CN105086283B - A kind of high flowing flame-proof PVC/ABS alloy material and preparation method thereof - Google Patents
A kind of high flowing flame-proof PVC/ABS alloy material and preparation method thereof Download PDFInfo
- Publication number
- CN105086283B CN105086283B CN201510557616.3A CN201510557616A CN105086283B CN 105086283 B CN105086283 B CN 105086283B CN 201510557616 A CN201510557616 A CN 201510557616A CN 105086283 B CN105086283 B CN 105086283B
- Authority
- CN
- China
- Prior art keywords
- alloy material
- proof pvc
- abs
- lubrication prescription
- abs alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention belongs to technical field of alloy material, discloses a kind of high flowing flame-proof PVC/ABS alloy material and preparation method thereof.Material of the present invention is mixed including ABS resin, polyvinyl chloride resin, fire retardant, antioxidant, lubricant, stabilizer and processing aid, and after the blending of material each group, finished product is obtained through melting, extruding pelletization.High flowing flame-proof PVC/ABS alloy material produced by the present invention, fire resistance is good, mobility is strong, surface perception is good, easy processing shaping, Product Process is simple to operate, and cost is low, steady quality, can be widely applied to the fields such as machinery, electronic instrument, household electrical appliances and building.
Description
Technical field
The invention belongs to Material Field, and in particular to a kind of high flowing flame-proof PVC/ABS alloy material and preparation method thereof.
Background technology
ABS resin is formed by three kinds of monomer copolymerizations of acrylonitrile-butadiene-styrene (ABS), has both maintained the gloss of polystyrene
And processing fluidity, there is the impact resistance of rubber again, and the rigidity of acrylonitrile, have heat-resist, good stability of the dimension,
The advantages that being easy to processing and forming, it is a kind of function admirable, widely used engineering plastics.Defect is that weatherability is poor, inflammable, price
Also it is higher.PVC is using polyvinyl chloride resin as base-material, is mixed with a variety of auxiliary agents such as stabilizer, plasticizer, filler, colouring agent and modifying agent
Close, formed through plasticizing, processing and forming.PVC plastic have rigidity is good, intensity is high, fire-retardant, corrosion-resistant, electric insulating quality it is good with
And the soft or hard excellent properties such as adjustable, and raw material sources are abundant, and it is cheap, it is the universal material of sexual valence comparative superiority, lacks
It is that melt viscosity is big to fall into.PVC/ABS alloys are the advantage and disadvantage for PVC and ABS and mutually learnt from other's strong points to offset one's weaknesses in the performance for preparing
A kind of plastic alloy.But the defects of PVC/ABS alloys itself, such as mobility is poor to limit its development and application.
The content of the invention
The purpose of the present invention is that a kind of high flowing flame-proof PVC/ABS alloy material is provided the defects of presence for prior art
And preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of high flowing flame-proof PVC/ABS alloy material, the material by ABS resin, polyvinyl chloride resin, fire retardant, antioxidant,
Lubricant, stabilizer and processing aid mix, and the mass ratio of each component is followed successively by 20~25：63~70：5~8：0.4~
1：0.1~0.3：1~2：0.5~1.
In some preferable technical schemes, described ABS resin is ABS709 and ABS757 mixtures, the quality of the two
Than for 55~67：33~45.
In some preferable technical schemes, described fire retardant is chlorine-based flame retardant；Preferably chlorinated paraffin, tetrachloro are adjacent
Any one in phthalate anhydride and haloflex；Most preferably haloflex.
In some preferable technical schemes, described antioxidant is the mixture of antioxidant 1010 and irgasfos 168, two
Person's mass ratio is 1:2.
In some preferable technical schemes, the lubricant is the mixture of interior lubrication prescription and outer lubrication prescription, interior lubrication prescription with it is outer
Lubrication prescription mass ratio is 2:1.Described interior lubrication prescription be Solsperse 2000, stearic amide, stearic acid butyl ester, glyceryl monostearate and
One or more in fatty acid pentaerythritol ester, outer lubrication prescription are that EB-FF, PE wax, methylene bis-stearamides and ethylene are double stearic
One or more in sour acid amides.
In some preferable technical schemes, described stabilizer is organic tin stabilizer, preferably Methyl stannum mercaptide,
Butanethiol tin, double butyl stannous chloride, dibutyl tin laurate, laurate dibutyitin maleate and maleic acid dibutyl
One or more in tin.
In some preferable technical schemes, described processing aid is fatty acid amide, silicone oil, White Mineral Oil, silicone
One or more in class compound and ethylene bis stearic acid amide.
A kind of preparation method of above-mentioned high flowing flame-proof PVC/ABS alloy material, this method are carried out as follows：
(1) ABS resin, polyvinyl chloride resin, fire retardant, antioxidant, lubricant, stabilizer and processing is weighed by mass parts ratio to help
Agent is stirred in high-speed mixer and is sufficiently mixed；
(2) blends described above is sent into double screw extruder through metering, through being kneaded fusing, extruding pelletization, wrapped after drying
Dress up as finished product.
In some preferable technical schemes, described double screw extruder draw ratio is 36~40, extruder temperature control
At 130~180 DEG C, screw speed controls at 150~300 revs/min system.
The preparation method of foregoing high flowing flame-proof PVC/ABS alloy material, raw materials used mass ratio are as follows：
ABS resin, polyvinyl chloride resin, fire retardant, antioxidant, lubricant, the mass ratio of stabilizer and processing aid are followed successively by 20
~25：63~70：5~8：0.4~1：0.1~0.3：1~2：0.5~1.
In some preferable technical schemes, described ABS resin is ABS709 and ABS757 mixtures, the quality of the two
Than for 55~67：33~45.Described fire retardant is chlorine-based flame retardant；Preferably chlorinated paraffin, tetrachlorophthalic tetrachlorophthalic anhydrid, chlorine
Change any one in polyethylene；Most preferably haloflex.Described antioxidant is antioxidant 1010 and irgasfos 168
Mixture, the two mass ratio are 1:2.The lubricant is the mixture of interior lubrication prescription and outer lubrication prescription, interior lubrication prescription and outer lubrication prescription quality
Than for 2:1；Described interior lubrication prescription is Solsperse 2000, stearic amide, stearic acid butyl ester, glyceryl monostearate, aliphatic acid season
One or more in Doutrate, outer lubrication prescription are in EB-FF, PE wax, methylene bis-stearamides or ethylene bis stearic acid amide
One or more.Described stabilizer is organic tin stabilizer, preferably Methyl stannum mercaptide, butanethiol tin, double butyl
Stannous chloride, dibutyl tin laurate, laurate dibutyitin maleate, the one or more in dibutyitin maleate.
Described processing aid is one in fatty acid amide, silicone oil, White Mineral Oil, silicone compound, ethylene bis stearic acid amide
Kind or several mixtures.
Beneficial effects of the present invention：
The present invention is by between ABS resin, polyvinyl chloride resin, fire retardant, antioxidant, lubricant, stabilizer and processing aid
Synergy, not only increases alloy material mechanical property, also substantially increases the mobility of alloy material.And described alloy
Material has excellent fire resistance, reaches UL94 standard V-0 levels.
Embodiment
With reference to embodiment, the invention will be further described, but protection scope of the present invention not limited to this：
Various raw materials and auxiliary agent in embodiment 1~3 and comparative example 1~2 are commercially available general commodity.
Embodiment 1~3
Raw material and each component dosage used in the embodiment 1~3 of table 1 and comparative example 1~2
Implement the preparation method of 1-3 and comparative example 1~2：
(1) ABS resin, polyvinyl chloride resin, fire retardant, antioxidant, lubricant, stabilizer are weighed by mass parts ratio in table 1 and added
Work auxiliary agent is stirred in high-speed mixer and is sufficiently mixed；
(2) blends described above is sent into double screw extruder through metering, through being kneaded fusing, extruding pelletization, wrapped after drying
Dress up as finished product.
Wherein, described double screw extruder draw ratio is 40, with accurate temperature controller device and vacuum extractor, wherein squeezing
At 150~180 DEG C, screw speed is controlled at 180~220 revs/min for out-of-machine temperature control.
Performance detection：
The method of testing for the alloy material that embodiment 1~3 and comparative example 1~2 are prepared is：Density presses GB/T1033-
2008 measure, melt flow rate (MFR) are determined by GB/T 3682-2000, and heat distortion temperature is determined by GB/T1634-2004, bending
Performance is determined by GB/T 9341-2000, and combustibility presses UL94 standard tests.Specific measurement result is as shown in table 2.
Claims (5)
- A kind of high 1. flowing flame-proof PVC/ABS alloy material, it is characterised in that the material by ABS resin, polyvinyl chloride resin, fire retardant, Antioxidant, lubricant, stabilizer and processing aid mix, and the mass ratio of each component is followed successively by 20~25：63~70：5~ 8：0.4~1：0.1~0.3：1~2：0.5~1；And：Described ABS resin is ABS709 and ABS757 mixtures, and the mass ratio of the two is 55~67：33~45；Described fire retardant is any one in chlorinated paraffin, tetrachlorophthalic tetrachlorophthalic anhydrid and haloflex；Described antioxidant is the mixture of antioxidant 1010 and irgasfos 168, and the two mass ratio is 1:2；The lubricant is the mixture of interior lubrication prescription and outer lubrication prescription, and interior lubrication prescription is 2 with outer lubrication prescription mass ratio:1, described interior lubrication prescription For the one or more in stearic amide, butyl stearate, glyceryl monostearate and fatty acid pentaerythritol ester, outer lubrication prescription For the one or more in EB-FF, PE wax, methylene bis-stearamides and ethylene bis stearic acid amide；Described stabilizer is Methyl stannum mercaptide, butanethiol tin, double butyl stannous chloride, dibutyl tin laurate, bay One or more in sour dibutyitin maleate and dibutyitin maleate.
- 2. high flowing flame-proof PVC/ABS alloy material according to claim 1, it is characterised in that：Described fire retardant is Haloflex.
- 3. high flowing flame-proof PVC/ABS alloy material according to claim 1, it is characterised in that wherein described processing helps Agent is the one or more in fatty acid amide, silicone oil, White Mineral Oil, silicone compound and ethylene bis stearic acid amide.
- 4. a kind of preparation method of high flowing flame-proof PVC/ABS alloy material according to any one of claims 1 to 3, its It is characterised by carrying out as follows：（1）ABS resin, polyvinyl chloride resin, fire retardant, antioxidant, lubricant, stabilizer and processing aid are weighed by mass parts ratio to exist Stirring is sufficiently mixed in high-speed mixer；（2）Blends described above is sent into double screw extruder through metering, through being kneaded fusing, extruding pelletization, is packaged into after drying For finished product.
- 5. the preparation method of high flowing flame-proof PVC/ABS alloy material according to claim 4, it is characterised in that described Double screw extruder draw ratio is 36~40, and at 130~180 DEG C, screw speed is controlled 150~300 for extruder temperature control Rev/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510557616.3A CN105086283B (en) | 2015-09-02 | 2015-09-02 | A kind of high flowing flame-proof PVC/ABS alloy material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510557616.3A CN105086283B (en) | 2015-09-02 | 2015-09-02 | A kind of high flowing flame-proof PVC/ABS alloy material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105086283A CN105086283A (en) | 2015-11-25 |
| CN105086283B true CN105086283B (en) | 2018-02-13 |
Family
ID=54567665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510557616.3A Active CN105086283B (en) | 2015-09-02 | 2015-09-02 | A kind of high flowing flame-proof PVC/ABS alloy material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105086283B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105602161A (en) * | 2016-03-24 | 2016-05-25 | 叶青 | PVC (polyvinyl chloride) alloy |
| CN107118498A (en) * | 2017-05-05 | 2017-09-01 | 安徽彩晶光电有限公司 | A kind of modified ABS plastic alloy material for casing of liquid crystal television set |
| CN109796704A (en) * | 2019-02-20 | 2019-05-24 | 厦门源亚泰塑胶科技有限公司 | A kind of hard ABS/PVC alloy and preparation method thereof improving mobility |
| CN115772303B (en) * | 2021-09-08 | 2024-04-09 | 中国石油化工股份有限公司 | High-fluidity flame-retardant polyvinyl chloride injection molding composition and preparation method thereof |
| CN114516996B (en) * | 2022-03-28 | 2023-08-22 | 金发科技股份有限公司 | Boiling-resistant PVC alloy material and preparation method and application thereof |
| CN114524986B (en) * | 2022-04-07 | 2023-09-08 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | Environment-friendly flame-retardant PVC/PE composite material and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382388B (en) * | 2010-09-01 | 2014-05-28 | 中国石油化工股份有限公司 | PVC/ABS alloy material with high anti-impact strength and preparation method thereof |
| CN102964715B (en) * | 2011-09-01 | 2015-11-04 | 合肥杰事杰新材料股份有限公司 | A kind of flaming retarding cold resistant PVC/ABS Alloy And Preparation Method |
| CN102731926B (en) * | 2012-06-08 | 2014-07-09 | 佛山市顺德区圆融新材料有限公司 | Environment-friendly low-cost composite material capable of substituting flame retardant ABS |
| CN104277355A (en) * | 2014-08-15 | 2015-01-14 | 辽宁工程技术大学 | Flame-retardant toughening HPVC (polyvinyl with high degree of polymerization)/ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
-
2015
- 2015-09-02 CN CN201510557616.3A patent/CN105086283B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105086283A (en) | 2015-11-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105086283B (en) | A kind of high flowing flame-proof PVC/ABS alloy material and preparation method thereof | |
| CN103509289B (en) | A kind of injection grade flame-proof PVC/ABS alloy material and preparation method thereof | |
| CN102002203B (en) | Flame-retarded ASA (Acrylic ester-Styrene-Acrylonitrile) modified resin and preparation method thereof | |
| CN104194161A (en) | Precipitation resistant, toughening and flame-retardant polypropylene composite material and preparation method thereof | |
| CN105348646B (en) | A kind of modified polypropene base electric cable material with low smoke and halogen free and preparation method | |
| CN102040786A (en) | Antiflaming PVC (poly vinyl chloride)/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof | |
| CN109705462A (en) | A kind of dedicated V0 grade halogen-free flame-retardant polypropylene material of extrusion plastic uptake and preparation method thereof | |
| CN108003494A (en) | A kind of environmental protection antistatic plate timber-used graphene modified hard PVC plastic and preparation method | |
| CN108641214A (en) | Fire-retardant uvioresistant pvc sheathing compound of low temperature resistant oil proof and preparation method thereof | |
| CN105111731A (en) | Reinforced polyamide resin material for aluminum alloy building profiles and preparation method of reinforced polyamide resin material | |
| CN108299752A (en) | A kind of halogen-free flameproof PE/PS alloy materials and preparation method thereof | |
| CN107082960A (en) | A kind of flame retardant type high-gloss polypropylene composite and preparation method thereof | |
| CN102051007B (en) | Soft polrvinyl chloride composition and preparation method thereof | |
| CN110305440B (en) | Environment-friendly flame-retardant ABS (acrylonitrile-butadiene-styrene) composite material and preparation method thereof | |
| CN101161719B (en) | Special material for injection grade non-halogen flame-retardant wire plug and preparation method thereof | |
| CN103937124B (en) | High speed extrusion cloudy surface polyvinyl chloride cable material and preparation method thereof | |
| CN104194138A (en) | Low-die-orifice-curtain-coating low-smoke halogen-free flame-retardant polyolefin sheath material and preparation method thereof | |
| TWI609904B (en) | Plasticizer composition | |
| CN108912642B (en) | Antistatic, low-smoke, halogen-free and flame-retardant PC/ABS alloy material and preparation process thereof | |
| CN104448607B (en) | A kind of high fire prevention PVC-U pipe and preparation method thereof | |
| CN106147191B (en) | A kind of high fire-retardance rank Halogen polycarbonate film material and preparation method thereof | |
| CN102775693A (en) | Transparent polyvinyl chloride composition and its preparation method | |
| CN110066476A (en) | Fire-retardant anti-impact type height flowing alloy material and preparation method thereof | |
| CN107325428A (en) | A kind of PVC and preparation method thereof | |
| CN106366433B (en) | Low halogen transparent polypropylene film material of a kind of low cost and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170809 Address after: 222000 Jiangsu Province, Lianyungang City Lianyun District Banqiao Industrial Park, Xianghe Road No. 8 Applicant after: Lianyungang Engineering Investment Group Li Hai Chemical Co., Ltd. Address before: Banqiao Industrial Park in Jiangsu Province, Lianyungang City Lianyun District 222046 longitudinal road four Southeast Applicant before: Lianyungang Sea Water Chemical Co., Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |