CN1500833A - Engineering plastic (ABS) plastic-wood panel - Google Patents
Engineering plastic (ABS) plastic-wood panel Download PDFInfo
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- CN1500833A CN1500833A CNA021489955A CN02148995A CN1500833A CN 1500833 A CN1500833 A CN 1500833A CN A021489955 A CNA021489955 A CN A021489955A CN 02148995 A CN02148995 A CN 02148995A CN 1500833 A CN1500833 A CN 1500833A
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Abstract
The ABS plastic-wood board has the materials including ABS copolymer, wood dust and assistants. The ABS copolymer has water content 0.01-0.05 % and is powder; and wood dust has water content of 0.3-1.0 % and granularity of 150-300 mesh. The assistants include stuffing titania, calcium carbonate or silica white of granularity 150-300 mesh; toughening agent EVA; crosslinking agent isooctyl thioacetate octyl tin; coupling agent gamma-amino propyl trimethoxyl silane or tri(dioctyl pyrophosphoryl oxy) isopropyl phthalate; impact modifier TBPDO; fire retardant antimonous oxide and tetrabromo bisphenol A bis(2, 3-dibromopropyl) ether; antiager DLTP, tetra[beta-(3, 5-ditert-butyl-4-hydroxyphenyl propyl ester) pentaerythritol ester and UV327.
Description
Technical field that the present invention belongs to
The invention belongs to the composite plastic wood plate material that is mixed and made into engineering plastics (ABS), wood powder and auxiliary agent.
The prior art background
Wood plank has purposes widely, but because the forest reserves are limited, timber resources is fully used and seeks the surrogate with good use properties.
Summary of the invention
The objective of the invention is to propose a kind of plastic wood sheet technical scheme, can make full use of timber resources, and have good use properties, is a kind of novel material of alternative wood plank.
ABS plastic wood sheet of the present invention., its component comprises Acrylonitrile Butadiene, wood powder and auxiliary agent.ABS (acrylonitrile/butadiene/styrene multipolymer) water content 0.01%～0.05%, meal is less than 150 orders, and consumption is 100 parts; Wood powder water content 0.3～1.0%, granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts; The different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part; 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
Be to improve or increase functions of use, the auxiliary agent that uses in the ABS plastic wood sheet of the present invention can also comprise 2 parts～15 parts of 10 parts～15 parts in two (dibromo-phenoxy base) ethane of anti-impact modifier and tetrabromophthalate (second-ethylhexyl) esters (TBPDO); 3 parts～10 parts in two (2, the 3-dibromopropyl) ethers of 1 part～10 parts of fire retardant antimonous oxides and tetrabromo-bisphenol; 0.5 part～5 parts of (1010) 0.5 parts～5 parts of 0.5 part～2.0 parts, four [β-(3.5-di-tert-butyl-4-hydroxy phenyl propyl ester)] pentaerythritol esters of antiaging agent silicon in February thiodipropionate (DLTP) and (2-hydroxyl-3,5-5-di-tert-butyl-5-oxygen base)-benzene well triazoles (UV327);
The moulding process of plastic wood sheet of the present invention is according to above-mentioned prescription, and abs polymer and wood powder through processing treatment, mixing, granulation, are mixed different pellet heating and meltings again, adopt extrude, injection moulding, casting or calendering formation make sheet material.The equipment of moulding wooden moulding has been prior art.
Embodiments of the invention are as follows:
One of embodiment:
ABS water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts, the different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part, 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
This routine plastic wood sheet is common ABS plastic wood sheet.
Two of embodiment:
ABS water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts, and the different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part; 2 parts～15 parts of 10 parts～1 5 parts in two (dibromo-phenoxy base) ethane of anti-impact modifier and tetrabromophthalate (second-ethylhexyl) esters (TBPDO), 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
This routine plastic wood sheet has shock resistance, can make wrapping material, sleeper, wallboard and products such as furniture, floor.
Three of embodiment:
ABS water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts, the different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part, 1 part～10 parts in fire retardant three itching two antimony and tetrabromo-bisphenol two (2, the 3-dibromopropyl) ether is 3 parts～10 parts, 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
This routine plastic wood sheet has flame retardant properties, can make PLASTIC LAMINATED.
Four of embodiment:
ABS water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts, the different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part, 0.5 part～2.0 parts of antiaging agent silicon in February thiodipropionates (DLTP), (1010) 0.5 parts～5 parts of four [β-(3.5-di-tert-butyl-4-hydroxy phenyl propyl ester)] pentaerythritol esters and (2-hydroxyl-3,5-5-di-tert-butyl-5-oxygen base)-0.5 part～5 parts of benzene well triazoles (UV327), 2 parts～15 parts of 10 parts～15 parts in two (dibromo-phenoxy base) ethane of anti-impact modifier and tetrabromophthalate (second-ethylhexyl) esters (TBPDO), 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
This routine plastic wood sheet has ageing resistance, can make the product of outdoor use.
Five of embodiment:
ABS water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts, the different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part, 2 parts～15 parts of 10 parts～15 parts in two (dibromo-phenoxy base) ethane of anti-impact modifier and tetrabromophthalate (second-ethylhexyl) esters (TBPDO); 3 parts～10 parts in two (2, the 3-dibromopropyl) ethers of 1 part～10 parts of fire retardant antimonous oxides and tetrabromo-bisphenol; (1010) 0.5 parts～5 parts of 0.5 part～2.0 parts, four [β-(3.5-di-tert-butyl-4-hydroxy phenyl propyl ester)] pentaerythritol esters of antiaging agent silicon in February thiodipropionate (DLTP) and (2-hydroxyl-3,5-5-di-tert-butyl-5-oxygen base)-and 0.5 part～5 parts of benzene well triazoles (UV327), 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
This routine plastic wood sheet material material has fire-retardant and ageing-resistant performance, can make the products such as wall dunnage of PLASTIC LAMINATED, outdoor application.
Six of embodiment:
ABS water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts, the different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part, 2 parts～15 parts of 10 parts～15 parts in two (dibromo-phenoxy base) ethane of anti-impact modifier and tetrabromophthalate (second～ethylhexyl) esters (TBPDO); 3 parts～10 parts in two (2, the 3-dibromopropyl) ethers of 1 part～10 parts of fire retardant antimonous oxides and tetrabromo-bisphenol; (1010) 0.5 parts～5 parts of 0.5 part～2.0 parts, four [β-(3.5-di-tert-butyl-4-hydroxy phenyl propyl ester)] pentaerythritol esters of antiaging agent silicon in February thiodipropionate (DLTP) and (2-hydroxyl-3,5-5-di-tert-butyl-5-oxygen base)-and 0.5 part～5 parts of benzene well triazoles (UV327), 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
That this routine plastic wood sheet material material has is fire-retardant, shock resistance, ageing resistance, of many uses.
Seven of embodiment:
ABS water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts; The different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part; 0.5～30 part of whipping agent Cellmic C 121 (ADAC), 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
This example is the ABS foaming plate.
Eight of embodiment:
ABS water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts, and the different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part; 0.5～5 part of processing aid Zinic stearas, 0.5～5 part of calcium stearate, 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
This routine ABS sheet material is easy to processing.
Nine of embodiment:
ABS water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts, and the different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part; 5～30 parts of antiseptic-germicide Haier antiseptic-germicides (KHFS-2), 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
This routine ABS sheet material has anti-microbial property.
Ten of embodiment:
ABS water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts, and the different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part; Anti-crisp dose 2,0.5～5 part of 6-toluene di-tert-butyl phenol (antioxidant 264), 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
This routine ABS sheet material has good anti-aging use properties.
11 of embodiment:
ABS water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts, and the different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part; Add 5～20 parts of new LDPE (film grade)s and an amount of hexanodioic acid that becomes, 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
This routine ABS plate just has the use properties of anti-low temperature brittleness.
12 of embodiment:
The ABS consumption is 100 parts; The wood powder consumption is 50 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders-300 orders, and consumption is 2 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts; 2 parts of 10 parts in two (dibromo-phenoxy base) ethane of anti-impact modifier and tetrabromophthalate (second～ethylhexyl) esters (TBPDO); The different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5 part; 0.5 part of antiaging agent silicon in February thiodipropionate (DLTP), four [β-(3.5-di-tert-butyl-4-base phenyl propyl ester)] (1010) 0.5 parts of pentaerythritol esters and (2-hydroxyl-3,5-5-di-tert-butyl-5-oxygen base)-and 0.5 part of benzene well triazole (UV327), 15～30 parts of 10～20 parts of coupling agent gamma-amino propyl trimethoxy silicanes or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
13 of embodiment:
The ABS consumption is 100 parts; 90 parts of wood powders; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and consumption is 4 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 15 parts; The different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5 part; 8 parts of 10 parts in two (dibromo-phenoxy base) ethane of anti-impact modifier and tetrabromophthalate (second-ethylhexyl) esters (TBPDO); 0.8 part of antiaging agent silicon in February thiodipropionate (DLTP), four [β (3.5-di-tert-butyl-4-base phenyl propyl ester)] (1010) 1 parts of pentaerythritol esters and (2-hydroxyl-3,5-5-di-tert-butyl-5-oxygen base)-and 1 part of benzene well triazole (UV327), 25～40 parts of 15～20 parts of coupling agent gamma-amino propyl trimethoxy silicanes or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
14 of embodiment:
The ABS consumption is 100 parts; The wood powder consumption is 150 parts; Filler uses a kind of 5 parts among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide); Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 20 parts, and the different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 1 part; 15 parts of 15 parts of two (dibromo-phenoxy base) second of anti-impact modifier and tetrabromophthalate (second-ethylhexyl) esters (TBPDO); 1.0 parts of antiaging agent silicon in February thiodipropionates (DLTP), four [β-(3.5-di-tert-butyl-4-base phenyl propyl ester)] (1010) 1 parts of pentaerythritol esters and (2-hydroxyl-3,5-5-di-tert-butyl-5-oxygen base)-and 1 part of benzene well triazole (UV327), 30～50 parts of 20～30 parts of coupling agent gamma-amino propyl trimethoxy silicanes or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
The waste and scrap that the abs polymer that plastic wood sheet of the present invention uses can be to use, wood powder can become powder with depleted timber tankage, water footpath material, brush wood, waste and old wood and low-quality wood working, and timber resources is fully used.The plastic wood sheet of making according to above-mentioned prescription can substitute wood plank and use, and is easy to process, but can follow closely, can bore, can dig, can glue greasepaint; And there is not timber inherent defective, as knot, be full of cracks, warpage, the spot that easily adds lustre to, malicious spot and rotten etc.
Plastic wood sheet of the present invention can also reclaim second stage employ.
That the plastic wood sheet of making according to above-mentioned prescription has is water-fast, acid and alkali-resistance, do not damaged by worms, long fungi and characteristics such as pollution-free.These characteristics relevant with the ratio of wood powder in the prescription, the wood powder ratio changes, and the performance of plastic wood sheet will change.The scope that the ratio of wood powder provides less than the present invention also can be made plastic wood sheet, but increases cost, improves seldom on use properties, and the ratio of performance to price is unreasonable.
Claims (12)
1, a kind of ABS plastic wood sheet., its component comprises Acrylonitrile Butadiene, wood powder and auxiliary agent, it is characterized in that: ABS (propylene fine/butadiene/styrene copolymers) relative density is 1.01～1.07g/cm
2, water content 0.01%～0.05%, meal, consumption are 100 parts; Wood powder water content 0.3～1.0%, granularity 150 orders～300 orders, consumption are 50 parts～170 parts; Filler uses a kind of among titanium dioxide or lime carbonate or the white carbon black (silicon-dioxide), and granularity is 150 orders～300 orders, and consumption is 2～5 parts; Auxiliary agent comprises that toughner ethylene/vinyl acetate (EVA) consumption is 10 parts～20 parts; The different monooctyl ester dioctyltin of linking agent ethyl thioglycollic acid consumption is 0.5～1 part; 5～50 parts of 1～30 part of coupling agent gamma-amino propyl trimethoxy silicane or three (dioctyl pyrophosphoryl oxygen base) phthalandione isopropyl esters.
2, ABS plastic wood sheet as claimed in claim 1 is characterized in that: auxiliary agent also comprises 2 parts～15 parts of 10 parts～15 parts in two (dibromo-phenoxy base) ethane of anti-impact modifier and tetrabromophthalate (second-ethylhexyl) esters (TBPDO).
3, ABS plastic wood sheet as claimed in claim 1 is characterized in that: auxiliary agent also comprises 3 parts～10 parts in 1 part～10 parts of fire retardant antimonous oxides and two (2, the 3-dibromopropyl) ethers of tetrabromo-bisphenol.
4, ABS plastic wood sheet as claimed in claim 1, it is characterized in that: auxiliary agent also comprises 0.5 part～5 parts of (1010) 0.5 parts～5 parts and 2 (2 '-hydroxyl-3,5 '=tertiary butyl-5-oxygen base) benzene well triazoles (UV327) of 0.5 part～2.0 parts, four of antiaging agent silicon in February thiodipropionates (DLTP) [β-(3.5-di-tert-butyl-4-hydroxy phenyl propyl ester)] pentaerythritol ester.
5, ABS plastic wood sheet as claimed in claim 1 is characterized in that: auxiliary agent also comprises 2 parts～15 parts of 10 parts～15 parts in two (dibromo-phenoxy base) ethane of anti-impact modifier and tetrabromophthalate (2-ethylhexyl) esters (TBPDO); (1010) 0.5 parts～5 parts of 0.5 part～2.0 parts, four [β-(3.5-di-tert-butyl-4-hydroxy phenyl propyl ester)] pentaerythritol esters of antiaging agent silicon in February thiodipropionate (DLTP) and (2-hydroxyl-3,5-5-di-tert-butyl-5-oxygen base)--0.5 part～5 parts of-benzene well triazoles (UV327).
6, ABS plastic wood sheet as claimed in claim 1 is characterized in that: auxiliary agent also comprises 2 parts～15 parts of 10 parts～15 parts in two (dibromo-phenoxy base) ethane of anti-impact modifier and tetrabromophthalate (second-ethylhexyl) esters (TBPDO); 3 parts～10 parts in two (2, the 3-dibromopropyl) ethers of 1 part～10 parts in fire retardant three itching two antimony and tetrabromo-bisphenol; 0.5 part～5 parts of (1010) 0.5 parts～5 parts of 0.5 part～2.0 parts, four [β-(3.5-di-tert-butyl-4-hydroxy phenyl propyl ester)] pentaerythritol esters of antiaging agent silicon in February thiodipropionate (DLTP) and (2-hydroxyl-3,5-5-di-tert-butyl-5-oxygen base)-benzene well triazoles (UV327).
7, ABS plastic wood sheet as claimed in claim 1 is characterized in that: auxiliary agent also comprises 0.5～30 part of whipping agent Cellmic C 121 (ADAC).
8, ABS plastic wood sheet as claimed in claim 1 is characterized in that: auxiliary agent also comprises 0.5～5 part of processing aid Zinic stearas, 0.5～5 part of calcium stearate.
9, ABS plastic wood sheet as claimed in claim 1 is characterized in that: auxiliary agent also comprises 5～30 parts of antiseptic-germicide Haier antiseptic-germicides (KHFS-2).
10, ABS plastic wood sheet as claimed in claim 1 is characterized in that: auxiliary agent also comprises anti-crisp dose 2,0.5～5 part of 6-toluene di-tert-butyl phenol (antioxidant 264).
11, ABS plastic wood sheet as claimed in claim 1 is characterized in that: auxiliary agent also comprises plasticizer phthalic acid ester 0.5-5 in two ninth of the ten Heavenly Stems part.
12, ABS plastic wood sheet as claimed in claim 1 is characterized in that: add 5～20 parts of new LDPE (film grade)s and an amount of hexanodioic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA021489955A CN1500833A (en) | 2002-11-18 | 2002-11-18 | Engineering plastic (ABS) plastic-wood panel |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA021489955A CN1500833A (en) | 2002-11-18 | 2002-11-18 | Engineering plastic (ABS) plastic-wood panel |
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| CN1500833A true CN1500833A (en) | 2004-06-02 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNA021489955A Pending CN1500833A (en) | 2002-11-18 | 2002-11-18 | Engineering plastic (ABS) plastic-wood panel |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100406511C (en) * | 2004-10-21 | 2008-07-30 | 俞立群 | Plastic lignified board and its making method |
| CN100450747C (en) * | 2006-02-20 | 2009-01-14 | 华中农业大学 | Decorative material made from rape straw and preparing method |
| CN100460472C (en) * | 2005-12-02 | 2009-02-11 | 中国科学院化学研究所 | Surface grafting organic functional molecular nano silicon dioxide, and its preparing method |
| CN101016401B (en) * | 2007-03-02 | 2010-05-26 | 浙江大学 | Injection moulding composition based on reclaiming ABS |
| CN101153119B (en) * | 2007-09-07 | 2011-01-12 | 东北林业大学 | Nethod of producing Clubbed composite material of wood-wool |
| CN102746607A (en) * | 2012-07-05 | 2012-10-24 | 浙江富丽新材料有限公司 | Insulated and heat conducting environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) resin and preparation method thereof |
| CN103602020A (en) * | 2013-11-12 | 2014-02-26 | 青岛广联达精密机械有限公司 | Construction floor material |
| CN105924884A (en) * | 2016-06-06 | 2016-09-07 | 湖州中辰建设有限公司 | Flame-retardant and aging-resistant ABS plastic-wood composite board for building purposes |
| CN105936730A (en) * | 2016-06-06 | 2016-09-14 | 湖州中辰建设有限公司 | Wear resistant ABS plastic-wood composite board for buildings |
| CN109422995A (en) * | 2017-08-24 | 2019-03-05 | 合肥杰事杰新材料股份有限公司 | A kind of acrylonitrile-butadiene-styrene copolymer composition and preparation method thereof |
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2002
- 2002-11-18 CN CNA021489955A patent/CN1500833A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100406511C (en) * | 2004-10-21 | 2008-07-30 | 俞立群 | Plastic lignified board and its making method |
| CN100460472C (en) * | 2005-12-02 | 2009-02-11 | 中国科学院化学研究所 | Surface grafting organic functional molecular nano silicon dioxide, and its preparing method |
| CN100450747C (en) * | 2006-02-20 | 2009-01-14 | 华中农业大学 | Decorative material made from rape straw and preparing method |
| CN101016401B (en) * | 2007-03-02 | 2010-05-26 | 浙江大学 | Injection moulding composition based on reclaiming ABS |
| CN101153119B (en) * | 2007-09-07 | 2011-01-12 | 东北林业大学 | Nethod of producing Clubbed composite material of wood-wool |
| CN102746607A (en) * | 2012-07-05 | 2012-10-24 | 浙江富丽新材料有限公司 | Insulated and heat conducting environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) resin and preparation method thereof |
| CN102746607B (en) * | 2012-07-05 | 2014-06-11 | 浙江富丽新材料有限公司 | Insulated and heat conducting environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) resin and preparation method thereof |
| CN103602020A (en) * | 2013-11-12 | 2014-02-26 | 青岛广联达精密机械有限公司 | Construction floor material |
| CN105924884A (en) * | 2016-06-06 | 2016-09-07 | 湖州中辰建设有限公司 | Flame-retardant and aging-resistant ABS plastic-wood composite board for building purposes |
| CN105936730A (en) * | 2016-06-06 | 2016-09-14 | 湖州中辰建设有限公司 | Wear resistant ABS plastic-wood composite board for buildings |
| CN109422995A (en) * | 2017-08-24 | 2019-03-05 | 合肥杰事杰新材料股份有限公司 | A kind of acrylonitrile-butadiene-styrene copolymer composition and preparation method thereof |
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