CN1565183A - Bactericidal compositions containing enostroburin and thiocarbamate - Google Patents
Bactericidal compositions containing enostroburin and thiocarbamate Download PDFInfo
- Publication number
- CN1565183A CN1565183A CN 03133420 CN03133420A CN1565183A CN 1565183 A CN1565183 A CN 1565183A CN 03133420 CN03133420 CN 03133420 CN 03133420 A CN03133420 A CN 03133420A CN 1565183 A CN1565183 A CN 1565183A
- Authority
- CN
- China
- Prior art keywords
- enestroburin
- thiocarbamate
- bactericidal
- bactericidal composition
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000005720 sucrose Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Abstract
The invention discloses a sterilization composition containing strobilurin and any one of dithiocarbamate bactericidal agent, wherein the weight portion of the two active components is 1:100 to 100:1, the dithiocarbamate bactericidal agents are selected from mancozeb, maneb, zineb, iprovalicarb, amobam, thiram or ziram. The weight percentage content of the active constituents in the composition is 0.5-95%, and the composition comprises at least two carrying agents, at least one of which is surface active agent. The composition can be prepared into suspending agent, aqueous emulsion, wet powder, and wet pelletized granule.
Description
Technical field
The invention belongs to the disinfectant use in agriculture field.
Background technology
Enestroburin is the outstanding bactericide of plurality of plant diseases such as control cereal, paddy rice, fruit, vegetables and economic crops, its fungicidal spectrum wide, active high, have prevention and therapeutic action and good compatibility arranged, to good control efficiency being arranged by mastigomycetes, the plurality of plant diseases that causes in conjunction with bacterium, sac fungi, basidiomycetes and imperfect fungus with environmental organism.This compound is formulated, is disclosed first in CN1191670A by Chinese Shenyang Chemical Engineering Inst.Enestroburin belongs to the new type bactericide of methoxy acrylic, and this series bactericidal agent activity is high, consumption is few, has treatment and protective effect, is widely used in preventing and treating corps diseases.But because the action site of this series bactericidal agent is very single, germ can produce adaptive variation to medicament, the preventive effect of medicament is reduced even invalid, develops immunity to drugs.The resistance of Enestroburin is found as yet in the field at present, but is had the relevant report that produces resistance in Europe with veriety.
Summary of the invention
For fear of the resistance of using the agent of Enestroburin list to bring take place, degradation problem under the drug effect, the invention discloses a kind of bactericidal composition, preparation of compositions and application that contains Enestroburin and thiocarbamate.
Enestroburin chemical name: 3-methoxyl group-2-[2-((((1-methyl-3-(4-chlorphenyl)-2-acrylic fork) amino) oxygen)-methyl) phenyl] methyl acrylate, structural formula is as follows:
Chinese common name: Enestroburin molecular formula: C
22H
22CINO
4Molecular weight: 399.87
Carbamates bactericidal agent of the present invention mainly is selected from:
Mancozeb chemical name: the polycomponent coordination compound of ethylene bisdithiocarbamic manganese and zinc salt;
Maneb chemical name: ethylene bisdithiocarbamic manganese;
Zineb chemical name: ethylene two (zinc dithiocarbamate);
Propineb chemical name: acrylic bisdithiocarbamic zinc;
Ambam chemical name: acrylic bisdithiocarbamic ammonium;
In generation,, gloomy salt chemical name claimed: two (zinc dithiocarbamate) metal complexes of ethylene;
Tmtd chemical name: tetramethyl thiuram disulfide;
Diram chemical name: N, N dimethyl dithiocarbamic acid ammonium or
Ziram chemical name: two (dimethyl dithiocarbamic acid) zinc.
Bactericidal composition disclosed by the invention, wherein containing Enestroburin and any one Carbamates bactericidal agent is active component.Also can contain two or more Carbamates bactericidal agent in this bactericidal composition, can realize purpose of the present invention equally.
Have now found that the use that is mixed of Enestroburin and sulfo-amino hydrochlorate has obvious synergistic effect, the control efficiency of corps diseases is significantly increased, and can enlarge fungicidal spectrum, delay the drug-fast generation of pathogen.Enestroburin possesses different structure types and different mechanism of action with sulfo-amino Barbiturates medicament, and the two is composite can to delay to a certain extent that the pathogen pesticide resistance produces and development, can reduce use cost simultaneously.
In the bactericidal composition that the present invention proposes, Enestroburin and thiocarbamate are 1: 100 to 100: 1 based on the ratio of weight and number of active component; Suitable ratio is 1: 20 to 20: 1.
Active component is 0.5% to 95% of a gross weight in the composition of the present invention.The amount of application of compound also depended on the ratio of a kind of compound and another kind of compound and the degree of synergistic effect when the amount that contains active component in the present composition depended on independent the use.
Composition of the present invention also comprises carrier, and contains at least two kinds of carriers.Carrier can be solid or liquid, also comprises being generally gas but compression back is the material of liquid, and any carrier that is generally used for preparing microbicide compositions all can use.The product safety that composition and carrier are made is applied to the place of processing, for example farmland, orchard or warehouse etc., and be easy to store transportation or loading and unloading.The present composition can be mixed with suspending agent, (water) emulsion, wetting powder, (aqueous dispersion) granule, also can use the solution and the powder that are included in the polymer capsule, as has flooded the natural or synthetic material or the carrier of active substance.
These preparations can be prepared by method in common.For example, active substance is mixed with liquid flux and/or solid carrier, add surfactant such as dispersant, stabilizing agent, wetting agent simultaneously, can also add adhesive, defoamer, oxidant.Agriculturally useful compositions is mixed with various preparations usually, is diluted before use or directly use by the user.Exist a spot of supporting surfactant to help dilution in the preparation.Therefore, at least a carrier is a surfactant in the composition of the present invention.
The present invention also comprises the preparation method of above-mentioned bactericidal composition.If water is as thinner, organic solvent also can be used as attached cosolvent or stabilizing agent and antifreezing agent.The organic solvent that is fit to comprises aromatic hydrocarbons, for example benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chloro aliphatic hydrocarbon, for example chlorobenzene, vinyl chloride, trichloroethanes, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, for example petroleum distillate, cyclohexane, light mineral oil, paraffin and coal; Yet, particularly suitable be polar solvent, i.e. alcohols, for example isopropyl alcohol, butanols, ethylene glycol, propane diols, glycerine, sorbierite, phenmethylol, furfuryl alcohol and cyclohexanol, and their ether and ester; Ketone, for example acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone, butyrolactone, and dimethyl formamide, dimethyl sulfoxide (DMSO) and N-methyl-pyrrolidones; Also have vegetable oil and the molten fiber of methyl.Simultaneously, mixtures of different liquids also is suitable for.
Surfactant can be emulsifier, dispersant or wetting agent; Can be nonionic or ionic.The example of the surfactant that is fit to comprises the sodium salt or the calcium salt of polyacrylic acid and lignin sulfonic acid; Contain the fatty acid of at least 12 carbon atoms or the polycondensation product of fatty amine or acid amides and oxirane and/or expoxy propane in the molecule; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In molecule, contain the sulfuric acid of 10 carbon atoms or the alkali metal or the alkali salt of sulfonic acid at least, preferable is sodium salt, for example, and the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, and alkylaryl sodium sulfonate, for example neopelex; And the copolymer of polymers of ethylene oxide and oxirane and expoxy propane.Particularly following material can be used as emulsifier: nonionic emulsifier, for example polyoxyethylene fatty acid fat, polyoxyethylene aliphatic alcohol ether, polyoxyethylene fatty amine, instantiation such as ethoxylated castor oil, polyoxyethylene (n
20) phenethyl phenolic group oleic acid ester, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, the different thionic acid calcium of oleic acid, triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, hexichol ethyl phenolic group polyoxyethylene (n18) ether formaldehyde condensation products, diphenyl phenolic group polyoxyethylene (n
18) polyoxypropylene (n
20) ether and anion emulsifier; Or directly use commercially available emulsifier: agricultural newborn 0201B, agricultural newborn 0203B, farming breast 100
#, farming breast 500
#, farming breast 600
#, agricultural newborn 600-2
#, farming breast 1601, farming breast 2201, agricultural newborn NP-10, agricultural newborn NP-15, farming breast 507
#, agricultural newborn OX-635, agricultural newborn OX-622, agricultural newborn OX-653, agricultural newborn OX-667, agricultural newborn CS-7, peaceful breast 36
#Particularly following material can be used as dispersant: sodium lignin sulfonate; draw back powder; calcium lignosulfonate; condensation compound of methyl naphthalene sulfonic acid and formaldehyde; naphthalene sulfonic acid-formaldehyde condensation product; the methanonaphthalene sodium sulfonate; oleic acid methylamino ethylsulfonic acid sodium; epoxidized polyether; to tertbutyl ether; the dibutyl naphthalene sulfonic acid-formaldehyde condensation product; phosphate such as calgon; the alkylphenol-polyethenoxy based phosphates; alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate; N-methyl-fatty acyl group-sodium taurocholate alkylphenol polyoxyethylene formaldehyde condensation products; aralkyl phenol polyethenoxy ether phosphate alkylphenol polyoxyethylene; the castor oil ethylene oxide adduct; ethylene oxide-propylene oxide block copolymer alkylphenol polyoxyethylene formaldehyde condensation products; alkylphenol-polyethenoxy polyethenoxy ether and methylcellulose.Particularly following material can be used as wetting agent: sldium lauryl sulfate; alkylol polyoxyethylene groups ether sodium sulfate; octylphenol polyethylene oxyethylene group ether sulfate; alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate; sodium alkyl sulfonate; neopelex; Negel; dialkyl succinylsuccinate sulfonate; lauryl alcohol polyethylene glycol oxide base ether sulfonic acid sodium; the alkyl amide taurate; aliphatic alcohol polyethenoxy base ether; alkylphenol-polyethenoxy base ether; the polyoxyethylene poly-oxygen propylene aether block copolymer; sorbitan fatty acid ester polyoxyethylene groups ether etc.
Adhesive; can be for example carbonyl methylol, polyvinyl alcohol or the polyvinyl acetate that synthesize or natural water-soluble polymer for example xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc., add in the preparation with powder, particle or latex form.
Defoamer is: bubble enemy, silicone, C
8～10Fatty alcohol, phosphoric acid ester, C
10～20Saturated fat acids (as capric acid) and acid amides.
Oxidant is: potassium chlorate, sodium chlorate, potassium perchlorate, sodium nitrate, potassium nitrate, potassium permanganate etc.
Fire retardant is: ammonium chloride, magnesia, bentonite, white carbon black, diatomite, zinc oxide etc.
Can contain toner in the preparation, for example inorganic pigment iron oxide, titanium oxide or Prussia orchid; Organic dyestuff is alizarin, azo dyes, metal phthalocyanine or kiton colors for example.
The solid carrier that is fit to comprises natural or synthetic clay and silicate, for example natural silica and diatomite; Magnesium silicate is talcum for example; Magnesiumaluminumsilicate is atlapulgite for example; Alumina silicate is kaolinite, kaolin for example; White carbon black; Calcium carbonate, precipitated calcium carbonate; Calcium sulphate; Lime stone; Sodium sulphate; Ammonium salt such as ammonium sulfate, hexamethylene diamine; Synthetic hydrated silica and synthetic calcium silicates or alumina silicate; Element is carbon and sulphur for example; Natural and synthetic resin is cumarone resin, polyvinyl chloride and styrene polymer and copolymer for example; Solid polystream phenol; Pitch; Paraffin; Solid fertilizer, for example perphosphate.The solid carrier that is specially adapted to pulvis comprises the rock dust of natural formation, chalk, quartz, clay, imvite, silica, diatomite, float stone, gypsum, talcum, bentonite, kaolin, potter's clay and synthetic for example microdispersed silicic acid of the mineral matter that grinds or aluminium oxide; The particulate vector that is fit to comprises broken and natural rock classification for example calcite, marble, float stone, sepiolite and dolomite and the synthetic particle made by the powder of organic matter and inorganic matter.In addition, the also available organic material preparation of particulate vector, for example wood chip, peanut shell, cocoa husk, corncob, corn starch, soluble starch and dry tobacco rods.
According to the preparation type of composition, solid pharmaceutical preparation contains 5% to 85% active substance by weight, preferably is 10-80%; Liquid preparation contains 1-70% active substance by weight; Suspension preparation contains the active substance of 10-60% by weight.Below all percentage compositions be percetage by weight.
Wetting powder contains the active component of 10-85% by weight usually, except solid inert carrier, contain the dispersant of 3-10% by weight usually, if desired, contain stabilizing agent and/or other additive of 0-10%, for example bleeding agent or sticker by weight.(water dispersible) granule is made 10-100 international standard sieve mesh (1.676-0.152mm) particle usually, can be by reuniting or soaking into the method preparation.Usually granule contains the active component of 0.5-75% by weight and the additive of 0-10%, for example stabilizing agent, surfactant, slow release regulator and adhesive by weight.Suspending agent need stir usually, to obtain stable non-deposition flowable product, it contains the active component of 10-75% usually, the dispersant of 0.5-15%, the thixotropic agent of 0.1-10%, other additive of 0-10%, for example defoamer, corrosion inhibitor, stabilizing agent, bleeding agent and sticker, water or organic liquid, wherein active component is undissolved basically.Some organic solid or mineral salt can be dissolved in the preparation, to help preventing deposition or as antifreezing agent.Moisture dispersion liquid and emulsion, for example the composition that obtains of dilute with water wetting powder of the present invention or concentrate also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have dense thick pulpous state denseness.
The product that the present invention describes can be the finished product preparation form to be provided, and promptly each material mixes in the composition, but the composition of composition also can provide directly mixing in bucket (jar) before using with independent preparation.Concentrate of the present invention mixes the concentration that obtains required active substance usually with water.
Composition of the present invention can be used for preventing and treating the disease that is caused various plants by disease fungus, as cereal, wheat, paddy rice, grape, strawberry, cucumber, custard squash, capsicum, pimento, eggplant, tomato, Kidney bean, cowpea, leek, lettuce, Chinese cabbage, sunflower, lichee, tobacco, rubber and some flowers, traditional Chinese medicine, lawn etc.The place of using of microbicide compositions of the present invention is farmland, orchard or warehouse etc.
Composition of the present invention also can with other compound with weeding, desinsection or bactericidal property particularly protective fungicide mix use, can also mix use with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
The present invention comprises that also a kind of scene kills the method for fungi, before or after crop and/or fruit are susceptible, uses composition of the present invention to the place of crop and/or fruit and growth or storage.Can use composition of the present invention by common method, as cast, injection, spraying, dusting, distribution.Amount of application of the present invention is with weather condition or crop state variation.The duration of protective effect is usually relevant with the content of individualized compound in the composition, also relevant with extraneous factor, weather for example, but by using suitable formulation can slow down climatic influences.
Composition of the present invention has following advantage: the one, and composition shows fabulous synergistic effect in certain ratio range, mixed composition has obviously improved bactericidal effect than its single agent, thereby reduced using dosage, when reducing peasant's drug cost, reduced influence degree.The 2nd, enlarged fungicidal spectrum, the medicament characteristic also obtains extremely strong mutual supplement with each other's advantages, a kind of medicament can be prevented and treated the various crop disease simultaneously, a kind of use means extremely easily and effectively are provided, the downy mildew of various plants such as cereal, vegetables, fruit, lawn and tropical crop, eqpidemic disease, anthracnose, rice blast, powdery mildew, late blight, head blight, brown spot, scab, banded sclerotial blight, leaf spot, stalk break etc. have all been had good control efficiency.The 3rd, the interracial structure of said composition differs bigger, does not have cross resistance, and the resistance that can effectively delay single agent after the mixing takes place and development.
Embodiment
Following example further specifies the present invention, but the present invention is limited to these examples absolutely not.All proportionings in the preparation are weight percentage; The treatment dosage of biologically-active moiety is effective content.
Preparation of compositions and biologically active embodiment
1. the preparation of wetting powder
By the prescription requirement, former medicine, various auxiliary agent and filler etc. are fully mixed, after ultrafine crusher is pulverized, promptly obtain converted products.As example 1～5 prescription
Embodiment 1 (20% wetting powder)
Enestroburin 4%, maneb 16%, lauryl sodium sulfate 2%, carboxymethyl cellulose 3%, white carbon black 10%, calcium lignosulfonate 10%, precipitated calcium carbonate complements to 100%.
Embodiment 2 (30% wetting powder)
Enestroburin 25%, Propineb 5%, lauryl sodium sulfate 2%, white carbon black 10%, sodium lignin sulfonate 10%, precipitated calcium carbonate complements to 100%.
Embodiment 3 (40% wetting powder)
Enestroburin 5%, mancozeb 35%, neopelex 1%, white carbon black 10%, sodium lignin sulfonate 10%, precipitated calcium carbonate complements to 100%.
Embodiment 4 (50% wetting powder)
Enestroburin 5%, tmtd 45%, neopelex 2%, white carbon black 10%, naphtholsulfonic acid formaldehyde condensation products sodium salt 10%, precipitated calcium carbonate complements to 100%.
Embodiment 5 (63% wetting powder)
Enestroburin 3%, zineb 60%, lauryl sodium sulfate 1.5%, white carbon black 5%, sodium lignin sulfonate 8%, precipitated calcium carbonate complements to 100%.
2, the preparation of aqueous emulsion
Former medicine, solvent, emulsifier added with co-emulsifier be in the same place, make and be dissolved into even oil phase.Water, antifreeze etc. is mixed, becomes the homogeneous water.Under high-speed stirred, water is joined oil phase or oil phase is joined water, form the aqueous emulsion of favorable dispersibility.As example 6～9 prescriptions.
Embodiment 6 (10% aqueous emulsion)
Enestroburin 1%, for gloomy amine 9%, polyvinyl alcohol 0.8%, sorbitan fatty acid ester polyoxyethylene groups ether 5%, alkyl-diethylene glycol ether-sodium sulfonate 2.5%, farming breast 2,201 2%, dimethyl formamide 8%, ethylene glycol 5%, water complements to 100%.
Embodiment 7 (15% aqueous emulsion)
Enestroburin 1%, mancozeb 14%, polyvinyl alcohol 0.9%, alkylaryl polyoxyethylene poly-oxygen propylene aether 3.5%, farming breast 2,201 5%, dimethyl formamide 12%, ethylene glycol 5%, water complements to 100%.
Embodiment 8 (25% aqueous emulsion)
Enestroburin 5%, zineb 25%, polyvinyl alcohol 1.2%, in triphenylethylene phenol+oxirane, phosphorylation, the triethanolamine and 9.5%, alkyl-diethylene glycol ether-sodium sulfonate 3.5%, farming breast 2,201 13%, dimethyl formamide 8%, ethylene glycol 5%, water complements to 100%.
Embodiment 9 (31.5% aqueous emulsion)
Enestroburin 30%, for gloomy amine 1.5%, polyvinyl alcohol 1.8%, sorbitan fatty acid ester polyoxyethylene groups ether 10%, alkyl-diethylene glycol ether-sodium sulfonate 3.5%, farming breast 2,201 2%, dimethyl formamide 12%, ethylene glycol 5%, water complements to 100%.
3, the preparation of water-dispersible granules
Former medicine and powder carrier, wetting spreader-sticker and binding agent etc. are mixed pulverizing, after adding water again and mediating, add in the comminutor that the certain specification screen cloth is housed and carry out granulation.And then drying, screening (pressing the screen cloth scope) promptly get granular product.As example 10～11 prescriptions.
Embodiment 10 (50% water-dispersible granules)
Enestroburin 6.25%, tmtd 43.75%, methyl naphthalene sulfonate formaldehyde condensate 10%, epoxidized polyether 5%, soluble starch 5%, polyvinylpyrrolidone 5%, attapulgite complements to 100%.
Embodiment 11 (60% water-dispersible granules)
Enestroburin 10%, mancozeb 50%, methanonaphthalene sodium sulfonate 10%, neopelex 15%, polyvinylpyrrolidone 5%, attapulgite complements to 100%.
4, the preparation of suspending agent
By the prescription requirement, be medium with water, former medicine, dispersant, suspending agent and antifreezing agent etc. are added in the sand milling still, carry out porphyrize, make suspending agent.As example 12～14 prescriptions.
Embodiment 12 (10% suspending agent)
Enestroburin 1%, generation gloomy amine 9%, methyl naphthalene sulfonate formaldehyde condensate 5.5%, white carbon black 5%, aluminium-magnesium silicate 2.0%, ethylene glycol 10%, tributyl phosphate a little, diatomite 5%, water complements to 100%.
Embodiment 13 (25% suspending agent)
Enestroburin 5%, Propineb 20%, calcium lignosulfonate 5%, white carbon black 2%, urea 10%, tributyl phosphate a little, water complements to 100%.
Embodiment 14 (35% suspending agent)
Enestroburin 5%, mancozeb 30%, methyl naphthalene sulfonate formaldehyde condensate 2.5%, bentonite 1.0%, farming breast 16013%, glycerine 8%, tributyl phosphate a little, water complements to 100%.
5, biologically active
The test grading standard of field efficacy is carried out the grade scale classification record of medicine inspecting institute of the Ministry of Agriculture " agricultural chemicals field trial criterion ", calculates control efficiency with disease index.
Embodiment 15 bacteriostatic activities (potato late blight)
Measure the fungistatic effect of the preparation of maneb, Enestroburin and example 1 in the toxic dielectric method of indoor employing to potato late blight.Test method: add quantitative pharmacy respectively in the PDA medium, cool off back inoculation phytophthora infestans (P.infestans de Bary), cultivate 24 ℃ of unglazed photographs under the condition inoculation back, cultivates and carried out result's investigation in 96 hours.Test result is as follows:
Embodiment 16 bacteriostatic activities (corn southern leaf blight)
Measure the fungistatic effect of the preparation of Enestroburin, Propineb and example 2 in the toxic dielectric method of indoor employing to corn southern leaf blight.Test method: add quantitative pharmacy respectively in the PDA medium, cool off back inoculation corn southern leaf blight (Bipolarismayghi), cultivate 24 ℃ of unglazed photographs under the condition inoculation back, cultivates and carried out result's investigation in 96 hours.Test result is as follows:
Embodiment 17 bacteriostatic activities (bakanae disease of rice)
The toxic dielectric method of indoor employing measure Enestroburin, generation gloomy amine and the preparation of example 6 to the fungistatic effect of bakanae disease of rice.Test method: add quantitative pharmacy respectively in the PDA medium, cool off back inoculation bakanae disease of rice (Fusarium moniliforera), cultivate 24 ℃ of unglazed photographs under the condition inoculation back, cultivates and carried out result's investigation in 96 hours.Test result is as follows:
Embodiment 18 bacteriostatic activities (cercospora brown spot of peanut)
Measure the fungistatic effect of the preparation of Enestroburin, Propineb and example 13 in the toxic dielectric method of indoor employing to the cercospora brown spot of peanut.Test method: add quantitative pharmacy respectively in the PDA medium, cool off back inoculation peanut Cercospora bacteria (Cercosporaarachidicola Hori), cultivate 24 ℃ of unglazed photographs under the condition inoculation back, cultivates and carried out result's investigation in 96 hours.Test result is as follows:
Embodiment 19 disease-controlling effects (cucumber downy mildew)
Measure the fungistatic effect of Enestroburin, mancozeb and 5 pairs of cucumber downy mildews of example at indoor employing Plating.Test method: cucumber leaves is put into the culture dish processing of preserving moisture, and by the design dosage spray medicament respectively, inoculate bacterium of downy mildew of cucumber (Psudoperonospora cubensis) pathogen after 24 hours, result's investigation is carried out in the cultivation of preserving moisture in the controlled environment chamber after the inoculation after 6 days.Test result is as follows:
Embodiment 20 disease-controlling effects (powdery mildew of cucumber)
Adopt the greenhouse pot culture cucumber seedling, measure the control efficiency of the preparation of Enestroburin, mancozeb and embodiment 7 powdery mildew of cucumber.Cucumber variety: the close thorn in Shandong, pathogen: powdery mildew of cucumber bacterium (Erysiphe cihporacearum); When choosing cucumber and growing to 3～4 leaves, the growing way uniformity carries out foliar spray by design dosage and handles on the crop sprayer, inoculate pathogen after 24 hours, and inoculation back moist chamber is preserved moisture to cultivate and carried out result's investigation after 7 days.Test result is as follows:
Embodiment 21 disease-controlling effects (scab of cucumber)
Adopt the greenhouse pot culture cucumber seedling, measure the control efficiency of the preparation of Enestroburin, tmtd and embodiment 10 scab of cucumber.Cucumber variety: the close thorn in Shandong, pathogen: cucumber apple scab (Cladosporium cucumerium); When choosing cucumber and growing to 3～4 leaves, the growing way uniformity carries out foliar spray by design dosage and handles on the crop sprayer, inoculate pathogen after 24 hours, and inoculation back moist chamber is preserved moisture to cultivate and carried out result's investigation after 7 days.Test result is as follows:
Embodiment 22 disease-controlling effects (downy mildew of garpe)
Adopt greenhouse pot culture to insert the skewer grape seedling, measure the control efficiency of the preparation of Enestroburin, zineb and embodiment 8 downy mildew of garpe.Grape variety: huge rich, pathogen: downy mildew of garpe (Plasmopara viticola): when the slotting skewer grape seedling in greenhouse grows to 3～4 leaves, select the blade of 2 growth uniformities, carrying out foliar spray by design dosage on the crop sprayer handles, inoculate pathogen after 24 hours, preserve moisture after the inoculation to cultivate and carry out result's investigation after 7 days.Test result is as follows:
Embodiment 23 field sub-district control efficiency (alternaria leaf spot of apple)
In the preparation of field test Enestroburin, Propineb and embodiment 9 control efficiency to apple fallen leaves spot disease.Apple variety: new Red Star, pathogen: zonate spot bacterium (Alterlaria mali); Dispenser when apple orchard first meeting scab, spray medicine 3 times, 7 days at interval, 15 days investigation preventive effects after the 5th dispenser.Test result is as follows:
Embodiment 24 field sub-district control efficiency (tomato late blight)
In greenhouse by solar heat, measure the control efficiency of the preparation of Enestroburin, zineb and embodiment 3 to tomato late blight.Tomato variety: hair powder 402, pathogen: tomato late blight (Phytophthora infestans); In the late March in spring, dispenser when field first meeting scab, spray medicine 4 times, 7 days at interval, 7 days investigation preventive effects after the 4th dispenser.Test result is as follows:
Embodiment 25 field sub-district control efficiency (leaf spot of peanut)
In the preparation of field test Enestroburin, mancozeb and embodiment 14 control efficiency to leaf spot of peanut.Peanut varieties: farming is spent No. 26, pathogen: tail spore bacterium (Cercospora personata.); Dispenser when peanut field first meeting scab, spray medicine 3 times, 7 days at interval, 15 days investigation preventive effects after the 3rd dispenser.Test result is as follows:
Embodiment 26 field sub-district control efficiency (bakanae disease of rice)
In greenhouse by solar heat, measure the control efficiency of the preparation of Enestroburin, zineb and embodiment 12 to bakanae disease of rice.Rice varieties: No. 5, the Liao Dynasty stalk, pathogen: bakanae disease of rice (Fusarium moniliforera), the chemicals treatment mode is seed soaking, seed soaking concentration is 800,400,200,100ug/ml.Before rice transplanting, investigate preventive effect.Test result is as follows:
Claims (9)
1, a kind of bactericidal composition contains bactericide Enestroburin and any one thiocarbamate bactericide; Enestroburin and thiocarbamate are 1: 100 to 100: 1 based on the ratio of weight and number of active component.
2, bactericidal composition according to claim 1 is characterized in that: Enestroburin and thiocarbamate are 1: 20 to 20: 1 based on the ratio of weight and number of active component.
3, bactericidal composition according to claim 1 and 2 is characterized in that: described thiocarbamate bactericide is selected from gloomy salt of mancozeb, maneb, zineb, Propineb, ambam, generation, tmtd, Diram or ziram.
4, bactericidal composition according to claim 3 is characterized in that: described thiocarbamate bactericide is selected from mancozeb, maneb, zineb, Propineb, ambam or tmtd.
5, bactericidal composition according to claim 1 and 2 is characterized in that: the active component weight percentage in the composition is 0.5-95%.
6, bactericidal composition according to claim 1 is characterized in that: contain at least two kinds of carriers in the composition, wherein at least a is surfactant.
7, bactericidal composition according to claim 1 is characterized in that: said composition can be mixed with suspending agent, aqueous emulsion, wetting powder or water dispersion granule.
8, the described bactericidal composition of claim 1 is used to prevent and treat the purposes of the plant disease that is caused by disease fungus.
9, the method for fungi is killed at a kind of scene, it is characterized in that: before or after crop and/or fruit are susceptible, use claim 1 or 7 described bactericidal compositions to the place of crop and/or fruit and growth or storage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031334202A CN100352347C (en) | 2003-06-10 | 2003-06-10 | Bactericidal compositions containing enostroburin and thiocarbamate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031334202A CN100352347C (en) | 2003-06-10 | 2003-06-10 | Bactericidal compositions containing enostroburin and thiocarbamate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1565183A true CN1565183A (en) | 2005-01-19 |
| CN100352347C CN100352347C (en) | 2007-12-05 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031334202A Expired - Lifetime CN100352347C (en) | 2003-06-10 | 2003-06-10 | Bactericidal compositions containing enostroburin and thiocarbamate |
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| CN (1) | CN100352347C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090011935A1 (en) * | 2006-03-14 | 2009-01-08 | Basf Se | Method of Inducing Tolerance of Plants Against Bacterioses |
| US8273686B2 (en) | 2006-03-24 | 2012-09-25 | Basf Se | Method for combating phytopathogenic fungi |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2132048A1 (en) * | 1993-09-24 | 1995-03-25 | Horst Wingert | Fungicidal mixtures |
| CN1062711C (en) * | 1998-02-10 | 2001-03-07 | 化工部沈阳化工研究院 | Pesticide and fungicide of unsaturated oximido ethers |
-
2003
- 2003-06-10 CN CNB031334202A patent/CN100352347C/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090011935A1 (en) * | 2006-03-14 | 2009-01-08 | Basf Se | Method of Inducing Tolerance of Plants Against Bacterioses |
| US8273686B2 (en) | 2006-03-24 | 2012-09-25 | Basf Se | Method for combating phytopathogenic fungi |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100352347C (en) | 2007-12-05 |
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