CN102113508A - Insecticidal/acaricidal composition contaning biphenthrin - Google Patents
Insecticidal/acaricidal composition contaning biphenthrin Download PDFInfo
- Publication number
- CN102113508A CN102113508A CN2010100038424A CN201010003842A CN102113508A CN 102113508 A CN102113508 A CN 102113508A CN 2010100038424 A CN2010100038424 A CN 2010100038424A CN 201010003842 A CN201010003842 A CN 201010003842A CN 102113508 A CN102113508 A CN 102113508A
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- CN
- China
- Prior art keywords
- biphenthrin
- component
- composition
- insecticidal
- acetamiprid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an insecticidal/acaricidal composition containing biphenthrin. The insecticidal/acaricidal composition comprises active components A and B. Component A is biphenthrin, component B is one of pyridaben, acetamiprid, carbosulfan and isoprocarb, and the mass ratio of component A and component B is (50:1) to (1:50). The preferential mass ratio of component A and component B is (5:1) to (20:3). The cumulative mass percentage of component A and component B is 1-99% of the total mass, and preferably, the cumulative mass percentage of component A and component B is 3-60% of the total mass. The insecticidal/acaricidal composition which blends the two active components, has distinct synergistic action, and can reduce the use amounts of active components and delay the generation of drug resistance of destructive insects and harmful acarids. The insecticidal/acaricidal composition can be used for preventing and controlling a variety of destructive insects and harmful acarids on cotton, vegetable, fruit trees, and tee trees.
Description
Technical field
The present invention relates to the agent of a kind of agricultural insecticidal acaricide, especially relate to and contain the Biphenthrin insecticide acaricide composition.
Background technology
Biphenthrin, English common name bifenthrin has another name called Uranus, the spirit of worm mite, Bi Fenning belongs to the pyrethroid insecticidal/acaricidal agent, has the stomach poison function of tagging.Insecticidal spectrum is wide, and effect is difficult for moving in soil rapidly, and environmentally safe, the lasting period is longer.Be mainly used in insect and the control of pest mite of cotton, vegetables, fruit tree and tea tree etc.Chemical name: (1R, S)-along (Z) 2,2-dimethyl-3-(2-chloro-3-3-3-three fluoro-1-acrylic) cyclopropane-carboxylic acid-2-methyl-3-phenyl benzyl ester.In the U.S. is topmost dry crop control of insect medicament.
The insecticide that contains a kind of active constituent is to agricultural insect management, and often because of using continuously, insect is easy to generate pesticide resistance, and medication causes the pollution grows worse of environment etc. often.Advantage of the present invention and good effect are that the agricultural chemicals with two kinds of different structures, the mechanism of action and insecticidal spectrums carries out composite, being the control resistant insect, enlarging insecticidal spectrum, improving the effective way of drug effect and delaying drug resistance development, is the important means of present insect control of pest mite.
In Chinese patent, the report of existing Biphenthrin and Avermectin, butyl ether urea, azacyclotin, thiophene worm piperazine, dichlorvos, Nitenpyram or malathion, but do not see Biphenthrin and pyridaben, Acetamiprid, hundred one-tenth of fourth sulphur grams or different the third one-tenth desinsection of forming, the report of miticide composition so far.
Pyridaben, English common name pyridaben has another name called pyridaben, is a kind of heterocyclic miticide.All have very high activity each breeding time to Panonychus citri, tetranychid, goitre mite, and flea beetle is also had good activity, can be used for the production of pollution-free vegetable.
Acetamiprid, English common name acetamiprid has another name called Mospilan, and Mo Bilang, clear, the acetamiprid of pyrrole worm are a kind of novel pesticides, are used to prevent and treat agricultural and go up important insect, as aphid, thrips, aleyrodid, flea beetle etc.
Carbosulfan, English common name carbosulfan, be a kind of wide spectrum, low toxicity carbamic acid class desinsection, kill line, miticide, have interior suction, tag and stomach poison function.Can anti-eliminate aphis, plant hopper, leafhopper, Jie restrain various pests, nematode and mite classes such as worm, thrips, leaf miner, wireworm, flea beetle.
Mobucin, English common name isoprocarb, chemical name isopropyl phenyl methyl carbamate belongs to carbamate insecticide.Mobucin has good preventive effect to plant hopper, leafhopper etc., and quick-acting is strong, and adult is had special efficacy.
Summary of the invention
The objective of the invention is to: provide the insecticide acaricide composition that contains Biphenthrin of a kind of efficient, wide spectrum, low toxicity, various pests and evil mites such as cause harm with solution cotton, vegetables, fruit tree and tea tree.
To achieve these goals, technical scheme of the present invention is: a kind of insecticide acaricide composition that contains Biphenthrin is provided, form by two kinds of effective constituents A and B, the A composition is a Biphenthrin, the B composition is a kind of in pyridaben, Acetamiprid, carbosulfan, the Mobucin, and it is 50: 1～1: 50 that described two kinds of composition A and B form mass ratio.
Preferably, described two kinds of composition A and B composition mass ratio is 5: 1～20: 3.
Preferably, the mass accumulation percentage of described two kinds of composition A and B accounts for 1%～99% of gross mass.
Preferably, the mass accumulation percentage of described two kinds of composition A and B accounts for 3%～60% of gross mass.
Preferably, the described insecticide acaricide composition that contains Biphenthrin can be made into different application forms, comprises missible oil, wetting powder, water dispersible granules, microemulsion or suspending agent.
The invention has the advantages that: the insecticide acaricide composition that the present invention contains Biphenthrin utilizes two kinds of active constituents to be mixed, and has obvious synergistic effect, can reduce the effective ingredient dosage, delays the drug-fast generation of insect evil mite.Can be used for preventing and treating various pests and evil mite on cotton, vegetables, fruit tree and the tea tree etc.
Embodiment
The invention will be further described below in conjunction with preferred embodiment, but the present invention never is limited to following embodiment.Each component percentage composition all by quality ratio in following examples.
Embodiment one
11.5% Biphenthrin pyridaben, promptly both weight ratios are 20: 3 missible oil
Common process is formed, wherein
Biphenthrin 10%
Pyridaben 1.5%
Dimethylbenzene 5%
Cyclohexanone 10%
500#10% dimethylbenzene is mended to 100%
The described insecticide acaricide composition that contains Biphenthrin also can be made into different application forms, comprises wetting powder, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Biphenthrin and pyridaben accounts for 11.5% of gross mass.
At first former medicine is dissolved in proportion in the organic solvents such as part dimethylbenzene, methyl alcohol, fully dissolving adds emulsifier fully to stir then, then dimethylbenzene equal solvent amount is supplied 100%, and fully stirs; Carry out the packing of product at last after the assay was approved.
Embodiment two
12% Biphenthrin Mobucin, promptly both weight ratios are 5: 1 missible oil
Common process is formed, wherein
Biphenthrin 10%
Mobucin 2%
Dimethylbenzene 5%
Cyclohexanone 10%
500#10% dimethylbenzene is mended to 100%
The described insecticide acaricide composition that contains Biphenthrin also can be made into different application forms, comprises wetting powder, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Biphenthrin and Mobucin accounts for 12% of gross mass.
At first former medicine is dissolved in proportion in the organic solvents such as part dimethylbenzene, methyl alcohol, fully dissolving adds emulsifier fully to stir then, then dimethylbenzene equal solvent amount is supplied 100%, and fully stirs; Carry out the packing of product at last after the assay was approved.
Embodiment three
10.6% Biphenthrin Acetamiprid, promptly both weight ratios are 50: 3 wetting powder
Common process is formed, wherein
Biphenthrin 10%
Acetamiprid 0.6%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 6%
Sodium methylene bis-naphthalene sulfonate 8%
Kaolin is mended to 100%
The described insecticide acaricide composition that contains Biphenthrin also can be made into different application forms, comprises missible oil, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Biphenthrin and Acetamiprid accounts for 10.6% of gross mass.
At first former medicine, auxiliary agent, filler are mixed in proportion, and fully stir, pulverize then, after the assay was approved, wetting powder can carry out the packing of product.
Embodiment four
10.6% Biphenthrin Acetamiprid, promptly both weight ratios are 50: 3 water dispersible granules
Common process is formed, wherein
Biphenthrin 10%
Acetamiprid 0.6%
Lauryl sodium sulfate 5%
Calcium lignosulfonate 8%
Sucrose 2%
Sodium methylene bis-naphthalene sulfonate 5%
Polyvinylpyrrolidone 10%
Kaolin is mended to 100%
The described insecticide acaricide composition that contains Biphenthrin also can be made into different application forms, comprises missible oil, wetting powder, microemulsion or suspending agent.The mass accumulation percentage of described Biphenthrin and Acetamiprid accounts for 10.6% of gross mass.
Embodiment five
12% Biphenthrin carbosulfan, promptly both weight ratios are 5: 1 microemulsion
Common process is formed, wherein
Biphenthrin 10%
Carbosulfan 2%
Acetone 2%
Glycerine 2.5%
Calcium dodecyl benzene sulfonate 10%
The newborn 0203B 12% of farming
Water is mended to 100%
The described insecticide acaricide composition that contains Biphenthrin also can be made into different application forms, comprises missible oil, wetting powder, water dispersible granules or suspending agent.The mass accumulation percentage of described Biphenthrin and carbosulfan accounts for 12% of gross mass.
Embodiment six
10.6% Biphenthrin Acetamiprid, promptly both weight ratios are 50: 3 suspending agent
Common process is formed, wherein
Biphenthrin 10%
Acetamiprid 0.6%
Polyoxyethylene alkyl ether 1.2%
Polyoxyethylene nonylphenol ether 1.4%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Propane diols 3%
Water is mended to 100%
The described insecticide acaricide composition that contains Biphenthrin also can be made into different application forms, comprises missible oil, wetting powder, water dispersible granules or microemulsion.The mass accumulation percentage of described Biphenthrin and Acetamiprid accounts for 10.6% of gross mass.
Above used auxiliary agent, surfactant and the carrier of various preparations of preparation is known in those skilled in the art.
But used additives during preparation missible oil:
Solvent and cosolvent: aromatic hydrocarbons, aliphatic hydrocarbon, ethers, phenols, ketone, alcohols etc. are arranged, for example benzene, benzinum, methyl alcohol, dimethylbenzene, ethanol, n-butanol, toluene, isoamyl alcohol, ethyl acetate, chloroform, kerosene, methyl-sulfoxide, phenol, machine oil etc.Account for 15～90% by weight.
Emulsifier: the polyethenoxy ether class of nonionic, anionic sodium alkyl sulfate, alkylbenzenesulfonate etc. are arranged.As aliphatic alcohol polyethenoxy base ether, alkylphenol polyoxyethylene, styryl phenol polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy ether etc., emulsifier can be one or more mixing.Account for 5～30% by weight.
PH value conditioning agent: one or more of sodium hydroxide, potassium hydroxide, hydrochloric acid, acetic acid etc. are arranged, account for 0.5～1% by weight.
Synergist: be in Butacide, sulfoxide, alkyl carbonate, chlorination fat, the formaldehyde one or more, account for 0.5～25% by weight.
But during the preparation wetting powder there be used additives:
Carrier: kaolin, atlapulgite, diatomite, mud coal, precipitated calcium carbonate, white carbon, pyrophyllite, talcum powder, calcite etc. are arranged.Can be one or more mixing, consumption accounts for 10～75% by weight.
Dispersant: industrial by-products and anionic dispersing agent are arranged, available lignosulfite, sodium lignin sulfonate, calcium lignosulfonate, non-ionic surface active agent such as polyoxyethylene polyoxypropylene base ether block copolymers, alkylphenol-polyethenoxy base phosphate.Can be one or more mixing, consumption accounts for 4～35% by weight.
Wetting agent: the withered powder of natural products and anionic surfactant such as tea, spaonin powder, washing powder, soapberry powder, silkworm excrement, bay alcohol radical sodium sulphate, dodecyl sodium sulfate are arranged, draw back powder, No. 2000 series of farming breast, wetting and penetrating agent F etc.Can be one or more mixing, consumption accounts for 3～35% by weight.During the preparation microemulsion, its auxiliary agent is:
Solvent: one or more in alcohols, ketone, ester class and the aromatic hydrocarbon account for preparation by weight 10～60%.
Emulsifier: be alkyl benzene sulfonate calcium salt, alkyl benzene sulphonate magnesium salts, alkyl benzene sulphonate aluminium salt, alkyl benzene sulphonate sodium salt, alkyl benzene sulphonate barium salt, C8-C20 alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, benzylbiphenyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy (N=15～30) ether, phenethyl phenol polyethenoxy polyoxypropylene, polyoxyethylene nonylphenol ether, homemade Nongru-700 number, in No. 300 etc. one or more, consumption accounts for 5～30% by weight.
Stabilizing agent: be in 3-chloro-1,2 epoxy prapane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, the sorb sodium alkoxide one or more, consumption accounts for 0.5～15% by weight.
Antifreezing agent: be in ethylene glycol, glycerine, propane diols, polyethylene glycol, the sorbierite one or more, consumption accounts for 0.5～10% by weight.
Defoamer: one or more in organosilicon, methyl alcohol, ethanol, the epoxy soybean wet goods, consumption accounts for 0.5～8% by weight.
Adjuvant used during the preparation water dispersible granules:
Wetting agent: sodium alkyl benzene sulfonate, sodium lignin sulfonate, fatty alcohol, alkyl sulfate, alkyl phenol gather
In oxygen vinethene, lignosulfite, the withered powder of tea and the spaonin powder etc. one or more, consumption accounts for 5～30% by weight.
Binding agent: in soybean lecithin, gelatin, polyvinyl alcohol, polyethylene glycol, soybean protein, dextrin, rosin, the starch etc. one or more are arranged, and consumption accounts for 1～10% by weight
Disintegrant: in bentonite, ammonium sulfate, urea, magnesium chloride, the sodium chloride etc. one or more are arranged, and consumption accounts for 5～20% by weight.
Carrier: in kaolin, precipitated calcium carbonate, white carbon, montmorillonite, diatomite, quicklime, tobacco, the rice husk etc. one or more are arranged, and consumption accounts for 10～70% by weight.
Preparation used auxiliary agent during suspending agent:
Solvent: one or more in castor oil, machine oil, the dichloroethane, consumption account for 10～60 by weight.
Wetting agent: one or more in aliphatic alcohol sulfate, alkylaryl sulfonates, alkylphenol polyoxyethylene, the fatty alcohol-polyoxyethylene ether, consumption account for 5～20% by weight.
Dispersant: lignin sulfonic acid salt such as sodium lignin sulfonate, calcium lignosulfonate, alkylsulfonate are as in the salt that draws back powder, naphthalene sulfonic acid-formaldehyde condensation product one or more, and consumption accounts for 5～30% by weight.
Tackifier: one or more in dispersed silica gel, aerosil, clay mineral such as bentonite, macromolecular compound such as the xanthans, consumption account for 1～10% by weight.
Stabilizing agent: one or more in sulphur ortho acid glue, the Magnesiumaluminumsilicate, consumption accounts for 0.5～5% by weight.
Defoamer: one or more in silicic acid ketone, C8～C10 fatty alcohol, C10～C20 aliphatic saturated monocarboxylic acid and ester class thereof, the polymerization glycerine, consumption accounts for 0.5～8% by weight.
Biological Examples one: composite dose of indoor activity of Biphenthrin to small brown rice planthopper
1, test medicine
(1), 10.6% Biphenthrin. Acetamiprid (10: 0.6) (2), 12% Biphenthrin. carbosulfan (10: 2) (3), 12% Biphenthrin. Mobucin (10: 2) (4), 11.5% Biphenthrin. the single agent of pyridaben (10: 1.5) is 10% Biphenthrin, 0.6% Acetamiprid, 2% carbosulfan, 2% Mobucin, 1.5% pyridaben, and formulation is missible oil.
2, examination worm
Company gives birth to and to survey the small brown rice planthopper of taking place on the corn experimental field.
3, test method
(1) test period: test in 2008.11.25 and carry out
(2) test method: the clip maize straw, adopt and to soak the stalk method, prepare that medicament soaks stalk, the air-dry insect box that is placed on (in 18cm * 13cm * 7cm), is trembled into the small brown rice planthopper nymph from the cornstalk somely then gently, built lid.The dead borer population of periodic investigation behind the medicine calculates lethality.
4, result of the test
Soak the stalk method and tested composite dose of indoor activity of several Biphenthrins the corn small brown rice planthopper, dilute 20,000 times after, found that (seeing Table 1):
1d behind the medicine, 11.5% Biphenthrin. pyridaben is very high to the quick-acting of small brown rice planthopper, lethality reaches 95.5%, next is 10.6% Biphenthrin. Acetamiprid and 12% Biphenthrin. and carbosulfan, lethality rate to the examination worm is respectively 41.5% and 55.8%, all is higher than the activity 29.9% of contrast medicament 10% Biphenthrin to the examination worm; And 3d behind the medicine, 12% Biphenthrin. carbosulfan and 11.5% Biphenthrin. pyridaben is respectively 97.4% and 95.5% to the lethal effect of examination worm, 10.6% Biphenthrin. Acetamiprid and 12% Biphenthrin. Mobucin is respectively 49.1% and 74.4% to the lethal effect of examination worm, all is higher than the activity 37.3% of single agent 10% Biphenthrin.The built reactive presentation of results, 4 kinds composite dose all shows tangible quick-acting and synergistic effect.
Compare with single agent from the above-mentioned test explanation agricultural chemicals that the present invention was mixed, the control of insect is had significant effect.
Composite dose of table 1 is to corn small brown rice planthopper laboratory test results
| Medicament | Extension rate (ten thousand times) | The insect population radix | 1d borer population alive | Lethality (%) | 2d borer population alive | Lethality (%) | 3d borer population alive | Lethality (%) |
| 10.6% Biphenthrin. Acetamiprid | 2 | 53 | 22 | 41.5 | 26 | 49.1 | 26 | 49.1 |
| 12% Biphenthrin. carbosulfan | 2 | 77 | 43 | 55.8 | 68 | 88.3 | 75 | 97.4 |
| 12% Biphenthrin. Mobucin | 2 | 90 | 26 | 28.9 | 45 | 50.0 | 67 | 74.4 |
| 11.5% Biphenthrin. pyridaben | 2 | 67 | 63 | 94.0 | 63 | 94.0 | 64 | 95.5 |
| 10% biphenyl | 2 | 67 | 20 | 29.9 | 29 | 43.3 | 25 | 37.3 |
| 0.6% Acetamiprid | 2 | 58 | 0 | 0 | 0 | 0 | 0 | 0 |
| 2% carbosulfan | 2 | 76 | 0 | 0 | 0 | 0 | 0 | 0 |
| 2% Mobucin | 2 | 56 | 0 | 0 | 2 | 3.6 | 4 | 7.1 |
| 1.5% pyridaben | 2 | 54 | 0 | 0 | 3 | 5.6 | 4 | 7.4 |
| Blank | - | 128 | 0 | 0 | 0 | 0 | 0 | 0 |
Biological Examples two: composite dose of field effect of Biphenthrin to the mango two spotted spider mite
Spray-on process has been tested the different composite dose of field efficacies to the mango two spotted spider mite (seeing Table 2) of Biphenthrin.The result shows, 1d behind the medicine, behind Biphenthrin and Acetamiprid, carbosulfan, Mobucin or pyridaben composite, composite dose preventive effect is all more than 90%, apparently higher than the preventive effect of single agent 10% Biphenthrin 84.2%, illustrate that composite effect has tangible quick-acting and synergistic effect.
Compare with single agent from the above-mentioned test of pesticide effectiveness explanation agricultural chemicals that the present invention was mixed, the control of insect is had significant effect.
Composite dose of table 2 is to mango two spotted spider mite field effect
| Medicament | Extension rate (ten thousand times) | The insect population radix | 1d borer population alive | Preventive effect (%) | 2d borer population alive | Preventive effect (%) | 3d borer population alive | Preventive effect (%) |
| 10.6% Biphenthrin. Acetamiprid (10: 0.6) | 1 | 122 | 13 | 91.1 | 4 | 97.4 | 1 | 99.3 |
| 12% Biphenthrin. carbosulfan (10: 2) | 1 | 108 | 0 | 100 | 0 | 100 | 1 | 99.3 |
| 12% Biphenthrin. Mobucin (10: 2) | 1 | 109 | 0 | 100 | 0 | 100 | 1 | 99.3 |
| 11.5% Biphenthrin. pyridaben (10: 1.5) | 1 | 233 | 21 | 92.4 | 2 | 99.3 | 0 | 100 |
| 10% biphenyl EC | 1 | 101 | 16 | 84.2 | 14 | 86.1 | 8 | 92.1 |
| 0.6% Acetamiprid EC | 1 | 73 | 0 | 0 | 0 | 0 | 0 | 0 |
| 2% carbosulfan EC | 1 | 68 | 0 | 0 | 0 | 0 | 0 | 0 |
| 2% Mobucin EC | 1 | 94 | 0 | 0 | 0 | 0 | 0 | 0 |
| 1.5% pyridaben EC | 1 | 90 | 0 | 0 | 2 | 2.2 | 6 | 6.7 |
| Blank | - | 102 | 0 | 0 | 0 | 0 | 0 | 0 |
Claims (5)
1. the insecticide acaricide composition that contains Biphenthrin, it is characterized in that: form by two kinds of effective constituents A and B, the A composition is a Biphenthrin, and the B composition is a kind of in pyridaben, Acetamiprid, carbosulfan, the Mobucin, and it is 1: 50～50: 1 that described two kinds of composition A and B form mass ratio.
2. the insecticide acaricide composition that contains Biphenthrin as claimed in claim 1 is characterized in that: it is 5: 1～20: 3 that described two kinds of composition A and B form mass ratio.
3. the insecticide acaricide composition that contains Biphenthrin as claimed in claim 1 is characterized in that: the mass accumulation percentage of described two kinds of composition A and B accounts for 1%～99% of gross mass.
4. the insecticide acaricide composition that contains Biphenthrin as claimed in claim 3 is characterized in that: the mass accumulation percentage of described two kinds of composition A and B accounts for 3%～60% of gross mass.
5. the insecticide acaricide composition that contains Biphenthrin as claimed in claim 1 is characterized in that: described insecticide acaricide composition can be made into different application forms, comprises missible oil, wetting powder, water dispersible granules, microemulsion or suspending agent.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107205388A (en) * | 2015-04-17 | 2017-09-26 | 龙灯农业化工国际有限公司 | Synergistic insecticidal compositions |
| CN110352978A (en) * | 2018-04-11 | 2019-10-22 | 大韩民国山林厅国立山林科学院 | Biocidal composition comprising carbamate compound and the control method using it |
| WO2020021406A1 (en) * | 2018-07-26 | 2020-01-30 | Upl Ltd | A stable liquid agrochemical formulation |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| BR102017012557A2 (en) * | 2017-01-11 | 2018-07-24 | Upl Ltd | a method for controlling adult insect populations |
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Non-Patent Citations (1)
| Title |
|---|
| KIM, YOUNG-JOON; LEE, SI-HYEOCK; LEE, SI-WOO; AHN, YOUNG-JOON: "Fenpyroximate resistance in Tetranychus urticae (Acari: Tetranychidae):", 《PEST MANAGEMENT SCIENCE》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107205388A (en) * | 2015-04-17 | 2017-09-26 | 龙灯农业化工国际有限公司 | Synergistic insecticidal compositions |
| CN107205388B (en) * | 2015-04-17 | 2021-08-03 | 龙灯农业化工国际有限公司 | Synergistic insecticidal composition |
| CN110352978A (en) * | 2018-04-11 | 2019-10-22 | 大韩民国山林厅国立山林科学院 | Biocidal composition comprising carbamate compound and the control method using it |
| WO2020021406A1 (en) * | 2018-07-26 | 2020-01-30 | Upl Ltd | A stable liquid agrochemical formulation |
| CN112512317A (en) * | 2018-07-26 | 2021-03-16 | Upl有限公司 | Stable liquid agrochemical formulations |
| TWI791872B (en) * | 2018-07-26 | 2023-02-11 | 印度商Ｕｐｌ有限公司 | A stable liquid agrochemical formulation and a preparation process thereof, and a method of controlling or preventing unwanted pests on plants or propagation material thereof |
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