CN1329124A - water-based mud extreme pressure lubricant - Google Patents
water-based mud extreme pressure lubricant Download PDFInfo
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- CN1329124A CN1329124A CN 01115906 CN01115906A CN1329124A CN 1329124 A CN1329124 A CN 1329124A CN 01115906 CN01115906 CN 01115906 CN 01115906 A CN01115906 A CN 01115906A CN 1329124 A CN1329124 A CN 1329124A
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- China
- Prior art keywords
- extreme pressure
- fatty acid
- acid
- oil
- pressure lubricant
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Links
- 239000000314 lubricant Substances 0.000 title claims abstract description 76
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 41
- 239000000194 fatty acid Substances 0.000 claims abstract description 41
- 229930195729 fatty acid Natural products 0.000 claims abstract description 41
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 31
- 238000005553 drilling Methods 0.000 claims abstract description 28
- -1 fatty acid ester Chemical class 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract 2
- 239000003921 oil Substances 0.000 claims description 31
- 235000019198 oils Nutrition 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 21
- 235000013311 vegetables Nutrition 0.000 claims description 12
- 150000002632 lipids Chemical class 0.000 claims description 10
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 7
- 239000010775 animal oil Substances 0.000 claims description 7
- 239000013543 active substance Substances 0.000 claims description 6
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 4
- 239000004519 grease Substances 0.000 claims description 4
- 241001494479 Pecora Species 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 235000012343 cottonseed oil Nutrition 0.000 claims description 3
- 239000002385 cottonseed oil Substances 0.000 claims description 3
- 239000000944 linseed oil Substances 0.000 claims description 3
- 235000021388 linseed oil Nutrition 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 claims description 2
- 229940063655 aluminum stearate Drugs 0.000 claims description 2
- 238000004945 emulsification Methods 0.000 claims description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 229960004232 linoleic acid Drugs 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 238000005120 petroleum cracking Methods 0.000 claims description 2
- 239000003760 tallow Substances 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 150000002148 esters Chemical class 0.000 abstract description 2
- 239000002002 slurry Substances 0.000 description 21
- 239000002689 soil Substances 0.000 description 21
- 239000013535 sea water Substances 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 12
- 239000013505 freshwater Substances 0.000 description 8
- 230000001050 lubricating effect Effects 0.000 description 7
- 238000005461 lubrication Methods 0.000 description 7
- 235000010469 Glycine max Nutrition 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000005987 sulfurization reaction Methods 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 4
- 244000068988 Glycine max Species 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 3
- 229940077388 benzenesulfonate Drugs 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 238000009775 high-speed stirring Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- KZMAWJRXKGLWGS-UHFFFAOYSA-N 2-chloro-n-[4-(4-methoxyphenyl)-1,3-thiazol-2-yl]-n-(3-methoxypropyl)acetamide Chemical compound S1C(N(C(=O)CCl)CCCOC)=NC(C=2C=CC(OC)=CC=2)=C1 KZMAWJRXKGLWGS-UHFFFAOYSA-N 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- 238000004537 pulping Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 1
- 239000005069 Extreme pressure additive Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- XKGDWZQXVZSXAO-ADYSOMBNSA-N Ricinoleic Acid methyl ester Chemical group CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OC XKGDWZQXVZSXAO-ADYSOMBNSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention relates to a mud extreme pressure lubricant used when a drilling tool operates under extremely high pressure, which comprises 5-20% of sulfurized fatty acid or sulfurized oil ester, 0-40% of fatty acid, 10-50% of fatty acid ester, 0.5-3% of surfactant and 30-60% of white oil with the flash point higher than 80 ℃.
Description
The present invention relates to a kind of MUD LUBRICANTS that is used for drilling operation, relate in particular to a kind of mud extreme pressure lubricant that under extremely high pressure, uses in the operation when drilling tool.
In drilling process,, improve drilling speed in order to reduce moment of torsion, prolong drilling life of bit, reduce the number of times that makes a trip, reduce the mud drum of drill bit and drill collar, reduce pump pressure, usually use MUD LUBRICANTS, make mud form oil-in-water emulsion mud, reduce oil water interfacial tension, and make the metallic surface of drilling tool have good glossy wetting, reduce the mud drum of drill bit and drill collar, reduce the possibility that adheres to bit freezing.
Under certain the pressure of the drill and drilling speed condition; use common MUD LUBRICANTS; can reduce the rotary torque of drilling tool; prolong the work-ing life of drill bit; but bear at drilling tool under the condition of very high loads; even best regular mud lubricant can not satisfy the lubricating requirement of bit bearing, often wearing and tearing in advance of drill bit at this moment, thereby have to pull out of hole in the past at the complete blunt of drill teeth; in case the bearing extreme wear may make gear wheel drop in the well; in order to prevent this situation, must add special additive, make drilling tool under the extremely high pressure condition; can form firm chemical films in the metal surface of drill stem of friction; surface of drill stem is played a protective role, prolong bit life, reduce the number of times that makes a trip; reduce the drilling rod moment of torsion; improve drilling speed, alleviate wearing and tearing, improve drilling efficiency drilling rod and drill bit.
The objective of the invention is to defective at described regular mud lubricant; a kind of mud extreme pressure lubricant is provided; this lubricant is particularly useful for water-based mud; bear at drilling tool under the condition of very high loads and use; can form firm chemical films in the metal surface of drill stem of friction; reach the protection surface of drill stem, prolong the purpose of bit life.
In the mud extreme pressure lubricant of the present invention, selected sulfide aliphatic acid or sulfuration grease as raw material.That is, this mud extreme pressure lubricant is higher than 80 ℃ white oil by a kind of sulfide aliphatic acid or vulcanized oil, a kind of lipid acid, a kind of ester of lipid acid, a kind of tensio-active agent and flash-point and forms.
Mud extreme pressure lubricant provided by the invention is a kind of mud extreme pressure lubricant that is used for water-base drilling fluid, its composition comprises: the sulfide aliphatic acid of 5-20% or sulfuration grease, the lipid acid of 0-40%, the fatty acid ester of 10-50%, the tensio-active agent of 0.5-3%, the flash-point of 30-60% are higher than 80 ℃ white oil, and each component sum is 100 weight %.
Mud extreme pressure lubricant provided by the invention is a kind of special additive, and it can form firm chemical films in the metallic surface of bearing friction, and this chemical films can alleviate the friction and wear between the contact surface.Under the same conditions, extreme-pressure additive of the present invention is added in the common lubricant, the metallic surface that is rubbed can become smooth, it is glossy wet to reduce the possibility of pressure differential sticking that drilling tool is become, especially in irregular hole diameter and inclined shaft and orientation well, can alleviate wearing and tearing to drilling rod and drill collar.
Sulfide aliphatic acid of the present invention is selected from the sulfide of vegetables oil mixed fatty acid, the sulfide of single fat acid or the sulfide of animal oil fatty acid, wherein, vegetables oil mixed fatty acid such as Castor Oil Fatty Acid, soy(a)-bean oil fatty acid, cottonseed oil fatty acid, linseed oil fatty acid etc., single fat is sour as linolic acid, oleic acid etc., animal oil fatty acid such as lard lipid acid, tallow fatty acid, the acid of sheep grease fat etc.; Vulcanized oil is selected from the sulfide of animal oil or vegetables oil, wherein, and vegetables oil such as Viscotrol C, soya-bean oil, Oleum Gossypii semen, vegetable seed wet goods, animal oil such as lard, butter, sheep wet goods.
The used lipid acid of the present invention can be the vegetables oil mixed fatty acid of speaking of above.And the lower vegetables oil mixed fatty acid of the also preferred described zero pour of lipid acid described in the fatty acid ester component, as soy(a)-bean oil fatty acid, Castor Oil Fatty Acid, rapeseed oil fatty acid, cottonseed oil fatty acid.Fatty acid ester then is preferably fatty acid methyl ester or fatty-acid ethyl ester.
The action principle one of mud extreme pressure lubricant provided by the invention is to make mud form oil-in-water emulsion mud, reduces oil water interfacial tension; The 2nd, form firm chemical films in the metallic surface.The tensio-active agent that the present invention uses is the additive with emulsification function, preferably can be anion surfactant or nonionogenic tenside, more preferably, anion surfactant is selected sulfonated petro-leum or petroleum benzene sulfonate for use, promptly, the carbochain of this sulfonate or benzene sulfonate is the petroleum cracking product, is preferably wherein C
10-C
15The sulfonate or the benzene sulfonate of alkane; The tensio-active agent of non-ionic type is preferably the Soxylat A 25-7 of alkylphenol, and alkyl wherein can be C
6-C
12Alkyl, and polyoxyethylated molecular weight is preferably at about 200-600.
The defoamer that also can comprise appropriate amount in the extreme pressure lubricant of the present invention, usage quantity are about 0.5-2%, and this defoamer is preferably silicone oil or aluminum stearate, or the close product of effect.
Every test-results shows, extreme pressure lubricant of the present invention is except that the effect with regular mud lubricant, can also bear under the condition of very high loads at drilling tool, surface of drill stem in friction forms firm chemical films, thereby effectively reduces the drilling tool moment of torsion, improves drilling speed, prolong bit life, minimizing can be widely used in the drilling operation of oil-gas field development the wearing and tearing of drilling tool, is particluarly suitable for using in the drilling operation of inclined shaft and orientation well.
Further describe the present invention below by embodiment, but the present invention is not constituted any qualification.
Embodiment 1
According to following prescription each material is mixed with extreme pressure lubricant of the present invention.
Sulfuration soy(a)-bean oil fatty acid 12.5%
Ricinolic acid methyl esters 40%
White oil (flash-point is higher than 80 ℃) 45.5%
Polyoxyethylene nonylphenol ether (the molecule 1 .0% of Soxylat A 25-7
Amount is at 200-600)
Silicone oil 1.0%
Embodiment 2
According to following prescription each material is mixed with extreme pressure lubricant of the present invention.
Sulfuration soya-bean oil 12.5%
Linseed oil fatty acid 20%
Castor Oil Fatty Acid ethyl ester 21%
White oil (flash-point is higher than 80 ℃) 45%
Polyoxyethylene nonylphenol ether (the molecule 1 .5% of Soxylat A 25-7
Amount is at 200-600)
Embodiment 3
According to following prescription each material is mixed with extreme pressure lubricant of the present invention.
Sulfuration soya-bean oil 11.5%
Castor Oil Fatty Acid 20%
Castor Oil Fatty Acid ethyl ester 21%
White oil (flash-point is higher than 80 ℃) 45%
(moieties is C to petroleum sodium sulfonate
10-C
15Oil 1.5%
Lysate)
Aluminum foil stearate 1%
The experimental example part
The preparation of mud
According to following prescription, earlier will
Soil is made into 8% fresh water
Soil paste, aquation was diluted to 3% with seawater after 16 hours, added other treatment agent then, and airtight aquation 16 hours can make mud (seawater
Soil mud).Surplus is a seawater in the prescription.
NaOH (sodium hydroxide) 0.2%
Na
2CO
3(yellow soda ash) 0.2%
N-PAN (polypropylene cyanogen ammonium) 0.5%
DFD (treated starch) 1%
PAC-HV (Polyanionic Cellulose one is high sticking) 0.3%
PF-TEX (sulfonated gilsonite) 2%
PF—PLUS(80A51) 0.3％
KCl (Repone K) 5%
Seawater to 100%
Experimental example 1
Preparation 6%
Soil paste is pressed the extreme pressure lubricant that different ratios adds embodiment 1 preparation, stirs, and measures the extreme pressure lubricant of embodiment 1 preparation at seawater with E-P extreme boundary lubrication combined instrument
Moment of torsion in the soil matrix slurry, calculated torque is fallen, and wherein the base slurry is
Soil adds seawater and is made into 6% after the pulping in fresh water
Soil paste, the result is as shown in table 1.The torque drop calculation formula is:
Torque drop=(add in base slurry torque-Ji slurry lubricant after torque)/base slurry torque * 100%
Table 1 extreme pressure lubricant is at seawater
Torque drop project base slurry in the soil paste (6% sea base slurry+1% extreme pressure base slurry+2% extreme pressure base slurry+3% extreme pressure
Water
Soil paste) lubricants lubricant moment of torsion reading 54 5.0 3.1 2.3 torque drops (%) 91.7 94 95.7 lubricating coefficients 0.54 0.050 0.031 0.023 experimental example 2
With the mud high-speed stirring of aforesaid method (experimental example) preparation 5 minutes, press the extreme pressure lubricant that different ratios adds embodiment 1 preparation, stir, measure the moment of torsion that mud adds the extreme pressure lubricant front and back with E-P extreme boundary lubrication combined instrument, formula calculating torque with reference to experimental example 2 falls, and the result is as shown in table 2.
The torque drop project of table 2 extreme pressure lubricant in sea-water mud do not add lubricant and adds lubricant 1% and add lubricant 2% and add lubricant 3% moment of torsion reading 13.5 9.6 8.7 7.0 torque drops (%) 0 28 36 48 lubricating coefficients 0.135 0.096 0.087 0.072
Experimental example 3
The fresh water of preparation 6%
The soil matrix slurry is pressed the extreme pressure lubricant that different ratios adds embodiment 1 preparation, stirs, and measures fresh water with E-P extreme boundary lubrication combined instrument
Add the torque before and after the extreme pressure lubricant of embodiment 2 preparations in the soil matrix slurry, calculate torque with reference to the formula of experimental example 2 and fall, the result is as shown in table 3.
Table 3 extreme pressure lubricant is at fresh water
Torque drop project base slurry in the soil paste (6% fresh water base slurry+1% extreme pressure base slurry+2% extreme pressure base slurry+3% extreme pressure
Soil paste) lubricants lubricant moment of torsion reading 52 4.2 3.0 1.9 torque drops (%) 92 94 96 lubricating coefficients 0.52 0.042 0.030 0.019
Experimental example 4
Measure 6% seawater with E-P extreme boundary lubrication combined instrument
Add the moment of torsion before and after the extreme pressure lubricant of embodiment 2 preparations in the soil matrix slurry, calculate torque with reference to the formula of experimental example 2 and fall, wherein the base slurry is
Soil adds seawater and is made into 6% after the pulping in fresh water
Soil paste, the result is as shown in table 4.Table 4 extreme pressure lubricant is at seawater
Torque drop in the soil paste
Base slurry (6% seawater base slurry+1% extreme pressure base slurry+2% extreme pressure base slurry+3% utmost point project
Soil paste) lubricants pressure lubricating agent moment of torsion reading 54 5.2 3.2 2.1 torque drops (%) 90 94 96 lubricating coefficients 0.54 0.052 0.032 0.021
Experimental example 5
The lubricity experiment of lubricant in mud
The mud high-speed stirring that will prepare by preceding method 5 minutes, press the extreme pressure lubricant that different ratios adds embodiment 2 preparations, stir, measure the moment of torsion that adds the extreme pressure lubricant front and back in the mud with E-P extreme boundary lubrication combined instrument, formula calculating torque with experimental example 2 falls, and the test result of this normal temperature lubricity is as shown in table 5.Again the mud of mud and adding lubricant is poured in the digestion tank, under 120 ℃ in the roller process furnace heat rolled 16 hours, moment of torsion after this extreme pressure lubricant heat in mud is rolled 120 ℃ * 16h is measured with E-P extreme boundary lubrication combined instrument in cooling back, calculates torque equally and falls, and the result is as shown in table 6.
The torque drop project of table 5 extreme pressure lubricant in mud do not add lubricant and adds lubricant 1% and add lubricant 2% and add lubricant 3% moment of torsion reading 13.5 9.8 8.6 7.2 torque drops (%) 0 27 36 46 lubricating coefficients 0.135 0.098 0.086 0.072
Table 6 extreme-pressure lubricant heat in mud torque drop project behind the 120 ℃ * 16h of rolling does not add lubricant and adds lubricant 1% and add lubricant 2% and add lubricant 3% moment of torsion reading 12.6 6.8 5.6 4.2 torque drops (%) 0 46 55 66 lubricating coefficients 0.126 0.068 0.056 0.042
Experimental example 6
The mensuration of extreme pressure value
To get two parts of high-speed stirring 5 minutes according to the mud that preceding method prepares, the extreme pressure lubricant of embodiment 2 preparations of a copy of it adding 2%, stir, be 1000 rev/mins at rotating speed, to apply moment of torsion be that 100inch-pounds, time are under the condition of 5min, with the extreme pressure value that E-P extreme boundary lubrication combined instrument is measured the extreme pressure value of this mud and added the mud of 2% extreme pressure lubricant, the result is as shown in table 8.
Table 8 mud and be added with the extreme pressure value of the mud of 2% extreme pressure lubricant
From table 1-8 experimental data as can be seen, this extreme pressure lubricant is at seawater
Soil paste, fresh water
All have fabulous oilness in soil paste and the mud, the mud that adds 2% extreme pressure lubricant has higher extreme pressure value.This product can be widely used in the drilling operation of oil-gas field development, and is especially more effective in the drilling operation of inclined shaft and orientation well.
Claims (10)
1, a kind of extreme pressure lubricant that is used for water-base drilling fluid, its composition comprises: the tensio-active agent of the lipid acid of the sulfide aliphatic acid of 5-20% or vulcanized oil, 0-40%, the fatty acid ester of 10-50%, 0.5-3%, the flash-point of 30-60% are higher than 80 ℃ white oil, and each component sum is 100 weight %.
2, the described extreme pressure lubricant of claim 1, wherein, described sulfide aliphatic acid is selected from the sulfide of vegetables oil mixed fatty acid, the sulfide of single fat acid or the sulfide of animal oil fatty acid; Vulcanized oil is selected from the vulcanized oil of animal oil or vegetables oil.
3, the described extreme pressure lubricant of claim 1, wherein, described lipid acid is selected from vegetable fatty acids.
4, the described extreme pressure lubricant of claim 1, wherein, described fatty acid ester is fatty acid methyl ester or fatty-acid ethyl ester, lipid acid wherein is the vegetables oil mixed fatty acid.
5, the described extreme pressure lubricant of claim 1, wherein, tensio-active agent is selected from anionic or the nonionic surface active agent with emulsification function.
6, the described extreme pressure lubricant of claim 1 is wherein gone back the defoamer that selectivity includes 0.5-2%.
7, the described extreme pressure lubricant of claim 2, wherein, the vegetables oil mixed fatty acid is selected from Castor Oil Fatty Acid, linseed oil fatty acid, soy(a)-bean oil fatty acid or cottonseed oil fatty acid; Animal oil fatty acid is selected from lard lipid acid, tallow fatty acid or the acid of sheep grease fat; Single fat acid is selected from linolic acid, oleic acid.
8, the described extreme pressure lubricant of claim 5, wherein, anion surfactant is C
10-C
15The alkylsulfonate or the alkylbenzene sulfonate of petroleum cracking thing; Nonionogenic tenside is the Soxylat A 25-7 of alkylphenol.
9, the described extreme pressure lubricant of claim 8, wherein, the alkyl in the Soxylat A 25-7 molecule of alkylphenol is C
8-C
14Alkyl, and polyoxyethylated molecular weight is at 200-600.
10, the described extreme pressure lubricant of claim 6, wherein, defoamer is silicone oil or aluminum stearate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011159065A CN1165595C (en) | 2001-04-30 | 2001-04-30 | water-based mud extreme pressure lubricant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011159065A CN1165595C (en) | 2001-04-30 | 2001-04-30 | water-based mud extreme pressure lubricant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1329124A true CN1329124A (en) | 2002-01-02 |
| CN1165595C CN1165595C (en) | 2004-09-08 |
Family
ID=4662272
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011159065A Expired - Fee Related CN1165595C (en) | 2001-04-30 | 2001-04-30 | water-based mud extreme pressure lubricant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1165595C (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735778A (en) * | 2009-12-03 | 2010-06-16 | 中国海洋石油总公司 | Highly-efficient lubricant for drilling fluid |
| CN101886015A (en) * | 2010-06-29 | 2010-11-17 | 吴莉 | Lubrication anti-wear agent |
| CN101892036A (en) * | 2010-08-09 | 2010-11-24 | 中国石油集团川庆钻探工程有限公司长庆钻井总公司 | Process for preparing drilling fluid for preventing polycrystalline diamond compact (PDC) bit balling |
| CN102344783A (en) * | 2011-07-22 | 2012-02-08 | 石家庄华莱鼎盛科技有限公司 | High-efficient antisticking lubricant for drilling fluid |
| CN102676127A (en) * | 2012-05-02 | 2012-09-19 | 陆明富 | Method for making low-fluorescence lubricant for drilling fluid |
| CN102851006A (en) * | 2012-09-30 | 2013-01-02 | 中国石油集团西部钻探工程有限公司 | Bio-oil lubricant for drilling wells and preparation method of bio-oil lubricant |
| CN102952528A (en) * | 2011-08-31 | 2013-03-06 | 中国石油化工股份有限公司 | Degradable drilling fluid lubricant and preparation method thereof |
| CN103013464A (en) * | 2012-12-27 | 2013-04-03 | 河北华运鸿业化工有限公司 | Low fluorescent lubricating agent for drilling fluid and method for preparing low fluorescent lubricating agent |
| CN103555302A (en) * | 2013-10-31 | 2014-02-05 | 中船勘察设计研究院有限公司 | drilling wall-protecting slurry prepared from seawater |
| CN103571441A (en) * | 2013-10-11 | 2014-02-12 | 四川康克石油科技有限公司 | Wear-resistant drag reducer for drilling fluid and preparation method thereof |
| CN103965841A (en) * | 2014-05-01 | 2014-08-06 | 克拉玛依市奥泽工贸有限责任公司 | Microemulsion white oil for drilling fluid as well as preparation and application methods thereof |
| CN104830292A (en) * | 2015-05-06 | 2015-08-12 | 天津中油渤星工程科技有限公司 | Low toxicity and low fluorescence lubricant for drilling fluid and preparation method thereof |
| CN107502317A (en) * | 2017-09-07 | 2017-12-22 | 杨锋 | A kind of drilling fluid extreme-pressure lubricant and preparation method thereof |
| CN107556988A (en) * | 2017-08-22 | 2018-01-09 | 中国石油天然气集团公司 | A kind of high temperature resistance environmentally-frielubricant lubricant for drilling fluid and preparation method thereof |
| CN108276973A (en) * | 2018-01-30 | 2018-07-13 | 四川泓华油气田工程科技有限公司 | Drilling fluid environment protective lubricant and preparation method thereof |
| CN109135688A (en) * | 2018-08-08 | 2019-01-04 | 天津渤海中联石油科技有限公司 | Drilling fluid fluid lubricant and preparation method thereof |
| CN109439294A (en) * | 2018-11-14 | 2019-03-08 | 山东得顺源石油科技有限公司 | A kind of high density drilling fluid heat and salinity tolerance extreme-pressure lubricant and preparation method thereof |
| CN109666461A (en) * | 2017-10-13 | 2019-04-23 | 中国石油化工股份有限公司 | A kind of drilling fluid drag reducer |
-
2001
- 2001-04-30 CN CNB011159065A patent/CN1165595C/en not_active Expired - Fee Related
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735778A (en) * | 2009-12-03 | 2010-06-16 | 中国海洋石油总公司 | Highly-efficient lubricant for drilling fluid |
| CN101886015A (en) * | 2010-06-29 | 2010-11-17 | 吴莉 | Lubrication anti-wear agent |
| CN101892036B (en) * | 2010-08-09 | 2012-12-12 | 中国石油集团川庆钻探工程有限公司长庆钻井总公司 | Process for preparing drilling fluid for preventing polycrystalline diamond compact (PDC) bit balling |
| CN101892036A (en) * | 2010-08-09 | 2010-11-24 | 中国石油集团川庆钻探工程有限公司长庆钻井总公司 | Process for preparing drilling fluid for preventing polycrystalline diamond compact (PDC) bit balling |
| CN102344783A (en) * | 2011-07-22 | 2012-02-08 | 石家庄华莱鼎盛科技有限公司 | High-efficient antisticking lubricant for drilling fluid |
| CN102344783B (en) * | 2011-07-22 | 2012-08-22 | 石家庄华莱鼎盛科技有限公司 | High-efficient antisticking lubricant for drilling fluid |
| CN102952528A (en) * | 2011-08-31 | 2013-03-06 | 中国石油化工股份有限公司 | Degradable drilling fluid lubricant and preparation method thereof |
| CN102676127A (en) * | 2012-05-02 | 2012-09-19 | 陆明富 | Method for making low-fluorescence lubricant for drilling fluid |
| CN102851006A (en) * | 2012-09-30 | 2013-01-02 | 中国石油集团西部钻探工程有限公司 | Bio-oil lubricant for drilling wells and preparation method of bio-oil lubricant |
| CN103013464A (en) * | 2012-12-27 | 2013-04-03 | 河北华运鸿业化工有限公司 | Low fluorescent lubricating agent for drilling fluid and method for preparing low fluorescent lubricating agent |
| CN103013464B (en) * | 2012-12-27 | 2015-07-01 | 河北华运鸿业化工有限公司 | Low fluorescent lubricating agent for drilling fluid and method for preparing low fluorescent lubricating agent |
| CN103571441A (en) * | 2013-10-11 | 2014-02-12 | 四川康克石油科技有限公司 | Wear-resistant drag reducer for drilling fluid and preparation method thereof |
| CN103571441B (en) * | 2013-10-11 | 2017-03-15 | 四川康克石油科技有限公司 | A kind of drilling fluid Wear-resistant drag reducer and preparation method thereof |
| CN103555302A (en) * | 2013-10-31 | 2014-02-05 | 中船勘察设计研究院有限公司 | drilling wall-protecting slurry prepared from seawater |
| CN103965841A (en) * | 2014-05-01 | 2014-08-06 | 克拉玛依市奥泽工贸有限责任公司 | Microemulsion white oil for drilling fluid as well as preparation and application methods thereof |
| CN104830292A (en) * | 2015-05-06 | 2015-08-12 | 天津中油渤星工程科技有限公司 | Low toxicity and low fluorescence lubricant for drilling fluid and preparation method thereof |
| CN104830292B (en) * | 2015-05-06 | 2017-12-05 | 天津中油渤星工程科技有限公司 | A kind of drilling fluid less toxic low fluorescence lubricant and preparation method thereof |
| CN107556988A (en) * | 2017-08-22 | 2018-01-09 | 中国石油天然气集团公司 | A kind of high temperature resistance environmentally-frielubricant lubricant for drilling fluid and preparation method thereof |
| CN107502317A (en) * | 2017-09-07 | 2017-12-22 | 杨锋 | A kind of drilling fluid extreme-pressure lubricant and preparation method thereof |
| CN109666461A (en) * | 2017-10-13 | 2019-04-23 | 中国石油化工股份有限公司 | A kind of drilling fluid drag reducer |
| CN108276973A (en) * | 2018-01-30 | 2018-07-13 | 四川泓华油气田工程科技有限公司 | Drilling fluid environment protective lubricant and preparation method thereof |
| CN109135688A (en) * | 2018-08-08 | 2019-01-04 | 天津渤海中联石油科技有限公司 | Drilling fluid fluid lubricant and preparation method thereof |
| CN109439294A (en) * | 2018-11-14 | 2019-03-08 | 山东得顺源石油科技有限公司 | A kind of high density drilling fluid heat and salinity tolerance extreme-pressure lubricant and preparation method thereof |
| CN109439294B (en) * | 2018-11-14 | 2020-09-22 | 山东得顺源石油科技有限公司 | Temperature-resistant and salt-resistant extreme pressure lubricant for high-density drilling fluid and preparation method thereof |
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| CN1165595C (en) | 2004-09-08 |
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Assignee: COSL Chemicals (Tianjin) Co., Ltd. Assignor: China Oilfield Services Limited Contract fulfillment period: 2008.2.1 to 2021.2.1 contract change Contract record no.: 2008990000063 Denomination of invention: Water base mud extreme pressure lubricant Granted publication date: 20040908 License type: General permission Record date: 2008.4.7 |
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