CN1471824A - Compound pesticide for preventing and treating rice sheath blight disease - Google Patents
Compound pesticide for preventing and treating rice sheath blight disease Download PDFInfo
- Publication number
- CN1471824A CN1471824A CNA031320503A CN03132050A CN1471824A CN 1471824 A CN1471824 A CN 1471824A CN A031320503 A CNA031320503 A CN A031320503A CN 03132050 A CN03132050 A CN 03132050A CN 1471824 A CN1471824 A CN 1471824A
- Authority
- CN
- China
- Prior art keywords
- jinggangmeisu
- sheath blight
- preventing
- recompounded pesticide
- blight disease
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000575 pesticide Substances 0.000 title claims abstract description 19
- 235000007164 Oryza sativa Nutrition 0.000 title claims abstract description 16
- 201000010099 disease Diseases 0.000 title claims abstract description 16
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 title claims abstract description 16
- 235000009566 rice Nutrition 0.000 title claims abstract description 16
- 240000007594 Oryza sativa Species 0.000 title claims 2
- 150000001875 compounds Chemical class 0.000 title 1
- 150000003851 azoles Chemical class 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000012752 auxiliary agent Substances 0.000 claims description 11
- 239000004615 ingredient Substances 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 239000000080 wetting agent Substances 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 241000209094 Oryza Species 0.000 abstract description 14
- 239000003814 drug Substances 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 8
- 229930195482 Validamycin Natural products 0.000 abstract description 4
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 abstract description 3
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 abstract 2
- -1 validamycin compound Chemical class 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 10
- 238000005303 weighing Methods 0.000 description 5
- 241001530056 Athelia rolfsii Species 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 241000233866 Fungi Species 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 206010033307 Overweight Diseases 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000813090 Rhizoctonia solani Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 230000009036 growth inhibition Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000002547 new drug Substances 0.000 description 1
- 235000020825 overweight Nutrition 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 210000001082 somatic cell Anatomy 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a new medicine for preventing and treating rice sheath blight disease, rice blast and false smut, which comprises hexaconazole and validamycin as effective components, wherein the hexaconazole and validamycin compound pesticide has obvious synergistic effect, avoids the negative effect of reducing field control effect by singly and frequently using validamycin in an excessive way, has scientific and better field control effect, has obvious economic benefit and has large-area popularization and application prospect.
Description
Technical field
The present invention relates to a kind of new drug of preventing and treating rice sheath blight disease, rice blast, false smut.
Background technology
Rice sheath blight disease is a kind of common disease, the frequently-occurring disease of China paddy rice.This disease surpasses reported first in 1934 by Wei Jing.Now spread all over each rice district of China, general south overweights the north, annual hundred million mu of the about 10-20 of area that take place.Light underproduction 5-10%, heavy reached at 50-70%.The control rice sheath blight disease mainly relies on chemical agent.Application of special effects medicine mazn before the beginning of the eighties, but mazn is a class organic arsenic preparation, contaminated environment not only very easily causes poisoning (can not ear) thereby is banned use of by country in paddy rice booting stage.Behind the mazn forbidding, alternative medicament mainly is a jinggangmeisu.Jinggangmeisu is a class antibiotic, finds that six effective ingredients are arranged the seventies by Shanghai pesticide research institute.But main active ingredient is based on the A component.Jinggangmeisu is similar by the Validamycin of Japan's military field pharmaceutical industries exploitation to 1972.Jinggangmeisu toxicity is low, and low price is the govern-house-variety of preventing and treating rice sheath blight disease since the early 1980's always.The mould poison in well ridge is the very strong agricultural antibiotic of interior absorption, after the mycelia of Rhizoctonia solani Kuhn touches this medicament, can be absorbed very soon and in thalline, conduct by mycelial cell, disturb and the normal development of inhibition somatic cells, thereby play therapeutic action, under laboratory condition, obviously growth is undesired behind the mycelia contact medicament, but after crossing certain hour, mycelial growth still can recover, so about general 7-10d of field efficacy phase.Though germ is not very too high to the pesticide resistance of jinggangmeisu, go up the long-term single jinggangmeisu that frequently excessively uses owing to produce, field efficacy descends to some extent, and the lasting period is short partially.
Own azoles alcohol is the domestic novel germicide of preventing and treating multiple diseases of exploitation in recent years.Its characteristics are super-high-efficient, high activity, and for example per hectare 30g prevents and treats the coffee rust, and effect is better than triazolone per hectare 250g low toxicity, the oral LD of rat acute
50Male 2189mg/kg, female 6071mg/kg; Not having obviously residually, is the up-and-coming bactericide of a class.But also be not used to prevent and treat rice sheath blight disease at present.
Summary of the invention
The purpose of this invention is to provide a kind of low toxicity, efficient, cheap, have the Recompounded pesticide of preventing and treating rice sheath blight disease of broad prospect of application.
Effective ingredient of the present invention is the pure and mild jinggangmeisu of own azoles.
Wherein, the effective ingredient of own azoles alcohol is 0.1g.a.i~10g.a.i; The jinggangmycin A composition is 1g.a.i~20g.a.i in the jinggangmeisu.
In research process of the present invention, respectively and composite jinggangmycin pure about own azoles have been carried out comparative study to inhibitory action, proportioning screening, synergy test and the field of rice sheath blight disease to the sheath blight disease controlling effect, obtained following achievements:
1, composite dose and single agent are to the toxicity regression of sheath blight fungus
Composite after measured dose and single agent to sheath blight fungus Growth Inhibition virulence regression equation are:
Jinggangmeisu: Y=3.1741+0.9908x r=0.9903
IC
50=69.6386mg/L
Own azoles alcohol: Y=5.3891+2.1394x r=0.9893
IC
50=0.65785mg/L
Own azoles alcohol and jinggangmeisu mixture: Y=5.7011+2.1354x r=0.9939
IC
50=0.4696mg/L
Y is the banded sclerotial blight repressed probability value of growing in the following formula, and x is the logarithm value of drug concentration, IC
50Be concentration in suppressing.The pure and mild jinggangmeisu ratio of own azoles is 1: 3.125 in composite dose of the following formula
2, coefficient of synergism
The toxicity index that with the jinggangmeisu is each medicament of standard medicament is TI
Well=100, TI
Oneself=10584.79, TI
Mix=14829.3
Composite dose theoretical toxicity index is TTI=2642.81
Co-toxicity coefficient is 561.12
Be synergy according to synergy criterion co-toxicity coefficient greater than 100, therefore own azoles alcohol and the mould composite extremely significant synergistic effect that has in well ridge.
3, composite dose of field efficacy to banded sclerotial blight
Through the test in Guangxi and Jiangsu field control banded sclerotial blight in 2 years, the result showed that composite dose has fabulous control efficiency to banded sclerotial blight.7d, 14d preventive effect be respectively up to 93.14-98.1%, 85.9-93% behind the medicine, and single with jinggangmeisu (every 667m
250g, 2 bags) preventive effect is respectively 79.4-85.2% and 64.8-82.9%, and composite dose preventive effect is significantly higher than singly uses jinggangmeisu.
Comprehensive indoor antibacterial test, co-toxicity coefficient and field control effect, own azoles alcohol has the notable synergistic effect with pesticide of composite jinggangmycin, avoid single frequent excessive use jinggangmeisu to reduce the negative interaction of field efficacy, have scientific and field efficacy effect preferably, its remarkable in economical benefits has the prospect of large scale application.
The present invention also can increase other auxiliary agent formation wetting powder and suspending agent is convenient to produce use.
Wherein, Recompounded pesticide is a wetting powder, and wherein auxiliary agent accounts for 5~20% of gross weight, and auxiliary agent mainly is made up of wetting agent, dispersant.
Recompounded pesticide is a suspending agent, and wherein auxiliary agent accounts for 5~10% of gross weight, and auxiliary agent mainly is made up of dispersant, wetting agent, thickener, stabilizing agent and defoamer.
Specific embodiment
Embodiment 1:
Preparation suspension pesticide 100kg takes by weighing own azoles alcohol, and making its effective ingredient is 4.8kg.a.i; Take by weighing jinggangmeisu, making its effective ingredient is 15kg.a.i; Take by weighing wetting agent NNO 5kg respectively, dispersant LS 5kg, thickener 0.5kg, stabilizing agent 0.5kg, defoamer 0.05kg, water 69.15kg fully mixes above-mentioned each component, and divides packing.
Thickener can be gum Arabic or methylcellulose or carboxymethyl cellulose or polyvinyl alcohol.
Defoamer can be the organosilicon anti-foaming agent.
Stabilizing agent can be a Magnesiumaluminumsilicate.
Embodiment 2:
Preparation Wettable pesticide powder 100kg.
Take by weighing own azoles alcohol, making its effective ingredient is 2.4kg.a.i; Take by weighing jinggangmeisu, making its effective ingredient jinggangmycin A is 7.5kg.a.i; Divide the dispersant LS 5kg that has another name called, lubricant NNO 5kg, inserts potter's clay 80.1kg fully mixes above-mentioned each component, and divides packing.
Claims (6)
1, a kind of Recompounded pesticide of preventing and treating rice sheath blight disease is characterized in that its effective ingredient is the pure and mild jinggangmeisu of own azoles.
2, according to the described Recompounded pesticide of claim 1, the effective ingredient that it is characterized in that own azoles alcohol is 0.1g.a.i~10g.a.i; The jinggangmycin A composition is 1g.a.i~20g.a.i in the jinggangmeisu.
3, according to the described Recompounded pesticide of claim 2, it is characterized in that Recompounded pesticide is a wetting powder, form by own azoles alcohol, jinggangmeisu and auxiliary agent, inserts, wherein auxiliary agent accounts for 5~20% of gross weight.
4,, it is characterized in that auxiliary agent mainly is made up of wetting agent, dispersant according to the described Recompounded pesticide of claim 3.
5, according to the described Recompounded pesticide of claim 2, it is characterized in that Recompounded pesticide is a suspending agent, form by own azoles alcohol, jinggangmeisu and auxiliary agent, water, wherein auxiliary agent accounts for 5~10% of gross weight.
6,, it is characterized in that auxiliary agent mainly is made up of dispersant, wetting agent, thickener, stabilizing agent and defoamer according to the described Recompounded pesticide of claim 5.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03132050 CN1193668C (en) | 2003-07-14 | 2003-07-14 | Application of compound pesticide in preventing and treating rice sheath blight disease |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03132050 CN1193668C (en) | 2003-07-14 | 2003-07-14 | Application of compound pesticide in preventing and treating rice sheath blight disease |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1471824A true CN1471824A (en) | 2004-02-04 |
CN1193668C CN1193668C (en) | 2005-03-23 |
Family
ID=34153963
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 03132050 Expired - Fee Related CN1193668C (en) | 2003-07-14 | 2003-07-14 | Application of compound pesticide in preventing and treating rice sheath blight disease |
Country Status (1)
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CN (1) | CN1193668C (en) |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100350840C (en) * | 2005-07-01 | 2007-11-28 | 浙江威尔达化工有限公司 | Bactericidal composition |
CN101032256B (en) * | 2007-04-13 | 2010-06-02 | 彭国均 | Pesticide of composite jinggangmycin |
CN103503889A (en) * | 2012-06-18 | 2014-01-15 | 张长平 | Compound insecticidal sterilization composition, and preparation and application thereof |
CN103734139A (en) * | 2013-12-28 | 2014-04-23 | 上海艳紫化工科技有限公司 | Pesticidal suspending agent obtained by compounding validamycin and hexaconazole |
CN104106574A (en) * | 2014-06-27 | 2014-10-22 | 何芳 | Sterilizing pesticide composition |
CN104957184A (en) * | 2015-08-06 | 2015-10-07 | 杨新兰 | Bactericide containing epoxiconazole and radix astragali |
CN105028525A (en) * | 2015-06-26 | 2015-11-11 | 芜湖福民生物药业有限公司 | Candicidin composition as well as preparation method and application thereof |
CN105053039A (en) * | 2015-08-06 | 2015-11-18 | 杨新兰 | Bactericide containing hexaconazole and radix astragali |
CN105145587A (en) * | 2015-10-26 | 2015-12-16 | 广西南宁益土生物科技有限责任公司 | Bactericide containing hexaconazole and cinnamyl aldehyde |
CN106614804A (en) * | 2016-12-23 | 2017-05-10 | 芜湖福民生物药业股份有限公司 | Validamycin composition for controlling rice sheath blight disease and preparation method thereof |
CN106718393A (en) * | 2016-11-29 | 2017-05-31 | 宜春学院 | Rice green smut prevention and controls |
CN106719822A (en) * | 2016-05-31 | 2017-05-31 | 徐挺 | A kind of sterilized compound and its application in agricultural chemicals |
CN108424275A (en) * | 2018-05-29 | 2018-08-21 | 青岛农业大学 | A kind of special foliage-spray medicine fertilizer of novel rice |
CN108424276A (en) * | 2018-05-29 | 2018-08-21 | 青岛农业大学 | A kind of special foliage-spray medicine fertilizer of novel rice |
CN109644996A (en) * | 2018-12-10 | 2019-04-19 | 上海惠光环境科技有限公司 | Suspension agent composition containing jinggangmycin A and hexaconazole |
EP3982731A4 (en) * | 2019-06-15 | 2023-07-19 | JDM Scientific Research Organisation Private Limited | Synergistic fungicidal composition |
-
2003
- 2003-07-14 CN CN 03132050 patent/CN1193668C/en not_active Expired - Fee Related
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100350840C (en) * | 2005-07-01 | 2007-11-28 | 浙江威尔达化工有限公司 | Bactericidal composition |
CN101032256B (en) * | 2007-04-13 | 2010-06-02 | 彭国均 | Pesticide of composite jinggangmycin |
CN103503889A (en) * | 2012-06-18 | 2014-01-15 | 张长平 | Compound insecticidal sterilization composition, and preparation and application thereof |
CN103734139B (en) * | 2013-12-28 | 2016-02-17 | 上海艳紫化工科技有限公司 | Jinggangmeisu and the composite agricultural chemicals suspension agent of own azoles alcohol |
CN103734139A (en) * | 2013-12-28 | 2014-04-23 | 上海艳紫化工科技有限公司 | Pesticidal suspending agent obtained by compounding validamycin and hexaconazole |
CN104106574A (en) * | 2014-06-27 | 2014-10-22 | 何芳 | Sterilizing pesticide composition |
CN105028525A (en) * | 2015-06-26 | 2015-11-11 | 芜湖福民生物药业有限公司 | Candicidin composition as well as preparation method and application thereof |
CN104957184A (en) * | 2015-08-06 | 2015-10-07 | 杨新兰 | Bactericide containing epoxiconazole and radix astragali |
CN105053039A (en) * | 2015-08-06 | 2015-11-18 | 杨新兰 | Bactericide containing hexaconazole and radix astragali |
CN105145587A (en) * | 2015-10-26 | 2015-12-16 | 广西南宁益土生物科技有限责任公司 | Bactericide containing hexaconazole and cinnamyl aldehyde |
CN106719822A (en) * | 2016-05-31 | 2017-05-31 | 徐挺 | A kind of sterilized compound and its application in agricultural chemicals |
CN106718393A (en) * | 2016-11-29 | 2017-05-31 | 宜春学院 | Rice green smut prevention and controls |
CN106614804A (en) * | 2016-12-23 | 2017-05-10 | 芜湖福民生物药业股份有限公司 | Validamycin composition for controlling rice sheath blight disease and preparation method thereof |
CN108424275A (en) * | 2018-05-29 | 2018-08-21 | 青岛农业大学 | A kind of special foliage-spray medicine fertilizer of novel rice |
CN108424276A (en) * | 2018-05-29 | 2018-08-21 | 青岛农业大学 | A kind of special foliage-spray medicine fertilizer of novel rice |
CN109644996A (en) * | 2018-12-10 | 2019-04-19 | 上海惠光环境科技有限公司 | Suspension agent composition containing jinggangmycin A and hexaconazole |
CN109644996B (en) * | 2018-12-10 | 2021-11-16 | 上海惠光环境科技有限公司 | Suspending agent composition containing validamycin A and hexaconazole |
EP3982731A4 (en) * | 2019-06-15 | 2023-07-19 | JDM Scientific Research Organisation Private Limited | Synergistic fungicidal composition |
Also Published As
Publication number | Publication date |
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CN1193668C (en) | 2005-03-23 |
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