CN1411723A - Nimbin and new nicotine pesticide mixed pesticide preparation - Google Patents
Nimbin and new nicotine pesticide mixed pesticide preparation Download PDFInfo
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- CN1411723A CN1411723A CN02134906A CN02134906A CN1411723A CN 1411723 A CN1411723 A CN 1411723A CN 02134906 A CN02134906 A CN 02134906A CN 02134906 A CN02134906 A CN 02134906A CN 1411723 A CN1411723 A CN 1411723A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The prsent invention relates to a compounding method of pesticide, in particular, it is a compounding method of pesticide with nimbin and amoben pesticide as main raw material. In the mixed pesticide the synergistic effect of nimben and some amoben pesticides can be used for overcoming the resistance of pests, expanding its application range and prolong its effective period.
Description
Technical field
The invention belongs to mixed pesticide and preparation method thereof, relate to nimbin particularly and anabasine insecticide is mixed.
Technical background
A large amount of chemical insecticides that use have brought many negative effects on the agricultural, develop immunity to drugs, kill a large amount of useful natural enemies, contaminated environment, cause person poultry poisoning etc. as initiation.
Nimbin is a kind of compound from plant seal chinaberry, has good insecticidal activity, and very fast degraded in environment does not injure natural enemy and other non-target organism, and its shortcoming is unstable, and the processing formulation is less.Anabasine insecticide is the novel chemical insecticide of a class, and wherein some insecticidal effect is better, but possesses the shortcoming of general chemical insecticide, and is narrower etc. as easy initiation pesticide resistance, control spectrum.
The objective of the invention is to by after nimbin and some anabasine insecticides reasonably are mixed, acquisition can overcome pest resistance to insecticide, expanding prevention spectrum, the nimbin mixed insecticide that reduces consumption, has multiple formulation.
Technology contents
The present invention is mixed to obtain being mixed with nimbin and anabasine insecticide and obtains cream preparation or wetting powder or oily suspension emulsion or microemulsion or water-dispersible granules or microcapsule formulations or effervescent tablet.Nimbin content is 0.05-80% by weight, and anabasine insecticide is 1-80% by weight, and all the other are auxiliary agents.Nimbin is one or more among nimbin A, B, D, E, F, G, H, I, K, the L, and when use was multiple, total usage amount can not be greater than the maximum of deal.Nimbin can be former medicine, also can be neem oil, also can be plant extract or the nimbin preparation that contains nimbin.
Anabasine insecticide is flonicamid or clothianidin or dinotefuran or thiophene worm piperazine thiamethoxam) or one or more of Buddhist nun rattan pyrrole indigo plant (nitenpyram) or nithiazine or Acetamiprid (acetamiprid) or thiacloprid, can be former medicine or preparation.Use when multiple, total usage amount can not be greater than the maximum of deal.
Above-mentioned said auxiliary agent is:
When preparation missible oil, its auxiliary agent is:
The surfactant comprise preparation is 5-30% by weight, surfactant is the polyethenoxy ether class of nonionic, or the sodium alkyl sulfate of anionic or in the alkyl benzene sulfonate one or more, to use when multiple, total usage amount can not be greater than the maximum of deal;
Solvent accounts for preparation 10-80% by weight, solvent is various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers, in available benzene,toluene,xylene, naphthalane, gasoline, kerosene, machine oil, MEK, propylene glycol, butyl glycol ether, the benzinum one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Cosolvent accounts for preparation 0.5-20% by weight, and cosolvent is one or more in methyl alcohol, isoamyl alcohol, phenol, ethyl acetate, the dimethyl sulfoxide (DMSO), uses when multiple, and total usage amount can not be greater than the maximum of deal;
PH value conditioning agent accounts for preparation 0.5-1% by weight, and pH value conditioning agent is one or more in sodium hydroxide, ammonium hydroxide, acetic acid, the hydrochloric acid, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Synergist accounts for preparation 0.5-25% by weight, and synergist is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat, the formaldehyde, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Anti-photodissociation agent accounts for preparation 0.5-15% by weight, and anti-photodissociation agent is one or more in p-aminobenzoic acid, castor oil, the Angelica oil, uses when multiple, and total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-25% by weight, and stabilizing agent is one or more in epoxidized soybean oil, the epoxidized linseed, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Penetrating agent accounts for preparation 0.5-20% by weight, and penetrating agent is one or more in Laurocapram, JFC-2, the maleic acid di-sec-octyl sodium sulfonate, uses when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation wetting powder, its auxiliary agent is:
Wetting agent accounts for preparation 3-35% by weight, wetting agent is natural products wetting agent and anionic wetting agent, available tea is withered, spaonin powder, soapberry powder, silkworm excrement, river cinnamic alcohol base sodium sulphate, neopelex, washing powder, draw back in the powder one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Dispersant accounts for preparation 4-30% by weight, dispersant is industrial by-products and anionic dispersing agent, in available lignosulfite, lignin and derivative sulfonate, naphthalene, alkylsulfonate and the alkyl naphthalene formaldehyde condensate sulfonates one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Filler accounts for preparation 10-70% by weight, and filler is mineral carrier or synthetic vectors, and one or more in available kaolin, diatomite, the white carbon use when multiple, and total usage amount can not be greater than the maximum of deal;
When making up oil suspending agent, its auxiliary agent is:
Organic solvent accounts for preparation 10-60% by weight, and organic solvent is one or more in castor oil, transformer oil, machine oil, the dichloroethane, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Wetting agent accounts for preparation 5-20% by weight, and wetting agent is one or more in aliphatic alcohol sulfate, alkylaryl sulfonates, alkylphenol polyoxyethylene, the fatty alcohol-polyoxyethylene ether, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Dispersant accounts for preparation 5-30% by weight, dispersant is lignin sulfonic acid salt such as sodium lignin sulfonate, calcium lignosulfonate, and alkylnaphthalene sulfonate is as drawing back powder, one or more in the salt of naphthalene sulfonic acid-formaldehyde condensation product, use when multiple, total usage amount can not be greater than the maximum of deal;
Tackifier account for preparation 1-10% by weight, and tackifier are one or more in dispersed silica gel, aerosil, clay mineral such as bentonite, macromolecular compound such as the xanthans, use when multiple, and total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-5% by weight, and stabilizing agent is one or more in xanthan gum, the Magnesiumaluminumsilicate, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Defoamer accounts for preparation 0.5-8% by weight, and defoamer is organosilicon ketone, C
8-C
10Fatty alcohol, C
10-C
20In aliphatic saturated monocarboxylic acid and ester class thereof, the polymerization glycerine one or more use when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation microemulsion, its auxiliary agent is:
Solvent accounts for preparation 10-80% by weight, and solvent is one or more in alcohols, ketone, ester point and the aromatic hydrocarbon, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Emulsifier accounts for preparation 5-30% by weight, and emulsifier is alkyl benzene sulfonate calcium salt, alkyl benzene sulphonate magnesium salts, alkyl benzene sulphonate aluminium salt, alkyl benzene sulphonate sodium salt, alkyl benzene sulphonate barium salt, C
8-C
20Alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, benzylbiphenyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy (N=15～30) ether, phenethyl phenol polyethenoxy polyoxypropylene, polyoxyethylene nonylphenol ether, alkylphenol polyoxyethylene first condensation product, xenol APEO, homemade Nongru-700 number, in No. 300 one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-15% by weight, stabilizing agent is a 3-chloro-1, in 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, the sorb sodium alkoxide one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Antifreezing agent accounts for preparation 0.5-10% by weight, and antifreezing agent is one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, the sorbierite, uses when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation water-dispersible granules, its auxiliary agent is:
Wetting agent accounts for preparation 5-20% by weight, wetting agent is a saponin, lignosulfite, the hydrolysate of animal waste, alkyl sulfate, alpha-alkene sulfonate, benzene sulfonamide acid alkali metal salt and amine salt, dialkyl group succinic acid sulfonate sodium, fatty alcohol, fatty acid amide N methyl taurine sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, alkylphenol polyoxyethylene sulphate, Negel, fatty acid or fatty acid ester sulphate, sodium lignin sulfonate, petroleum sodium sulfonate, alkyl biphenyl ether sulfonic acid sodium, naphtholsulfonic acid formaldehyde condensation products sodium salt, polyoxyethylene carboxylate sodium sulfonate and ammonium salt, alkylphenol polyoxyethylene, in the aliphatic alcohol polyethenoxy one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Binding agent accounts for preparation 1-10% by weight, binding agent is one or more in starch, dextrin, gum Arabic, soybean protein, casein, gelatine and gelatin, sodium silicate, gypsum, polyvinyl acetate, polyvinyl alcohol, rosin, shellac, paraffin, pitch, the ethene-vinyl acetate copolymer resins, use when multiple, total usage amount can not be greater than the maximum of deal;
Disintegrant accounts for preparation 5-20% by weight, and disintegrant is one or more in sulphur ammonium, calcium chloride, salt, magnesium chloride, aluminium chloride, urea, the bentonite, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Carrier accounts for preparation 10-70% by weight, carrier is one or more in soybean, tobacco, acorn, corncob cellulose, rice husk, sulphur, diatomite, quicklime, magnesium lime, apatite, calcite, dolomite, gypsum, mica, talcum, pyrophyllite, clay, kaolinite, nacrite, dickite, anauxite, montmorillonite, atlapulgite, the float stone, use when multiple, total usage amount can not be greater than the maximum of deal;
When the preparation microcapsule formulations, its auxiliary agent is:
Dispersant accounts for preparation 10-30% by weight, dispersant is one or more of polyvinyl alcohol, polyethylene glycol, gelatin, gum Arabic, carboxymethyl cellulose, Magnesiumaluminumsilicate, sodium lignin sulfonate, use when multiple, total usage amount can not be greater than the maximum of deal;
Capsule skin material accounts for preparation 10-70% by weight, capsule skin material is a gelatin, gum Arabic, starch, polyvinylpyrrolidone, carboxymethyl cellulose, hydroxy ethyl fiber, the methyl fiber, the arabinose galactan, polyvinyl alcohol, polyacrylic acid, ethyl cellulose, polyethylene, polymethacrylates, polyamide, polyethylene-vinylacetate, cellulose nitrate, silicone, polyesters, polyureas, poly-(terephthaldehyde's base), paraffin, palm wax, spermaceti, beeswax, stearic acid, octadecanol, the tristerin class, shellac, acetic acid benzoic acid cellulose, in the zein one or more, use when multiple, total usage amount can not be greater than the maximum of deal.
Mixture provided by the present invention has following advantage:
1, after nimbin and anabasine insecticide are mixed, can widen the scope of application of medicament, prolong the lasting period, improve drug effect.
2, after nimbin and aforementioned each anabasine insecticide were mixed, the dosage of mixture reduced, and has reduced production cost under the prerequisite that drug effect increases substantially.
3, after nimbin and aforementioned each anabasine insecticide were mixed, mixture had obvious synergistic effect, and it can delay the pesticide resistance generation, and antagonism is administered significant.
4, mixture preparation can greatly alleviate the toxic action to various natural enemies, helps alleviating the destruction to ecotope.
In order to understand essence of an invention better, describe the technology contents of invention below in detail with example, but content of the present invention is not limited thereto.The preparation of one: 10% nimbin+thiophene worm piperazine missible oil of embodiment, each set of dispense ratio is:
Nimbin is 0.3% (weight);
Thiophene worm piperazine is 9.7% (weight);
Surfactant: the dodecyl phenol polyethenoxy ether is 12% (weight);
Organic solvent: dimethylbenzene is 40% (weight);
Cosolvent: methyl alcohol is 15% (weight);
Anti-photodissociation agent: castor oil is 1% (weight);
Stabilizing agent: epoxidized soybean oil is 12% (weight);
Penetrating agent: Laurocapram is 10% (weight);
Each component is put into modulation kettle mixes well and is product.The preparation of two: 30% nimbin+thiophene worm piperazine wetting powders of embodiment, each set of dispense ratio is:
Nimbin is 0.1% (weight)
Thiophene worm piperazine is 29.9% (weight).
Wetting agent: bay alcohol radical sodium sulphate is 10% (weight);
Dispersant: alkylsulfonate is 10% (weight);
Carrier: kaolin is 50% (weight);
With each component drying, cooling, mixing, the levigate product that promptly gets.The preparation of three: 30% nimbin+Acetamiprid oil-suspending agents of embodiment, each set of dispense ratio is:
Nimbin is 10% (weight)
Acetamiprid is 20% (weight);
Dispersant: sodium lignin sulfonate is 10% (weight);
Tackifier: bentonite is 3% (weight);
Stabilizing agent: xanthan gum is 2% (weight);
Defoamer: organic silicone is 3% (weight);
Solvent: castor oil is 52% (weight);
Each component put into send into homogeneous blender mixing after the sand milling still grinds and promptly get product.The preparation of embodiment nimbin+acetamiprid micro emulsion agent in four: 20%, each set of dispense ratio is:
Nimbin is 5% (weight);
Acetamiprid is 15% (weight);
Emulsifier: alkyl benzene sulfonate calcium salt is 20% (weight);
Stabilizing agent: cresyl glycidyl ether is 13% (weight);
Solvent: butanone is 20% (weight);
Antifreezing agent: sorbierite is 2% (weight);
Deionized water is 25% (weight).
Mixture is stirred heating phase inversion product in agitator.The preparation of five: 50% nimbin+thiacloprid water-dispersible granules of embodiment, each set of dispense ratio is:
Nimbin is 8% (weight);
Thiacloprid is 42% (weight);
Wetting agent: sodium lignin sulfonate is 8% (weight);
Binding agent: polyvinyl acetate is 9% (weight);
Carrier: atlapulgite is 23% (weight);
Disintegrant: urea is 10% (weight);
Mixture is carried out granulation after the ultra-fine grinding, drying, screening promptly get product.The preparation of six: 30% nimbin+thiacloprid microcapsule formulations of embodiment, each set of dispense ratio is:
Nimbin is 5% (weight);
Thiacloprid is 25% (weight);
Dispersant: polyvinyl alcohol is 10% (weight);
Cyst material: gelatin is 60% (weight);
Each component was mixed high-speed stirred 2 hours, saltout and isolate polymer, the formation micro-capsule of heating, freeze drying promptly gets product again.
Nimbin and anabasine insecticide are mixed and make the test effect of pesticidal preparations:
Table 1 is: 3% nimbin acetamiprid EC is to the control efficiency of diamondback moth larvae
Table 2 is: 10% nimbin thiophene worm piperazine missible oil is to the control efficiency of diamondback moth larvae
Table 3 is: 10% nimbin thiacloprid missible oil is to the control efficiency of diamondback moth larvae
As can be seen from Table 1,2000 times of 3% nimbin acetamiprid EC to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 68.62%, 85.53%, 93.59%, 82.60%, 1000 times of 0.3% nimbin emulsion to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 11.75%, 67.69%, 84.57%, 70.65%, 1000 times of 3% acetamiprid EC to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 7.89%, 13.99%, 14.55%, 3.59%.
As can be seen from Table 2,2000 times of 10% nimbin thiophene worm piperazine missible oil to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 68.11%, 83.44%, 94.17%, 81.91%, 1000 times of 0.3% nimbin emulsion to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 12.36%, 67.82%, 84.64%, 70.58%, 1500 times of 25% thiophene worm piperazine water dispersible granules to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 15.60%, 20.63%, 21.15%, 10.60%.
As can be seen from Table 3,2000 times of 10% nimbin thiacloprid missible oil to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 57.92%, 70.91%, 87.47%, 88.13%, 1000 times of 0.3% nimbin emulsion to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 12.36%, 67.85%, 84.62%, 70.39%, 1500 times of 25%thiacloprid suspending agent to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 14.21%, 16.94%, 32.30%, 22.89%.
Contrast with former agricultural chemicals from the above-mentioned test of pesticide effectiveness explanation agricultural chemicals that the present invention was mixed, the control of insect is had remarkable control efficiency.
Computing formula is in the table:
Insect population rate (%)=[insect population radix before (borer population of living behind insect population radix-medicine before the medicine)/medicine] * 100% that goes down
Dilute behind the heavy medicine prodrug behind 1 day medicine behind 3 days medicines behind 7 days medicines and to handle the insect population worm insect population of living in 14 days and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect
Multiple complex radical number (head) number (head) moves back rate (%) decline rate (%) and (%) counts (head) and move back rate (%) decline rate (%) and (%) count (head) and move back rate (%) decline rate (%) and (%) count (head) and move back (%) 3% nimbin, 1 113 32 71.68 68.93 68.62 16 85.84 85.68 85.53 11 90.27 93.67 93.59 19 83.19 82.72 82.60 acetamiprid ECs 2,000 2 98 35 64.29 17 82.65 6 93.88 18 81.63 of rate (%) decline rate (%)
3 96 28 70.83 11 88.54 3 96.88 16 83.330.3% nimbins, 1 109 94 13.76 12.62 11.75 35 67.89 68.01 67.69 17 84.40 84.77 84.57 31 71.56 70.84 70.65 missible oil 1,000 2 102 92 9.80 36 64.71 20 80.39 34 66.67
3 105 90 14.29 30 71.43 11 89.52 27 74.293% Acetamiprids, 1 124 114 8.06 8.80 7.89 110 11.29 14.84 13.99 108 12.90 15.66 14.55 117 5.65 4.22 3.59 missible oil 1,000 2 113 109 3.54 100 11.50 102 9.73 110 2.65
3 115 98 14.78 90 21.74 87 24.35 110 4.35 contrasts 1 101 99 1.98 0.99 99 1.98 1.00 99 1.98 1.30 99 1.98 0.65
2 105 105 0.00 106 -0.95 104 0.95 104 0.95
3 102 101 0.98 100 1.96 101 0.98 103 -0.98
Table 1
Dilute behind the heavy medicine prodrug behind 1 day medicine behind 3 days medicines behind 7 days medicines and to process the insect population worm insect population of living in 14 days and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect
Multiple complex radical number (head) number (head) moves back rate (%) decline rate (%) and (%) counts (head) and move back rate (%) decline rate (%) and (%) count (head) and move back rate (%) decline rate (%) and (%) count (head) and move back (%) 10% nimbin, 1 120 37 69.17 68.21 68.11 20 83.33 83.54 83.44 11 90.83 94.22 94.17 22 81.67 82.07 81.91 Diacloden missible oil 2,000 2 110 40 63.64 21 80.91 6 94.55 21 80.91 of rate (%) decline rate (%)
3 110 31 71.82 15 86.36 3 97.27 18 83.640.3% nimbins, 1 109 94 13.76 12.62 12.36 35 67.89 68.01 67.82 17 84.40 84.77 84.64 31 71.56 70.84 70.58 missible oil 1,000 2 102 92 9.80 36 64.71 20 80.39 34 66.67
3 105 90 14.29 30 71.43 11 89.52 27 74.2925% Diaclodens, 1 135 115 14.81 15.84 15.60 111 17.78 21.10 20.63 109 19.26 21.85 21.15 118 12.59 11.39 10.60 water dispersible granules 1,500 2 124 110 11.29 101 18.55 103 16.94 112 9.68
3 126 99 21.43 92 26.98 89 29.37 111 11.90 contrasts 1 112 112 0.00 0.29 111 0.89 0.59 111 0.89 0.89 110 1.79 0.88
2 116 116 0.00 116 0.00 116 0.00 115 0.86
3 113 112 0.88 112 0.88 111 1.77 113 0.00
Table 2
Dilute behind the heavy medicine prodrug behind 1 day medicine behind 3 days medicines behind 7 days medicines and to process the insect population worm insect population of living in 14 days and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect
Multiple complex radical number (head) number (head) moves back rate (%) decline rate (%) and (%) counts (head) and move back rate (%) decline rate (%) and (%) count (head) and move back rate (%) decline rate (%) and (%) count (head) and move back (%) 10% nimbin, 1 140 45 67.86 58.13 57.92 40 71.43 71.06 70.91 21 85.00 87.59 87.47 18 87.14 88.31 88.13thiacloprid missible oil 2,000 2 130 60 53.85 41 68.46 16 87.69 14 89.23 of rate (%) decline rate (%)
3 131 62 52.67 35 73.28 13 90.08 15 88.550.3% nimbins, 1 109 94 13.76 12.62 12.36 35 67.89 68.01 67.85 17 84.40 84.77 84.62 31 71.56 70.84 70.39 missible oil 1,000 2 102 92 9.80 36 64.71 20 80.39 34 66.67
3 105 90 14.29 30 71.43 11 89.52 27 74.2925%thiacloprid, 1 155 135 12.90 14.46 14.21 132 14.84 17.35 16.94 109 29.68 32.97 32.30 118 23.87 24.04 22.89 suspending agents 1,500 2 145 130 10.34 129 11.03 103 28.97 112 22.76
3 149 119 20.13 110 26.17 89 40.27 111 25.50 contrasts 1 131 131 0.00 0.50 131 0.00 0.49 131 0.00 0.99 129 1.53 1.49
2 136 135 0.74 134 1.47 133 2.21 133 2.21
3 133 132 0.75 133 0.00 132 0.75 132 0.75
Table 3
Claims (10)
1. the mixed insecticide preparation of nimbin and anabasine insecticide, it is characterized in that by nimbin 0.05-80% and anabasine insecticide 1-80% by weight by weight, all the other are that additive mixture becomes missible oil, or wetting powder, or oil-suspending agent, or microemulsion, or water-dispersible powder, or microcapsule formulations, or effervescent tablet.
2. mixed insecticide preparation according to claim 1, it is characterized in that nimbin can be one or more among nimbin A, B, D, E, F, G, H, I, K, the L, use when multiple, total usage amount can not be greater than the maximum of deal, and nimbin can be former medicine, neem oil, the plant extract that contains nimbin or nimbin preparation.
3. mixed insecticide preparation according to claim 1, it is characterized in that anabasine insecticide is one or more of flonicamid or clothianidin or dinotefuran or thiophene worm piperazine or Buddhist nun rattan pyrrole indigo plant or nithiazine or Acetamiprid or thiacloprid, can be former medicine or preparation.Use when multiple, total usage amount can not be greater than the maximum of deal.
4, mixed insecticide preparation according to claim 1 is characterized in that said auxiliary agent: when preparation missible oil, its auxiliary agent is:
The surfactant comprise preparation is 5-30% by weight, surfactant is the polyethenoxy ether class of nonionic, or the sodium alkyl sulfate of anionic or in the alkyl benzene sulfonate one or more, to use when multiple, total usage amount can not be greater than the maximum of deal;
Solvent accounts for preparation 10-80% by weight, solvent is various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers, in available benzene,toluene,xylene, naphthalane, gasoline, kerosene, machine oil, MEK, propylene glycol, butyl glycol ether, the benzinum one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Cosolvent accounts for preparation 0.5-20% by weight, and cosolvent is one or more in methyl alcohol, isoamyl alcohol, phenol, ethyl acetate, the dimethyl sulfoxide (DMSO), uses when multiple, and total usage amount can not be greater than the maximum of deal;
PH value conditioning agent accounts for preparation 0.5-1% by weight, and pH value conditioning agent is one or more in sodium hydroxide, ammonium hydroxide, acetic acid, the hydrochloric acid, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Synergist accounts for preparation 0.5-25% by weight, and synergist is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat, the formaldehyde, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Anti-photodissociation agent accounts for preparation 0.5-15% by weight, and anti-photodissociation agent is one or more in p-aminobenzoic acid, castor oil, the Angelica oil, uses when multiple, and total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-25% by weight, and stabilizing agent is one or more in epoxidized soybean oil, the epoxidized linseed, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Penetrating agent accounts for preparation 0.5-20% by weight, and penetrating agent is one or more in Laurocapram, JFC-2, the maleic acid di-sec-octyl sodium sulfonate, uses when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation wetting powder, its auxiliary agent is:
Wetting agent accounts for preparation 3-35% by weight, wetting agent is natural products wetting agent and anionic wetting agent, available tea is withered, spaonin powder, soapberry powder, silkworm excrement, bay alcohol radical sodium sulphate, neopelex, washing powder, draw back in the powder one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Dispersant accounts for preparation 4-30% by weight, dispersant is industrial by-products and anionic dispersing agent, in available lignosulfite, lignin and derivative sulfonate, naphthalene, alkylsulfonate and the alkyl naphthalene formaldehyde condensate sulfonates one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Filler accounts for preparation 10-70% by weight, and filler is mineral carrier or synthetic vectors, and one or more in available kaolin, diatomite, the white carbon use when multiple, and total usage amount can not be greater than the maximum of deal;
When making up oil suspending agent, its auxiliary agent is:
Organic solvent accounts for preparation 10-60% by weight, and organic solvent is one or more in castor oil, transformer oil, machine oil, the dichloroethane, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Wetting agent accounts for preparation 5-20% by weight, and wetting agent is one or more in aliphatic alcohol sulfate, alkylaryl sulfonates, alkylphenol polyoxyethylene, the fatty alcohol-polyoxyethylene ether, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Dispersant accounts for preparation 5-30% by weight, dispersant is lignin sulfonic acid salt such as sodium lignin sulfonate, calcium lignosulfonate, and alkylnaphthalene sulfonate is as drawing back powder, one or more in the salt of naphthalene sulfonic acid-formaldehyde condensation product, use when multiple, total usage amount can not be greater than the maximum of deal;
Tackifier account for preparation 1-10% by weight, and tackifier are one or more in dispersed silica gel, aerosil, clay mineral such as bentonite, macromolecular compound such as the xanthans, use when multiple, and total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-5% by weight, and stabilizing agent is one or more in xanthan gum, the Magnesiumaluminumsilicate, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Defoamer accounts for preparation 0.5-8% by weight, and defoamer is organosilicon ketone, C
8-C
10Fatty alcohol, C
10-C
20In aliphatic saturated monocarboxylic acid and ester class thereof, the polymerization glycerine one or more use when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation microemulsion, its auxiliary agent is:
Solvent accounts for preparation 10-80% by weight, and solvent is one or more in alcohols, ketone, ester class and the aromatic hydrocarbon, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Emulsifier accounts for preparation 5-30% by weight, and emulsifier is alkyl benzene sulfonate calcium salt, alkyl benzene sulphonate magnesium salts, alkyl benzene sulphonate aluminium salt, alkyl benzene sulphonate sodium salt, alkyl benzene sulphonate barium salt, C
8-C
20Alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, benzylbiphenyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy (N=15～30) ether, phenethyl phenol polyethenoxy polyoxypropylene, polyoxyethylene nonylphenol ether, alkylphenol polyoxyethylene first condensation product, xenol APEO, homemade Nongru-700 number, in No. 300 one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-15% by weight, stabilizing agent is a 3-chloro-1, in 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, the sorb sodium alkoxide one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Antifreezing agent accounts for preparation 0.5-10% by weight, and antifreezing agent is one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, the sorbierite, uses when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation water-dispersible granules, its auxiliary agent is:
Wetting agent accounts for preparation 5-20% by weight, wetting agent is a saponin, lignosulfite, the hydrolysate of animal waste, alkyl sulfate, alpha-alkene sulfonate, benzene sulfonamide acid alkali metal salt and amine salt, dialkyl group succinic acid sulfonate sodium, fatty alcohol, fatty acid amide N methyl taurine sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, alkylphenol polyoxyethylene sulphate, Negel, fatty acid or fatty acid ester sulphate, sodium lignin sulfonate, petroleum sodium sulfonate, alkyl biphenyl ether sulfonic acid sodium, naphtholsulfonic acid formaldehyde condensation products sodium salt, polyoxyethylene carboxylate sodium sulfonate and ammonium salt, alkylphenol polyoxyethylene, in the aliphatic alcohol polyethenoxy one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Binding agent accounts for preparation 1-10% by weight, binding agent is one or more in starch, dextrin, gum Arabic, soybean protein, casein, gelatine and gelatin, sodium silicate, gypsum, polyvinyl acetate, polyvinyl alcohol, rosin, shellac, paraffin, pitch, the ethene-vinyl acetate copolymer resins, use when multiple, total usage amount can not be greater than the maximum of deal;
Disintegrant accounts for preparation 5-20% by weight, and disintegrant is one or more in sulphur ammonium, calcium chloride, salt, magnesium chloride, aluminium chloride, urea, the bentonite, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Carrier accounts for preparation 10-70% by weight, carrier is one or more in soybean, tobacco, acorn, corncob cellulose, rice husk, sulphur, diatomite, quicklime, magnesium lime, apatite, calcite, dolomite, gypsum, mica, talcum, pyrophyllite, clay, kaolinite, nacrite, dickite, anauxite, montmorillonite, atlapulgite, the float stone, use when multiple, total usage amount can not be greater than the maximum of deal;
When the preparation microcapsule formulations, its auxiliary agent is:
Dispersant accounts for preparation 10-30% by weight, dispersant is one or more of polyvinyl alcohol, polyethylene glycol, gelatin, gum Arabic, carboxymethyl cellulose, Magnesiumaluminumsilicate, sodium lignin sulfonate, use when multiple, total usage amount can not be greater than the maximum of deal;
Capsule skin material accounts for preparation 10-70% by weight, capsule skin material is a gelatin, gum Arabic, starch, polyvinylpyrrolidone, carboxymethyl cellulose, hydroxy ethyl fiber, the methyl fiber, the arabinose galactan, polyvinyl alcohol, polyacrylic acid, ethyl cellulose, polyethylene, polymethacrylates, polyamide, polyethylene-vinylacetate, cellulose nitrate, silicone, polyesters, polyureas, poly-(terephthaldehyde's base), paraffin, palm wax, spermaceti, beeswax, stearic acid, octadecanol, the tristerin class, shellac, acetic acid benzoic acid cellulose, in the zein one or more, use when multiple, total usage amount can not be greater than the maximum of deal.
5. mixed insecticide preparation according to claim 1 is characterized in that producing 10% nimbin+each set of dispense ratio of thiophene worm piperazine missible oil and is:
Nimbin is 0.3% (weight),
Thiophene worm piperazine is 9.7% (weight),
Surfactant: the dodecyl phenol polyethenoxy ether is 12% (weight),
Organic solvent: dimethylbenzene is 40% (weight),
Cosolvent: methyl alcohol is 15% (weight),
Anti-photodissociation agent: castor oil is 1% (weight),
Stabilizing agent: epoxidized soybean oil is 12% (weight),
Penetrating agent: Laurocapram is 10% (weight).
6. mixed insecticide preparation according to claim 1 is characterized in that producing 30% nimbin+each set of dispense ratio of thiophene worm piperazine wetting powder and is:
Nimbin is 0.1% (weight),
Thiophene worm piperazine is 29.9% (weight),
Wetting agent: bay alcohol radical sodium sulphate is 10% (weight),
Dispersant: alkylsulfonate is 10% (weight),
Carrier: kaolin is 50% (weight).
7. mixed insecticide preparation according to claim 1 is characterized in that producing each set of dispense ratio of 30% nimbin+Acetamiprid oil-suspending agent and is:
Nimbin is 10% (weight),
Acetamiprid is 20% (weight),
Dispersant: sodium lignin sulfonate is 10% (weight),
Tackifier: bentonite is 3% (weight),
Stabilizing agent: xanthan gum is 2% (weight),
Defoamer: organic silicone is 3% (weight),
Solvent: castor oil is 52% (weight).
8. mixed insecticide preparation according to claim 1 is characterized in that producing each set of dispense ratio of 20% nimbin+acetamiprid micro emulsion agent and is:
Nimbin is 5% (weight),
Acetamiprid is 15% (weight),
Emulsifier: alkyl benzene sulfonate calcium salt is 20% (weight),
Stabilizing agent: cresyl glycidyl ether is 13% (weight),
Solvent: butanone is 20% (weight),
Antifreezing agent: sorbierite is 2% (weight)
Deionized water is 25% (weight).
9. mixed insecticide preparation according to claim 1 is characterized in that producing each set of dispense ratio of 50% nimbin+thiacloprid water-dispersible granules and is:
Nimbin is 7% (weight),
Thiacloprid is 43% (weight),
Wetting agent: sodium lignin sulfonate is 8% (weight),
Binding agent: polyvinyl acetate is 9% (weight),
Carrier: atlapulgite is 23% (weight),
Disintegrant: urea is 10% (weight).
10. mixed insecticide preparation according to claim 1 is characterized in that producing each set of dispense ratio of 30% nimbin+thiacloprid microcapsule formulations and is:
Nimbin is 5% (weight),
Thiacloprid is 25% (weight),
Dispersant: polyvinyl alcohol is 10% (weight),
Cyst material: gelatin is 60% (weight).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021349061A CN1175742C (en) | 2002-10-09 | 2002-10-09 | Nimbin and new nicotine pesticide mixed pesticide preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021349061A CN1175742C (en) | 2002-10-09 | 2002-10-09 | Nimbin and new nicotine pesticide mixed pesticide preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1411723A true CN1411723A (en) | 2003-04-23 |
| CN1175742C CN1175742C (en) | 2004-11-17 |
Family
ID=4747938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021349061A Expired - Fee Related CN1175742C (en) | 2002-10-09 | 2002-10-09 | Nimbin and new nicotine pesticide mixed pesticide preparation |
Country Status (1)
| Country | Link |
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| CN (1) | CN1175742C (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1330240C (en) * | 2006-03-23 | 2007-08-08 | 浙江新安化工集团股份有限公司 | Pest killing composition |
| CN100431417C (en) * | 2005-11-16 | 2008-11-12 | 中国农业科学院植物保护研究所 | Disinsection composition of acetamiprid and pymetrozine |
| CN103039497A (en) * | 2012-12-28 | 2013-04-17 | 广西安泰化工有限责任公司 | Insecticide composition containing dinotefuran and azadirachtin |
| CN103125481A (en) * | 2011-12-05 | 2013-06-05 | 上海生农生化制品有限公司 | Cycloxaprid oil suspending agent and preparing method thereof |
| CN103651507A (en) * | 2013-11-29 | 2014-03-26 | 许亚萍 | Insecticidal composition containing cycolxylidin and nimbin |
| CN103891754A (en) * | 2014-04-11 | 2014-07-02 | 柳州市惠农化工有限公司 | Pesticide composition containing clothianidin and fluazinam and preparation method and use thereof |
| CN106070264A (en) * | 2016-06-23 | 2016-11-09 | 扬州大学 | A kind of agricultural chemicals suspension agent preventing and treating rice-stem borer and preparation method and application |
| CN106518368A (en) * | 2016-10-28 | 2017-03-22 | 华南农业大学 | An organic pesticide-containing fertilizer and a preparing method thereof |
| CN107006531A (en) * | 2017-03-13 | 2017-08-04 | 仲恺农业工程学院 | A kind of environment-friendly pesticide and its application |
| CN109221285A (en) * | 2018-10-30 | 2019-01-18 | 大新县科学技术情报研究所 | A kind of composition of medicine for preventing and treating sugar cane cottony aphid |
| CN110169423A (en) * | 2019-07-02 | 2019-08-27 | 广东岭南职业技术学院 | A kind of insecticide composition and its preparation of shielding protection honeybee |
| CN110178851A (en) * | 2019-06-04 | 2019-08-30 | 广西汇丰生物科技有限公司 | A kind of Pesticidal combination of spirotetramat and Diacloden |
-
2002
- 2002-10-09 CN CNB021349061A patent/CN1175742C/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100431417C (en) * | 2005-11-16 | 2008-11-12 | 中国农业科学院植物保护研究所 | Disinsection composition of acetamiprid and pymetrozine |
| CN1330240C (en) * | 2006-03-23 | 2007-08-08 | 浙江新安化工集团股份有限公司 | Pest killing composition |
| CN103125481A (en) * | 2011-12-05 | 2013-06-05 | 上海生农生化制品有限公司 | Cycloxaprid oil suspending agent and preparing method thereof |
| CN103039497A (en) * | 2012-12-28 | 2013-04-17 | 广西安泰化工有限责任公司 | Insecticide composition containing dinotefuran and azadirachtin |
| CN103651507B (en) * | 2013-11-29 | 2015-08-26 | 许亚萍 | A kind of Pesticidal combination containing cycolxylidin and nimbin |
| CN103651507A (en) * | 2013-11-29 | 2014-03-26 | 许亚萍 | Insecticidal composition containing cycolxylidin and nimbin |
| CN103891754A (en) * | 2014-04-11 | 2014-07-02 | 柳州市惠农化工有限公司 | Pesticide composition containing clothianidin and fluazinam and preparation method and use thereof |
| CN103891754B (en) * | 2014-04-11 | 2016-08-17 | 柳州市惠农化工有限公司 | A kind of composition pesticide of clothianidin-containing and fluazinam and its production and use |
| CN106070264A (en) * | 2016-06-23 | 2016-11-09 | 扬州大学 | A kind of agricultural chemicals suspension agent preventing and treating rice-stem borer and preparation method and application |
| CN106518368A (en) * | 2016-10-28 | 2017-03-22 | 华南农业大学 | An organic pesticide-containing fertilizer and a preparing method thereof |
| CN107006531A (en) * | 2017-03-13 | 2017-08-04 | 仲恺农业工程学院 | A kind of environment-friendly pesticide and its application |
| CN109221285A (en) * | 2018-10-30 | 2019-01-18 | 大新县科学技术情报研究所 | A kind of composition of medicine for preventing and treating sugar cane cottony aphid |
| CN110178851A (en) * | 2019-06-04 | 2019-08-30 | 广西汇丰生物科技有限公司 | A kind of Pesticidal combination of spirotetramat and Diacloden |
| CN110169423A (en) * | 2019-07-02 | 2019-08-27 | 广东岭南职业技术学院 | A kind of insecticide composition and its preparation of shielding protection honeybee |
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| Publication number | Publication date |
|---|---|
| CN1175742C (en) | 2004-11-17 |
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