter made therefrom | |
| CN111607265A (en) | Preparation method of negative oxygen ion waterproof emulsion paint | |
| CN112010674B (en) | Anion ceramic tile with photocatalysis function and preparation process thereof | |
| KR100563558B1 (en) | Method manufacturing porcelain jade tile and porcelain jade tile | |
| CN111995359A (en) | Nixing pottery capable of controllably releasing negative oxygen ions and generating hydrogen-rich water and preparation method thereof | |
| CN103880476A (en) | Cold ceramic glaze with sterilization and antibacterial functions and preparation method thereof | |
| CN111533545A (en) | Multifunctional negative ion energy sheet and preparation method thereof | |
| CN102515866A (en) | Ceramic glaze with antibacterial capability and preparation method thereof | |
| CN112010678B (en) | Photocatalytic anion ceramic tile containing multiple dielectric substances and preparation process thereof | |
| CN102515868A (en) | Lead-free transparent bone china frit and preparation method thereof | |
| CN108675767A (en) | A kind of health porcelain and preparation method thereof | |
| CN109928635A (en) | A kind of preparation method of the black glaze of ceramics | |
| CN102417793A (en) | Electromagnetic wave shielding nanometer fragrant brightener capable of releasing trace element negative ions | |
| KR100563559B1 (en) | Method manufacturing porcelain jade tile and porcelain tile glaze | |
| CN101948160B (en) | Composition capable of generating multiple kinds of energy and preparation method thereof | |
| KR100368914B1 (en) | Method for preparing multi-function bath soap |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060517 |