CN1319649A - Method for making high-effiicent environment protection energy-saving metal wire-drawing solution - Google Patents
Method for making high-effiicent environment protection energy-saving metal wire-drawing solution Download PDFInfo
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- CN1319649A CN1319649A CN 01107565 CN01107565A CN1319649A CN 1319649 A CN1319649 A CN 1319649A CN 01107565 CN01107565 CN 01107565 CN 01107565 A CN01107565 A CN 01107565A CN 1319649 A CN1319649 A CN 1319649A
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- triethanolamine
- oleic acid
- stearic acid
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Abstract
The formula of high-effective energy-saving environment-protecting wire-drawing liquor contains the components of deionized water, triethanolamine, oleic acid, stearic acid, ammonia water, Tween-81, Tween-40, methyl silicon oil, EDTA and sodium benzoate according to a certain mixing ratio, and its production method includes the following steps: firstly, making triethanolamine and oleic acid produce reactino in reactor at a certain temp., after a certain time, at constant temp. adding stearic acid, then slow-adding ammonia water, heat-insulating at constant temp. for a certain time, adding other materials, stirring and completely dissolving them, cooling to a certain temp. and discharging material so as to obtain the invented product. Said invention product can reduce working temp. of wire-drawing machine, and is applicable to high-speed wire drawing machine.
Description
The present invention is a kind of manufacture method of high-effiicent environment protection energy-saving metal wire-drawing solution, belongs to the fine chemistry industry technology of preparing.
Be oil-in-water oil-in-water type coolant (claim wire drawing oil) by what in the copper stringy course of processing, adopt on the present domestic and international market, it contains a certain amount of mineral oil, sewage after make using has a certain amount of mineral oil, and can not biochemical degradation, so can not directly discharge.
Goal of the invention of the present invention is exactly all to contain mineral oil in order to overcome and to solve the wire drawing oil that adopts in the existing metal wire-drawing course of processing, sewage after the use also has mineral oil, can not biochemical degradation, the shortcoming that can't directly discharge and problem, the manufacture method of a kind of high-effiicent environment protection energy-saving metal wire-drawing solution of research invention, produced wire drawing liquid is nontoxic, tasteless, nonirritant, biodegradable, can be energy-efficient, can solve the environment protection sewage emission problem effectively after using.
The present invention realizes by following technical proposals: it is as follows that it makes recipe ratio (its following per-cent all is weight percentage):
Deionized water 40～45%
Triethanolamine 3.5～10.5%
Oleic acid 9.0～25%
Stearic acid 2.0～12.5%
Ammoniacal liquor (17%) 0.8～5.0%
Anhydrous sorbitol Soxylat A 25-7 monoleate 12.0～18%
Anhydrous sorbitol Soxylat A 25-7 monopalmitate 15.0～20%
Methyl-silicone oil 1.5～2.5%
Disodium ethylene diamine tetraacetate (EDTA) 0.1～0.5%
Sodium Benzoate 0.2～0.8% its manufacture method step is as follows: (1) adds in proper order by the above-mentioned prescription of wire drawing liquid; (1) deionized water, triethanolamine are added in the reactor of band well heater, agitator, begin to stir and be heated to 70～80 ℃; (2) oleic acid is slowly joined make triethanolamine and oleic acid carry out saponification reaction in the reactor to become oleic acid triethanolamine soap solution again, constant temperature is 20～40 minutes under 70～80 ° of temperature; (3) stearic acid is added in the reactor, ammoniacal liquor is slowly added after stearic acid dissolves fully by the time again, temperature remains on 70～80 ℃, constant temperature 20～40 minutes; (4) again unclassified stores is added one by one by above-mentioned prescription order, and be stirred to till the whole dissolvings of all materials; (5) solution is cooled to 40～50 ℃ and stops to stir, carry out discharging, make product of the present invention.
The present invention compared with prior art, have following advantage and beneficial effect: (1) the present invention forms by the kinds of surface promoting agent is composite, has good metal surface adsorption ability, when it and metallic contact, can on the metallic surface, form layer protecting film rapidly, make metal obtain lubrication protection in the metallic surface under external force, thereby reduced frictional force, reduced the load of machine, really reached energy-efficient purpose; (2) the present invention is formulated by multiple nontoxic, harmless tensio-active agent, can obtain biological degradation at short notice, can effectively solve the environmental issue of sewage discharge for a long time, and the BOD COD in the sewage effluent all meets state environmental emissioning standard; (3) the present invention is single aqueous phase solution, do not resemble and have the emulsion that the existing water of wire drawing oil has oil phase again now, mineral oil and water stratification during use, mineral oil does not work, hindered the thermolysis of the aqueous solution on the contrary at the mineral oil of solution surface, so use single aqueous phase system can reduce the working temperature of drawing wire machine, improve the work-ing life of wire drawing liquid; (4) product of the present invention meets the use of high-speed wire-drawing machine fully, and the per minute drawing speed is not less than 2800 meters, can be adapted to import high-speed wire-drawing machine fully through the special wire drawing liquid of preparing of the inventive method and use, and the drawing speed per minute can reach 3600 meters; (5) product of the present invention has possessed the static that is produced in the elimination drawing process, and has the resistance of oxidation of metallic copper and the cleansing power of metallic surface; (6) product of the present invention is a kind of high value added product, and domestic wire production is played effects such as certain energy-efficient, environmental protection, is the developing direction of wire production industry; (7) the present invention adopts water miscible tensio-active agent to carry out the aqueous solution of the composite water-soluble system of homogeneous, the demixing phenomenon that oil, water can in use not occur as wire drawing oil, mineral oil in the wire drawing oil is lubricate not, has played the heat dispersion that hinders drawing process on the contrary; (8) the present invention has solved the environment protection sewage emission problem that uses effectively.Mainly component is composite forms by new and effective extreme pressure agent, lubricant, clean-out system, antioxidant, rust-preventive agent etc. in the present invention, this environment protection metal wire drawing liquid is nontoxic, tasteless, to human body skin nonirritant, biodegradable, be widely used in the metal processing industries such as wire drawing of non-ferrous metals such as various copper, aluminium, stainless steel.Resultant metal wire drawing liquid of the present invention has good lubricating property and heat dispersion, is the ideal in the non-ferrous metal processing, efficient, energy-saving and environmental protection auxiliary agent.
Embodiments of the present invention are comparatively simple, as long as carry out step-by-step operation by described recipe ratio of top specification sheets and manufacture method step thereof, just can implement the present invention preferably.The contriver is through years of researches, test, detection and use checking, and the contriver has many successful embodiment.Below only for following three embodiment, embodiment has only changed the different weight percents processing condition when of filling a prescription, its manufacture method operation steps is fully by the described method steps operation of top specification sheets, its temperature and reaction times also change in the described temperature range of specification sheets, the time range fully in the above, all enforcement the present invention that can be successful.Wherein:
The weight percent recipe ratio of embodiment 1 is as follows:
Deionized water 40.0%
Triethanolamine 8.5%
Oleic acid 20.0%
Stearic acid 8.0%
Ammoniacal liquor (17%) 3.0%
Anhydrous sorbitol Soxylat A 25-7 monoleate 18.0%
Methyl-silicone oil 1.7%
EDTA 0.3％
Sodium Benzoate 0.5%
Its main technique condition heats up, constant temperature can be at 70 ℃; Constant temperature time 20 minutes;
The weight percent recipe ratio of embodiment 2 is as follows:
Deionized water 38.7%
Triethanolamine 10.0%
Oleic acid 25.0%
Stearic acid 2.5%
Ammoniacal liquor (17%) 1.0%
Anhydrous sorbitol Soxylat A 25-7 monopalmitate 20.0%
Methyl-silicone oil 2.0%
EDTA 0.3％
Sodium Benzoate 0.5%
Its main technique condition: 75 ℃ of intensification, constant temperature, constant temperature time 30 minutes;
The weight percent recipe ratio of embodiment 3 is as follows:
Deionized water 40.0%
Triethanolamine 4.2%
Oleic acid 9.5%
Stearic acid 12.0%
Ammoniacal liquor (17%) 4.5%
Anhydrous sorbitol Soxylat A 25-7 monoleate 12.0%
Anhydrous sorbitol Soxylat A 25-7 monopalmitate 15.0%
Methyl-silicone oil 2.0%
EDTA 0.3％
Sodium Benzoate 0.5%
Its main technique condition: 80 ℃ of intensification, constant temperature, constant temperature time 40 minutes.
Through described prescription of the present invention of top invention book and the prepared product of the present invention of manufacture method step---high-effiicent environment protection energy-saving metal wire-drawing solution can reach following each basic mechanical design feature index: (1) product of the present invention is a kind of yellow thick liquid, be mixed with different concentration by different extreme pressure intensity during use, (by the size of drawing brass wire diameter, this liquid dosage being become 10%～2% concentration) this product has good water-solubility, and being dissolved in behind the water is a kind of little yellow transparent liquid; (2) the pH value of product of the present invention is: pH=7.5～8.0; (3) product of the present invention is formulated by multiple actives, can obtain biological degradation at short notice, can effectively solve the environmental issue of sewage discharge for a long time, and the BOD COD in the sewage effluent all meets state environmental emissioning standard; (4) product of the present invention is formulated by the kinds of surface promoting agent, has the effect of good metal surface adsorption, can on the metallic surface, form layer protecting film rapidly, make metal obtain lubrication protection in the metallic surface under external force, thereby reduced frictional force, reduce the load of machine, really reach purpose of energy saving; (5) product of the present invention has added a certain amount of static inhibitor, so have in the good elimination process of metal working because the static that friction is produced; (6) the homogeneous water is used as lubricating product of the present invention, heat-eliminating medium owing to having adopted, so can effectively control the working temperature of machine, the heat that is produced in the metal processing is taken away rapidly.Simultaneously, because Ben Lasi liquid contains cleaning performance, thus can keep the heat exchange system cleaning, not blocked, guarantee the normal operation of heat exchanger; (7) product of the present invention has added the high-performance extreme-pressure agent, so have good extreme pressure property, can effectively protect the work-ing life of mould, improves metal surface; (8) product of the present invention meets the service requirements of high-speed wire-drawing machine fully, the per minute drawing speed is not less than 2800 meters, non-stop run does not break, if can be adapted to the use of import high-speed wire-drawing machine fully through the wire drawing liquid of particular requirement preparation, the drawing speed per minute can reach 3600 meters; (9) work-ing life of product of the present invention and environmental-protecting performance all conform with the modern high technology product requirement.
Claims (1)
- The present invention is a kind of manufacture method of high-efficient energy-saving environment friendly wire drawing liquid, it is characterized in that: it is as follows that it makes recipe ratio (its following per-cent all is weight percentage):Deionized water 40～45%Triethanolamine 3.5～10.5%Oleic acid 9.0～25%Stearic acid 2.0～12.5%Ammoniacal liquor (17%) 0.8～5.0%Anhydrous sorbitol Soxylat A 25-7 monoleate 12.0～18%Anhydrous sorbitol Soxylat A 25-7 monopalmitate 15.0～20%Methyl-silicone oil 1.5～2.5%Disodium ethylene diamine tetraacetate EDTA 0.1～0.5%Sodium Benzoate 0.2～0.8% its manufacture method step is as follows: (1) adds in proper order by the above-mentioned prescription of wire drawing liquid; (1) deionized water, triethanolamine are added in the reactor of band well heater, agitator, begin to stir and be heated to 70～80 ℃; (2) oleic acid is slowly joined make triethanolamine and oleic acid carry out saponification reaction in the reactor to become oleic acid triethanolamine soap solution again, constant temperature is 20～40 minutes under 70～80 ° of temperature; (3) stearic acid is added in the reactor, ammoniacal liquor is slowly added after stearic acid dissolves fully by the time again, temperature remains on 70～80 ℃, constant temperature 20～40 minutes; (4) again unclassified stores is added one by one by above-mentioned prescription order, and be stirred to till the whole dissolvings of all materials; (5) solution is cooled to 40～50 ℃ and stops to stir, carry out discharging, make product of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01107565 CN1128202C (en) | 2001-02-23 | 2001-02-23 | Method for making high-effiicent environment protection energy-saving metal wire-drawing solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01107565 CN1128202C (en) | 2001-02-23 | 2001-02-23 | Method for making high-effiicent environment protection energy-saving metal wire-drawing solution |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1319649A true CN1319649A (en) | 2001-10-31 |
| CN1128202C CN1128202C (en) | 2003-11-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01107565 Expired - Fee Related CN1128202C (en) | 2001-02-23 | 2001-02-23 | Method for making high-effiicent environment protection energy-saving metal wire-drawing solution |
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| CN (1) | CN1128202C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102433208A (en) * | 2011-10-21 | 2012-05-02 | 鞍山海华油脂化学有限公司 | Environment-friendly steel wire drawing lubricating agent and production method thereof |
| CN102433211A (en) * | 2011-10-27 | 2012-05-02 | 姜堰市华润化工厂 | Copper drawing water-based cold rolling liquid and preparation method thereof |
| CN102559351A (en) * | 2011-11-14 | 2012-07-11 | 武汉大学 | Automobile radial tire steel cord wet-pulling lubricating agent |
| CN103992862A (en) * | 2014-04-25 | 2014-08-20 | 蚌埠市正园电子科技有限公司 | Drawing oil containing lecithin |
| CN103992865A (en) * | 2014-04-25 | 2014-08-20 | 蚌埠市正园电子科技有限公司 | Anti-freezing flame-retardation drawing oil |
| CN103992856A (en) * | 2014-04-25 | 2014-08-20 | 蚌埠市时代电子有限公司 | Sustained-release anti-oxidation high-efficiency drawing oil |
| CN106221885A (en) * | 2016-07-27 | 2016-12-14 | 四会市格鲁森润滑技术有限公司 | Environmentally friendly total synthesis water-base copper drawing fluid and preparation method thereof |
| CN110283650A (en) * | 2019-07-10 | 2019-09-27 | 深圳市长裕环保有限公司 | Water-soluble easy to wash punching drawing oil and preparation method thereof |
-
2001
- 2001-02-23 CN CN 01107565 patent/CN1128202C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102433208A (en) * | 2011-10-21 | 2012-05-02 | 鞍山海华油脂化学有限公司 | Environment-friendly steel wire drawing lubricating agent and production method thereof |
| CN102433208B (en) * | 2011-10-21 | 2013-10-09 | 鞍山海华油脂化学有限公司 | Environment-friendly steel wire drawing lubricating agent and production method thereof |
| CN102433211A (en) * | 2011-10-27 | 2012-05-02 | 姜堰市华润化工厂 | Copper drawing water-based cold rolling liquid and preparation method thereof |
| CN102559351A (en) * | 2011-11-14 | 2012-07-11 | 武汉大学 | Automobile radial tire steel cord wet-pulling lubricating agent |
| CN102559351B (en) * | 2011-11-14 | 2013-05-08 | 武汉大学 | Automobile radial tire steel cord wet-pulling lubricating agent |
| CN103992865A (en) * | 2014-04-25 | 2014-08-20 | 蚌埠市正园电子科技有限公司 | Anti-freezing flame-retardation drawing oil |
| CN103992862A (en) * | 2014-04-25 | 2014-08-20 | 蚌埠市正园电子科技有限公司 | Drawing oil containing lecithin |
| CN103992856A (en) * | 2014-04-25 | 2014-08-20 | 蚌埠市时代电子有限公司 | Sustained-release anti-oxidation high-efficiency drawing oil |
| CN103992862B (en) * | 2014-04-25 | 2016-04-13 | 蚌埠市正园电子科技有限公司 | A kind of oil of the wire drawing containing Yelkin TTS |
| CN103992856B (en) * | 2014-04-25 | 2016-05-11 | 蚌埠市时代电子有限公司 | The anti-oxidant efficient wire drawing oil of a kind of spacetabs type |
| CN103992865B (en) * | 2014-04-25 | 2016-05-11 | 蚌埠市正园电子科技有限公司 | A kind of antifreeze fire-retardant wire drawing oil |
| CN106221885A (en) * | 2016-07-27 | 2016-12-14 | 四会市格鲁森润滑技术有限公司 | Environmentally friendly total synthesis water-base copper drawing fluid and preparation method thereof |
| CN110283650A (en) * | 2019-07-10 | 2019-09-27 | 深圳市长裕环保有限公司 | Water-soluble easy to wash punching drawing oil and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1128202C (en) | 2003-11-19 |
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