CN1390159A - Method for production of a foil-like support material coated with an adhesive - Google Patents

Method for production of a foil-like support material coated with an adhesive Download PDF

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Publication number
CN1390159A
CN1390159A CN 00815599 CN00815599A CN1390159A CN 1390159 A CN1390159 A CN 1390159A CN 00815599 CN00815599 CN 00815599 CN 00815599 A CN00815599 A CN 00815599A CN 1390159 A CN1390159 A CN 1390159A
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China
Prior art keywords
coating
carrier material
coated
coating substance
substance
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Pending
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CN 00815599
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Chinese (zh)
Inventor
迪特尔·祖贝克
舒莱曼·科克曼
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Citius Buerotechnik GmbH
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Citius Buerotechnik GmbH
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Publication of CN1390159A publication Critical patent/CN1390159A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22Addition to the formed paper
    • D21H23/52Addition to the formed paper by contacting paper with a device carrying the material
    • D21H23/56Rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/28Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/40Distributing applied liquids or other fluent materials by members moving relatively to surface
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/32Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming a linkage containing silicon in the main chain of the macromolecule
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/82Paper comprising more than one coating superposed
    • D21H19/824Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented

Landscapes

  • Application Of Or Painting With Fluid Materials (AREA)
  • Paper (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

A method for coating a support material, with a coating substance, on a known coating device, using the so-called rolling-doctor process, is disclosed. Said method is characterised in that the coating parameters of the coating device and the composition of the coating substance are chosen to suit the surface properties, such that a layer forms on the support material, comprising irregularly distributed drops of various sizes.

Description

Manufacture method with the foil-like support material of adhesive coating
The present invention relates to the field of sticking tablet, wherein, adhesive is on separating film or the carrier thin film separably, and transfers on the substrate under the situation of pressurization.Therefore the present invention relates to a kind of vertically hung scroll shape one side scribble adhesive layer carrier material manufacture method and as a kind of coating substance that is used to be coated on the carrier material of intermediate products.Carrier material can for example relate to paper, plastic sheeting or metal forming, and they are through silicidation in case of necessity.
Carrier material one side by this type can be known with adhesive coating comprehensively.The sticking tablet of this coating for example is applied in the coating rolling device illustrated in EP-0 267 396.Wherein, vertically hung scroll shape carrier material is the comprehensive coating of a side at first, then is cut into fillet and is wound into reel.This reel is packed into then and is coated with in the rolling device as standby reel.By rolling device, adhesive layer can be coated on smooth substrate for example on the paper.By tractive motion, make adhesive layer and its carrier material separate and transfer in the substrate by the coating rolling device here, to the substrate that will add adhesive.The carrier strip auto reeling of unstowing is in the coating rolling device.
When adhesive layer is transferred in the substrate by the coating rolling device, confirmed already, because the cohesiveness of adhesive can not reach the avulsion glossily of adhesive layer and carrier material, because adhesive is put wire drawing in avulsion.
For fear of this disadvantageous effect, by the known a kind of carrier material of DE 94 07 704U, it is by replacing comprehensive adhesive layer by the coating of forming one by one.The advantage of this point-like coating is can obtain smooth avulsion line when being coated on adhesive layer in the substrate, because " wire drawing " do not occur (Fadenziehen) in the zone of coating adhesive between dots of adhesive.
The point-like coating of carrier material especially realizes by flexographic rotary printing art (relief printing plate roller coating) usually by for example typography under so-called " hot-melts " situation.This process is very complicated and expensive.
Therefore the purpose of this invention is to provide a kind of quick coating process, this method can stick with glue agent point-like coating carrier material, the cheap and operation simply of this external enwergy.Another purpose is a kind of adhesive of preparation, can carry out by method of the present invention with it.
The coating of this point-like is applied on the carrier material by a kind of known coating apparatus by the present invention.By its traditional application, this coating apparatus is used for comprehensively and coating equably.Confirmed unexpectedly already that this same coating apparatus also can be used in to having the carrier material coating of point-like coating.But the traditional application mode that is used for evenly coating with coating apparatus is different, select rightly and the carrier material of assembly adhesive stick and certain in case of necessity technological parameter by the present invention, obtain a kind of coating of forming by some uneven dot patterns basically thereby replace uniform coating.
Here, the selectable operational factor of coating apparatus is mated rightly with each adhesive material and carrier material, so that obtain described point-like coated pattern.
Usually the bonding comprehensively bonding force that maximum is provided.Employing sticks with glue the foil-like support material of agent coating by method preparation of the present invention, they according to said method provide so high dots of adhesive density, so that this dot density can compare with the more approaching 100% desirable covering comprehensively of general mechanical typography with simple mode as intaglio printing or flexographic rotary printing art.However do not observe the disadvantageous situation of comprehensive coating that preface is mentioned, as " wire drawing ".
Further specify by form of implementation of the present invention referring to accompanying drawing.
The work of Fig. 1 illustrative coating apparatus according to said method;
Fig. 2 schematically illustrates another kind of rolling scraper coating apparatus structure;
Fig. 3-5 is depicted in the different layouts of rolling scraper in the coating process.
As seen from Figure 1, coating apparatus comprises the groove 1 of containing liquid coating substance 2 in one.The cylindrical roller 3 that is coated with immerses in the coating substance 2.The axis that is coated with roller is a little more than the surface of coating substance 2 and extend perpendicular to the figure paper plane in Fig. 1.Being coated with roller 3 is rotated around its axis by motor drives.This rotatablely moves and carries out in the counterclockwise direction in Fig. 1.
This coating apparatus also comprises 4,5 and pressure rollers 6 of two slewing rollers.The axis of slewing rollers 4,5 and pressure roller 6 is parallel to the axis that is coated with roller 3 respectively and extends.Slewing rollers 5 and pressure roller 6 can move along the vertical direction perpendicular to its axis respectively.
The vertically hung scroll shape carrier material 7 that is coated with is along 4,5 guidings of two slewing rollers.Carrier material 7 is pulled out (not expression Fig. 1) in the end that it is in first slewing rollers, 4 fronts from standby reel.Be positioned at the place, end after second slewing rollers 5 its another, carrier material is wound on (expression among Fig. 1) on the cylindrical sleeve by coiler device.The coiling of coating is undertaken by rotatable chill roll with the effect of spreading and drive unit.Drive unit makes chill roll rotate around its axis, so carrier material 7 pulled out from standby reel, via slewing rollers 4,5 guidings and be wound on the winder.
Between the pressure roller 6 and second slewing rollers 5, adorn a rolling scraper 8.Rolling scraper 8 is made of a thin bar with external screw thread type.The axis of bar is parallel to the axis that is coated with roller 3 and extends.Mode as an alternative, rolling scraper also can be made of the thin bar of its outside coiling fine wire.Except that the rolling slurry-scraping method, also can use other layouts of funny point-like scraper and the rolling scraper shown in Fig. 3 to 5 shown in Figure 2.The upright position that rolling scraper 8 is arranged to make it is substantially in two slewing rollers 4 and 5 two the imaginary line between bottom.Pressure roller 6 can be vertically so mobile, makes it at a lower position carrier material 7 not only is pressed in rolling scraper 8 upsides but also be pressed in and be coated with roller 3 upsides.
The coating of coating substance 2 on carrier material 7 undertaken by following mode:
When being coated with roller 3 and rotatablely moving, coating substance 2 is attached on the outside that is coated with roller 3.When carrier material 7 is pressed in when being coated with on the roller 3 by pressure roller 6, can be coated in all sidedly on the downside of carrier material 7 attached to the coating substance 2 that is coated with roller 3 outsides.Because carrier material 7 spurs through slewing rollers 4,5 by coiler device, so carrier material 7 obtains a planar coating.Be coated with between roller 3 and the rolling scraper 8, on the carrier material 7 of carrier material 7 downsides, constituting a more or less uniform coating substance layer.The thickness of this uniform coating depends primarily on the character of coating substance and the surface characteristic of carrier material here.
And then, the downside of carrier material 7 is pulled by rolling scraper 8.This rolling scraper 8 is rotated around its axis by motor drives.Form as an alternative, rolling scraper 8 also can transfixion.
Rolling scraper 8 strikes off the part of comprehensive coating from carrier material 7.The coating substance 2 that strikes off flows back in the groove 1 subsequently.All the other coating substances of staying on the carrier material 7 constitute a uniform coating there usually.
Yet unexpectedly confirm, under the situation that the composition and the surface characteristic of carrier material 7 of coating substance 2 are mated rightly (back also will illustrate in greater detail), at the surface of carrier material formation drop.The size and the spacing of these drops that form on carrier material 7 downsides also depend primarily on the characteristic of rolling scraper 8, especially depend on its depth of thread or are wound on thickness wiry on the rolling scraper 8.
Between slewing rollers 5 and coiler device, establish dryer section.After slewing rollers 5 were pulled out, it was by this heatable dryer section at carrier material.In this process, make the liquid coating substance drying on the carrier material 7.
As top mentioned, constitute a uniform coating with coating back on carrier material 7 or constitute the drop one by one of inhomogeneous arrangement irrelevant, this depends primarily on the character of coating substance 2 and the surface characteristic of carrier material 7.Under the situation that constitutes drop, the size of drop and their spacing depend primarily on the surface characteristic of coating substance 2 and carrier material 7.
The formation of coating substance 2 drops mainly realizes by the appropriate characteristic on coating substance 2 and carrier material 7 surfaces of selecting on carrier material 7.The key here is that the surface tension of coating substance 2 and carrier material 7 is coordinated with each other in such a way, that is, make the drop that constitutes on carrier material 7 be lower than the superficial density (Flaechendichet) of the coating substance 2 of a regulation at least.
By coating substance 2 of the present invention is a kind of adhesive suspension, and it comprises:
A) adhesive mixture, except that anhydrating, form by following ingredients, 2 to 12% butyl polyacrylates, 1 to 5% copolymer of forming by acrylonitrile and alkyl acrylate, 40 to 95% carboxylic acrylate, 0 to 50% polyvinyl acetate, 0 to 2% defoamer, 0 to 5% is used to adjust the material of pH value, and
B) 20 to 50 weight % water, more than all with regard to by a) and b) with regard to the mixture formed.Especially comprise 4 to 10 weight % butyl polyacrylates, the copolymer that 2 to 4 weight % are made up of acrylonitrile and alkyl acrylate, 50 to 90 carboxylic acrylate copolymers by adhesive suspension of the present invention.Defoamer can have 0 to 2 weight %, especially 0.5 to 1.8 weight %.Be used to adjust the needed amount of material of pH value usually in 0 to 5% scope.Can adopt a kind of polyether derivative of aliphatic acid as defoamer.Use so-called " dispersant " as the material of adjusting pH value.The compound that plays alkaline reaction that they are normally nitrogenous, for example ethylaminoethanol, especially 2 amino 2 methylpropanols (adding 10% water) or organic amine, for example alkylamine or ammonia solutions.
Common additive can be added, as dyestuff, oxidation stabilizers, filler etc. in adhesive mixture.The content of water is 20% to 50 weight % in coating substance 2 that is the adhesive suspension, 25 to 45 weight % preferably, especially 30% to 43% and preferred 35 to 40%.Correspondingly, the solids content with regard to total adhesive suspension is 50% to 80%, preferably 55% to 75%, especially 57% to 70%, preferred 60% to 65%.
Can use plastic sheeting as carrier material 7, for example by the plastic sheeting of poly terephthalic acid second two fat, polybutylene terephthalate, triacetate, polyamide, polyimides, Merlon, PVC, polypropylene, polyethylene, cellulose acetate, polyacrylate system, but also can use the metal forming of silicon processing in case of necessity, for example lead or Copper Foil.Proved the advantageously paper of two sides silicon processing already as carrier material 7.The paper that therefore preferred silicon is handled is as mainly using by this type.The thickness of carrier material is arbitrarily, and preferred here the employing has weight per unit area from 10g/m 2The stable carrier material that rises.The important characteristic of carrier material is the character that does not absorb water basically, so the cohesiveness in coated adhesive suspension is greater than at coated liquid adhesive suspension and the adhesive force between the carrier mass.Cause the droplet-shaped of adhesive suspension on film to distribute just because of this characteristic according to estimates.
The composition of the coating substance 2 that illustrates in routine 1-5 below is applicable to this carrier material, thereby causes the point-like coating that forms drop after coating on the carrier material 7.The following describes some embodiment, wherein, if not explanation in addition, percentage is all with regard to weight.
Middle for example some original materials that adopt below are in their character and thereby different aspect their effect.The difference of these original material character, by the production standard mainly following different aspect these: their solids content, viscosity, speed are fallen, the minimum temperature of pH value, density, particle mean size, film forming, dispersal pattern, surface characteristic, their mechanical performance such as intensity, stretch breaking strength and ultimate elongation and their glass transition temperature, their photostability and their eye impressions.
Example 1
Following ingredients is mixed illustrated as following.
A) polyether derivative of 0.06 partial fatty acid (antifoaming agent) in 20ml water
B) 0.05 part dispersant (having PH=8-9.5)
C) aqueous suspension of 0.35 polypropylene segment acid butyl ester
D) the copolymer aqueous suspension formed by acrylonitrile and acrylate of 0.22 part
E) the carboxylic acrylate copolymer aqueous suspension of 3.00 parts
F) the carboxylic acrylate copolymer aqueous suspension of 2.7 parts
G) 0.06 part water body colored paint color Lanco-Beit (Langer﹠amp; CO. company); Wherein, ingredient e) with f) different reasons is ingredient e) have than f) high solids content, that is 69%, another pH value and bigger viscosity.
A) insert in the reaction vessel composition and under the situation of gentle agitation, at room temperature add b).Continue to stir in such a way now, that is, adding original material c in succession) to g) time in addition can prevent to generate faint foam.After finishing interpolation, mixture stirred 10 minutes under about 50 rev/mins again.This stirring can extend to 30 minutes.Forming a kind of thus is not the suspension of very sticking watery and viscous.After 1 to 2 hour, can process the additives that this makes.This additives can make it leave standstill 10-20 hour.The coating of non-viscous form causes the asymmetric glue spots of inhomogeneous layout by rolling Pulp scraping device or funny point-like scraper.
As mentioned above, improve the adhesivity of coating substance by increasing ingredient e) and amount f) and correspondingly adjust antifoaming agent (composition a) and the pH value realization.By the discharging time of the B8 liquid flow cup of the Simex company of pressing DIN53211, determine the viscosity of mentioned component from one.The average discharging time that reaches is 4.1s+/0.3s.
Example 2
Following ingredients is mixed illustrated as following.
A) polyether derivative of 0.1 partial fatty acid (antifoaming agent) in 100ml water
B) 0.15 part dispersant (PH adjustment)
C) aqueous suspension of 3.00 polypropylene segment acid butyl esters
D) the copolymer aqueous suspension formed by acrylonitrile and acrylate of 1.00 parts
E) the carboxylic acrylate copolymer aqueous suspension of 8.00 parts
F) the carboxylic acrylate copolymer aqueous suspension of 16.00 parts
G) 10.00 part polyvinyl acetate ester copolymer aqueous suspensions
H) 0.08 part water body colored paint color Lanco-Beit (Langer﹠amp; CO. company) wherein, ingredient e) with f) different reasons is ingredient e) have than f) high solids content, that is 69%, another pH value and bigger viscosity.This mixture causes improving adhesivity.
A) insert in the reaction vessel composition and under the situation of gentle agitation, at room temperature add b).Continue to stir in such a way now, that is, adding original material c in succession) to h) time in addition can prevent to form faint foam.After finishing interpolation, mixture stirred 10 minutes under about 50 rev/mins again.This stirring can extend to 30 minutes.Forming a kind of thus is not the suspension of very sticking watery and viscous.After 1 to 2 hour, can process the additives that this makes.This additives can make it leave standstill 10-20 hour.The coating of non-viscous form causes the asymmetric glue spots of inhomogeneous layout here equally by rolling Pulp scraping device or funny point-like scraper.
Example 3
Following ingredients is mixed illustrated as following.
A) polyether derivative (antifoaming agent) of 0.15 partial fatty acid in the watery boric acid of 250ml
B) 0.2 part dispersant (PH adjustment)
C) aqueous suspension of 8.00 polypropylene segment acid butyl esters
D) the copolymer aqueous suspension formed by acrylonitrile and acrylate of 1.60 parts
E) the carboxylic acrylate copolymer aqueous suspension of 10.00 parts
F) the carboxylic acrylate copolymer aqueous suspension of 22.00 parts
G) 22.00 part polyvinyl acetate ester copolymer aqueous suspensions
H) 3.00 part polyvinyl acetate ester copolymer aqueous suspensions
I) 0.08 part water body colored paint pigment Lanco-Beit (Langer ﹠amp; CO. company) wherein, ingredient e) with f) different reasons is ingredient e) have than f) high solids content, that is 69%, another pH value and bigger viscosity.This mixture causes improving adhesivity.
A) insert in the reaction vessel composition and under the situation of gentle agitation, at room temperature add b).Continue to stir in such a way now, that is, adding original material c in succession) to i) time in addition can prevent to form faint foam.After finishing interpolation, mixture stirred 10 minutes under about 50 rev/mins again.This stirring can extend to 30 minutes.Forming a kind of thus is not the suspension of very sticking watery and viscous.After 1 to 2 hour, can process the additives that this makes.This additives can make it leave standstill 10-20 hour.Also make the coating of non-viscous form cause the asymmetric glue spots of inhomogeneous layout here by rolling Pulp scraping device or funny point-like scraper.
At g) and h) between difference be that bigger solids content, another kind of pH value and bigger viscosity h) are especially arranged.
Proved already under above-mentioned all situations as carrier material especially favourable, the about 40-42g/m of weight per unit area 2Two-sided layer of silicone (the 1.8g/m that is coated with 2) paper.With thickness is that 23 μ m and front and back have 1.3g/m respectively 2The transparent polyester film of silicone coating also can obtain similar good result.
In order on carrier material 7, to reach a kind of viscous coating substance 2 more uniform dot patterns, when in above-mentioned coating apparatus, being coated with, proved already advantageously that the passage rate of carrier material 7 was 5-15m/min.For the liquid state of drying on carrier material, be that to be 80-110 ℃ be appropriate for temperature on the dryer section of 8m in length.
For the applying implenent that makes carrier material 7 has required for this reason area density, adopt rolling scraper 8 with individual features.By the rolling scraper that selection has the surface appearance of regulation that is especially has the regulation depth of thread, can be predefined in the area density of coating substance 2 on the carrier material 7.Have a kind of scraper 8 that rolls to prove favourable already here, when this rolling scraper was coated with at carrier material 7 usefulness primary standard substances, formation had wet feed 5-25g/m comprehensively uniformly on carrier material 7 2Coating (scraper: 5-25 μ).
Example 4
A) polyether derivative of 0.15 partial fatty acid (antifoaming agent) in 150ml water
B) 0.2 part dispersant (PH adjustment) or AMP
C) aqueous suspension of 4 polypropylene segment acid butyl esters
D) the copolymer aqueous suspension formed by acrylonitrile and acrylate of 0.8 part
E) the carboxylic acrylate copolymer aqueous suspension of 4.00 parts
F) the carboxylic acrylate copolymer aqueous suspension of 15.00 parts
G) 6.00 part polyvinyl acetate ester copolymer aqueous suspensions
H) 8 polypropylene segment acid butyl ester aqueous suspensions
I) 0.08 part water body colored paint color Lanco-Beit (Langer ﹠amp; CO. company)
To a) insert in the reaction vessel and under the situation of gentle agitation, at room temperature add b).Continue to stir in such a way now, that is, adding original material c in succession) to g) time in addition can prevent to form faint foam.After finishing interpolation, mixture stirred 10 minutes under about 50 rev/mins again.The additives of making can be processed immediately or after one hour.
Example 5
A) polyether derivative of 0.25 partial fatty acid (antifoaming agent) in 250ml water
B) 0.25 part dispersant (PH adjustment) or AMP
C) aqueous suspension of 6.0 polypropylene segment acid butyl esters
D) the copolymer aqueous suspension formed by acrylonitrile and acrylate of 1.0 parts
E) the carboxylic acrylate copolymer aqueous suspension of 5.00 parts
F) the carboxylic acrylate copolymer aqueous suspension of 15.00 parts
G) 8.00 part polyvinyl acetate ester copolymer aqueous suspensions
H) 5.00 part polyvinyl acetate ester copolymer aqueous suspensions
I) aqueous suspension of 12 polypropylene segment acid butyl esters
J) coloured dye colour Lanco-Beit (the Langer ﹠amp of 0.1 part water body; CO. company)
To a) insert in the reaction vessel and under the situation of gentle agitation, at room temperature add b).Continue to stir in such a way now, that is, adding original material c in succession) to g) time in addition can prevent to form faint foam.After finishing interpolation, mixture stirred 10 minutes under about 50 rev/mins again.The additives of making can be processed immediately or after one hour.

Claims (6)

1. on the known coating apparatus of scraping sizing process work that rolls by what is called, be coated with the method for carrier material with coating substance, this equipment comprises the groove 1 that is used to hold coating substance 2, be used for coating substance 2 is coated in and be coated with roller 3 on the carrier material 7, be used to strike off the rolling scraper 8 of unnecessary coating substance 2, and be used for carrier material 7 is pressed in the pressure roller 6 that is coated with on roller 3 and the rolling scraper 8, wherein, coating apparatus is applied to the conforming layer of a coating substance of coating on carrier material by tradition, it is characterized by: select the composition of the painting parameter of coating apparatus and coating substance in such a way and be complementary with the surface characteristic of carrier material, that is, make on carrier material and to constitute one by uneven distribution, coating with drop composition of different size.
2. it is characterized by in accordance with the method for claim 1: coating substance comprises
A) adhesive mixture, except that anhydrating, mainly form by following ingredients, 2 to 12% butyl polyacrylates, 1 to 5% copolymer of forming by acrylonitrile and alkyl acrylate, 40 to 97% carboxylic acrylate, 0 to 50% polyvinyl acetate, 0 to 2% defoamer, 0 to 5% is used to adjust the material of pH value, is used to the pigment of the q.s that dyes in case of necessity, and
B) 20 to 50 weight % water, more than all with regard to by a) and b) with regard to the mixture formed.
3. in accordance with the method for claim 2, it is characterized in that defoamer is a kind of polyether derivative of aliphatic acid.
4. in accordance with the method for claim 2, it is characterized in that the material that is used to adjust pH value is an organic amine, alkanolamine or ammonia.
5. according to the described method of one of all claims in prostatitis, it is characterized by, carrier material is plastic foil or the metal forming that the paper of silicone coating is arranged or silicone coating is arranged in case of necessity.
6. according to the described method of one of all claims in prostatitis, it is characterized by, after coating, the carrier material of coating passes through dry location, and the drop in this dry location on carrier material 7 is dried, and consolidates this securely attached on the carrier material 7.
CN 00815599 1999-11-13 2000-11-10 Method for production of a foil-like support material coated with an adhesive Pending CN1390159A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19964122.6 1999-11-13
DE19964122 1999-11-13

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Publication Number Publication Date
CN1390159A true CN1390159A (en) 2003-01-08

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EP (1) EP1230035A2 (en)
JP (1) JP2003513794A (en)
CN (1) CN1390159A (en)
AU (1) AU1279401A (en)
WO (1) WO2001036111A2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005035860A1 (en) * 2005-02-17 2006-08-24 Karl W. Niemann Gmbh & Co.Kg Process for coating workpieces with non-slip coating

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Publication number Priority date Publication date Assignee Title
US2417009A (en) * 1939-09-19 1947-03-04 Bert C Miller Inc Process of coating with thermoplastic material
DE2123384A1 (en) * 1971-05-12 1972-11-23 Deutsche Solvay-Werke Gmbh, 5650 Solingen-Ohligs Non-tacky vinyl chloride (co) polymer for moulded sheet - film,articles prodn
DE3019371C2 (en) * 1980-05-21 1982-07-01 Beiersdorf Ag, 2000 Hamburg Process for coating webs with solvent-based coating compounds
DE3040086A1 (en) * 1980-10-24 1982-06-03 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING POLYACRYLIC ACID ESTER DISPERSIONS AND THEIR USE
DE3633833C1 (en) * 1986-10-04 1993-05-06 Vits Maschinenbau Gmbh Method and device for applying a liquid or pasty substance to a material web
EP0333417A3 (en) * 1988-03-18 1991-08-28 Amcor Limited Coating process
JP3097786B2 (en) * 1992-04-16 2000-10-10 富士写真フイルム株式会社 How to apply organic solvent-based coating liquid
DE4228436C2 (en) * 1992-08-27 1994-08-11 Neschen Hans Gmbh & Co Kg Pressure sensitive polyacrylic acid pressure sensitive adhesive and its use for the production of self-adhesive, flat substrates
DE4324357C1 (en) * 1993-07-16 1994-11-03 Neschen Hans Gmbh & Co Kg Dispersion contact adhesives for transparent surface protection films, and use thereof

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WO2001036111A3 (en) 2001-12-13
WO2001036111A2 (en) 2001-05-25
EP1230035A2 (en) 2002-08-14
JP2003513794A (en) 2003-04-15
AU1279401A (en) 2001-05-30

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