CN1572415A - CVD coated cutting tool insert - Google Patents
CVD coated cutting tool insert Download PDFInfo
- Publication number
- CN1572415A CN1572415A CNA2004100593056A CN200410059305A CN1572415A CN 1572415 A CN1572415 A CN 1572415A CN A2004100593056 A CNA2004100593056 A CN A2004100593056A CN 200410059305 A CN200410059305 A CN 200410059305A CN 1572415 A CN1572415 A CN 1572415A
- Authority
- CN
- China
- Prior art keywords
- layer
- tic
- preferred
- coating
- thickness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005520 cutting process Methods 0.000 title claims abstract description 34
- 239000011248 coating agent Substances 0.000 claims abstract description 19
- 238000000576 coating method Methods 0.000 claims abstract description 19
- 238000003801 milling Methods 0.000 claims abstract description 19
- 229910000601 superalloy Inorganic materials 0.000 claims abstract description 9
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 7
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 5
- 239000010959 steel Substances 0.000 claims abstract description 5
- 239000000853 adhesive Substances 0.000 claims description 13
- 230000001070 adhesive effect Effects 0.000 claims description 13
- 239000010935 stainless steel Substances 0.000 claims description 9
- 239000013078 crystal Substances 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 229910001256 stainless steel alloy Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 abstract description 2
- 229910052594 sapphire Inorganic materials 0.000 abstract 1
- 235000013339 cereals Nutrition 0.000 description 11
- 229910045601 alloy Inorganic materials 0.000 description 10
- 239000000956 alloy Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 239000000758 substrate Substances 0.000 description 8
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- 229910009043 WC-Co Inorganic materials 0.000 description 4
- 238000005275 alloying Methods 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 229910052715 tantalum Inorganic materials 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910000851 Alloy steel Inorganic materials 0.000 description 3
- 244000273256 Phragmites communis Species 0.000 description 3
- 235000014676 Phragmites communis Nutrition 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 210000002615 epidermis Anatomy 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910000816 inconels 718 Inorganic materials 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- 229910001339 C alloy Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010011376 Crepitations Diseases 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- 229910001080 W alloy Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000003966 growth inhibitor Substances 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000007514 turning Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F2005/001—Cutting tools, earth boring or grinding tool other than table ware
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
- Y10T428/24975—No layer or component greater than 5 mils thick
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Chemical Vapour Deposition (AREA)
Abstract
The present invention relates to a coated cemented carbide insert (cutting tool), particularly useful for milling of stainless steels and super alloys but also milling of steels in toughness demanding applications. The cutting tool insert is characterised by a cemented carbide body comprising WC, NbC and TaC, a W-alloyed Co binder phase, and a coating comprising an innermost layer of TiCxNyOz with equiaxed grains, a layer of TiCxNyOz with columnar grains and a layer of alpha-Al2O3.
Description
Technical field
The present invention relates to a kind of coated cemented carbide insert (cutter), be particularly useful for milling stainless steel and superalloy, but also be used for steel being carried out milling in the purposes that requires toughness.
Background technology
During various materials being carried out milling, think that blade is according to different abrasion mechanism wearing and tearing with cutting tool coated with hard alloy.Seldom run into the wear type of a single state, for example chemical abrasion, fretting wear and adhesion wear run into complicated abrasive manner often.Determining by purposes in the highest flight of any abrasion mechanism, and depend on the performance of workpiece and the cutting parameter that is applied and the performance of cutter material.Under high cutting speed, the heat that produces in cutting zone is quite big, and plastic deformation can appear in blade, and this produces higher wearing and tearing by other mechanism conversely.Cutter life often also is subjected to the restriction of being peeled off by the sword that the so-called reeds that forms perpendicular to blade causes.These crackles are that the heat and the mechanical load of the variation that is subjected in the interrupted cut process by blade causes.This carries out in the machined more obvious at the use cooling agent, strengthened thermal change in this processing.
Usually compare with other steel, many stainless steels especially its material behavior of superalloy are seen least desirable from the machinable aspect.The low heat conductivity of these materials causes producing high temperature in cutter and the workpiece contact area.Reduce the cutter temperature with cooling agent and can bring very large thermal change, and produce high inner cutter load.These workpiece materials are often easy deformation sclerosis also.The strain hardening meeting of workpiece in cutting zone causes high cutting force, perhaps even in hardened layer cuts, and the two all can cause tool wear to be accelerated.In addition, most of stainless steels and superalloy demonstrate good tack for many coating materials, and owing to the adhesion wear that again cuts the blade that causes of smear metal with peel off rapidly quite obvious.Therefore obviously be used for to have the cutter material characteristic outside required those characteristics that have usually to the cutting tool coated with hard alloy that stainless steel and superalloy carry out milling.
Usually, can take measures to improve cutting ability for specific wear type.But often these measures have negative effect to other polishing machine, therefore must carefully optimize the cutting tool composite material that many performances are designed success.The straightforward procedure that improves the common needed toughness of milling cutter is to improve the bonding agent phase content.But this also will reduce wearability immediately, and anti-plastic deformation ability.Add cubic carbide for example TiC, TaC and NbC be the mode that another kind is used for affecting cutting performance, and big addition can obtain relative good toughness properties with the combination of highly adhesive phase content.But, thisly be added on that reeds forms and blade peels off and has negative effect on the tendency.
Owing to obviously be difficult to improve simultaneously all cutting performances, so in the above-mentioned wear type one or more commercially available carbide alloy kind is optimized.Therefore, they also have been optimized for specific application.
US6,062,776 has disclosed a kind of low and medium alloy steel and stainless coated cutting insert that in labile state milling has for example casting surface of initial surface, forges epidermis, hot rolling or cold rolling epidermis or pre-machining surface that be particularly useful for.This blade is characterized in that, comprises: a kind of WC-Co carbide alloy, and it has the low content cubic carbide, and W-the alloying adhesive is mutually with quite low; And a kind of coating, it comprises the TiC with columnar grain
xN
yO
zInnermost layer, TiN top layer and κ-Al
2O
3Internal layer.
US6,177,178 disclosed a kind of be particularly useful under moistening or drying condition grinding have or do not have the initial surface zone in and the coating milling cutting insert of low-alloy steel.This blade is characterized in that, comprises: a kind of WC-Co carbide alloy, and it has the low content cubic carbide and high W-the alloying adhesive is mutually; And a kind of coating, it comprises the TiC with columnar grain
xN
yO
zInnermost layer, one κ-Al
2O
3Internal layer and a preferred TiN top layer.
US6,250,855 have disclosed and a kind of stainless steel with different component and microstructure have been wet or the coating milling cutting insert of dried milling.Comprise the WC-Co that does not add any cubic carbide, low W alloy Co adhesive and include based on the carbide chip of coating WC-Co by component (Ti with certain content
xAl
1-x) hard wear-resistant coating of the sandwich construction that constitutes of N sublayer.
EP1103635 provides a kind of and is particularly useful for low and medium alloy steel and stainless steel wets and dried milling and the cutter knife that is used for stainless steel is carried out turning.This cutter is made of the cobalt hard alloy substrate that has the multiple layer refractory coating on it.Its cobalt content of this substrate is 9.0-10.9wt%, and contains the TaC/NbC of 1.0-2.0wt%.This coating comprises a MTCVDTiC
xN
yO
zThe layer and by κ-Al
2O
3And TiC
xN
yO
zThe laminated coating that layer consists of.
Have been found that now and to realize improving cutting ability by many different characteristics of this cutter of combination.This cutting tip is owing to have excellent performance for milling stainless steel and superalloy, and for for the steel in the operation that needs toughness, having excellent properties.Under these machining conditions, cutting tool according to the present invention has improved performance aspect above-mentioned many wear types.
Summary of the invention
The cutting tool according to the present invention blade comprises the carbide alloy substrate that its cubic carbide amount is relatively low, arrives high W-alloying adhesive phase and tiny of medium WC grain size during it has.This substrate is provided with a wear-resistant coating, and this coating comprises the TiC that is made of equi-axed crystal
xN
yO
zLayer, the TiC that is consisted of by columnar grain
xN
yO
zLayer and one deck α-Al at least
2O
3Layer.
Brief description of drawings
Fig. 1 demonstrates according to coated cemented carbide insert of the present invention, wherein with 2500 times of multiplication factors:
1. cemented carbide body
2. innermost TiC
xN
yO
zLayer
3. the TiC that has columnar grain
xN
yO
zLayer
4. α-Al
2O
3Layer
Detailed description of preferred embodiments
Coated cutting tool insert according to the present invention is provided with a cemented carbide body, and its composition is: 11.3-12.7wt%Co, be preferably 11.5-12.5wt%Co, and most preferably be 11.8-12.4wt%Co; Total content is 0.5-2.5wt%, be preferably 0.7-1.9wt%, most preferably be the cubic carbide of metal Ti, Nb and the Ta of 1.0-1.8wt%; And measurement WC.Ti, Ta and/or Nb also can be replaced by other carbide that is selected from the element of the IVb of family, Vb in the periodic table of elements or VIb.The content of Ti preferably with the corresponding degree of technology impurity on.In preferred embodiments, the weight ratio between Ta and Nb is 1.0-12.0, is preferably 1.5-11.4, most preferably is 3.0-10.5.
Cobalt binder and tungsten moderate are to the height alloying.Can be expressed as S-value=σ/16.1 at the W content of adhesive in mutually, wherein σ is the magnetic moment of the adhesive phase measured, with μ Tm
3/ kg represents.This S value depends at the W content of adhesive in mutually, and increases along with reducing of W content.Therefore, for pure cobalt or for the adhesive in the saturated carbide alloy of carbon, S=1, for its W content corresponding to the adhesive of the boundary line that forms the η phase mutually for, S=0.78.
Have been found that now according to the present invention its S value of cemented carbide body for 0.81-0.95, be preferably 0.82-0.94, most preferably be in the 0.85-0.92 situation, can realize the improvement of cutting ability.
In addition, the tungsten carbide average intercepted length mutually of measuring in polishing and the exemplary cross section of polishing is 0.3-0.8 μ m, is preferably 0.4-0.8 μ m.This intercepted length is by being to carry out graphical analysis on the microphoto of 10000x to measure in multiplication factor, and is calculated to be the mean value of about 1000 intercepted lengths.
According to preferred embodiment, this coating comprises:
One TiC
xN
yO
zGround floor (innermost layer), 0.7≤x+y+z≤1 wherein, preferred z<0.5, more preferably y>x and z<0.2, y>0.7 most preferably, and have equi-axed crystal, and its gross thickness<1 μ m, preferred>0.1 μ m.
One TiC
xN
yO
zLayer, 0.7≤x+y+z≤1 wherein, preferred z<0.2, x>0.3 and y>0.2, x>0.4 most preferably, its thickness is 0.5-5 μ m, is preferably 1-4 μ m, most preferably is 1.5-3 μ m, has columnar grain.
An Al who is consisted of mutually by α
2O
3Layer.This Al
2O
3Its thickness of layer is 0.2-5 μ m, is preferably 0.5-4 μ m, and most preferably is 1-3 μ m.
In a further preferred embodiment, after applying, adopting wet blasting or brushing operation that aforesaid cutter knife is processed, thereby can improve the surface quality on the rake face of coated cutting tool.
The invention still further relates to a kind of method of making coated cutting tool, its composition of this cutter is: 11.3-12.7wt%Co, be preferably 11.5-12.5wt%Co, and most preferably be 11.8-12.4wt%Co; Total content is 0.5-2.5wt%, be preferably 0.7-1.9wt%, most preferably be the cubic carbide of metal Ti, Nb and the Ta of 1.0-1.8wt%; And measurement WC.Ti, Ta and/or Nb also can be replaced by other carbide that is selected from the element of the IVb of family, Vb in the periodic table of elements or VIb.The content of Ti preferably with the corresponding degree of technology impurity on.In preferred embodiments, the weight ratio between Ta and Nb is 1.0-12.0, is preferably 1.5-11.4, most preferably is 3.0-10.5.
Desired average intercepted length depends on crystallite dimension and grinding and the sintering condition of initial powder, and must be definite by testing.Desired S value depends on initial powder and sintering condition, and also must be definite by testing.
In 700-950 ℃ temperature range, adopt acetonitrile to utilize the MTCVD technology with TiC as carbon and nitrogenous source
xN
yO
zBe deposited on the carbide alloy alloy in order to form this layer, 0.7≤x+y+z≤1 wherein, preferred z<0.2, x>0.3 and y>0.2, x>0.4 most preferably, and have the columnar grain form.
Innermost TiC
xN
yO
zLayer and alumina layer are according to known deposition techniques.
The invention still further relates to use according to cutter knife recited above come with 30-500m/ minute, be preferably 50-400m/ minute cutting speed milling stainless steel and superalloy, and be 0.04-0.20mm according to cutting speed and its average depth of cut numerical value of blade geometry.
Embodiment 1:
Kind A: thus by conventional abrasive flour, compacting green compact and producing according to carbide alloy substrate of the present invention at 1430 ℃ of following sintering subsequently, its component be 12wt%Co, 1.3wt%TaC, 0.2wt%NbC and measurement WC and have corresponding to the S value be 0.90 and adhesive W alloyization mutually.After sintering, this microstructure observed and show that the average intercepted length of tungsten carbide phase is 0.59 μ m.This substrate scribbles according to the present invention: the thick TiC of 0.2 μ m
xN
yO
zLayer, wherein z<0.1 and y>0.6 has equi-axed crystal; 2.5 the columnar grain TiC that μ m is thick
xN
yO
zLayer, it is to adopt acetonitrile to form 835-850 ℃ of deposit as carbon nitrogen source, thus the carbon-nitrogen ratio that forms is about x/y=1.5, and z<0.1; And α-Al of 1.2 μ m
2O
3Layer, it is to form in about 1000 ℃ of deposit.With XRD to Al
2O
3Layer the analysis showed that without any κ-Al
2O
3Vestige.
Kind B: preparing the substrate identical with the substrate (according to the present invention) of kind A with manufacture method of its chemical composition with thick WC powder, is 0.7 μ m thereby cause the average intercepted length of its WC phase.Method according to kind A of the present invention applies substrate.
Kind C: by conventional abrasive flour, compacting green compact and under 1430 ℃, carry out SINTERING PRODUCTION subsequently and go out this substrate, its component is 12wt%Co, 0.52wt%Cr and measurement WC, its W alloy adhesive corresponds to 0.87 S value, and the average intercepted length of the WC in sintered body is 0.58 μ m, and this substrate is combined with the coating according to kind A (according to the present invention).
During the face milling that is applied with fluid coolant is therein used to testing according to the blade of kind A, kind B and kind C.
Operation | Face milling |
Tool diameter | 80mm |
Workpiece | Bar, 600mm * 75mm |
Material | SS2333 |
Blade type | SEKN1203 |
Cutting speed | 300m/ minute |
The amount of feeding | 0.25mm/ tooth |
The number of teeth | 6 |
Cutting depth | 3.5mm |
Cutting width | 35mm |
Cooling agent | Have |
The result | Cutter life (minute) |
Kind A (according to kind of the present invention) | 10 |
Kind B (according to kind of the present invention) | 9 |
Kind C (according to coating of the present invention) | 6 |
Cutter life is subjected to the restriction that the blade relevant with reeds peels off.This test shows that it is subjected to the influence of WC grain size less, and for example TaC and NbC are added with Cr its poor-performing of material as grain growth inhibitor to replace cubic carbide.
Embodiment 2:
The substrate of kind D: kind A (according to the present invention) scribbles the thick TiC with equi-axed crystal of 0.3 μ m
xN
yO
zLayer, the thick columnar grain TiC of 2.5 μ m that goes out 835-850 ℃ of deposit
xN
yO
zLayer and the thick κ-Al of 1.3 μ m that goes out in about 1000 ℃ of deposit
2O
3Layer.This coating is carried out XRD analysis to be shown and not to have α-Al
2O
3The Al of phase
2O
3
In Inconel 718 parts being carried out the face milling operation, the blade of kind A and kind D is tested.
Operation | Face milling |
Tool diameter | 63mm |
Workpiece | Ingot casting |
Material | Inconel 718 |
Blade type | OFMT0504 |
Cutting speed | 40m/ minute |
The amount of feeding | 0.12mm/ tooth |
The number of teeth | 6 |
Cutting depth | 2mm |
Cutting width | 38mm |
Cooling agent | Emulsion |
Cutting time | 12 minutes |
The result | Flank wear |
Kind A (according to kind of the present invention) | 0.15mm |
Kind D (according to substrate of the present invention) | 0.20mm |
Before arriving maximum cutter life, stop test, and study the wearing and tearing of these blades.The blade of kind A shows lower average flank wear, and the blade of kind D takes second place, and it is more not obvious on the blade of kind A that blade peels off tendentiousness in addition.That is, the blade of kind A demonstrates better wear resistance and toughness properties when comparing with the blade of kind D.
Embodiment 3:
Kind E: the substrate of kind A (according to the present invention) is coated with the coating structure of with good grounds kind A, and increases by 0.4 thick outside rich nitrogen TiC
xN
yO
zLayer.
Operation | Square shoulder milling |
Workpiece | Bar |
Material | SS2333 |
Blade type | APKT1604 |
Cutting speed | 250m/ minute |
Tool diameter | 25mm |
The amount of feeding | 0.28mm/ tooth |
The number of teeth | 2 |
Cutting depth | 2.5mm |
Cutting width | 3-12mm |
Cooling agent | Do not have |
The result | Cutter life (minute) |
Kind A (according to kind of the present invention) | 17 |
Kind E] (according to kind of the present invention) | 14 |
Cutter life is subjected to the restriction that flank wear and blade peel off.When the blade that uses in kind A, the possibility that smear metal is attached to cutting tip is than much lower when the blade that uses in kind E.The cutter life of kind E is poorer to be to cause owing to the more obvious blade that occurs because of cutting again of adhesion wear and smear metal peels off.
Embodiment 4:
Kind F: from competitor's commercially available carbide cutting blade, its component is 10.5wt%Co, 0.43wt%Cr and measurement WC.The W alloy adhesive corresponds to 0.91 S value, and the average intercepted length of WC is 0.6 μ m.This blade scribbles the thick coating of 4.9 μ m, and this coating has TiN and TiAl alternately
1-xThe N layer.
Operation | Face milling |
Tool diameter | 80mm |
Workpiece | Bar, 300mm * 80mm |
Material | SS2343 |
Blade type | SEET13 |
Cutting speed | 275m/ minute |
The amount of feeding | 0.17mm/ tooth |
The number of teeth | 1 |
Cutting depth | 4mm |
Cutting width | 50mm |
Cooling agent | Do not have |
Cutting time | 13 minutes |
The result | The maximum side wearing and tearing |
Kind A (according to kind of the present invention) | 0.15 |
Kind F (prior art) | 0.45 |
The wearing and tearing of when arriving maximum cutter life for the poorest kind, measuring these blades.
Claims (3)
1. cutter knife, it comprises cemented carbide body and coating, be particularly useful for stainless steel and superalloy carries out milling and in the purposes that requires toughness steel being carried out milling, it is characterized in that, its composition of described body is: 11.3-12.7wt%Co, be preferably 11.5-12.5wt%Co, most preferably be 11.8-12.4wt%Co; Total content is 0.5-2.5wt%, be preferably 0.7-1.9wt%, most preferably be the cubic carbide of metal Ti, Nb and the Ta of 1.0-1.8wt%; And weigh WC, and its average intercepted length of described WC grain is 0.3-0.8 μ m, is preferably 0.4-0.8 μ m, adhesive corresponds at 0.81-0.95, is preferably S value and W alloyization in the 0.82-0.94 scope, and described coating comprises:
TiC
xN
yO
zGround floor (innermost layer), 0.7≤x+y+z≤1 wherein, preferred z<0.5, more preferably y>x and z<0.2, y>0.7 most preferably, and have equi-axed crystal, and its gross thickness<1 μ m, preferred>0.1 μ m;
TiC
xN
yO
zLayer, 0.7≤x+y+z≤1 wherein, preferred z<0.2, x>0.3 and y>0.2, x>0.4 most preferably, its thickness is 0.5-5 μ m, is preferably 1-4 μ m, most preferably is 1.5-3 μ m, has columnar grain; And
The Al that is consisted of mutually by α
2O
3Layer, this Al
2O
3Its thickness of layer is 0.2-5 μ m, is preferably 0.5-4 μ m, and most preferably is 1-3 μ m.
2. method of making cutter knife, this cutter knife comprises cemented carbide body and coating, its composition is: 11.3-12.7wt%Co, be preferably 11.5-12.5wt%Co, most preferably be 11.8-12.4wt%Co; Total content is 0.5-2.5wt%, be preferably 0.7-1.9wt%, most preferably be the cubic carbide of metal Ti, Nb and the Ta of 1.0-1.8wt%; And weigh WC, and its average intercepted length of described WC grain is 0.3-0.8 μ m, is preferably 0.4-0.8 μ m, adhesive corresponds at 0.81-0.95, is preferably S value and W alloyization in the 0.82-0.94 scope, and described coating comprises:
TiC
xN
yO
zGround floor (innermost layer), 0.7≤x+y+z≤1 wherein, preferred z<0.5, more preferably y>x and z<0.2, y>0.7 most preferably, and have equi-axed crystal, and its gross thickness<1 μ m, preferred>0.1 μ m;
TiC
xN
yO
zLayer, 0.7≤x+y+z≤1 wherein, preferred z<0.2, x>0.3 and y>0.2, x>0.4 most preferably, its thickness is 0.5-5 μ m, is preferably 1-4 μ m, most preferably is 1.5-3 μ m, has columnar grain; And
The Al that is consisted of mutually by α
2O
3Layer, this Al
2O
3Its thickness of layer is 0.2-5 μ m, is preferably 0.5-4 μ m, and most preferably is 1-3 μ m.
According to the cutter knife of claim 1-2 with 30-500m/ minute, be preferably 50-400m/ minute cutting speed milling stainless steel and the purposes in the superalloy, be 0.04-0.25mm wherein according to cutting speed and its average depth of cut numerical value of blade geometry.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE03017423 | 2003-06-16 | ||
SE0301742A SE526599C2 (en) | 2003-06-16 | 2003-06-16 | CVD coated carbide inserts |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1572415A true CN1572415A (en) | 2005-02-02 |
Family
ID=27607320
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNA2004100593056A Pending CN1572415A (en) | 2003-06-16 | 2004-06-16 | CVD coated cutting tool insert |
Country Status (5)
Country | Link |
---|---|
US (1) | US7150772B2 (en) |
EP (1) | EP1493845B1 (en) |
KR (1) | KR101133476B1 (en) |
CN (1) | CN1572415A (en) |
SE (1) | SE526599C2 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100418679C (en) * | 2005-06-22 | 2008-09-17 | 山高刀具公司 | Composite coatings for finishing of hardened steels |
CN101312927A (en) * | 2005-11-17 | 2008-11-26 | 倍锐特有限责任公司 | Laminated hard alloy piece |
CN101018879B (en) * | 2005-06-27 | 2011-04-06 | 山特维克知识产权股份有限公司 | Coated cutting cutter comprising carbide substrate and coating and its manufacture method |
CN101402147B (en) * | 2007-09-13 | 2012-03-21 | 山高刀具公司 | Coated cutting insert for milling applications |
CN101342602B (en) * | 2007-07-13 | 2013-03-13 | 山高刀具公司 | Coated cutting tool |
CN103537720A (en) * | 2012-07-17 | 2014-01-29 | 三菱综合材料株式会社 | Surface-wrapped cutting tool |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE529200C2 (en) * | 2005-11-21 | 2007-05-29 | Sandvik Intellectual Property | Coated cutting, method of making and use |
SE529856C2 (en) * | 2005-12-16 | 2007-12-11 | Sandvik Intellectual Property | Coated cemented carbide inserts, ways of making this and its use for milling |
SE532023C2 (en) * | 2007-02-01 | 2009-09-29 | Seco Tools Ab | Textured hardened alpha-alumina coated cutting for metalworking |
US8080323B2 (en) * | 2007-06-28 | 2011-12-20 | Kennametal Inc. | Cutting insert with a wear-resistant coating scheme exhibiting wear indication and method of making the same |
US20090004449A1 (en) * | 2007-06-28 | 2009-01-01 | Zhigang Ban | Cutting insert with a wear-resistant coating scheme exhibiting wear indication and method of making the same |
SE531946C2 (en) | 2007-08-24 | 2009-09-15 | Seco Tools Ab | Cutter for milling in cast iron |
SE532021C2 (en) * | 2007-09-13 | 2009-09-29 | Seco Tools Ab | CVD coated cemented carbide inserts for milling applications and manufacturing methods |
SE532043C2 (en) | 2007-10-10 | 2009-10-06 | Seco Tools Ab | CVD coated cutter for milling and manufacturing method |
SE532044C2 (en) | 2007-12-27 | 2009-10-06 | Seco Tools Ab | Use of a CVD coated cutter when milling |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100430360B1 (en) * | 1995-11-30 | 2004-07-16 | 산드빅 악티에볼라그 | Coated cutting insert and method of making it |
SE9504304D0 (en) * | 1995-11-30 | 1995-11-30 | Sandvik Ab | Coated milling insert |
SE509616C2 (en) * | 1996-07-19 | 1999-02-15 | Sandvik Ab | Cemented carbide inserts with narrow grain size distribution of WC |
US6251508B1 (en) * | 1998-12-09 | 2001-06-26 | Seco Tools Ab | Grade for cast iron |
SE519005C2 (en) * | 1999-03-26 | 2002-12-17 | Sandvik Ab | Coated cemented carbide inserts |
JP2001087907A (en) * | 1999-07-22 | 2001-04-03 | Mitsubishi Materials Corp | Machining tool of cemented carbide based on surface- covered tungsten carbide with its hard covering layer exhibiting excellent chipping resistance in intermittent heavy duty machining |
EP1103635B1 (en) * | 1999-11-25 | 2004-08-11 | Seco Tools Ab | Coated cutting insert for milling and turning applications |
US6733874B2 (en) * | 2001-08-31 | 2004-05-11 | Mitsubishi Materials Corporation | Surface-coated carbide alloy cutting tool |
-
2003
- 2003-06-16 SE SE0301742A patent/SE526599C2/en not_active IP Right Cessation
-
2004
- 2004-05-14 EP EP04445061.7A patent/EP1493845B1/en not_active Expired - Lifetime
- 2004-05-18 US US10/847,467 patent/US7150772B2/en active Active
- 2004-06-15 KR KR1020040044107A patent/KR101133476B1/en active IP Right Grant
- 2004-06-16 CN CNA2004100593056A patent/CN1572415A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100418679C (en) * | 2005-06-22 | 2008-09-17 | 山高刀具公司 | Composite coatings for finishing of hardened steels |
CN101018879B (en) * | 2005-06-27 | 2011-04-06 | 山特维克知识产权股份有限公司 | Coated cutting cutter comprising carbide substrate and coating and its manufacture method |
CN101312927A (en) * | 2005-11-17 | 2008-11-26 | 倍锐特有限责任公司 | Laminated hard alloy piece |
CN101342602B (en) * | 2007-07-13 | 2013-03-13 | 山高刀具公司 | Coated cutting tool |
CN101402147B (en) * | 2007-09-13 | 2012-03-21 | 山高刀具公司 | Coated cutting insert for milling applications |
CN103537720A (en) * | 2012-07-17 | 2014-01-29 | 三菱综合材料株式会社 | Surface-wrapped cutting tool |
Also Published As
Publication number | Publication date |
---|---|
SE0301742L (en) | 2004-12-17 |
SE526599C2 (en) | 2005-10-18 |
EP1493845A1 (en) | 2005-01-05 |
EP1493845B1 (en) | 2016-11-16 |
KR20040111066A (en) | 2004-12-31 |
US7150772B2 (en) | 2006-12-19 |
SE0301742D0 (en) | 2003-06-16 |
KR101133476B1 (en) | 2012-04-10 |
US20050037203A1 (en) | 2005-02-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1347076B1 (en) | PVD-Coated cutting tool insert | |
EP0914490B1 (en) | Cemented carbide insert for turning, milling and drilling | |
USRE39814E1 (en) | Cemented carbide insert and method of making same | |
US6632514B1 (en) | Coated cutting insert for milling and turning applications | |
IL180060A (en) | Coated cemented carbide cutting tool milling insert | |
CN1572415A (en) | CVD coated cutting tool insert | |
EP1997938A2 (en) | Coated cutting tool insert | |
JPH06220571A (en) | Sintered hard alloy and coated sintered hard alloy for cutting tool | |
KR20110100621A (en) | Improved coated cutting insert for rough turning | |
EP2039447B1 (en) | Coated cutting insert for milling applications | |
US8142848B2 (en) | Coated cutting insert for milling | |
EP1352697B1 (en) | Coated cutting tool insert | |
JP4351521B2 (en) | Surface coated cutting tool | |
JP2019155569A (en) | Surface-coated cutting tool having hard coating layer exerting excellent oxidation resistance and deposition resistance | |
JP2019155570A (en) | Surface-coated cutting tool having hard coating layer exerting excellent oxidation resistance and deposition resistance | |
EP2075350A2 (en) | CVD coated cutting tool insert for milling | |
EP1222316B1 (en) | Coated cemented carbide insert | |
JP3360565B2 (en) | Surface coated cemented carbide cutting tool with a hard coating layer exhibiting excellent wear resistance | |
JP3358530B2 (en) | Slow-away cutting insert made of surface-coated cemented carbide with excellent fracture resistance | |
JP5569739B2 (en) | Surface coated cutting tool with excellent chipping resistance | |
JP3236908B2 (en) | Surface coated WC based cemented carbide cutting tool | |
JP2005153099A (en) | Surface coated cutting tool |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C12 | Rejection of a patent application after its publication | ||
RJ01 | Rejection of invention patent application after publication |