CN1478040A - Child-resistant safety closure - Google Patents

Child-resistant safety closure Download PDF

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Publication number
CN1478040A
CN1478040A CNA018199992A CN01819999A CN1478040A CN 1478040 A CN1478040 A CN 1478040A CN A018199992 A CNA018199992 A CN A018199992A CN 01819999 A CN01819999 A CN 01819999A CN 1478040 A CN1478040 A CN 1478040A
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CN
China
Prior art keywords
stopper
external plug
brake equipment
wall
springing
Prior art date
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Granted
Application number
CNA018199992A
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Chinese (zh)
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CN1258468C (en
Inventor
R��ŵ��˹
R·诺比利
D·朗索尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Al Seck Easy Jsc
Clariant Products France Summary Co ltd
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Airsec SAS
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Publication of CN1478040A publication Critical patent/CN1478040A/en
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Publication of CN1258468C publication Critical patent/CN1258468C/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D50/00Closures with means for discouraging unauthorised opening or removal thereof, with or without indicating means, e.g. child-proof closures
    • B65D50/02Closures with means for discouraging unauthorised opening or removal thereof, with or without indicating means, e.g. child-proof closures openable or removable by the combination of plural actions
    • B65D50/04Closures with means for discouraging unauthorised opening or removal thereof, with or without indicating means, e.g. child-proof closures openable or removable by the combination of plural actions requiring the combination of simultaneous actions, e.g. depressing and turning, lifting and turning, maintaining a part and turning another one
    • B65D50/041Closures with means for discouraging unauthorised opening or removal thereof, with or without indicating means, e.g. child-proof closures openable or removable by the combination of plural actions requiring the combination of simultaneous actions, e.g. depressing and turning, lifting and turning, maintaining a part and turning another one the closure comprising nested inner and outer caps or an inner cap and an outer coaxial annular member, which can be brought into engagement to enable removal by rotation

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Closures For Containers (AREA)
  • Lock And Its Accessories (AREA)
  • Discharge Heating (AREA)
  • Glass Compositions (AREA)
  • Control Of Combustion (AREA)
  • Superstructure Of Vehicle (AREA)

Abstract

The invention concerns a safety screw cap closure device for a container provided with an outer screw thread opening, which consists of two interlocked coaxial caps, the outer one capable of driving the inner one by axial pressure and rotation: the outer cap (1) including, on the inner surface of one of its walls, snap-on means; the inner cap (40) comprising a screw thread on the inner surface of its cylindrical side wall (2) and snap-on means on the outer surface of its wall, opposite the inner cap wall (40) including the snap-on means, and elastic means for disengaging the snap-on means of the walls of both the inner and outer caps located between the upper end walls (3) of the two caps, and made of a material of different compositions from the composition of the caps.

Description

Protection child's safety interlocking mechanism
Technical field
The present invention relates to a kind of screw thread safety interlocking mechanism of container, protection child's mechanism, the opening of this container is equipped with an external screw-thread line.
The present invention be more particularly directed to a kind of screw thread safety interlocking mechanism that is used for such as the container of bottle, this mechanism comprises that a screw thread is screwed in the coaxial external plug that inside stopper on the described container and integral body cover this inside stopper, this external plug has when applying axle pressure and rotation on the stopper externally, drives the ability of this inside stopper by brake system.
Background technology
For the screw thread locking mechanism of the container of the opening that is equipped with threaded line, protection child's safety device is just occurring many years ago.
These devices comprise two stopper/lids that are enclosed within another, and each stopper forms the upper end wall of a lateral cylindrical wall and this cylindrical wall of sealing.
The inside that this inside stopper is included in its cylindrical wall lip-deep one allows this stopper to seal the thread of this container and some permissions drive this inside stopper by the rotation of this external plug device on its cylinder exterior wall and/or the end by screw thread.External plug whole cover this inside stopper on coaxial with this inside stopper, this external plug comprises multiple arrangement on portion's wall within it, these devices are used for, by on this external plug, apply axially/rotational pressure is along the closing direction of this container or open direction, rotation drives this inside stopper, this pressure allows the actuating device of this external plug to cooperate with device for mechanical corresponding to inner stopper, can transmit rotatablely moving of described inner stopper then.
In these two stoppers any one all comprises some springings, and these springings allow the actuating device machinery of outside and inner stopper to throw off, and these springings are realized with the stopper identical materials with injection molding.
The protection child's that some are such safety interlocking mechanism is described in a plurality of patents, and some such patent exemplarily is disclosed hereinafter.
The first kind of device that proposes in European patent EP 0631943 relates to (the protection child's) a kind of safety interlocking mechanism that comprises the container of thread, this safety interlocking mechanism comprises two nested stoppers, inner stopper is used to seal described container, external plug is used to drive this inside stopper, so that open or close this container by the aggregate motion of compression and/or rotation.
In this device:
The inside stopper that-this screw thread is screwed into comprises, on the outer surface of its cylindrical wall, one groove that constitutes by continuous laminar rib, this groove is a radial groove shape and extends on the outer surface of the wall of the upper end of inner stopper, the thin slice of this radial groove has along the limit of the length of the hand of rotation opened orientation and is preferably placed at minor face in the plane of longitudinal central axis of the closing member that comprises this container;
-this external plug comprises, externally the inside of the wall of the upper end of stopper is lip-deep, some projections, this surface, inside is deliberately made and is protruded shape (closing this cylindrical wall), when applying axle pressure on by the wall in the upper end of described external plug and causing the elastic deformation of described wall, these projections are engaged in the groove of this inside stopper.
From this moment, by on the surface, inside of the wall of the protrusion end of this exterior stopper, implementing axle pressure, on described stopper, apply rotation then, by the projection of this external plug, the rotation idol is delivered on the radial groove of this inside stopper, so that turn on this inside stopper from this container.
As mentioned above, this mechanism also is included in the laminar groove that is orientated on the cylinder exterior wall of this inside stopper, the effect of this groove is feasible, when the projection of external plug is not engaged in the inclination thin slice of radial groove of this inside stopper, the inside stopper that the rotation screw thread is screwed in this external plug easily.
This mechanism also comprises and passes through external plug, irrespectively rotate second drive system that drives this inside stopper with this first drive system along hand of spiral, so that this external plug is in shutoff operation, drive this inside stopper by simple rotation, and there is no need applying axle pressure on the exterior wall of the protrusion end of this external plug: this drive system is by the device formation of for example representing with projection on the device of for example using " anterior face " expression on a plurality of inner cylindrical wall that are positioned at this external plug and the outer cylinder wall that some are positioned at this inside stopper.
This mechanism that is called safety interlocking mechanism that is used for child has a plurality of shortcomings that show in use.
For example this external plug (as inner stopper) is made by a kind of polymeric material that how much has elastic performance, the projection on the surface, inside of the wall of the upper end of this external plug is made with identical materials and the topside injection-molded on the described inner surface by described stopper obtains: as the upper wall of the upper end of this external plug for protrude and repeatedly impelled axial compression-rotation so that open this container by implementing couple, the elastic memory of this structural materials dies down and the distortion of the wall of this upper end may become similar constantly by the fatigue effect of material, makes projection can engage and make this inside stopper can be screwed into the rotation of direction or rotational direction along any one screw thread relatively consistently and drives.
Therefore, when producing the fatigue effect of material, the wall of the upper end of this external plug is no longer separated fully with the outer surface of the wall of the end of this inside stopper: because can with the braking of necessary axial compression-these two stoppers of irrelevant to rotation ground generation, so this mechanism no longer is perfectly safe.
Related to one as another device of the target of European patent EP 0602925 and comprised the locking mechanism that the child of the container of a thread does not open, this locking mechanism also comprises two stoppers that are enclosed within on another, this inside stopper is used to close described container, and this external plug is used for by axial compression and/or rotatablely moves driving this inside stopper to open or closing containers.
In this mechanism:
-this external plug comprises that the inside of the wall of end is lip-deep thereon, and microscler braking bar that some are radial oriented and the springing in the part in the central are so that keep the wall of the upper end of the wall of upper end of this external plug and this inside stopper to separate;
The inside stopper that-screw thread is screwed into comprises, and is lip-deep in the inside of its cylindrical wall, a thread and some radial oriented microscler braking bars on the wall of end thereon.These have inclination (along the hand of spiral of this inside stopper) surface and are subjected to rotation along hand of spiral so that drive the inside plug period of the day from 11 p.m. to 1 a.m when described external plug, rest on the braking bar of this external plug.But, when described stopper is subjected to rotation along rotational direction, during the axial force on the wall of the upper end of this external plug that before do not applied, the bar on the surface, inside of the wall of the upper end of this external plug just slides on this bevelled surface and inner stopper is not driven.
Therefore cause, axle pressure on the wall of this upper end by being applied to this inside stopper continuously obtains turning on of this inside stopper, therefore described wall is near the wall of upper end that should the inside stopper, and cause the braking of bar of wall of the upper stopper upper end of this inside stopper, therefore this inside stopper is driven by the external plug rotation.
Be applied to the pressure on the wall of upper end of this external plug from relieving, owing to cause two open circuited elastic systems of stopper, so the disengagement of the braking bar of the braking bar of this external plug and this inside stopper.
Yet, comprise the mechanism that is called safety interlocking mechanism that is used for child of two stoppers, also have the shortcoming that occurs when using.
For example for external plug, device that is made of the braking bar of external plug and the springing that occurs on the surface, inside of the wall of the upper end of described stopper all are to have some natural elastomeric polymeric material (passing through injection-molded) by a kind of mono-to implement.Or rather, this springing is made of 4 tongues, and these 4 tongues vertically are connected to by an end in their end on the surface, inside of wall of upper end of described stopper.These 4 tongues constitute and the coaxial virtual cylindrical wall of this external plug.When exerting pressure on the wall in the upper end of this external plug, these 4 tongues tend to be separated from each other in their bottom, and are then on the wall of the upper end of this inside stopper, crushed during the applying of whole above-mentioned pressure.
When unclamping described pressure, this tongue must return a upright position.But, in fact, being used on this external plug unscrewed the repetition of the axial stress (axle pressure-rotation) of this mechanism, the fatigue of drive configuration polymeric material, this fatigue is by the similar constant distortion of this springing and all or part of fracture of this springing is shown.
Therefore, when static the surface of the upper end of two stoppers separate fully no longer each other and their position close mutually, tend to cause the accidental braking of the driving gear of the driving gear of external plug and inner stopper.Therefore this mechanism that is called safety interlocking mechanism that is used for child no longer is perfectly safe.
As another device of the target of European patent EP 0725012, the locking mechanism that a kind of child who comprises the container of a thread does not open is proposed, this locking mechanism comprises:
Be used for driven inside stopper that cylinder lateral sidewall and end wall are housed;
The cylinder of band opening drives shell, makes the upper shed of this cylindrical shell have slightly the diameter greater than the diameter of the support of inner stopper, and this makes this inside stopper occur on described cylindrical shell.
In case be inserted in this cylindrical shell, this inside stopper in the bottom by described cylindrical shell against a circle keep described cylindrical shell, this inside stopper the top by described cylindrical shell on outer fringe surface against an outer annular thing keep described cylindrical shell.
Cylinder driving shell is included in a plurality of brake equipments on its inside face, and these brake equipments can also be the guide piecees of this stopper.
For inner stopper, make this inside stopper can be on the outside lateral sidewall of described stopper by the mono-brake equipment of the inside stopper that cylindrical shell drove.When on shell, applying the pressure that shell is descended and be braked and be used to drive the rotating machinery idol of shell of this inside stopper, from this moment, by the brake equipment of cylindrical shell and a plurality of brake equipments of described inner stopper, carry out the Mechanical Driven of cylindrical shell to inner stopper.
Open circuited springing is that the blade by the bottom circle of this inside stopper constitutes, these blades have identical constituent and connect described bottom circle by an end in this blade tip, and these blades are contained in the described circle when exerting pressure on cylindrical shell from the top down.
Therefore show, because these devices that use in this device must apply vertical power on cylindrical shell, at first need to grip the whole outer rim of described shell according to a more uncomfortable motion, on the outer rim of this shell, apply the vertical power that is used to produce to the braking of described shell and stopper then, rotation by this cylindrical shell at last drives this inside stopper, so these devices cause being difficult to drive inner stopper.
Also show, open circuited springing is positioned on the bottom circle of this inside stopper and with the structural materials that is same as this stopper and cylindrical shell (constituent) to be implemented, when this material of frequent use, this material may lose a part of elastic performance, and may reach fatigue state, for example this material can produce the crack and lose its elasticity, even fracture.
At last, as another unit describe of the target of patent GB2209156 a kind of safety interlocking mechanism of the fire extinguishing hole that is used to supply water.This device comprises the external plug that the inside stopper made with polyamide technology and aluminum alloy are made.
Inner stopper is provided with a thread on the wall within it, and this thread cooperates with the thread of water outlet ozzle.
By constituting the outer boundary ring of guide piece, this external plug remain on a coaxial position of this inside stopper in, this outer boundary ring coaxially keeps two stoppers, constitutes the disconnection springing of these two stoppers.
One spring only leans against in the suitable coaxial endless groove between their opposed upper faces.
Constituting of device driven compressed-rotated to external plug to inner stopper:
Be positioned at lip-deep 3 teeth in inside of the upper end of external plug, these 3 teeth when producing compression-rotation, are engaged in 3 cavitys, and these 3 cavitys are on the outer surface of the upper end of this inside stopper.
Yet fact proved that such device is difficult to implement, because:
Need one relatively the operation of machinery accurately and side by side make these 3 teeth enter into 3 cavitys bigger slightly than the diameter of tooth, therefore need good hand skill and need a large amount of effort, so that can implement the driving of opening or closing;
A kind of disconnection springing of the metal spring of determining by diameter can have very long service life, but because this being applied in especially needs big manpower and special manually skill when handling, so seldom handle this springing;
This safety interlocking mechanism proof is not suitable for the locking mechanism such as the container of bottle fully.
Goal of the invention
From now on, with a plurality of targets of pointing out according to device of the present invention, so that the above-mentioned shortcoming of removal that can be best and propose repair and the improved way of employed different device in the known relatively safety interlocking mechanism.
First target of the present invention is to implement the device of the safety interlocking mechanism of the container that a kind of screw thread that a kind of child of preventing unscrews is screwed into, this device comprises two stoppers that thermoplastic polymer is made that are enclosed within another, this mechanism utilizes the braking work of external plug on inner stopper by apply an axial compression-rotation idol on the wall of the upper end of this mechanism.
Another target of the present invention is the safety interlocking mechanism that implements the container that a kind of screw thread that a kind of child of preventing unscrews is screwed into, this mechanism comprises a "cut-off" drvice, this "cut-off" drvice, when the pressure from the wall of the upper end that is applied to this mechanism stops, disconnecting this driving immediately with external plug and driven inner stopper.
Another one target of the present invention is the safety interlocking mechanism that implements the container that a kind of screw thread that a kind of child of preventing unscrews is screwed into, the multiple arrangement of this mechanism has allowed to drive braking and the disengagement of external plug with driven inner stopper, so this multiple arrangement is not fully partly to be subjected to owing to apply axial compression-rotation repeatedly by chance on the wall of the upper end of described mechanism.Fatigue, constant distortion or fracture.
Another target of the present invention is the safety interlocking mechanism that implements the container that a kind of screw thread that a kind of child of preventing unscrews is screwed into, the multiple arrangement of this mechanism has allowed to drive with braking and the disengagement of external plug with driven inner stopper, this multiple arrangement has compensated the adjustment between this inside and outside stopper and has used the gap, and when this multiple arrangement is braked, given their good connectivities, and when this multiple arrangement is thrown off, given their zero-lash independence.
Summary of the invention
Above-mentioned all targets can realize by target of the present invention, locking mechanism.
According to the present invention, be equipped with the safety interlocking mechanism that the screw thread of container of the opening of band external screw-thread line is screwed into, comprise two coaxial stoppers, these two stoppers are made with the thermo-plastic polymer material, and one is enclosed within on another, and one is external plug, and another is inner stopper, each stopper all is made of the upper end of closing this cylinder lateral sidewall
-this external plug comprises, more lip-deep brake equipments of portion within it, and this brake equipment makes this external plug rotation drive this inside stopper by applying the machinery idol of an axial compression-rotation;
-the lip-deep thread in inside that this inside stopper is included in its cylinder lateral sidewall and some the brake equipments on its outer surface corresponding to the brake equipment of external plug, when external plug was subjected to the machinery idol of axial compression-rotation, this brake equipment drove this inside stopper by this external plug rotation;
-when on this external plug, stopping to apply axial compression-rotating machinery idol, make the open circuited springing of brake equipment of this inside stopper and external plug;
-guarantee the guide piece of inside and outside stopper of the coaxality of these stoppers,
It is characterized in that this disconnection springing:
-be arranged between the wall of upper end of inside and outside stopper,
-forming by a kind of thermo-plastic polymer material, this thermo-plastic polymer material has shape memory, and its constituent is different from the constituent of the material that constitutes stopper itself.
Or rather, according to first flexible program, be equipped with the safety interlocking mechanism that the screw thread of container of the opening of an external screw-thread line is screwed into, this mechanism comprises two one the coaxial stopper of being made by the thermo-plastic polymer material that is enclosed within on another, one is external plug, another is inner stopper, and each stopper all is made of cylinder lateral sidewall and the wall of closing the upper end of this cylinder lateral sidewall, and this mechanism is:
-external plug comprises that the inside of the wall of end is lip-deep thereon, and some brake equipments, this brake equipment make this external plug rotation drive this inside stopper by applying the machinery idol of an axial compression-rotation;
-the lip-deep thread in inside that this inside stopper is included in its cylinder lateral sidewall and some brake equipments on the outer surface of the wall of end thereon corresponding to the brake equipment of external plug, when external plug was subjected to the machinery idol of axial compression-rotation, this brake equipment drove this inside stopper by this external plug rotation;
-some guarantee the guide piece of inside and outside stopper of the coaxality of these stoppers;
-when on this external plug, stopping to apply axial compression-rotating machinery idol, the disconnection springing of the brake equipment of the wall of the upper end of this inside stopper and external plug, this disconnects springing:
-be arranged between the wall of upper end of inside and outside stopper,
-forming by a kind of thermo-plastic polymer material, this thermo-plastic polymer material has shape memory, and its constituent is different from the constituent of the material that constitutes stopper itself.
Or rather, according to second flexible program, be equipped with the safety interlocking mechanism that the screw thread of container of the opening of an external screw-thread line is screwed into, this mechanism comprises two one the coaxial stopper of being made by the thermo-plastic polymer material that is enclosed within on another, one is external plug, another is inner stopper, and each stopper all is made of cylinder lateral sidewall and the wall of closing the upper end of this cylinder lateral sidewall, and this mechanism is:
-external plug comprises that lip-deep in the inside of its cylinder lateral sidewall, some brake equipments, this brake equipment make this external plug rotation drive this inside stopper by applying the machinery idol of an axial compression-rotation;
-the lip-deep thread in inside and some brake equipments on its cylinder lateral sidewall outer surface that this inside stopper is included in its cylinder lateral sidewall corresponding to the brake equipment of external plug, when external plug was subjected to the machinery idol of axial compression-rotation, this brake equipment drove this inside stopper by this external plug rotation;
-some guarantee the guide piece of inside and outside stopper of the coaxality of these stoppers;
-when on this external plug, stopping to apply axial compression-rotating machinery idol, make the open circuited springing of cylinder lateral sidewall brake equipment of this inside stopper and external plug, this open circuited springing:
-be arranged between the wall of upper end of inside and outside stopper,
-forming by a kind of thermo-plastic polymer material, this thermo-plastic polymer material has shape memory, and its constituent is different from the constituent of the material that constitutes stopper itself.
Detailed description of the present invention
Mechanism according to the present invention comprises two stoppers that are enclosed within on another, the topside of each stopper equipment such as device of external plug, when this external plug is subjected to an axle pressure, when rotating then, this external plug moves by downward motion vertical, and braking is on this inside stopper and drive the opening or closing movement on request of this inside stopper.
Stop axial compression from stopper externally, be used for the motion that intrinsically safe mechanism must guarantee the reverse rising of this external plug, promptly to produce the disconnection of this inside stopper and external plug: be arranged in its disengaged position from this external plug, and be subjected to mono-and rotatablely moved, no longer in the motion of turning on, drive this inside stopper.
Such device is ultra-safe for child, must set up axial compression-rotation idol simultaneously for opening this mechanism, and child also never acquires the cooperation of this gesture.
According to the outside of mechanism of the present invention and inner stopper is to implement by the refining molding process that is suitable for implementing them, by for example polyethylene, polypropylene, ethylene/propylene copolymer and its composite, polyamide, polystyrene (PS), acrylonitrile-butadiene-styrene copolymer (ABS), polymers such as styrene-acrylonitrile (SAN), polyvinyl chloride (PVC), polycarbonate (PC), polymethacryl methyl (PMMA), polyethylene terephthalate (PET) is implemented.
According to the present invention, be very different with prior art, be rotated subsequently from stopping to apply axial compression in this external plug, the springing of this shape memory can make external plug and inner stopper throw off, the springing of this shape memory is made of the elastomeric thermoplastic polymers material with shape memory, is made of the composite of the composite that is different from the material that is used to make inside and outside stopper.
The springing of this shape memory can be derived from natural or synthetic thermoplastic elastomer enforcement at least by using.Employed elastic body can preferably be selected in such group, this group comprises the elastic body of natural rubber type, the elastic body of neoprene type, olefin homo rubber particularly, isobutylene/isoprene copolymer for example, vinyl ethylene acetate (EVA) poly-mer, the rare rubber of ethene-third (EPR), epdm polymer (EPDM), ethene-ester acrylate polymer (EMA-EMA), fluoropolymer, diolefin rubber, polybutene rubbers for example, butylene-styrene copolymer (SBR) is based on the rubber of coacervation prod, for example polyester and polyurethane thermoplastic rubber, silica gel, the styrene rubber of styrene-butylene-styrene (SBS) and styrene-isoprene-phenylethene (SIS) and other may be used singly or in combin.
Can implement this shape memory springing by thermoplastic polymer foam.
Shape memory springing according to the present invention can have such shape: be preferably the generally cylindrical body type, the truncated cone build, cylinder-truncated cone build, the height that cylinder-hemisphere build or hemisphere build, the diameter of this shape are adapted to the diameter of this mechanism and this shape equals to make required minor increment when the brake equipment of this outside and inner stopper is not in cooperation position at least.
As mentioned above, the springing according to shape memory of the present invention can be the different spaces shape.This spatial form is solid, and in this case, is mainly plate-like, truncated cone shape, dome shape; Perhaps can also be hollow, in this case, be mainly capsule shape, truncated cone shape, cap shape vault, such shape is installed with hole, so that limit the sucker effect when being implemented, is released in the axle pressure (beginning rotation) on the external plug then.
Springing according to the present invention is arranged between the wall of upper end of two stoppers: by molded in the lip-deep bonding of this stopper or duplicating on described stopper, can between two walls, freely insert this springing, this springing of bonding on the inside face of the perhaps careless externally wall of the upper end of stopper or on the outside face of the wall of the upper end of inner stopper.
By thermoplastic, polymeric materials implement according to shape memory springing of the present invention, one in the method for plastic shaping that can be by being suitable for allowing producing described device obtains.
In general known brake equipment, but this brake equipment must be at it in shape by the form fit of described Hookean region according to brake equipment of the present invention according to this brake equipment, and this Hookean region is between the wall of the upper end of inside and outside stopper.
When brake equipment is set on the surface, inside of cylinder lateral sidewall of external plug and on the outer surface of the cylinder lateral sidewall of inner stopper the time, these brake equipments are generally known type and need not carry out any change: they for example constitute:
-have square, rectangle, the thin slice that is provided with at least a portion of height triangle or other shaped cross, that be positioned at described lateral sidewall and along bus,
-be positioned at the annular element of the trough of belt mouth of the outer rim on the described relevant surfaces.
When on the surface of relative cylinder lateral sidewall and on the surface of the upper end of described stopper this brake equipment being set simultaneously, this brake equipment is generally known type, for example thin slice.Some are described in the such thin slice in the European patent EP 0631943, constituted a kind of groove, this groove, under the necessary limited radial groove shape of the radical length of each thin slice, continuous rib by chip shape constitutes, this rib extends on the surface in the surface that is fit to of the wall of upper end at least, so as to set up one with stopper coaxial, the necessary standby surface of springing of the present invention is set.
This radical length maximum equals the radius of wall surface of the upper end of inside and outside stopper, is reduced to the radius of lower surface of the geometric configuration of springing of the present invention.
When on the inside face of the wall of the upper end of stopper externally and on the outside face of the wall of the upper end of inner stopper this brake equipment being set, constituting of these devices, the tooth on annular element for example, has square, rectangle, the thin slice in the cross section of triangle or other shape, in radial position, the radial dimension of this device be defined as can set up one be provided with springing of the present invention necessary, with the coaxial standby surface of stopper.
This radial dimension maximum equals the radius of wall surface of the upper end of inside and outside stopper, the radius of the lower surface of the geometric space shape that is reduced to springing of the present invention of contracting.
When on the inside face of the wall of the upper end of stopper externally and on the outside face of the wall of the upper end of inner stopper this brake equipment being set, being configured as of these devices, the tooth on annular element for example, has square, rectangle, the thin slice in the cross section of triangle or other shape, in radial position, the radical length of this device be defined as can set up one be provided with springing of the present invention necessary, with the coaxial standby surface of stopper.
Brake equipment can be arranged on the preceding counter surface that equip brake equipment according to the present invention, this counter surface has:
-on the counter surface that the cylindrical side of stopper is faced the wall and meditated such as be installed in tooth on the annular element or stopper on radially thin slice, the perhaps identical form of the reeded annular element of outer rim;
-such as the lip-deep tooth on the annular element and the different form of radially thin slice on the outer surface of the wall of inner stopper upper end of being installed in the inside of the wall of the upper end of stopper externally.
According to special flexible program of the present invention, externally on the inside face of the wall of the upper end of stopper and on brake equipment each in these surfaces of opposite disposed on the outer surface of the wall of the upper end of inner stopper, be made of a band tooth annular element, the apparent diameter less than the apparent diameter of stopper of this brake equipment is identical for each annular element preferably.
Constitute the tooth each interval of each annular element, when being subjected to an axle pressure and beginning to rotate then with convenient external plug, the tooth of the annular element of external plug can easily be embedded between the tooth of annular element of inner stopper.
The permission of this annular element the tooth of braking of external plug and inner stopper have such shape:
-parallelepiped, this parallelepiped finishes in their mechanical cooperative end part by two planes bevelled, symmetry, that separated by a horizontal plane each other,
-parallelepiped or cylinder, this parallelepiped or cylinder finish in their mechanical cooperative end part by the hemisphere or the truncated cone.
The F-SP of this tooth is configured such that, when this external plug is not subjected to axial compression and only is subjected to rotatablely moving, this external plug can be along a direction or along another direction rotation, and can not drive inner stopper, if the toe joint of the tooth of the annular element of external plug and the annular element of inner stopper touches, the tooth of the annular element of external plug just slides on the tooth of inner stopper, and can not brake each other;
-the number of teeth order that is arranged in each annular element is basically by the diameter decision of annular element: the preferred number of tooth has 4 teeth at least for each annular element.Preferred mode is, number of teeth order and this annular element be that the ratio of the diameter of unit is included between 0.15 (4/24) and 0.5 (12/24) with the millimeter.
According to the present invention, in order to ensure good coaxality, the guide piece of the relative interior stopper of external plug can be positioned at a stopper/or cylinder lateral sidewall of another stopper/or another cylinder lateral sidewall on, on the surface, inside of stopper on the outer surface of inner stopper and/or externally.
Guide piece can be by having square, rectangle, and the thin slice of triangle and other shape constitutes, and this thin slice is positioned on the whole height of cylinder lateral sidewall or the part height and along the bus setting of described wall.
When guide piece only relates to when being used for the mono-guide function, guide piece is arranged on external plug and inner stopper one of the cylinder lateral sidewall and/or another, and the height of guide piece relates to the whole of described lateral sidewall or part height.
According to the present invention, these guide piecees can have two functions simultaneously, and first function is a guide function, and second function is the actuating device that drives inner stopper along the single direction that screw thread is screwed into by external plug.
For two functions can guaranteeing simultaneously, be preferably placed on the whole height of cylinder lateral sidewall of these two stoppers by be screwed into this thin slice that direction guiding and device driven constitute along screw thread.The cross sectional shape of these thin slices is roughly has triangle, the waveform of square-section, and the initial point of this waveform is positioned on the bus of cylinder lateral surface, and the terminal point of this waveform is orientated along a clinoplane:
-when this thin slice is positioned on the surface, inside of cylinder lateral sidewall of external plug, is arranged in and has the entad direction of tendency,
-when this thin slice is positioned on the outer surface of cylinder lateral sidewall of inner stopper, be arranged in direction with tendency to drift away.
Therefore work as external plug except being subjected to this axial compression, during the direction rotation that also is subjected to being screwed into along screw thread, the end of the guiding thin slice of external plug just begins to touch the end of the guiding thin slice of inner stopper, and is screwed into direction along screw thread and drives this inside stopper.
The opposite external plug of working as is except being subjected to whole axial compression, also be subjected to when screw thread is turned on the rotation of direction, the clinoplane of the guiding thin slice of external plug makes on the clinoplane of the guiding thin slice of inner stopper and slides, and the direction of not turning on along described screw thread drives described inner stopper.
Except a single springing, external plug and inner stopper, thread, brake equipment and guide piece all are simultaneously by implementing with a kind of polymeric material injection-molded that is used for injection-molded production traditionally, this springing is by the material different with the material that is used for stopper, is independent of to carry out patrix system on stopper or in two stoppers one and implement.
Description of drawings
Be composed of the explanation of number by following public by accompanying drawing, the present invention will be better understood, and these accompanying drawings are only made example and do not limited specific embodiments of the invention.Accompanying drawing comprises:
-Fig. 1 is the transparent view of external plug;
-Fig. 2 is the transparent view of springing of the present invention;
-Fig. 3 is the transparent view of inner stopper of the present invention;
-Fig. 4 is the transparent view of closing appliance that includes the container of hygroscopic material;
-Fig. 5 is the vertical sectional view of mechanism of the present invention, comprises external plug and inner stopper;
-Fig. 6 is the B-B horizontal cross of mechanism of the present invention;
-Fig. 7 is the interior views of the external plug of mechanism of the present invention;
-Fig. 8 is the vertical sectional view of the external plug of mechanism of the present invention; With
-Fig. 9 is the transparent view of the tooth that brake equipment of the present invention had.
1-4 with reference to the accompanying drawings, comprise an external plug (1) according to safety interlocking of the present invention mechanism, one shape memory springing (20), an inner stopper (40) and holds the closing appliance (60) of the container of the water wetted material that can absorb container (not shown) in-to-in moisture.
External plug (1) comprises the upper end wall (3) of a cylinder lateral sidewall (2) and closed this cylinder lateral sidewall.Have the brake equipment (Fig. 7) that is formed by annular element (4) on the surface, inside of upper end wall (3), the diameter of this brake equipment promptly has 12 teeth (5) less than the diameter of this stopper.The surface, inside of cylinder lateral sidewall is provided with the device to the center (Fig. 5,6,7) of some thin slices (6) formation of carrying out two functions in the embodiment shown simultaneously, and these two functions are:
-first function is, when externally apply on the stopper (1), when decontroling axle pressure then, this external plug of coaxial guiding (1) moves with respect to inner stopper (40);
-the second function be, when externally not applying whole axle pressure on the stopper, assists actuating device to drive this inside stopper along the single direction rotation that the screw thread of this mechanism is screwed into.As shown in Figure 6, the cross section of this thin slice (6) is roughly elongated rectangular shape, the producing along the inclination angle of planar obit simulation (7) along to the direction location (along arrow) of central tendency and at the root and tangent plane (8) formation one angle " α " of this thin slice (6) of this thin slice (6).
Inner stopper (40) also comprises the upper end wall (42) of a cylinder lateral sidewall (41) and closed this cylinder lateral sidewall.On the outer surface of upper end wall (42), has the brake equipment (Fig. 3) that forms by annular element (43), the diameter of this brake equipment is less than the diameter of this inside stopper, but equals to be positioned at the diameter of the lip-deep annular element in inside (4) of wall of the upper end of external plug (1).This annular element (43) includes the tooth with annular element (4) similar number.
Also be provided with some guide piecees on the outer surface of cylinder lateral sidewall (41), these guide piecees comprise some thin slices (45), and these thin slices (in the embodiment shown) are carried out two functions simultaneously:
-first function is that guiding external plug (1) moves with respect to the coaxial of inner stopper (40);
-the second function be, when externally not applying whole axle pressure on the stopper, assists actuating device to drive this inside stopper along the single direction rotation that the screw thread of this mechanism is screwed into.As shown in Figure 6, the cross section of this thin slice (45) is roughly elongated triangular shaped, and the inclination angle along planar obit simulation (46) of this thin slice (45) produces along the direction location (along arrow) of tendency entad and at the root and tangent plane (47) formation one angle " β " of this thin slice (45).
This annular element (4,43) tooth (5,44) be shaped as parallelepiped rectangle type (Fig. 9), it comprises that some are when passing through inclined-plane (clinoplane) (92,93) glancing impact is at the lateral sidewall (90 of its mechanical abutting end extension, 91), inclined-plane (92,93) are separated from each other by a horizontal plane (94).
This shape of tooth is such, when not having axle pressure on the stopper externally, but on described external plug, apply when rotatablely moving, the clinoplane (92 of the tooth (5) of annular element (4), 93) and the tooth (44) of annular element (43) can slide over each other (their chances near and when causing contacting with each other), and the tooth of described annular element can not be braked the rotation that also can not cause by external plug and drives this inside stopper.
With good grounds shape memory springing of the present invention (20) (Fig. 2) between the wall of the upper end of inner stopper and external plug.Described springing (20) is hollow cylinder-truncated cone type, comprises a circular ring-shaped part (21), one cylinder-truncated cone sidewall (22) and include a cross bar (2 3) and the wall of the upper end that has hole of some openings (24).
The diameter of the springing of this shape memory is inserted into this springing in annular element (4) and (43) being convenient to less than the internal diameter of braking annular element (4) and (43).
Combination by thermoplastic elastomer is annotated the shape memory springing of realizing by mould and is placed on two walls (3) of upper end of stopper and the position of function place between (42).
The thickness of shape memory springing (20) is slightly greater than the distance between the wall of end (3) and (42), so that except whole axial compression, this external plug (1) can be rotatablely moved (along opening direction), and does not drive this inside stopper (40).
During axial compression on this external plug (1), the springing of shape memory (20) is compressed, and is deformed in the border that is contained in annular element (4) and (43) fully.Shape memory springing deformation in compression is discharged the air that is present in the zone that can brake two annular elements (4) and (43).
External plug can be rotated and be driven this inside stopper, particularly turns on direction along screw thread.When the axial compression end, the shape memory springing recovers its initial shape, particularly by reclaiming the air of initial volume.These two stoppers are by being thrown off braking away from each other: external plug no longer can drive this inside stopper, the particularly direction of turning on along screw thread.
Finish according to mechanism of the present invention, need a lid (60), be used to close this container (48) (constituting inner stopper (40)), in this container, be marked with material, for example can absorb osed top container (not shown) in-to-in moisture by described mechanism with property.
In above-mentioned example according to mechanism of the present invention, closing by thin slice (6) and (45) of this mechanism undertaken according to the present invention, when external plug (1) is subjected to when screw thread is screwed into single the rotatablely moving of direction, this thin slice (6) and (45) are only leaned on mutually: the thin slice (6) of the external plug that drives along the direction of arrow (49) begins to contact the thin slice (45) of inner stopper (40) and drive described inner stopper along closing direction by its steep surface.
In opposite mode, external plug (4) is turned on direction along screw thread and is subjected to along single the rotatablely moving of arrow (50), and thin slice (6) is gone up at the clinoplane (46) of this thin slice (45) by its clinoplane (7) and slided: inner stopper is not subjected to turn on the driving of moving along screw thread.
Open mechanism of the present invention in order to turn on by screw thread, external plug (1) must be subjected to axle pressure, turns on the direction rotation along screw thread then.Like this, external plug (1) is by the close inner stopper of extrusion shapes memory springing (20).
The tooth of the annular element (4) of external plug (1) is braked in the tooth of the annular element (43) of inner stopper (40): inner stopper is just driven by external plug (1) rotation, and closing organ is turned on easily and separated with the container (not shown) easily.
According to another flexible program (not shown), the thin slice (6) or the thin slice (45) on the inner stopper (40) on having only stopper (1) externally, the thin slice that is participated in only is used for guide function, and this safety shutdown mechanism comprises all devices in first embodiment.In this case, be by the axial compression on the stopper externally according to the opening and closing of mechanism of the present invention.Be that suitable rotation is carried out then, make braking annular element (4) and (43) be braked, and the hand of rotation that the edge externally applies on the stopper (1) drives inner stopper (40).

Claims (27)

1. equip the safety shutdown mechanism that the screw thread of container of the opening of a band external screw-thread line is screwed into, this mechanism comprises two made by the thermo-plastic polymer material, coaxial stoppers that are enclosed within another, one is external plug, another is inner stopper, and each stopper is made of cylinder lateral sidewall and the wall of closing the upper end of this cylinder lateral sidewall:
-external plug comprises that portion is lip-deep within it, and some can make this external plug rotation drive the brake equipment of inner stopper by the machinery idol that applies axial compression-rotation;
-inner stopper is included in the lip-deep thread in inside of its cylinder lateral sidewall, with some and the cooresponding brake equipment of brake equipment of this external plug on its outer surface, when external plug was subjected to the machinery idol of axial compression-rotation, this brake equipment can make this inside stopper be driven by the external plug rotation;
-when stopping to apply axial compression-rotating machinery idol on the stopper externally, make the open circuited springing of brake equipment of inner stopper and external plug;
The guide piece of the coaxality of guaranteeing them of-inner stopper and external plug,
It is characterized in that, disconnect springing:
-be arranged between the wall of upper end of inner stopper and external plug,
-constituting by thermo-plastic polymer material with shape memory, the constituent of this material is different with the constituent of the material that constitutes stopper self.
2. equip the safety shutdown mechanism that the screw thread of container of the opening of a band external screw-thread line is screwed into, this mechanism comprises two made by the thermo-plastic polymer material, coaxial stoppers that are enclosed within another, one is external plug, another is inner stopper, each stopper is made of cylinder lateral sidewall and the wall of closing the upper end of this cylinder lateral sidewall, wherein:
-external plug comprises that the inside of end wall is lip-deep thereon, and some can make this external plug rotation drive the brake equipment of inner stopper by the machinery idol that applies axial compression-rotation;
-inner stopper is included in the lip-deep thread in inside of its cylinder lateral sidewall, with with the outer surface of end wall thereon on some and the cooresponding brake equipment of brake equipment of this external plug, when external plug was subjected to the machinery idol of axial compression-rotation, this brake equipment can make this inside stopper be driven by the external plug rotation;
-inner stopper and outer stopper in the guide piece of the coaxality of guaranteeing them;
-when stopping to apply axial compression-rotating machinery idol on the stopper externally, making the open circuited springing of brake equipment of wall of the upper end of inner stopper and external plug, this disconnects springing:
-be arranged between the wall of upper end of inner stopper and external plug,
-constituting by thermo-plastic polymer material with shape memory, the constituent of this material is different with the constituent of the material that constitutes stopper self.
3. equip the safety shutdown mechanism that the screw thread of container of the opening of a band external screw-thread line is screwed into, this mechanism comprises two by the thermo-plastic polymer material makes, one is enclosed within another coaxial stopper, one is external plug, another is inner stopper, each stopper is made of cylinder lateral sidewall and the wall of closing the upper end of this cylinder lateral sidewall, wherein:
-external plug comprises that lip-deep to pars intramuralis in its cylindrical side, some can make this external plug rotation drive the brake equipment of inner stopper by the machinery idol that applies axial compression-rotation;
-inner stopper is included in the lip-deep thread in inside of its cylinder lateral sidewall, with with some and the cooresponding brake equipment of brake equipment of this external plug on the outer surface of its cylinder lateral sidewall, when external plug was subjected to the machinery idol of axial compression-rotation, this brake equipment can make this inside stopper be driven by the external plug rotation;
The guide piece of the coaxality of guaranteeing them of-inner stopper and external plug;
-when stopping to apply axial compression-rotating machinery idol on the stopper externally, making the open circuited springing of brake equipment of the cylinder lateral sidewall of inner stopper and external plug, this disconnects springing:
-be arranged between the wall of upper end of inner stopper and external plug,
-constituting by thermo-plastic polymer material with shape memory, the constituent of this material is different with the constituent of the material that constitutes stopper self.
4. according to each described mechanism in claim 1 or 2 or 3, it is characterized in that this shape memory springing is by one and another surperficial separating of the wall of upper end.
5. according to each described mechanism in claim 1 or 2 or 3, it is characterized in that the shape memory springing is connected with another surface by of the wall of upper end.
6. according at least one described mechanism in each and the claim 4 or 5 in claim 1 or 2 or 3, it is characterized in that, this shape memory springing realizes by at least a elastomeric material with shape memory, and this material is to select from one group of material that is made of at least a elastic body.
7. mechanism according to claim 6 is characterized in that, the springing of this shape memory realizes that by the material of selecting this group is made of the elastic body of natural rubber that is used singly or in combination and neoprene type in such group.
8. mechanism according to claim 7, it is characterized in that, this springing is preferably implemented by the material that is selected from such elastomer group, this elastomer group comprises, isobutylene/isoprene, vinyl ethylene acetate (EVA), ethylene, propylene (EPR), Ethylene Propylene Terpolymer monomer (EPDM), ethyl acrylate (EMA-EEA), fluoropolymer, polybutene, butylene styrol copolymer (SBR), lactoprene and poly-urethane rubber, silica gel, the styrene rubber of ethene-butylene-ethene (SBS) and styrene-isoprene-phenylethene (SIS) is used singly or in combination.
According to claim 1 or 2 or 3 and 4-8 in each described mechanism, it is characterized in that, this shape memory springing has such volume shape, be generally cylindrical body, the truncated cone, cylinder-truncated cone, cylinder-hemisphere or hemisphere type, its diameter is suitable for the diameter of this mechanism, and its brake equipment that equals external plug and inner stopper highly at least required minor increment when not being in cooperation position.
10. mechanism according to claim 9 is characterized in that the spatial form of this shape memory springing is solid.
11. mechanism according to claim 9 is characterized in that, the spatial form of this shape memory springing is hollow.
12. mechanism according to claim 11 is characterized in that, the hollow spatial form of this shape memory springing has hole.
13. according in claim 1 or 2 or 3 each and according at least one described mechanism among the claim 5-12, it is characterized in that, this shape memory springing by bonding or on molded and upper end wall one or another be connected.
14., it is characterized in that this shape memory springing is implemented with thermoplastic polymer foam according to each and claim 4 in claim 1 or 2 or 3 or 5 and 3 at least one described mechanisms of 8-1.
15. according at least one described mechanism among each and the claim 4-14 in claim 1 or 2 or 3, it is characterized in that, group below the thermoplastic, polymeric materials that uses in the formation of inner stopper and external plug is selected from, this group comprises: polyethylene, polypropylene, ethylene-propylene copolymer and their composite, nylon, polystyrene (PS), acrylonitrile-butadiene-styrene copolymer (ABS), styrene and acrylonitrile copolymer (SAN), polyvinylchloride (PVC), polycarbonate (PC), polymethacryl methyl (PMMA), polyethylene terephthalate (PET).
16. according at least one described mechanism among each and the claim 4-15 in claim 1 or 2, it is characterized in that, when brake equipment is arranged on the surface, inside of wall of upper end of external plug and on the outer surface of the wall of the upper end of inner stopper the time, these devices are from by the tooth that is provided with at annular element, square, rectangle, select in the device that the thin slice of triangular-section constitutes, this thin slice is in radial position, radical length equals to hold the radius on the surface of brake equipment at most, and this brake equipment is because the radius of the lower surface of the geometric space shape of springing and reduced.
17. according at least one described mechanism among each and the claim 4-15 in claim 1 or 2, it is characterized in that, when brake equipment is arranged on the surface on cylinder lateral sidewall opposite and on the surface of the upper end of external plug and inner stopper the time simultaneously, these brake equipments are some continuous ribs, this rib is formed at least one the lip-deep thin slice that radially extends in the suitable surface of wall of upper end of stopper, this thin slice is the shape of radially slotting, the radical length of this thin slice equals to hold the radius on the surface of this brake equipment at the most, and this brake equipment is because the radius of the lower surface of the geometric space shape of springing and reduced.
18. according at least one described mechanism among any and the claim 4-15 in claim 1 or 3, it is characterized in that, when brake equipment is arranged on the inside face of external plug cylinder lateral sidewall and on the outside face of the cylinder lateral sidewall of inner stopper the time, these brake equipments are selected from following group, this group comprises square, rectangle, to the small part height and the thin slice that be provided with along the annular element of bus or fluting that is positioned at described sidewall of triangular-section, the annular element of this bus or fluting is positioned at described upper end, the surface outer rim that relates to.
19. according in claim 1 or 2 each or 3 and claim 4-18 at least one described mechanism, it is characterized in that the brake equipment that is arranged on the counter surface of inside and outside stopper has identical form or different forms.
20. according at least one described mechanism among each and the claim 4-16 in claim 1 or 2, it is characterized in that, externally the brake equipment of the opposite disposed on the outside face of the wall of on the surface, inside of the wall of the upper end of stopper and the upper end of inner stopper is made of band tooth annular element on each of these surfaces, and the apparent diameter less than the diameter of stopper of this annular element is identical for each annular element preferably.
21. mechanism according to claim 20 is characterized in that, the tooth of braking annular element be shaped as parallelepiped, with two symmetries, the clinoplane that is separated by a horizontal plane ends at its mechanical cooperative end part each other.
22. mechanism according to claim 20 is characterized in that, the tooth of braking annular element be shaped as parallelepiped or cylinder, end at its mechanical cooperative end part with the hemisphere or the truncated cone.
23. according at least one described mechanism of claim 20-22, it is characterized in that the number of the tooth in each annular element preferably is 4 teeth of each annular element at least, the number of teeth and annular element be that the diameter ratio value of unit is 0.15-0.5 with the millimeter.
24. according at least one described mechanism among each and the claim 4-23 in claim 1 or 2 or 3, it is characterized in that, the guide piece of the relative interior stopper of external plug is positioned on one and another stopper one of the cylinder lateral sidewall and/or another, is positioned on the surface, inside of external plug and/or on the outer surface of inner stopper.
25. mechanism according to claim 24 is characterized in that, this guide piece has square by some, rectangle, triangular cross section, be positioned on the cylinder lateral sidewall and constitute along the thin slice that the bus of described wall is provided with.
26. according at least one described mechanism among each and the claim 4-23 in claim 1 or 2 or 3, it is characterized in that, the guide piece of the relative interior stopper of external plug also is the device that some directions that are screwed into along the mono-screw thread by external plug drive inner stopper simultaneously, and preferably is positioned on the whole height of cylinder lateral sidewall of two stoppers.
27. mechanism according to claim 25, it is characterized in that, some directions that are screwed into along screw thread by external plug lead simultaneously and the device that drives inner stopper is the thin slice of waveform feature with cross section of triangle or rectangle, its initial point is positioned on the bus of cylinder lateral surface, and its terminal point is orientated along clinoplane:
-when thin slice is externally on the surface, inside of the cylinder lateral sidewall of stopper, have on the direction of tendency entad,
-when thin slice is on the outer surface of the cylinder lateral sidewall of inner stopper, have on the direction of tendency to drift away.
CNB018199992A 2000-10-04 2001-10-04 Child-resistant safety closure Expired - Lifetime CN1258468C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0012667A FR2814724B1 (en) 2000-10-04 2000-10-04 SAFETY CLOSING DEVICE FOR CHILD-PROOF BY SCREWING A CONTAINER WITH A SCREW MOUTHPIECE
FR00/12667 2000-10-04

Publications (2)

Publication Number Publication Date
CN1478040A true CN1478040A (en) 2004-02-25
CN1258468C CN1258468C (en) 2006-06-07

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US (1) US20040045923A1 (en)
EP (1) EP1335864B1 (en)
JP (1) JP2004526631A (en)
CN (1) CN1258468C (en)
AT (1) ATE297350T1 (en)
AU (1) AU2001295660A1 (en)
CA (1) CA2424324C (en)
DE (1) DE60111416T2 (en)
ES (1) ES2243562T3 (en)
FR (1) FR2814724B1 (en)
WO (1) WO2002028737A1 (en)

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FR2814724B1 (en) 2003-04-04
CA2424324C (en) 2009-07-07
CA2424324A1 (en) 2002-04-11
JP2004526631A (en) 2004-09-02
FR2814724A1 (en) 2002-04-05
DE60111416D1 (en) 2005-07-14
EP1335864B1 (en) 2005-06-08
DE60111416T2 (en) 2006-03-16
AU2001295660A1 (en) 2002-04-15
US20040045923A1 (en) 2004-03-11
ES2243562T3 (en) 2005-12-01
WO2002028737A1 (en) 2002-04-11
CN1258468C (en) 2006-06-07
ATE297350T1 (en) 2005-06-15
EP1335864A1 (en) 2003-08-20

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