CN1561404A - Method for hot-dip finishing - Google Patents

Method for hot-dip finishing Download PDF

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Publication number
CN1561404A
CN1561404A CNA028191188A CN02819118A CN1561404A CN 1561404 A CN1561404 A CN 1561404A CN A028191188 A CNA028191188 A CN A028191188A CN 02819118 A CN02819118 A CN 02819118A CN 1561404 A CN1561404 A CN 1561404A
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CN
China
Prior art keywords
rotor
coating
container
liquid
liquation
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Granted
Application number
CNA028191188A
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Chinese (zh)
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CN1295373C (en
Inventor
R·布里斯伯格
W·特拉科夫斯基
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SMS Siemag AG
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SMS Demag AG
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Publication of CN1561404A publication Critical patent/CN1561404A/en
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Publication of CN1295373C publication Critical patent/CN1295373C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14Removing excess of molten coatings; Controlling or regulating the coating thickness
    • C23C2/24Removing excess of molten coatings; Controlling or regulating the coating thickness using magnetic or electric fields

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention relates to a method and a device for coating the surfaces of, in particular, strip-like material, for example, a non-ferrous metal strip or a steel strip, with at least one metallic coating by running through at least one container filled with the liquid melt coating material. The metal strip for coating runs through the molten bath of coating material within the container from bottom to top, suitable guide means are provided for the above. The sealing of the container base is achieved by means of circumferential permanent magnets.

Description

The processing method of hot dip finishing
The present invention relates to the surface of for example a kind of non-ferrous metal band of ribbon or a kind of steel band is particularly carried out the method for coating, these ribbons are coated at least a metallic coating when the container of liquation coated material is housed by at least one.The present invention also relates to be used to implement the device of this processing method.
Has the Zn alloy, Zn-Al alloy, the band of Al alloy or Al-Si alloy is at hot coating traditional in the coating position (title method 1) as described below: will be with in a process furnace and take out, cut off air, send in the liquation and by means of the difference of non-active roll arrange and commutation to vertical and keep stable, referring to Fig. 1.This is applicable to all described coating metal/alloys when hot dip coating is refining.
The shortcoming of processing method 1 is: running roller and running roller bearing are positioned within the liquation, and all material all is subjected to the chemical erosion effect of liquation.Shortened the work-ing life of all parts of packing in the liquation.Need a large amount of liquations to be equipped with corresponding big melt vessel in addition, so that lay these running rollers or whole molten bath equipment.When pot galvanize, want 200-400t liquid zinc usually.Because capacity is very big just can not to carry out quick adjustment to the temperature and the alloying constituent of liquation.Above the bigger change of described parameter all have to put up with, and under a stable condition, cause downgrade, this is because the measure of alloy technology aspect and the quality of band influence each other in same container.
The another one shortcoming is: especially strip (<0.5mm) time in order to realize cost effective device ability (approximately 180m/min), production rate can not be improved.Its reason is: produced relative movement between running roller in being in the pond and the band.If avoid this problem and improve pulling force, that just has the danger of tear-strap, its consequence is to cause the equipment of a lot of waste materials and long period to pause.
The maximum belt speed of hot zinc coating equipment on the other hand be limited in the nozzle conditioning system that is positioned on the zinc liquation, see Fig. 1.Adjust bed thickness by means of air or nitrogen, wherein along with the minimum available coat-thickness of the increase of belt speed just increases.That is to say, when high belt speed, can not produce thin coating.But shallow layer (<25g/m just 2, single face is when the thin plate of hot zinc coating) be popular for the application of some top grade.
As further exploitation, carry out for the ferrite steel band of being made by soft non-steel alloy that the processing method of hot dip finishing is known to have so-called vertical heat zinc-plated, it has done introduction in different patents such as EP0630421B1 and EP 0630420B1 and EP 0673444B1.
Band is from the top down by a Work container of filling the liquation shape metal of being made up of zinc alloy and/or aluminium alloy in this processing method (title method 2), and wherein band has carried out a kind of thermal treatment and band is entered in the liquation carrying out under the cut-out air before this.The liquation volume is compared with first method and is approximately lacked the 2-5t liquid Zn.And do not have a problem qualitatively recited above, this is because the measure of alloy technology aspect all is to carry out in a leading container that is positioned at this streamline next door, and in the Work container with quality irrelevant therewith.
Connection between Work container and the furnace chamber below it realizes by a gastight pottery passage, and the about 800mm height of this passage only is 20mm for the width maximum of being with of passing through.The sealing that Work container is downward and avoid liquation to flow to entering down in the furnace chamber these all under this passage, to be arranged in passage or be with lateral inductor block and realize by means of two.This inductor block has produced a kind of moving field, and it produces the power in the sensing, and this mechanical resistance has been ended liquation and moved downward.The work of this induction system is as a pump, thereby also guaranteed in passage the exchange to liquation.
Method 2 is characterised in that, even also can easily produce much higher belt speed for thin steel band one in the coating position of liquid-bath at least, reach 300m/min, because running roller is not all in coating container.
When band has passed through coating unit from bottom to top, for example when pot galvanize, reach after about 460 ℃ of the temperature, can with method 1 similarly just on the molten bath method according to nozzle cleaning finishing set up the refining layer desirable thickness of metal.This and method 1 are similarly by means of advertising pressurized air or nitrogen is realized.
With method 1 similarly, even if coating is thin when method 2, nozzle cleaning method for trimming has also limited the belt speed of maximum possible.Certainly method 2 provides bigger degree of freedom for equally also viscosity and the alloying constituent to the influential zinc-plated parameter of coat-thickness such as temperature, liquation.Its reason is: the belt speed when comparing when identical coat-thickness method 2 with method 1 can be selected highlyer.With method 1 mutually ratio method 2 still without large batch of check.So far just test with narrow band with model machine.These tests are very successful.
Yet the reason that prevention speed improves is: subsequently band is cooled to below 300 ℃.If temperature is higher than this, its danger just is: producing metallic particles and produce the surface imperfection that can not repair on material in first contact running roller or commutation running roller place the cooling tower.
Usually cool off by means of a plurality of air cooling sections of arranging one by one.But cooling effect and more precisely rate of cooling be subjected to the restriction of medium, and (for example 2 * 15m) can not at random improve on the distance of a regulation when using the heat-eliminating medium air.Along with the increase of the increase of belt speed or mass rate this cooling section distance that must extend.But this has caused the raising of commutation running roller in the cooling tower of hot dip finishing equipment.
The height of commutation running roller is usually between 30-60m on pressing in the method 1 described equipment.For method 2 must correspondingly continue when the high belt speed to extend cooling section and thereby on the 80-90m direction, improve the height of cooling tower as far as possible.This just makes the cost of investment on buildings and basis raise more.
Thereby extended in the unsettled band Duan Zaita of idling and the operation of be with has worsened, thereby vibration may appear and to quality product generation adverse influence.Other heat-eliminating medium is applied in epimere and then also has problems, at present still without extensive use.
Be by method 2 another problem for electromagnetic sealing: the Z-TEK that acts on the liquid liquation does not act on ferritic being with yet.Band and the passage magnetive attraction of inductor block by sealing cause a kind of undesirable contact just just possible by additional expensive measure.Additional ballast coil and complicated expensive regulation technology must be arranged for this reason.
Task of the present invention is to avoid the shortcoming of aforesaid method 1 and 2 and propose a kind of high speed hot dip finishing equipment that does not have cooling tower, this equipment complex minimum possible manufacturing expense, the cost of investment of optimization and when the best quality of production, reach high capacity of equipment.
The method that solves this task in the method for type described in a kind of preorder of claim 1 is: the permanent magnet by means of circular flow makes container sealing.More reliable and save money manyly than a kind of electromagnetic solution by means of the permanent magnet of circular flow to the sealing of container, and want much less when rotating required energy than electromagnetic sealing, this especially has superiority when outage.
Some technical schemes of method all are described in other dependent claims.Implement the device and the design thereof of this method and see other claim.
The present invention will be described according to some sketch illustrated embodiments.Be depicted as:
Fig. 1: a kind of traditional coating process of band;
Fig. 2: according to the coating process of a kind of further exploitation of technical background;
Fig. 3: the high speed hot dip finishing equipment by coating process of the present invention and a kind of respective design is in operation;
Fig. 4: the equipment when pressing starting state shown in Figure 3;
Fig. 5: by shown in Figure 3, the equipment when after operation, stopping.
Enter vertically downward in the container cutting off under the situation of air after commutating in stove according to Fig. 3, liquid-bath is located in this container.This solution pool seals up downwards.Need some power, but they not electromagnetic modes for this reason, but produce by means of permanent magnet around operation.This itself is known to make liquation guarantee sealing with permanent magnet.But come work with rectangular channel there.The spacing of this channel form and shape can not change.
And the present invention recommend with two rotors that are arranged side by side 5,5 '.These rotors be the pipe 6,6 made by high temperature resistant and material refractory liquid ', they are preferably made by pottery.Pipe 6,6 that these its diameters can freely be selected ' in have running roller to rotate, on the outside surface of these running rollers, be provided with permanent magnet 4.Rotor 5,5 ' can adjust to liquation or to band.Also can be when equipment downtime or closing gap 7 during the equipment starting.
Permanent magnet wants cost much lower than by means of the electromagnetic sealing of coil or inductor block, and much less when being used to rotate required energy than electromagnetic sealing, and this especially has superiority when having a power failure.
In addition, with respect to electromagnetic mode of operation, can produce bigger magneticstrength (factor 3) with permanent magnet.This high magneticstrength and the bigger power that draws thus need be used to be adjusted at desirable coat-thickness on the steel band for the cleaning finishing process.Must carry out by means of additional cleaning finishing nozzle in this former known method.
Addition thereto within magnetic seal and cleaning finishing needn't be carried out in by method of the present invention again, and this is because only be seldom several millimeters with 1 position of passing the narrowest passage of sealing unit.It is shorter to be with 1 tensioning can be than previously known method the time to get in addition, this be because directly under sealing unit, just can make be with 1 in a pond 9 li cool off immediately and commutate.Tensioning length in the present invention preferably only is about 5000mm, when method 1 the big 8-10 of this length doubly about, and bigger when method 2.
Another advantage by method of the present invention is: the liquation metal; preferably the zinc liquation is among the surface in the coating position is in a kind of shielding gas atmosphere; this protection gas is made of nitrogen/hydrogen mixture, and can not produce the oxidation that interference effect is arranged of liquid Zn.To add a lot of expenses when implementing like this in the method 1 and 2 known to former.The zinc pool surface can be accessed for some handwork.Just need not be provided with the channel space that leads to weld pool surface in the present invention in order to remove oxidation particle.
Be used in the embodiment shown in fig. 3 a kind of non-ferrous metal band, or a kind of steel band 1 equipment of carrying out the hot dip finishing is in a kind of state of continuous operation.That send into and want purified band 1 on 2 li on stove by a tensioning running roller 17, then through gate 18, it with oxygen seal closed protection air with respect to the air of environment in hot dip finishing equipment inside.
Making by guide roller 13 in back to back zinc-plated chamber 14 is with 1 to be diverted to vertical sensing coating area.Be with when entering coating area 19 1 passed through from the top down in vertical direction rotor 5,5 ' between 7 li liquid-baths that kept in gap 3 and therefore obtain desirable coating.
This liquid-bath 3 one be positioned at isolated rotor 5,5 ' between in the formed gap in the bottom when tape running by the time stop downwards by means of the power of the shifting magnetic field of the permanent magnet 4 of the magnetive attraction in magnetic field or rotation.The pipe 6,6 that rotor 5,5 ' be positioned at surrounds them ' within 19 li of the coating areas that outwards is surrounded by a passage shape shell, this zone laid rotor 5,5 ', spacing can change.Surround their pipe 6,6 ' then high temperature resistant and refractory liquid, nonmagnetic substance especially, preferably pottery is made.
Permanent magnet 4 is at these pipe 6,6 ' internal rotation.Be used to apply the needed and current liquation that will replenish from a liquid-collecting box 8 by means of an adjustable joint number amount of metal pump be transported to rotor 5,5 ' between the gap go for 7 li, can regulate solution for 8 li at liquid-collecting box.Carried out also following by gap 7 in the lower end of coating inside, then be used for water-cooled device 16 by one by a device 15 that is used for air-stable with 1.
After through pond 9 and tightening pulley 20, go out to do further to use or handle with regard to slave unit lira.
Other Figure 4 and 5 have all been represented the method by invention.
A) a kind of starting state and
B) shutdown after the operation.
A) starting state:
-band stops
-rotor rotation
-close gap between rotor
-input liquation
-close furnace chamber.
B) shutdown after the operation
-liquation returns
-rotor rotation
-space closure
-furnace chamber is opened.

Claims (9)

1. to ribbon especially, the method of coating is carried out on the surface of for example a kind of non-ferrous metal band or a kind of steel band, these ribbons have been coated the coating of at least a metal when the container of liquation shape coated material is housed by at least one, it is characterized in that container is realized sealing by means of the permanent magnet of circular flow.
2. by the described method of claim 1, it is characterized in that, just carried out the adjustment of desirable coat-thickness on metal strip simultaneously by means of the permanent magnet of circular flow.
3. by claim 1 or 2 described methods, it is characterized in that, the coated material of liquation shape is in the wedge gap between the rotor of two reverse rotations of a liquid-collecting box introducing, and wherein metal strip passes through liquid-bath from the top down and passes between spaced apart rotor.
4. by one in the aforesaid right requirement or multinomial described method, it is characterized in that metal strip is preferably under the shielding gas atmosphere under the situation of cut-out air in preheating oven back warp commutation back and vertically is passed down through liquid-bath.
5. by one in the aforesaid right requirement or multinomial described method, it is characterized in that the line space gas of bringing into that coating is crossed is stablized and/or water cooling.
6. especially for the device of implementing by one of aforesaid right requirement described method, it comprises that at least one container is used to place the liquation shape coated material that metal ribbon is used, it is characterized in that, for making container sealing be provided with two antiports, the rotor that can mutually adjust in case of necessity, wherein within rotor, be provided with rotating running roller, on the outside surface of running roller, fixed permanent magnet.
7. by the described device of claim 6, it is characterized in that the container that liquid-bath is housed is made of the top intermediate cavity between the rotor.
8. by claim 6 or 7 described devices, it is characterized in that these rotors are surrounded by a shell keeping under a kind of shielding gas atmosphere at least.
9. by one or multinomial described device in the claim 6 to 8, it is characterized in that, rotor case and one are used for metal strip from being delivered to the upper chamber of rotor case, and the liquid-collecting box of using with a liquation, and be arranged in for example being used for bringing the stable and water-cooled device of line space gas under the rotor case, and be connected with another pond in case of necessity.
CNB028191188A 2001-09-28 2002-09-25 Method for hot-dip finishing Expired - Fee Related CN1295373C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10148158A DE10148158A1 (en) 2001-09-28 2001-09-28 Process for hot-dip coating with reverse strip travel
DE10148158.6 2001-09-28

Publications (2)

Publication Number Publication Date
CN1561404A true CN1561404A (en) 2005-01-05
CN1295373C CN1295373C (en) 2007-01-17

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CNB028191188A Expired - Fee Related CN1295373C (en) 2001-09-28 2002-09-25 Method for hot-dip finishing

Country Status (18)

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US (1) US20050048216A1 (en)
EP (1) EP1430162B1 (en)
JP (1) JP2005504177A (en)
KR (1) KR20040045011A (en)
CN (1) CN1295373C (en)
AT (1) ATE327352T1 (en)
BR (1) BR0212938A (en)
CA (1) CA2461912A1 (en)
DE (2) DE10148158A1 (en)
ES (1) ES2264738T3 (en)
HU (1) HUP0401759A2 (en)
MX (1) MXPA04002746A (en)
PL (1) PL367442A1 (en)
RU (1) RU2300577C2 (en)
UA (1) UA78722C2 (en)
WO (1) WO2003029507A1 (en)
YU (1) YU25704A (en)
ZA (1) ZA200401565B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10240954B4 (en) * 2002-09-05 2012-05-31 Sms Siemag Aktiengesellschaft Device for the hot dip coating of a metal strand
EP1538233A1 (en) * 2002-09-13 2005-06-08 JFE Steel Corporation Method and apparatus for producing hot-dip coated metal belt
FR2958563A3 (en) * 2010-04-13 2011-10-14 Fives Stein METHOD AND DEVICE FOR COATING METAL BANDS

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2223499A (en) * 1936-08-20 1940-12-03 Crown Cork & Seal Co Method of coating metal
SE328454B (en) * 1968-09-20 1970-09-14 Asea Ab
JPS5129981B2 (en) * 1973-07-17 1976-08-28
JPS63286562A (en) * 1987-05-19 1988-11-24 Hitachi Cable Ltd Hot dipping method
DE3718178A1 (en) * 1987-05-29 1988-12-15 Hoesch Stahl Ag Method for the production of metallic fibres and an apparatus for carrying out the method
CA2072200C (en) * 1991-06-25 1996-12-17 Toshio Sato Method for controlling coating weight on a hot-dipping steel strip
IN191638B (en) * 1994-07-28 2003-12-06 Bhp Steel Jla Pty Ltd
JPH1017184A (en) * 1996-07-01 1998-01-20 Nippon Steel Corp Carrier roller of steel belt
JPH1143754A (en) * 1997-07-23 1999-02-16 Nisshin Steel Co Ltd Overhead provided with mechanism for preventing falling of hot-dip plating metal
JPH11172400A (en) * 1997-12-15 1999-06-29 Hitachi Ltd Continuous hot dip coating device and continuous hot dip coating method
CN2332733Y (en) * 1998-07-17 1999-08-11 张玉崑 Metal wire rod hot dipped steel wire appts. using electromagnetic force for coating
JP2000212714A (en) * 1999-01-18 2000-08-02 Hitachi Ltd Device and method for continuous hot dip metal coating
JP2000219944A (en) * 1999-01-29 2000-08-08 Nkk Corp Apparatus for producing steel sheet coated with hot-dip metal

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Publication number Publication date
ES2264738T3 (en) 2007-01-16
YU25704A (en) 2006-08-17
RU2300577C2 (en) 2007-06-10
US20050048216A1 (en) 2005-03-03
ZA200401565B (en) 2004-05-04
WO2003029507A1 (en) 2003-04-10
RU2004113102A (en) 2005-05-20
CN1295373C (en) 2007-01-17
MXPA04002746A (en) 2005-09-08
EP1430162A1 (en) 2004-06-23
DE50206923D1 (en) 2006-06-29
KR20040045011A (en) 2004-05-31
PL367442A1 (en) 2005-02-21
JP2005504177A (en) 2005-02-10
EP1430162B1 (en) 2006-05-24
ATE327352T1 (en) 2006-06-15
UA78722C2 (en) 2007-04-25
CA2461912A1 (en) 2003-04-10
HUP0401759A2 (en) 2004-12-28
BR0212938A (en) 2004-10-13
DE10148158A1 (en) 2003-04-17

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