CN104322549B - Composition pesticide containing pyrrole fluorine sulphur phosphorus and pleocidin - Google Patents
Composition pesticide containing pyrrole fluorine sulphur phosphorus and pleocidin Download PDFInfo
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- CN104322549B CN104322549B CN201410647695.2A CN201410647695A CN104322549B CN 104322549 B CN104322549 B CN 104322549B CN 201410647695 A CN201410647695 A CN 201410647695A CN 104322549 B CN104322549 B CN 104322549B
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- sulphur phosphorus
- pyrrole fluorine
- fluorine sulphur
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- 239000000203 mixture Substances 0.000 title claims abstract description 60
- ZBXICRCDECBVDN-UHFFFAOYSA-N [P].[S].[F].N1C=CC=C1 Chemical compound [P].[S].[F].N1C=CC=C1 ZBXICRCDECBVDN-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000000575 pesticide Substances 0.000 title claims abstract description 19
- 241000238631 Hexapoda Species 0.000 claims abstract description 12
- 241000244206 Nematoda Species 0.000 claims abstract description 9
- 238000010413 gardening Methods 0.000 claims abstract description 5
- 238000005507 spraying Methods 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 13
- 241000607479 Yersinia pestis Species 0.000 claims description 10
- 241000256247 Spodoptera exigua Species 0.000 claims description 9
- 241000243785 Meloidogyne javanica Species 0.000 claims description 8
- 241000344246 Tetranychus cinnabarinus Species 0.000 claims description 7
- 235000018290 Musa x paradisiaca Nutrition 0.000 claims description 6
- 241000196324 Embryophyta Species 0.000 claims description 5
- 241000255777 Lepidoptera Species 0.000 claims description 3
- 240000005561 Musa balbisiana Species 0.000 claims 1
- 239000003814 drug Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 13
- 231100000225 lethality Toxicity 0.000 description 12
- 230000002195 synergetic effect Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 7
- 230000003449 preventive effect Effects 0.000 description 6
- 241000234295 Musa Species 0.000 description 5
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 description 4
- AZSNMRSAGSSBNP-UHFFFAOYSA-N 22,23-dihydroavermectin B1a Natural products C1CC(C)C(C(C)CC)OC21OC(CC=C(C)C(OC1OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C1)C(C)C=CC=C1C3(C(C(=O)O4)C=C(C)C(O)C3OC1)O)CC4C2 AZSNMRSAGSSBNP-UHFFFAOYSA-N 0.000 description 3
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 description 3
- 239000005660 Abamectin Substances 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 229960002418 ivermectin Drugs 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 2
- 241001454293 Tetranychus urticae Species 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 description 1
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 description 1
- 240000000905 Nymphoides indica Species 0.000 description 1
- 235000017590 Nymphoides indica Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000005939 Tefluthrin Substances 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 235000010749 Vicia faba Nutrition 0.000 description 1
- 235000002098 Vicia faba var. major Nutrition 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- RQFQJYYMBWVMQG-IXDPLRRUSA-N chitotriose Chemical compound O[C@@H]1[C@@H](N)[C@H](O)O[C@H](CO)[C@H]1O[C@H]1[C@H](N)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)N)[C@@H](CO)O1 RQFQJYYMBWVMQG-IXDPLRRUSA-N 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 1
- 229960001591 cyfluthrin Drugs 0.000 description 1
- JZUKGAJJLZRHGL-UHFFFAOYSA-N diethoxy-[2-phenyl-5-(trifluoromethyl)pyrazol-3-yl]oxy-sulfanylidene-lambda5-phosphane Chemical compound CCOP(=S)(OCC)OC1=CC(C(F)(F)F)=NN1C1=CC=CC=C1 JZUKGAJJLZRHGL-UHFFFAOYSA-N 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical compound CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- -1 pleocidin Chemical compound 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of composition pesticide containing pyrrole fluorine sulphur phosphorus and pleocidin, the ratio of quality and the number of copies of pyrrole fluorine sulphur phosphorus component and pleocidin component is 30: 1-1: 30, composition is applied to crop or crop part by spraying, filling root or seed dressing, the insect of control agricultural, gardening or forestry plant, harmful mite or nematode.
Description
The application is the divisional application of " composition pesticide containing pyrrole fluorine sulphur phosphorus " application for a patent for invention, original application day: on November 21st, 2013, application number: 2013105935881
Technical field
The present invention relates to a kind of composition pesticide, be specifically related to a kind of containing pyrrole fluorine sulphur phosphorus to agricultural, gardening, forest pest, do harm to the synergistic composition that mite, nematode have excellent results.
Background technology
Pyrrole fluorine sulphur phosphorus (flupyrazofos) is organic phosphates new pesticides, has excellent preventive effect to the insect of various crop, especially has excellent effect to lepidoptera pest.For Reasonable Protection medicament, delay insect to the drug-fast generation of new medicament and the control efficiency improving medicament, be necessary to carry out rational composition research.Compounded pesticides containing the pyrrole fluorine sulphur phosphorus research of having announced at present is less, and the present invention found through experiments the composition pesticide of synergistic effect significantly containing pyrrole fluorine sulphur phosphorus.
Summary of the invention
The object of the present invention is to provide a kind of composition pesticide containing pyrrole fluorine sulphur phosphorus preventing and treating the insect of plant, harmful mite, nematode, it is undertaken composite by the composition of two kinds of different structures and mechanism of action, reach expanding prevention spectrum and improve drug effect, the more important thing is and avoid or delay the generation of insect to new composition resistance.
The object of the invention is to be realized by following measures.
The invention provides a kind of composition pesticide containing pyrrole fluorine sulphur phosphorus, it is characterized in that said composition includes component A and the B component of effective amount, component A is pyrrole fluorine sulphur phosphorus, B component be selected from Avermectin, pleocidin, emamectin-benzoate (calling emamectin benzoate in the following text), ivermectin, beta-cypermethrin, Cyhalothrin, tefluthrin, cyfluthrin, ethiprole, chitosan oligosaccharide one or more.
In above-mentioned composition, the ratio of quality and the number of copies of component A and B component is 30:1-1:30.
In above-mentioned composition of the present invention, the quality sum of component A and B component accounts for the 1-60% of composition gross mass.
Present invention also offers above-mentioned composition for preventing and treating the method for crop pest, it is characterized in that composition to be applied to crop by spraying, filling root or seed dressing.
Above-mentioned pest, refers to the cause harm insect of agricultural, gardening or forestry plant, harmful mite or nematode, preferably, insect is lepidoptera pest, and evil mite is Tetranychus cinnabarinus, and nematode is root-knot nematode, preferred further, insect is lepidopterous beet armyworm, and nematode is banana root-knot nematode.
Beneficial effect of the present invention is:
1, synergistic effect is obvious: composition shows good synergistic effect in certain ratio range, improves the effect of composition.
2, use cost is reduced: because of composite, there is raising preventive effect, the increase of control spectrum, decrease access times, reduce use cost;
3, delay pesticide resistance: the composition of two kinds of different mechanism of action is composite, and pest not easily develops immunity to drugs, delay insect to the drug-fast generation of single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but the present invention is never limited to following embodiment.
Embodiment 1 contains pyrrole fluorine sulphur phosphorus composition pesticide to the effect of Laphygma exigua Hubner
The beet armyworm that test adopts field to gather, for test after raising for 2 generations.Concrete grammar is as follows:
Leaf dish prepares: choose clean luxuriant dish, clean and dry, make into leaf dish for subsequent use with card punch.
Medicament is prepared: before test, former medicine is mixed with different concentration according to mix proportion scheme.
Dipping: soak 5 seconds with tweezers gripping leaf dish in liquid, take out and dry in the air on blotting paper, be put in 24 orifice plates after natural air drying, 2, every hole.3 plates are put in every concentration process altogether.
Connect worm: 1 beet armyworm 3 instar larvae is put in the 24 every holes of orifice plate, put into after building in insectary (25 ± 1 DEG C, 12H/12H).
Investigation statistics: process and check dead borer population after 48 hours, according to following formulae discovery synergistic action effect.
In theoretical lethality formula, the lethality of the medicament A that x is concentration when being a, the lethality of the medicament B that y is concentration when being b, more theoretical lethality and actual, evaluate the synergy of composition.Be synergistic effect when actual is greater than theoretical lethality, be antagonism when being less than theoretical lethality, test result is in table 1.
Table 1 composition is to the effect of Laphygma exigua Hubner
The effect of composition to Laphygma exigua Hubner is shown in Table 1, and can find out, relative to single dose, composition when active ingredient proportioning is 30:1-1:30, composition to the actual preventive effect of Laphygma exigua Hubner all higher than the theoretical preventive effect of composition; So, the composition of the composition of the composition of the composition of the composition of the composition of pyrrole fluorine sulphur phosphorus and Avermectin, pyrrole fluorine sulphur phosphorus and pleocidin, pyrrole fluorine sulphur phosphorus and emamectin benzoate, pyrrole fluorine sulphur phosphorus and ivermectin, pyrrole fluorine sulphur phosphorus and beta-cypermethrin, pyrrole fluorine sulphur phosphorus and Cyhalothrin is synergy to the synergy of Laphygma exigua Hubner, raising drug effect can be reached, reduce times for spraying, be beneficial to and increase economic efficiency and environmental ecology.
The composition pesticide of embodiment 2 containing pyrrole fluorine sulphur phosphorus is to the effect of two spotted spider mite
Examination worm: indoor broad bean seedling raises Tetranychus cinnabarinus throughout the year, before test, two-sided tape is attached to one end of slide, selects with writing brush and expand numerous length of time consistent one-tenth mite and be instead posted on adhesive tape, about 50, every slide note, is put in and is covered with in the 9cm culture dish of filter paper moisturizing.Microscopy after 2 hours, discards dead polypide.
Medicament is prepared: before test, former medicine is mixed with different concentration according to mix proportion scheme.
Dipping: from low concentration, pick up slide with tweezers, immersed the one end being stained with mite in concentration series solution to be measured, shake gently after 3 seconds and take out, elimination liquid also sucks unnecessary liquid with blotting paper, is put in culture dish.Every concentration 3 slides.
Investigation statistics: process and check two spotted spider mite death toll after 48 hours, according to following formulae discovery synergistic action effect.
In theoretical lethality formula, the lethality of the medicament A that x is concentration when being a, the lethality of the medicament B that y is concentration when being b, more theoretical lethality and actual, evaluate the synergy of composition.Be synergistic effect when actual is greater than theoretical lethality, be antagonism when being less than theoretical lethality, test result is in table 2.
Table 2 composition is to the effect of Tetranychus cinnabarinus
The effect of composition to Tetranychus cinnabarinus is shown in Table 2, and can find out, relative to single dose, composition under active ingredient proportioning is 30:1-1:30, composition to the actual preventive effect of Tetranychus cinnabarinus all higher than the theoretical preventive effect of composition; So, the composition of the composition of the composition of the composition of the composition of the composition of pyrrole fluorine sulphur phosphorus and Avermectin, pyrrole fluorine sulphur phosphorus and pleocidin, pyrrole fluorine sulphur phosphorus and emamectin benzoate, pyrrole fluorine sulphur phosphorus and ivermectin, pyrrole fluorine sulphur phosphorus and fenpropathrin, pyrrole fluorine sulphur phosphorus and Cyhalothrin is synergy to the synergy of Tetranychus cinnabarinus, raising drug effect can be reached, reduce times for spraying, be beneficial to and increase economic efficiency and environmental ecology.
The composition pesticide of embodiment 3 containing pyrrole fluorine sulphur phosphorus is to the effect of banana root-knot nematode
Be mixed into compost with sterilized soil and sterilizing river sand, fully after mixing, be mixed into medicament.Drug concentration contains the milligram number of the active ingredient of this medicament in every kilogram of soil, directly soil is mixed with corresponding dosage formulation, add clear water after fully mixing thoroughly and make water content 30%, mix rear quantitative loading basin alms bowl again thoroughly, the banana seedlings of growth 20d is transplanted in basin, transplants latter 7 days, every basin access root-knot nematode 2 instar larvae 500, be placed in greenhouse, Routine Management.Every chemicals treatment 6 basin, and be set to blank.The root knot number of the every basin plant of 40d " Invest, Then Investigate ", and carry out classification by Liu Weizhi (1995): 0 grade, without root knot; 1 grade, 1-2 root knot; 2 grades, 3-10 root knot; 3 grades, 11-30 root knot; 4 grades, 31-100 root knot; 5 grades, more than 100 root knots.Tiled by banana plant, statistics root knot number, the effect of different disposal is in table 3.
As seen from Table 3, after 40d, under same medicine concentration, root knot mean containing the banana of the different components process of pyrrole fluorine sulphur phosphorus is obviously less than the root knot number of corresponding single dose process, visible, containing pyrrole fluorine sulphur phosphorus composition pesticide to root-knot nematode higher than single dose, composition has synergistic effect.
The composition pesticide of table 3 containing pyrrole fluorine sulphur phosphorus is to the effect of banana root-knot nematode
Claims (9)
1. the composition pesticide containing pyrrole fluorine sulphur phosphorus, it is characterized in that said composition includes component A and the B component of effective amount, component A is pyrrole fluorine sulphur phosphorus, and B component is pleocidin, and the ratio of quality and the number of copies of component A and B component is 30:1-1:30.
2. composition pesticide according to claim 1, is characterized in that the quality sum of component A and B component accounts for the 1-60% of composition gross mass.
3. composition pesticide according to claim 1 and 2 is for preventing and treating the method for crop pest, it is characterized in that composition to be applied to crop by spraying, filling root or seed dressing.
4. method according to claim 3, is characterized in that crop pest refers to cause harm the insect of agricultural, gardening or forestry plant.
5. method according to claim 3, is characterized in that crop pest refers to cause harm the harmful mite of agricultural, gardening or forestry plant or nematode.
6. method according to claim 4, is characterized in that insect is lepidoptera pest.
7. method according to claim 5, it is characterized in that evil mite is Tetranychus cinnabarinus, nematode is root-knot nematode.
8. method according to claim 6, is characterized in that insect is lepidopterous beet armyworm.
9. method according to claim 7, is characterized in that nematode is banana root-knot nematode.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310593588.1A CN103651553B (en) | 2013-11-21 | 2013-11-21 | Flupyrazofos-containing pesticide composition |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310593588.1A Division CN103651553B (en) | 2013-11-21 | 2013-11-21 | Flupyrazofos-containing pesticide composition |
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| Publication Number | Publication Date |
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| CN104322549A CN104322549A (en) | 2015-02-04 |
| CN104322549B true CN104322549B (en) | 2015-12-30 |
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| CN201310593588.1A Active CN103651553B (en) | 2013-11-21 | 2013-11-21 | Flupyrazofos-containing pesticide composition |
| CN201410647695.2A Active CN104322549B (en) | 2013-11-21 | 2013-11-21 | Composition pesticide containing pyrrole fluorine sulphur phosphorus and pleocidin |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310593588.1A Active CN103651553B (en) | 2013-11-21 | 2013-11-21 | Flupyrazofos-containing pesticide composition |
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| CN104430496B (en) * | 2014-10-15 | 2016-08-24 | 刘国利 | For preventing and treating the Pesticidal combination of pear tree snout moth class pest |
| CN115399329A (en) * | 2022-06-17 | 2022-11-29 | 中国农业科学院植物保护研究所 | Synergistic pesticide composition containing spinosad and acephate and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4822779A (en) * | 1988-03-26 | 1989-04-18 | Korea Research Institute Of Chemical Technology | Phosphoric and thiophosphonic acid derivatives of 5-hydroxypyrazoles, compositions and use |
| CN1332171A (en) * | 2000-06-27 | 2002-01-23 | 韩国化学研究所 | Improved prep. of 3-trifluoro methyl-5-hydroxy-pyrazole phosphate derivatives in the presence of hydrosolvent |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009132670A (en) * | 2007-11-09 | 2009-06-18 | Sumitomo Chemical Co Ltd | Pest-controlling composition |
| WO2010069763A2 (en) * | 2008-12-16 | 2010-06-24 | Basf Se | Synergistic fungicidal mixtures |
-
2013
- 2013-11-21 CN CN201310593588.1A patent/CN103651553B/en active Active
- 2013-11-21 CN CN201410647695.2A patent/CN104322549B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4822779A (en) * | 1988-03-26 | 1989-04-18 | Korea Research Institute Of Chemical Technology | Phosphoric and thiophosphonic acid derivatives of 5-hydroxypyrazoles, compositions and use |
| CN1332171A (en) * | 2000-06-27 | 2002-01-23 | 韩国化学研究所 | Improved prep. of 3-trifluoro methyl-5-hydroxy-pyrazole phosphate derivatives in the presence of hydrosolvent |
Non-Patent Citations (2)
| Title |
|---|
| Developmental toxicity of flupyrazofos, a new organophosphorus insecticide, in rats;M K Chung et al;《Food and Chemical Toxicology》;20021231;第40卷;723-729 * |
| 含氟农药开发的新进展;刘长令;《精细与专用化学品》;20001231(第6期);3-6 * |
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| Publication number | Publication date |
|---|---|
| CN104322549A (en) | 2015-02-04 |
| CN103651553A (en) | 2014-03-26 |
| CN103651553B (en) | 2014-12-17 |
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