CN103992865B - A kind of antifreeze fire-retardant wire drawing oil - Google Patents
A kind of antifreeze fire-retardant wire drawing oil Download PDFInfo
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- CN103992865B CN103992865B CN201410172629.4A CN201410172629A CN103992865B CN 103992865 B CN103992865 B CN 103992865B CN 201410172629 A CN201410172629 A CN 201410172629A CN 103992865 B CN103992865 B CN 103992865B
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Abstract
The present invention relates to a kind of wire drawing oil, be specifically related to a kind of antifreeze fire-retardant wire drawing oil, wire drawing oil of the present invention is made up of the raw material of following weight portion: Di(dioctylpyrophosphato) ethylene titanate 0.2-0.5, soybean oil 160-180, rilanit special 40-50,2,5-ditert-butylhydro quinone 2-3,1,2-PD 6-8, tributyl phosphate 1-2, softex kw 0.5-1, nano-zinc borate 1-2, zinc stearate 2-3, anti-oxidant DLTP? 1-2, auxiliary agent 2-3; Wire drawing oil of the present invention has added nano-zinc borate, the zinc stearate powder through surface modification treatment in formula, effectively improve the resistance to elevated temperatures of wire drawing oil, lubricant effect is more good simultaneously, again in conjunction with other additive, make wire drawing oil meter prepared by the present invention reveal good anti-oxidant, antifreeze heatproof, fire retardancy, extended the service life of wire drawing oil, high-speed wire-drawing, the drawing process that can be applicable to various metals material are used.
Description
Technical field
The present invention relates to a kind of wire drawing oil, be specifically related to a kind of antifreeze fire-retardant wire drawing oil and preparation technology thereof.
Background technology
Wire drawing oil is the important industrial auxiliary agent of a class, in wire drawing, drawing process process, does high-efficiency lubricatingOil use, has lubricated, cleaning, the effect such as cooling, antirust, assists metal flow, avoids mould to drag colored bracing wire,Improve yield rate, reduce production loss. Existing wire drawing oil is mainly divided into oiliness wire drawing oil and water-based wire drawing oil,This two classes wire drawing oil cuts both ways in the time that reality is used, and as oiliness wire drawing oil exists heat dispersion poor, cleans chip removalDifficulty, the problems such as waste liquid difficult degradation, although and the wire drawing oil heat dispersion of water-based is good compared with oiliness wire drawing oil,Be that lubricant effect is not fully up to expectations, the wire drawing that is difficult to meet various metals line is drawn and is dialled technological requirement, therefore forImprove enterprise machined level, reduce production costs, need to improve wire drawing oil formula and technique, makeIt reaches good serviceability.
Summary of the invention
The object of the invention is to, a kind of antifreeze fire-retardant wire drawing oil is provided, to achieve these goals, thisThe technical scheme of bright employing is as follows:
An antifreeze fire-retardant wire drawing oil, is characterized in that, material of the present invention is made up of the raw material of following weight portion:Di(dioctylpyrophosphato) ethylene titanate 0.2-0.5, soybean oil 160-180, rilanit special40-50,2,5-ditert-butylhydro quinone 2-3,1,2-PD 6-8, tributyl phosphate 1-2, hexadecaneBase trimethylammonium bromide 0.5-1, nano-zinc borate 1-2, zinc stearate 2-3, anti-oxidant DLTP 1-2, helpAgent 2-3; Described auxiliary agent is made up of the raw material of following weight portion: butyl stearate 12-15, Graphene 1-2,Sodium metasilicate 1-2, xanthans 10-12, ethoxylated dodecyl alcohol 4-5, deionized water are appropriate; Preparation sideMethod is: first by adding ethoxylated dodecyl alcohol, Graphene in butyl stearate, at 1000-1500 rev/minUnder clock, stir 20-30min, make emulsion for subsequent use, then xanthans is mixed with appropriate deionized water, joinMake the xanthan gum solution that mass concentration is 60-70%, finally the aqueous solution, emulsion and other are remained intoDivide and mix, continue to stir 15-20min with 1000-1500 rev/min of rotating speed, stir and finish rear standing 2-4h,Obtain.
Described a kind of antifreeze fire-retardant wire drawing oil, its preparation technology is:
(1) first 1,2-PD, softex kw are mixed, be stirred well to cetylAfter trimethylammonium bromide dissolves, mixed liquor is for subsequent use;
(2) nano-zinc borate, zinc stearate are mixed with Di(dioctylpyrophosphato) ethylene titanate,Fully stir after 10-15min, then ball milling 20-30min, mixture is for subsequent use;
(3) soybean oil, rilanit special are mixed, be heated to 40-50 DEG C, add step (1) and step(2) gained material, stirs after 20-30min, adds other leftover materials, continues to stir 50-60min,After stirring finishes, naturally cool to room temperature, get product.
The wire drawing oil that the present invention prepares, using soybean oil, rilanit special as base oil, not only has excellentGood greasy property, and environmentally friendly easy degraded; But adopt vegetable oil as base oil exist oxidizable,The not shortcoming such as low temperature resistant high temperature in order to improve these shortcomings, has been added the nanometer through surface modification in raw materialThe powder such as Firebrake ZB, zinc stearate, it can be dispersed in base oil, effectively improves the resistance to of wire drawing oilHigh-temperature behavior, promotes lubricant effect, and in addition, the raw materials such as 2,5-ditert-butylhydro quinone, 1,2-PD alsoImproved anti-oxidant, the antifreeze ability of base oil, therefore, the wire drawing oil of preparation of the present invention in actual useShow good anti-oxidant, antifreeze heatproof, fire retardancy, extended the service life of wire drawing oil, Neng GoushiHigh-speed wire-drawing, drawing process for various metals material are used.
Detailed description of the invention
Embodiment
The present embodiment wire drawing oil by following weight portion (kilogram) raw material make: two (two octyloxy pyrophosphatesBase) ethylene titanate esters 0.3, soybean oil 180, rilanit special 40,2,5-ditert-butylhydro quinone 3,1,2-Propane diols 8, tributyl phosphate 1, softex kw 1, nano-zinc borate 1, zinc stearate 3,Anti-oxidant DLTP 1, auxiliary agent 3; Described auxiliary agent is made up of the raw material of following weight portion: butyl stearate 15,Graphene 1, sodium metasilicate 2, xanthans 10, ethoxylated dodecyl alcohol 4, deionized water are appropriate; PreparationMethod is: first by adding ethoxylated dodecyl alcohol, Graphene in butyl stearate, under 1500 revs/minStir 20min, make emulsion for subsequent use, then xanthans is mixed with appropriate deionized water, be mixed with qualityConcentration is 70% xanthan gum solution, finally the aqueous solution, emulsion and other residual components is mixed, and continuesStir 15min with 1500 revs/min of rotating speeds, stir and finish rear standing 3h, to obtain final product.
Described a kind of antifreeze fire-retardant wire drawing oil, its preparation technology is:
(1) first 1,2-PD, softex kw are mixed, be stirred well to cetylAfter trimethylammonium bromide dissolves, mixed liquor is for subsequent use;
(2) nano-zinc borate, zinc stearate are mixed with Di(dioctylpyrophosphato) ethylene titanate,Fully stir after 15min, then ball milling 30min, mixture is for subsequent use;
(3) soybean oil, rilanit special are mixed, be heated to 50 DEG C, add step (1) and step (2)Gained material, after stirring 30min, adds other leftover materials, continues to stir 50min, and stirring finishes certainly rearSo be cooled to room temperature, get product.
Wire drawing oil of the present invention can stablize at ambient temperature deposit at least one year, during this time without precipitating, lamination;Concrete each performance indications are as follows:
Claims (2)
1. an antifreeze fire-retardant wire drawing oil, it is characterized in that, this wire drawing oil is made up of the raw material of following weight portion: Di(dioctylpyrophosphato) ethylene titanate 0.2-0.5, soybean oil 160-180, rilanit special 40-50,2,5-ditert-butylhydro quinone 2-3,1,2-PD 6-8, tributyl phosphate 1-2, softex kw 0.5-1, nano-zinc borate 1-2, zinc stearate 2-3, anti-oxidant DLTP 1-2, auxiliary agent 2-3; Described auxiliary agent is made up of the raw material of following weight portion: butyl stearate 12-15, Graphene 1-2, sodium metasilicate 1-2, xanthans 10-12, ethoxylated dodecyl alcohol 4-5, deionized water are appropriate; Preparation method is: first will in butyl stearate, add ethoxylated dodecyl alcohol, Graphene, under 1000-1500 rev/min, stir 20-30min, make emulsion for subsequent use, again xanthans is mixed with appropriate deionized water, be mixed with the xanthan gum solution that mass concentration is 60-70%, finally the aqueous solution, emulsion and other residual components mixed, continue to stir 15-20min with 1000-1500 rev/min of rotating speed, stirring finishes rear standing 2-4h, to obtain final product.
2. a kind of antifreeze fire-retardant wire drawing oil as claimed in claim 1, its preparation technology is as follows:
(1) first 1,2-PD, softex kw are mixed, be stirred well to after softex kw dissolving, mixed liquor is for subsequent use;
(2) nano-zinc borate, zinc stearate are mixed with Di(dioctylpyrophosphato) ethylene titanate, fully stir after 10-15min, then ball milling 20-30min, mixture is for subsequent use;
(3) soybean oil, rilanit special are mixed, be heated to 40-50 DEG C, add step (1) and step (2) gained material, stir after 20-30min, add other leftover materials, continue to stir 50-60min, after stirring finishes, naturally cool to room temperature, get product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410172629.4A CN103992865B (en) | 2014-04-25 | 2014-04-25 | A kind of antifreeze fire-retardant wire drawing oil |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410172629.4A CN103992865B (en) | 2014-04-25 | 2014-04-25 | A kind of antifreeze fire-retardant wire drawing oil |
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| CN103992865A CN103992865A (en) | 2014-08-20 |
| CN103992865B true CN103992865B (en) | 2016-05-11 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106753732B (en) * | 2016-12-17 | 2019-09-13 | 大连大学 | A kind of soybean oil emulsion and preparation method thereof |
| US11180710B2 (en) * | 2017-04-27 | 2021-11-23 | The Lubrizol Corporation | Method of lubricating a mechanical device with high pyrophosphate level lubricant |
| CN107880973B (en) * | 2017-10-30 | 2020-12-04 | 湖南金泰检测检验有限公司 | Graphene oxide reinforced lubricant and preparation method thereof |
| CN112358908A (en) * | 2020-11-25 | 2021-02-12 | 中国科学院兰州化学物理研究所 | High-dropping-point flame-retardant steel wire rope lubricating grease composition and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1197108A (en) * | 1997-04-18 | 1998-10-28 | 郭紫鸣 | Aluminium wiredrawing lubricating grease |
| CN1319649A (en) * | 2001-02-23 | 2001-10-31 | 华南理工大学 | Method for making high-effiicent environment protection energy-saving metal wire-drawing solution |
| CN103614218A (en) * | 2013-10-21 | 2014-03-05 | 全威（铜陵）铜业科技有限公司 | Synthetic base wire drawing liquid and preparation method thereof |
-
2014
- 2014-04-25 CN CN201410172629.4A patent/CN103992865B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1197108A (en) * | 1997-04-18 | 1998-10-28 | 郭紫鸣 | Aluminium wiredrawing lubricating grease |
| CN1319649A (en) * | 2001-02-23 | 2001-10-31 | 华南理工大学 | Method for making high-effiicent environment protection energy-saving metal wire-drawing solution |
| CN103614218A (en) * | 2013-10-21 | 2014-03-05 | 全威（铜陵）铜业科技有限公司 | Synthetic base wire drawing liquid and preparation method thereof |
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| CN103992865A (en) | 2014-08-20 |
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Address after: 233000 No. 1259 Changqing South Road, hi tech Zone, Anhui, Bengbu Patentee after: Bengbu Zhengyuan Electronic Technology Co., Ltd Address before: 233000 No. 1259 Changqing South Road, hi tech Zone, Anhui, Bengbu Patentee before: BENGBU ZHENGYUAN ELECTRONIC TECHNOLOGY Co.,Ltd. |
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