CN1414045A - Super environmental protection latex paint with zero VOC - Google Patents
Super environmental protection latex paint with zero VOC Download PDFInfo
- Publication number
- CN1414045A CN1414045A CN 02135025 CN02135025A CN1414045A CN 1414045 A CN1414045 A CN 1414045A CN 02135025 CN02135025 CN 02135025 CN 02135025 A CN02135025 A CN 02135025A CN 1414045 A CN1414045 A CN 1414045A
- Authority
- CN
- China
- Prior art keywords
- name
- commodity
- environmental protection
- defoamer
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
An environment protection type emulsoid paint without VOC is prepared from water, sodium polyacrylate "5040", hydroxyethyl cellulose "250HBR", mineral oil modified silicone BYK-003, titanium white powder, filming agent and assistant. Its advantages are high hardness and adhesion, high resistance to dirt, zero VOC and no poison and harm.
Description
Technical field
The present invention relates to a kind of emulsion paint, specifically relate to be suitable for interior exterior wall finishing, can be applied to the aqueous latex paint with holding property of high-quality environment protective on surfaces such as cement, mortar, plaster, uralite, trinity mixture fill.
Background technology
At present, international and domestic environmental protection cry is more and more higher, and internally the restriction of outer wall paint VOC is also more and more tighter, however the VOC of domestic most emulsion paints all more than 60, What is more about 200.And the consumption of emulsion paint is to increase progressively every year, though be water-based therefore, can not underestimate environmental pollution, and be that considerable influence is arranged to HUMAN HEALTH.So people adopt multiple mode to solve the environmental issue of emulsion paint, yet, the environmental issue that solves emulsion paint at present can only be to sacrifice its performance and more expensive cost is made cost, as application number is 99107852, the applying date is on June 3rd, 1999, denomination of invention is the patent application of environment protection-type high-quality emulsoid paint, it comprises phenylpropyl alcohol or pure third, acrylate and vinyl acetate emulsion, membrane-forming agent, color stuffing, dispersion agent, the PH conditioning agent, defoamer, help defoamer, sanitas, thickening material, water, make by general emulsion paint manufacturing process, described membrane-forming agent is the higher alcohols of commodity CA-03 by name, ester organic compound, consumption are 1%～4% (weight meter); Described thickening material is the methacrylic acid of commodity ATX-01 by name and the cross-linked type latex emulsion resin of ethyl propenoate copolymerization, consumption 2.0%～5.0%; Described sanitas is for containing active ingredient 1,3, the described sanitas of Y N-series of 5-trihydroxyethyl s-triazine, 2-methyl-4-isothiazoline-3-ketone or 5-chloro-2-methyl-4-isothiazoline-3-ketone is for containing active ingredient 1,3, the YN-series of 5-trihydroxyethyl s-triazine, 2-methyl-4-isothiazoline-3-ketone or 5-chloro-2-methyl-4-isothiazoline-3-ketone, consumption 0.05%～0.08%.But film-forming temperature height, cost height, performances such as its hardness, sticking power, anti-pickup are still waiting further raising, and contain VOC.
Summary of the invention
The object of the present invention is to provide that a kind of high temperature does not after-tack, hardness, sticking power, polluting proofing property is higher than the generic latex lacquer, its VOC amount approaches zero; But and low temperature film forming (5 degrees centigrade), functional, nontoxic, harmless, really meet the super environmental protection latex paint of environmental protection characteristic requirement.
The present invention adopts following prescription to realize above-mentioned purpose: the super environmental protection latex paint of this zero VOC is made of water, dispersion agent, thickening material, defoamer, color stuffing, filmogen, other auxiliary agent, its prescription (part is the weight meter) composed as follows:
Water 5-20%
Dispersion agent 0.2-0.5%
Thickening material 0.2-1%
Defoamer 0.1-0.4%
Color stuffing 20-35%
Filmogen 30-55%
Other auxiliary agent 0.5-1.5%
The mixture of one or more of the dispersant A that wherein, dispersion agent selects that the polyacrylic acid sodium salt commodity are by name 5040 for use, poly carboxylic acid ammonia ammonium salt commodity are by name 5027, ammonium polyacrylate salt commodity A40 by name, modified polypropene acid sodium-salt trade(brand)name are 731-A, vinylformic acid phosphoric acid vinegar multipolymer sodium salt;
Thickening material selects for use Natvosol class commodity to be called one or more the mixture of 250HBR, Qp15000H, H6000yp2, commodity TR117, polyurethane thickener H600 by name;
Defoamer is selected one or more the mixture of mineral oil modified silicone Byk-003, CF-107,681-F, FStarA34 (a kind of defoamer that does not contain organic solvent of Henkel KGaA production), SNZ345 (Henkel KGaA is produced the mineral oil modified silicone) etc. for use;
Color stuffing is selected titanium white, dicalcium powder, kaolin, talcum powder for use;
Filmogen adopts pure third polymkeric substance of nucleocapsid structure.
Adopt above-mentioned super environmental protection latex paint beneficial effect to be:
1, make simply, the desired raw material kind is simplified, and cost is lower than like product;
2, its volatile organic matter quantity discharged is similar to zero;
But 3, low temperature film forming (5 degrees centigrade);
4, high temperature does not after-tack, and hardness is strong, scrubbing resistance, anti-aging, and strong adhesion good film-forming property, density height are so pollution resistance is better, and be higher than the generic latex lacquer;
5. have permanent stability preferably, life-time service can not produce and split phenomenon, good decorating effect, easy construction cruelly;
6, zero VOC is nontoxic, safe and reliable, is a kind of environment friendly emulsion paint truly.Be described further below in conjunction with embodiment.
Embodiment
The concrete prescription of the present invention can by in the following example the preparation (by 100 parts):
Water 15
Dispersion agent ammonium polyacrylate salt commodity are called A40 0.5
Thickening material Natvosol class commodity are called 250HBR 0.5
Defoamer mineral oil modified silicone commodity are called CF-107 0.3
Color stuffing titanium dioxide 30
Pure third polymkeric substance 53 of filmogen nucleocapsid structure
Other auxiliary agent commodity are called EPW B110 0.7
The blending process of above-mentioned prescription can adopt following step:
1,, adds color stuffing with dispersion agent, thickening material, defoamer mixing in water;
2, high speed dispersion is qualified to fineness, adds selected filmogen and other auxiliary agent under low speed;
3, after the assay was approved, filter and package.
According to described method and proportioning, according to its performance index of GB GB/T9756-2001 " synthetic resin emulsion interior wall coating " standard testing, the gained result is as follows:
| Test item title and unit | Technical requirements | Assay | Individual event is judged |
| Condition in container | No lump is uniform state after the stirring | Meet | |
| Application property | It is accessible to brush two roads | Meet | |
| Low-temperature stability | Never degenerate | Meet | |
| Time of drying (surface drying)/h | ????≤2 | Meet | |
| Appearance of film | Normally | Meet | |
| Contrast ratio (white and light color) | ????≥0.95 | ????0.96 | |
| Alkali resistance | 24h is no abnormal | Meet | |
| Abrasion resistance/time | ????≥1000 | ????＞10000 |
As can be seen from the table, every performance index of the present invention all reach or are better than the GB standard, can confirm of the present invention high-quality thus.
Claims (2)
1. the super environmental protection latex paint of one kind zero VOC is made of water, dispersion agent, thickening material, defoamer, color stuffing, filmogen, other auxiliary agent, it is characterized in that, its prescription consists of (part is the weight meter):
Water 5-20%
Dispersion agent 0.2-0.5%
Thickening material 0.2-1%
Defoamer 0.1-0.4%
Color stuffing 20-35%
Filmogen 30-55%
Other auxiliary agent 0.5-1.5%
2. the super environmental protection latex paint of zero VOC according to claim 1, it is characterized in that it is one or more the mixture of vinylformic acid phosphoric acid vinegar multipolymer sodium salt of modified polypropene acid sodium-salt, the commodity dispersant A by name of ammonium polyacrylate salt, the commodity 731-A by name of poly carboxylic acid ammonia ammonium salt, the commodity A40 by name of 5040 polyacrylic acid sodium salt, commodity by name 5027 that described dispersion agent can be selected trade(brand)name for use;
It is one or more the mixture of polyurethane thickener of Natvosol, commodity TR117 by name, the commodity H600 by name of 250HBR, Qp15000H, H6000yp2 that thickening material can be selected trade(brand)name for use;
Defoamer can select for use trade(brand)name to be respectively one or more mixture of the mineral oil modified silicone of byk-003, CF-107,681-F, FStarA34, SNZ345;
Color stuffing can be selected titanium dioxide, dicalcium powder, kaolin, talcum powder for use;
Filmogen adopts pure third polymkeric substance of nucleocapsid structure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02135025 CN1414045A (en) | 2002-10-25 | 2002-10-25 | Super environmental protection latex paint with zero VOC |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02135025 CN1414045A (en) | 2002-10-25 | 2002-10-25 | Super environmental protection latex paint with zero VOC |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1414045A true CN1414045A (en) | 2003-04-30 |
Family
ID=4748002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02135025 Pending CN1414045A (en) | 2002-10-25 | 2002-10-25 | Super environmental protection latex paint with zero VOC |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1414045A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1304494C (en) * | 2005-01-13 | 2007-03-14 | 山东科技大学 | Environmental protection moisture adjustable emulsion paint |
| CN101200606B (en) * | 2007-10-31 | 2010-09-08 | 傅校坤 | Room temperature cross-linking latex paint |
| CN102311686A (en) * | 2011-10-13 | 2012-01-11 | 沈阳顺风新城建筑材料有限公司 | White antialkali sealing priming paint and its preparation method |
| CN102816494A (en) * | 2012-09-17 | 2012-12-12 | 吴江市物华五金制品有限公司 | Hydrophobic moldproof low-VOC (volatile organic compound) environment-friendly latex paint |
| CN104673035A (en) * | 2015-03-11 | 2015-06-03 | 马清浩 | High-hardness scrubbing-resistant emulsion paint for inner and outer walls |
| CN108912760A (en) * | 2018-06-12 | 2018-11-30 | 劳安新材料江苏有限公司 | A kind of uvioresistant latex paint |
| CN111675933A (en) * | 2020-07-02 | 2020-09-18 | 山西中阳钢铁有限公司 | Odorless water-based paint produced by utilizing slag micropowder and preparation method thereof |
-
2002
- 2002-10-25 CN CN 02135025 patent/CN1414045A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1304494C (en) * | 2005-01-13 | 2007-03-14 | 山东科技大学 | Environmental protection moisture adjustable emulsion paint |
| CN101200606B (en) * | 2007-10-31 | 2010-09-08 | 傅校坤 | Room temperature cross-linking latex paint |
| CN102311686A (en) * | 2011-10-13 | 2012-01-11 | 沈阳顺风新城建筑材料有限公司 | White antialkali sealing priming paint and its preparation method |
| CN102816494A (en) * | 2012-09-17 | 2012-12-12 | 吴江市物华五金制品有限公司 | Hydrophobic moldproof low-VOC (volatile organic compound) environment-friendly latex paint |
| CN104673035A (en) * | 2015-03-11 | 2015-06-03 | 马清浩 | High-hardness scrubbing-resistant emulsion paint for inner and outer walls |
| CN108912760A (en) * | 2018-06-12 | 2018-11-30 | 劳安新材料江苏有限公司 | A kind of uvioresistant latex paint |
| CN111675933A (en) * | 2020-07-02 | 2020-09-18 | 山西中阳钢铁有限公司 | Odorless water-based paint produced by utilizing slag micropowder and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102010648B (en) | Floating coat-free shining base coat used for metal pieces and preparation method thereof | |
| CN101591491B (en) | Full water-borne granite multicolor paint and preparation method thereof | |
| CN103788794A (en) | Exterior deep base paint formulation | |
| CN1245465C (en) | Weatherability self-cleaning external wall coating material and its preparation method | |
| CN106497303B (en) | It is a kind of spray painting and preparation method thereof | |
| EP1568740A2 (en) | Thickening systems and aqueous-coating compositions, and methods of making and using the same | |
| CN100345922C (en) | High-saline-resistance lead red alcohol acid antirust paint and its preparing method | |
| US6815010B2 (en) | Method of inhibiting the loss of solar reflectance over time of an exterior elastomeric | |
| CN1900187A (en) | Environment friendly emulsion paint | |
| CN111500133A (en) | Sand-in-water multicolor paint and preparation method thereof | |
| CN101240135B (en) | Simple painted metal imitation fluorocarbon paint | |
| CN1414045A (en) | Super environmental protection latex paint with zero VOC | |
| CN102408827B (en) | Aqueous ultraviolet-curing transparent prime coat and preparation method thereof | |
| CN101280139A (en) | High-weather resistance fluorocarbon paint and construction method thereof | |
| CN107353741A (en) | A kind of black interiro wall latex paint and preparation method thereof | |
| CN108727922A (en) | One kind exempting from cover and imitates lime mineral varnish and preparation method thereof | |
| CN1876737A (en) | Gold brocade coating material | |
| CN109456700A (en) | A kind of high-elastic sand face texture paint of exterior wall and preparation method | |
| CN1876736A (en) | Highly effective rainproof paint | |
| US5240982A (en) | Amphoteric surfactants and copolymerizable amphorteric surfactants for use in latex paint | |
| CN111117331A (en) | Colorful water-based paint with fluorescent effect | |
| US20110229727A1 (en) | Low voc multicolor coating | |
| US5064888A (en) | Amphoteric surfactants and copolymerizable amphoteric surfactants for use in latex paints | |
| CN1414046A (en) | Aqueous metal latex paint | |
| US9428652B2 (en) | Color changing aqueous coatings |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |