CN108003494A - A kind of environmental protection antistatic plate timber-used graphene modified hard PVC plastic and preparation method - Google Patents
A kind of environmental protection antistatic plate timber-used graphene modified hard PVC plastic and preparation method Download PDFInfo
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- CN108003494A CN108003494A CN201711134081.4A CN201711134081A CN108003494A CN 108003494 A CN108003494 A CN 108003494A CN 201711134081 A CN201711134081 A CN 201711134081A CN 108003494 A CN108003494 A CN 108003494A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic and preparation method, the modified hard PVC plastic, include the component of following mass parts：100 parts of polyvinyl chloride resin, 15 parts of heat stabilizer, 2 10 parts of processing aid, 2 15 parts of anti-impact modifier, 4 18 parts of antistatic filler, 5 30 parts of filler, 0.3 3 parts of lubricant, 0.2 5.0 parts of coupling agent.This method uses melt-mixing method, is molded by twin-screw extrusion, and environmental protection antistatic plate timber-used graphene modified hard PVC plastic is made.The environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic of the present invention is environment friendly and pollution-free, and board dimension, shape can be customized according to user demand, and sheet resistance is 101‑109Ω is controllable, and anti-static effect is good, and persistently, environmental protection is excellent in cushion effect, and vicat temperature is high, and weather resistance is excellent, and processing performance is good, and comprehensive performance is high.
Description
Technical field
The present invention relates to field of compound material, antistatic field, belong to field of polymer composite material, and in particular to a kind of
Hard PVC material and preparation method thereof.
Background technology
Polyvinyl chloride（PVC）It is cheap, former with the excellent comprehensive performance such as fire-retardant, corrosion-resistant, insulation, wear-resistant
The advantages that material source facilitates, has been widely used in every field.But PVC material volume resistance is very big, make
It is also easy to produce during and takes electrostatic, there are potential hazard.Static charge accumulation will cause electrostatic to be inhaled to certain degree
Dirt, electric discharge, breakdown, cause fire, explosion, production obstacle situations such as occur.If assign PVC Antistatic types, chemical industry, weaving,
The fields such as semi-conductor industry, dangerous goods store, electronics and wireless telecommunications, for anlistatig plate, tubing, conveyer belt, equipment
Cover etc., is of great significance to reducing production cost, improving productivity effect.
It is addition antistatic additive to improve the most common method of PVC material antistatic property, but existing antistatic additive is universal
There are effect it is poor, strong to ambient humidity dependence the shortcomings that.There is a method in which it is exactly addition filling out with certain electric conductivity
Material, the hot spot that the distinctive electric conductivity of graphene is studied as everybody at present.The distinctive sp2 hybrid structures of graphene cause electronics to exist
The interference being subject to when wherein transmitting is very small and is not susceptible to scatter, and the movement in lattice is accessible, in room temperature
Under resistance value there was only 2/3rds of copper, there is superpower electric conductivity.Graphene mutually can connect to be formed in PVC polymer
Conductive network, therefore its antistatic property can be improved using the filling-modified PVC of graphene, widen its application field.
The content of the invention
In order to overcome shortcoming and defect existing in the prior art, it is an object of the invention to provide a kind of environmentally friendly antistatic
Plate graphene modified hard PVC plastic, the modified plastics anti-static effect is good, and persistently, environmental protection is excellent in cushion effect, dimension
Card temperature is high, and weather resistance is excellent, and processing performance is good, and comprehensive performance is high.Board dimension, shape, sheet resistance can be according to users
Demand customizes.
Another object of the present invention is to provide a kind of system of environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic
Preparation Method, restructuring Preparation Method technique is simple, easy to operate, stable quality, is adapted to large-scale industrial production.
The purpose of the present invention is achieved through the following technical solutions：A kind of environmental protection antistatic plate timber-used graphene modified hard
PVC plastic, the environmental protection antistatic plate timber-used graphene modified hard PVC plastic include the raw material of following parts by weight：
100 parts of polyvinyl chloride resin, 1-5 parts of heat stabilizer, 2-10 parts of processing aid, 2-15 parts of anti-impact modifier, antistatic is filled out
4-18 parts of material, 5-30 parts of filler, 0.3-3 parts of lubricant, 0.2-5.0 parts of coupling agent.
Further,
The polyvinyl chloride resin is SG-5 types, the one or more in s-1000；
The heat stabilizer is calcium-zinc composite stabilizing agent, the one or more in compound rare-earth stabilizer, hydrotalcite；
The processing aid is haloflex（CPE）, methyl methacrylate and esters of acrylic acid copolymer（ACR）In
It is one or more of；
The antistatic filler is graphene, the one or more in conductive black, carbon nanotubes, carbon fiber；
The anti-impact modifier is haloflex（CPE）, methyl methacrylate and esters of acrylic acid copolymer
（ACR）, methyl methacrylate-butadiene-styrene ternary graft copolymer（MBS）, acrylonitrile-butadiene-styrene (ABS) it is common
Polymers（ABS）And ethylene-vinyl acetate copolymer（EVA）In one or more；
The filler is nano-calcium carbonate, the one or more in activation nano-calcium carbonate, flyash；
The lubricant is stearic acid, the one or more in paraffin, PE waxes, OPE waxes；
The coupling agent is aluminate coupling agent, titanate coupling agent, boric acid ester coupler, one kind in silane coupling agent or several
Kind.
Present invention also offers the preparation method of above-mentioned environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic, institute
The method of stating includes the following steps：
（1）By following formulas（It is mass fraction）To weigh configuration raw material：100 parts of polyvinyl chloride resin, 1-5 parts of heat stabilizer, adds
2-10 parts of work auxiliary agent, 2-15 parts of anti-impact modifier, 4-18 parts of antistatic filler, 5-30 parts of filler, lubricant 0.3-
3 parts, 0.2-5.0 parts of coupling agent；
（2）By step（1）All raw materials weighed are put into batch mixer batch mixing 10-30 minutes, its rotating speed is 1000-3000 revs/min
Clock, is uniformly mixed；
（3）By step（2）Obtained mixture cool down and be put into material bin ageing at least 24 it is small when；
（4）By step（3）Resulting material passes through double screw extruder extrusion molding, obtains environmentally friendly antistatic plate timber-used graphene and changes
Property hard PVC.
Further improved as of the invention, the twin-screw extrusion temperature is 160-220 DEG C.
Further improved as of the invention, the double screw extruder is conical double screw extruder.
Specifically, in the present invention, polyvinyl chloride resin is major ingredient, SG types PVC has compared with high voidage, is easy to absorb all kinds of add
Work and modified additive.The addition of stabilizer enables PVC plastic to resist the destruction of heat, light, oxygen and humidity.Processing aid is to original
Material plasticizing level has effect, and then influences material property.Impact modifier is conducive to improve PVC black brittleness.Conductive filler
The certain electrical property of product is assigned, anti-static effect is good, persistently.It is steady that the addition of filler helps to improve product vicat temperature, size
It is qualitative etc..Lubricant mainly improves the processing performance of formula system in formula, and too high levels can reduce Mechanical Properties of Products.It is even
Connection agent can improve dispersiveness of the filler in PVC, also increase filler and the compatibility of PVC.
The beneficial effects of the invention are as follows：
1st, the modified hard PVC plastic environmental protection heavy metal free pollution that the present invention is provided by the compounding and screening of Multiple components,
The PVC plastic material shell is used for preparing PVC board；
2nd, modified hard PVC plastic of the invention has antistatic characteristic, overcomes existing PVC board and is easily produced using process
The problem of electrostatic, sheet resistance can be needed 10 according to user1-109 Ω is adjusted；
3rd, modified hard PVC plastic properties of the invention are excellent, and anti-static effect is good, persistently, environmental protection, impact strength
Height, vicat temperature is high, and weather resistance is excellent, and processing performance is good, and comprehensive performance is high；
4th, modified hard PVC plastic board dimension provided by the present invention, shape can be customized according to user demand；
5th, the preparation method step of modified hard PVC plastic provided by the present invention is simple, is adapted to industrialized production.
Embodiment
The present invention is described in more detail below in conjunction with specific embodiment.
Embodiment 1
It is as follows that each component of the present embodiment modified hard PVC plastic by mass fraction weighs each raw material：100 parts of polyvinyl chloride resin, calcium zinc are answered
Close 1.5 parts of stabilizer, 0.5 part of hydrotalcite, haloflex（CPE）4 parts, the copolymerization of methyl methacrylate and esters of acrylic acid
Thing（ACR）5 parts, 3 parts of graphene, 6 parts of conductive carbon black, 20 parts of calcium carbonate, 5 parts of flyash, 0.5 part of OPE waxes, silane coupling agent
3.0 part.
The manufacturing process of the present embodiment modified hard PVC plastic is as follows：
Add all raw materials weighed and be put into high speed mixer batch mixing 10-30 minutes, its rotating speed is controlled at 1500 revs/min, is risen
Temperature to 100 DEG C, obtained mixture cool down and be put into material bin be aged at least 24 it is small when, then by conical double screw extruder
Extrusion molding, 170 DEG C of extrusion temperature, obtains environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic.
Embodiment 2
It is as follows that each component of the present embodiment modified hard PVC plastic by mass fraction weighs each raw material：100 parts of polyvinyl chloride resin, calcium zinc are answered
Close 1.5 parts of stabilizer, 2.0 parts of compound rare-earth stabilizer, CPE8 parts, ethylene-vinyl acetate copolymer（EVA）3 parts, graphene 2
Part, 1 part of carbon nanotubes, 2 parts of carbon fiber, 25 parts of calcium carbonate, 0.3 part of PE waxes, 0.5 part of stearic acid, 1.0 parts of aluminate coupling agent,
0.5 part of boric acid ester coupler.
The manufacturing process of the present embodiment modified hard PVC plastic is as follows：
Add all raw materials weighed and be put into high speed mixer batch mixing 10-30 minutes, its rotating speed is controlled at 2000 revs/min, is risen
Temperature to 110 DEG C, obtained mixture cool down and be put into material bin be aged at least 24 it is small when, then by conical double screw extruder
Extrusion molding, 200 DEG C of extrusion temperature, obtains environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic.
Embodiment 3
It is as follows that each component of the present embodiment modified hard PVC plastic by mass fraction weighs each raw material：It is 100 parts of polyvinyl chloride resin, compound dilute
1.5 parts of soil stabilizer, 1.0 parts of hydrotalcite, haloflex（CPE）6.0 parts, methyl methacrylate-butadiene-styrene three
First graft copolymer（MBS）2.0 parts, acrylonitrile-butadiene-styrene copolymer（ABS）5.0 parts, 4 parts of graphene, carbon fiber 3
Part, 30 parts of flyash, 1.5 parts of paraffin, 1.5 parts of stearic acid, 2.0 parts of silane coupling agent.
The manufacturing process of the present embodiment modified hard PVC plastic is as follows：
Add all raw materials weighed and be put into high speed mixer batch mixing 10-30 minutes, its rotating speed is controlled at 2500 revs/min, is risen
Temperature to 105 DEG C, obtained mixture cool down and be put into material bin be aged at least 24 it is small when, then by conical double screw extruder
Extrusion molding, 210 DEG C of extrusion temperature, obtains environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic.
Embodiment 4
It is as follows that each component of the present embodiment modified hard PVC plastic by mass fraction weighs each raw material：100 parts of polyvinyl chloride resin, calcium zinc are answered
Close 5 parts of stabilizer, haloflex（CPE）10 parts, the copolymer of methyl methacrylate and esters of acrylic acid（ACR）3.0 parts,
Acrylonitrile-butadiene-styrene copolymer（ABS）8.0 parts, 10 parts of graphene, 18 parts of calcium carbonate, 10 parts of flyash, paraffin 0.5
Part, 1.5 parts of OPE waxes, 5.0 parts of aluminate coupling agent.
The manufacturing process of the present embodiment modified hard PVC plastic is as follows：
Add all raw materials weighed and be put into high speed mixer batch mixing 10-30 minutes, its rotating speed is controlled at 3000 revs/min, is risen
Temperature to 120 DEG C, obtained mixture cool down and be put into material bin be aged at least 24 it is small when, then by conical double screw extruder
Extrusion molding, 220 DEG C of extrusion temperature, obtains environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic.
Comparative example
It is as follows that each component of this comparative example hard PVC by mass fraction weighs each raw material：100 parts of polyvinyl chloride resin, Ca Zn composite are steady
Determine 5 parts of agent, haloflex（CPE）10 parts.
The manufacturing process of this comparative example modified hard PVC plastic is as follows：
Add all raw materials weighed and be put into high speed mixer batch mixing 10-30 minutes, its rotating speed is controlled at 2000 revs/min, is risen
Temperature to 110 DEG C, obtained mixture cool down and be put into material bin be aged at least 24 it is small when, then by conical double screw extruder
Extrusion molding, 180 DEG C of extrusion temperature, obtains environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic.
Test case
To the sheet resistance of the hard PVC of embodiment 1-4 and comparative example, tensile strength, notch impact strength and Wei Kawen
Degree is tested.
The test performance of the present invention and comparative example is as shown in table 1
As can be seen from the above table, electricity of the embodiment of the present invention, mechanics and thermal property are superior to comparative example.This is mainly due to anti-quiet
Electric filler forms conductive network in PVC, hence it is evident that reduces specimen surface resistance；Graphene has excellent mechanical property, intensity
Height, the generation such as the addition of graphene and carbon nanotubes, carbon fiber act synergistically, and greatly improve the tensile strength of sample；Stone
The addition of black alkene and anti-impact modifier etc. act synergistically, and greatly improve the notch impact strength of sample；The nothings such as graphene
The addition of machine filler helps to improve the heat endurance of sample, therefore embodiment sample vicat temperature is above comparative example.
Embodiment described above is merely a preferred embodiment of the present invention, and the simultaneously exhaustion of the feasible implementation of non-invention.It is right
For persons skilled in the art, on the premise of without departing substantially from the principle of the invention and spirit to any aobvious made by it and
The change being clear to, should all be contemplated as falling with the claims of the present invention.
Claims (10)
1. a kind of environmental protection antistatic plate timber-used graphene modified hard PVC plastic, it is characterised in that the composite material includes following
The raw material of mass ratio：100 parts of polyvinyl chloride resin, 1-5 parts of heat stabilizer, 2-10 parts of processing aid, 2-15 parts of anti-impact modifier,
4-18 parts of antistatic filler, 5-30 parts of filler, 0.3-3 parts of lubricant, 0.2-5.0 parts of coupling agent.
2. environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic according to claim 1, it is characterised in that described
Polyvinyl chloride resin is SG-5 types, the one or more in S-1000.
3. environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic according to claim 1, it is characterised in that described
Heat stabilizer is calcium-zinc composite stabilizing agent, the one or more in compound rare-earth stabilizer, hydrotalcite.
4. environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic according to claim 1, it is characterised in that described
Processing aid is haloflex（CPE）, methyl methacrylate and esters of acrylic acid copolymer（ACR）In one kind or several
Kind.
5. environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic according to claim 1, it is characterised in that described
Antistatic filler is graphene, the one or more in conductive black, carbon nanotubes, carbon fiber.
6. environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic according to claim 1, it is characterised in that described
Anti-impact modifier is haloflex（CPE）, methyl methacrylate and esters of acrylic acid copolymer（ACR）, methyl-prop
E pioic acid methyl ester-butadiene-styrene ternary graft copolymer（MBS）, acrylonitrile-butadiene-styrene copolymer（ABS）And second
Alkene-acetate ethylene copolymer（EVA）In one or more.
7. environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic according to claim 1, it is characterised in that described
Filler is nano-calcium carbonate, the one or more in activation nano-calcium carbonate, flyash.
8. environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic according to claim 1, it is characterised in that described
Lubricant is stearic acid, the one or more in paraffin, PE waxes, OPE waxes.
9. environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic according to claim 1, it is characterised in that described
Coupling agent is aluminate coupling agent, the one or more in titanate coupling agent, boric acid ester coupler, silane coupling agent.
10. the preparation method of environmentally friendly antistatic plate timber-used graphene modified hard PVC plastic according to claim 1, it is special
Sign is, includes the following steps：
（1）Component configures raw material as described in claim 1, and weighs；
（2）By step（1）All raw materials weighed are put into high speed mixer batch mixing 10-30 minutes, its rotating speed is 1000-3000
Rev/min, it is uniformly mixed；
（3）By step（2）Obtained mixture cool down and be put into material bin ageing at least 24 it is small when；
（4）By step（3）Resulting material passes through double screw extruder extrusion molding, obtains environmentally friendly antistatic plate timber-used graphene
Modified hard PVC plastic；The double screw extruder is conical double screw extruder, and the twin-screw extrusion temperature is
160-220℃。
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233149A (en) * | 2018-09-03 | 2019-01-18 | 付贤锋 | A kind of antistatic EVA-PVC composite material and preparation method |
| CN109575468A (en) * | 2018-10-24 | 2019-04-05 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | A kind of antistatic shock resistance high molecular composite |
| CN110885530A (en) * | 2019-12-06 | 2020-03-17 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | Anti-static flame-retardant PVC/ABS (polyvinyl chloride/acrylonitrile butadiene styrene) composite material with isolation structure and preparation method thereof |
| CN111732800A (en) * | 2020-07-17 | 2020-10-02 | 乐金华奥斯(天津)有限公司 | Static conductive carbon black gel and preparation process thereof |
| WO2021012889A1 (en) * | 2019-07-19 | 2021-01-28 | 苏州爱得华塑化有限公司 | Modified impact resistant rigid pvc material |
| CN113603981A (en) * | 2021-08-08 | 2021-11-05 | 明光智源复合材料有限公司 | Polymer composite material gas tank and manufacturing method thereof |
| CN114031867A (en) * | 2021-12-14 | 2022-02-11 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | MXene-graphene-PVC composite material and preparation method thereof |
| CN115612229A (en) * | 2022-11-15 | 2023-01-17 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | Permanent conductive and antistatic soft PVC material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775700A (en) * | 2012-08-17 | 2012-11-14 | 西安科技大学 | PVC (Polyvinyl Chloride)/graphite alkene antistatic composite material and preparation method thereof |
| CN104004294A (en) * | 2014-05-07 | 2014-08-27 | 武汉金牛经济发展有限公司 | Preparation method of graphene-modified hard polyvinyl chloride composite tubing |
-
2017
- 2017-11-16 CN CN201711134081.4A patent/CN108003494A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775700A (en) * | 2012-08-17 | 2012-11-14 | 西安科技大学 | PVC (Polyvinyl Chloride)/graphite alkene antistatic composite material and preparation method thereof |
| CN104004294A (en) * | 2014-05-07 | 2014-08-27 | 武汉金牛经济发展有限公司 | Preparation method of graphene-modified hard polyvinyl chloride composite tubing |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233149A (en) * | 2018-09-03 | 2019-01-18 | 付贤锋 | A kind of antistatic EVA-PVC composite material and preparation method |
| CN109575468A (en) * | 2018-10-24 | 2019-04-05 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | A kind of antistatic shock resistance high molecular composite |
| WO2021012889A1 (en) * | 2019-07-19 | 2021-01-28 | 苏州爱得华塑化有限公司 | Modified impact resistant rigid pvc material |
| CN110885530A (en) * | 2019-12-06 | 2020-03-17 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | Anti-static flame-retardant PVC/ABS (polyvinyl chloride/acrylonitrile butadiene styrene) composite material with isolation structure and preparation method thereof |
| CN111732800A (en) * | 2020-07-17 | 2020-10-02 | 乐金华奥斯(天津)有限公司 | Static conductive carbon black gel and preparation process thereof |
| CN113603981A (en) * | 2021-08-08 | 2021-11-05 | 明光智源复合材料有限公司 | Polymer composite material gas tank and manufacturing method thereof |
| CN114031867A (en) * | 2021-12-14 | 2022-02-11 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | MXene-graphene-PVC composite material and preparation method thereof |
| CN115612229A (en) * | 2022-11-15 | 2023-01-17 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | Permanent conductive and antistatic soft PVC material and preparation method thereof |
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