CN1454909A - 衣康酸共聚物及其制备方法和应用 - Google Patents
衣康酸共聚物及其制备方法和应用 Download PDFInfo
- Publication number
- CN1454909A CN1454909A CN 03112046 CN03112046A CN1454909A CN 1454909 A CN1454909 A CN 1454909A CN 03112046 CN03112046 CN 03112046 CN 03112046 A CN03112046 A CN 03112046A CN 1454909 A CN1454909 A CN 1454909A
- Authority
- CN
- China
- Prior art keywords
- methyl
- sodium
- acid
- potassium
- kilograms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 229920001577 copolymer Polymers 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 45
- -1 (methyl) propylene sulfonate Chemical compound 0.000 claims abstract description 43
- 239000003999 initiator Substances 0.000 claims abstract description 31
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000011591 potassium Substances 0.000 claims abstract description 26
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 26
- 239000011734 sodium Chemical group 0.000 claims abstract description 25
- 229910052708 sodium Chemical group 0.000 claims abstract description 25
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 18
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 17
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 17
- 239000000178 monomer Substances 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 4
- 239000007864 aqueous solution Substances 0.000 claims abstract description 3
- 238000006467 substitution reaction Methods 0.000 claims abstract description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 31
- 239000003125 aqueous solvent Substances 0.000 claims description 27
- 239000002253 acid Substances 0.000 claims description 19
- XZSFYGAQHBNTKT-UHFFFAOYSA-N but-2-ene-2-sulfonic acid Chemical class CC=C(C)S(O)(=O)=O XZSFYGAQHBNTKT-UHFFFAOYSA-N 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 8
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 8
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 7
- 239000011790 ferrous sulphate Substances 0.000 claims description 7
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 7
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 7
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 7
- 238000005260 corrosion Methods 0.000 claims description 6
- 230000007797 corrosion Effects 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- JHUFGBSGINLPOW-UHFFFAOYSA-N 3-chloro-4-(trifluoromethoxy)benzoyl cyanide Chemical compound FC(F)(F)OC1=CC=C(C(=O)C#N)C=C1Cl JHUFGBSGINLPOW-UHFFFAOYSA-N 0.000 claims description 5
- 208000006558 Dental Calculus Diseases 0.000 claims description 5
- 239000004159 Potassium persulphate Substances 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 235000019394 potassium persulphate Nutrition 0.000 claims description 5
- 239000004160 Ammonium persulphate Substances 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 4
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 4
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 4
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 claims description 4
- 235000019252 potassium sulphite Nutrition 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 3
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 3
- JPAOMENBKRZQDR-UHFFFAOYSA-N CC=CC.[Na] Chemical compound CC=CC.[Na] JPAOMENBKRZQDR-UHFFFAOYSA-N 0.000 claims description 3
- IPERVKGUUZSAHJ-UHFFFAOYSA-N [Na].C(C)C=CC Chemical compound [Na].C(C)C=CC IPERVKGUUZSAHJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 3
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 3
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 3
- 235000015067 sauces Nutrition 0.000 claims description 3
- KSMWLICLECSXMI-UHFFFAOYSA-N sodium;benzene Chemical compound [Na+].C1=CC=[C-]C=C1 KSMWLICLECSXMI-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 150000003254 radicals Chemical class 0.000 claims description 2
- DZGJGJJFKQDPMI-UHFFFAOYSA-N [K].C(=CC)S(=O)(=O)O Chemical compound [K].C(=CC)S(=O)(=O)O DZGJGJJFKQDPMI-UHFFFAOYSA-N 0.000 claims 1
- DCMRFHAITUGHAO-UHFFFAOYSA-N [K].C(C)C=CC Chemical compound [K].C(C)C=CC DCMRFHAITUGHAO-UHFFFAOYSA-N 0.000 claims 1
- PFQRYNJOKJDGQL-UHFFFAOYSA-N [K].C1(=CC=CC=C1)C(=CC)S(=O)(=O)O Chemical compound [K].C1(=CC=CC=C1)C(=CC)S(=O)(=O)O PFQRYNJOKJDGQL-UHFFFAOYSA-N 0.000 claims 1
- 239000002455 scale inhibitor Substances 0.000 abstract description 3
- 125000000542 sulfonic acid group Chemical group 0.000 abstract description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 abstract 1
- OELQSSWXRGADDE-UHFFFAOYSA-N 2-methylprop-2-eneperoxoic acid Chemical compound CC(=C)C(=O)OO OELQSSWXRGADDE-UHFFFAOYSA-N 0.000 abstract 1
- 229910006127 SO3X Inorganic materials 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 18
- WSNSMPZJJIYZCV-UHFFFAOYSA-N [Na]C Chemical compound [Na]C WSNSMPZJJIYZCV-UHFFFAOYSA-N 0.000 description 13
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000005764 inhibitory process Effects 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical group CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229920005613 synthetic organic polymer Polymers 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
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CN 03112046 CN1230456C (zh) | 2003-03-25 | 2003-03-25 | 衣康酸共聚物及其制备方法和应用 |
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CN 03112046 CN1230456C (zh) | 2003-03-25 | 2003-03-25 | 衣康酸共聚物及其制备方法和应用 |
Publications (2)
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CN1454909A true CN1454909A (zh) | 2003-11-12 |
CN1230456C CN1230456C (zh) | 2005-12-07 |
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CN 03112046 Expired - Fee Related CN1230456C (zh) | 2003-03-25 | 2003-03-25 | 衣康酸共聚物及其制备方法和应用 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103232571A (zh) * | 2013-04-08 | 2013-08-07 | 青岛科海生物有限公司 | 一种环保型衣康酸聚合物水处理剂的生产方法 |
CN103319658A (zh) * | 2013-07-01 | 2013-09-25 | 河北省科学院能源研究所 | 一种含有膦基和磺酸基的衣康酸聚合物及其制备方法 |
JP2017510693A (ja) * | 2014-03-14 | 2017-04-13 | ルブリゾル アドバンスド マテリアルズ, インコーポレイテッド | イタコン酸ポリマーおよびコポリマー |
CN109012190A (zh) * | 2018-09-18 | 2018-12-18 | 山东日益环保科技有限公司 | 一种反渗透阻垢剂及其制备方法和应用 |
CN109879451A (zh) * | 2019-04-04 | 2019-06-14 | 河北省科学院能源研究所 | 一种共聚物水处理剂的制备方法 |
-
2003
- 2003-03-25 CN CN 03112046 patent/CN1230456C/zh not_active Expired - Fee Related
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103232571A (zh) * | 2013-04-08 | 2013-08-07 | 青岛科海生物有限公司 | 一种环保型衣康酸聚合物水处理剂的生产方法 |
CN103232571B (zh) * | 2013-04-08 | 2015-11-25 | 青岛科海生物有限公司 | 一种环保型衣康酸聚合物水处理剂的生产方法 |
CN103319658A (zh) * | 2013-07-01 | 2013-09-25 | 河北省科学院能源研究所 | 一种含有膦基和磺酸基的衣康酸聚合物及其制备方法 |
CN103319658B (zh) * | 2013-07-01 | 2016-01-13 | 河北省科学院能源研究所 | 一种含有膦基和磺酸基的衣康酸聚合物及其制备方法 |
JP2017510693A (ja) * | 2014-03-14 | 2017-04-13 | ルブリゾル アドバンスド マテリアルズ, インコーポレイテッド | イタコン酸ポリマーおよびコポリマー |
JP2020063458A (ja) * | 2014-03-14 | 2020-04-23 | ルブリゾル アドバンスド マテリアルズ, インコーポレイテッド | イタコン酸ポリマーおよびコポリマー |
US11214758B2 (en) | 2014-03-14 | 2022-01-04 | Lubrizol Advanced Materials, Inc. | Itaconic acid polymers and copolymers |
CN109012190A (zh) * | 2018-09-18 | 2018-12-18 | 山东日益环保科技有限公司 | 一种反渗透阻垢剂及其制备方法和应用 |
CN109879451A (zh) * | 2019-04-04 | 2019-06-14 | 河北省科学院能源研究所 | 一种共聚物水处理剂的制备方法 |
CN109879451B (zh) * | 2019-04-04 | 2022-06-03 | 河北省科学院能源研究所 | 一种共聚物水处理剂的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN1230456C (zh) | 2005-12-07 |
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C14 | Grant of patent or utility model | ||
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EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Qingdao Kehai Biological Co., Ltd. Assignor: Qingdao Langyatai (Group) Co., Ltd. Contract record no.: 2011370000396 Denomination of invention: Itaconic acid copolymer, and preparing method and use thereof Granted publication date: 20051207 License type: Exclusive License Open date: 20031112 Record date: 20110824 |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20051207 Termination date: 20150325 |
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