CN1315989C - 采用碱促进的铁催化剂的烃合成方法 - Google Patents

采用碱促进的铁催化剂的烃合成方法 Download PDF

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Publication number
CN1315989C
CN1315989C CNB038111659A CN03811165A CN1315989C CN 1315989 C CN1315989 C CN 1315989C CN B038111659 A CNB038111659 A CN B038111659A CN 03811165 A CN03811165 A CN 03811165A CN 1315989 C CN1315989 C CN 1315989C
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CN
China
Prior art keywords
catalyst
iron
hydrocarbon synthesis
carbon
alkali metal
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Expired - Fee Related
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CNB038111659A
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English (en)
Chinese (zh)
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CN1653159A (zh
Inventor
F·G·博特斯
T·C·布罗姆菲尔德
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Sasol Technology Pty Ltd
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Sasol Technology Pty Ltd
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Publication of CN1653159A publication Critical patent/CN1653159A/zh
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Anticipated expiration legal-status Critical
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB038111659A 2002-04-16 2003-04-15 采用碱促进的铁催化剂的烃合成方法 Expired - Fee Related CN1315989C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US37266702P 2002-04-16 2002-04-16
ZA200202986 2002-04-16
US60/372,667 2002-04-16
ZA2002/2986 2002-04-16

Publications (2)

Publication Number Publication Date
CN1653159A CN1653159A (zh) 2005-08-10
CN1315989C true CN1315989C (zh) 2007-05-16

Family

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Family Applications (2)

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CNB038111659A Expired - Fee Related CN1315989C (zh) 2002-04-16 2003-04-15 采用碱促进的铁催化剂的烃合成方法
CNB038111616A Expired - Fee Related CN1281711C (zh) 2002-04-16 2003-04-15 采用烃合成催化剂和酸性催化剂的烃合成方法

Family Applications After (1)

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CNB038111616A Expired - Fee Related CN1281711C (zh) 2002-04-16 2003-04-15 采用烃合成催化剂和酸性催化剂的烃合成方法

Country Status (5)

Country Link
US (2) US7459485B2 (https=)
JP (1) JP2005522566A (https=)
CN (2) CN1315989C (https=)
AU (2) AU2003262193B2 (https=)
WO (2) WO2003087266A1 (https=)

Families Citing this family (24)

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JP2005522566A (ja) * 2002-04-16 2005-07-28 サソル テクノロジー （プロプリエタリ） リミテッド アルカリ被促進鉄触媒を使用した炭化水素の合成方法
WO2005049765A1 (en) * 2003-11-20 2005-06-02 Sasol Technology (Pty) Limited The use of a source of chromium with a precipitated catalyst in a fischer-tropsch reaction
US20070225382A1 (en) * 2005-10-14 2007-09-27 Van Den Berg Robert E Method for producing synthesis gas or a hydrocarbon product
KR20090007594A (ko) * 2006-05-16 2009-01-19 비자 인터내셔날 써비스 어쏘시에이션 맞춤 정보를 제공하는 방법 및 시스템
US7544719B2 (en) * 2006-07-12 2009-06-09 Rentech, Inc. Method for activating an iron-based fischer-tropsch catalyst
AU2007231719B2 (en) * 2006-11-01 2012-02-02 Air Products And Chemicals, Inc. Solid carbonaceous feed to liquid process
CN101631740A (zh) 2007-11-20 2010-01-20 国际壳牌研究有限公司 用于生产纯化的合成气物流的方法
WO2009130292A2 (en) * 2008-04-24 2009-10-29 Shell Internationale Research Maatschappij B.V. Process to prepare an olefin-containing product or a gasoline product
US7825164B1 (en) 2009-11-18 2010-11-02 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid fuels using mixture of synthesis gas conversion catalyst and dual functionality catalyst
US20110168604A1 (en) * 2010-01-12 2011-07-14 Van Egmond Cornelis F Method for co-hydrogenating light and heavy hydrocarbons
CN101781576A (zh) * 2010-03-03 2010-07-21 北京国力源高分子科技研发中心 一种二氧化碳制备液体燃料的方法
JP5649849B2 (ja) * 2010-04-19 2015-01-07 日揮触媒化成株式会社 一酸化炭素還元触媒の製造方法および一酸化炭素還元触媒
US8461220B2 (en) * 2010-06-10 2013-06-11 Chevron U.S.A. Inc. Process and system for reducing the olefin content of a fischer-tropsch product stream
US8481601B2 (en) 2010-11-23 2013-07-09 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid hydrocarbon mixtures using a catalyst system containing ruthenium and an acidic component
CA2830504C (en) * 2011-03-19 2021-05-04 Quanta Technologies, Llc Process to improve formulations of hydrocarbon conversion catalysts through removal and modification of detrimental particles and reuse of modified fractions
GB2513488A (en) 2011-10-21 2014-10-29 Igtl Technology Ltd Methods of preparation and forming supported active metal catalysts and precursors
GB201118228D0 (en) 2011-10-21 2011-12-07 Ingen Gtl Ltd Methods of preparation and forming supported active metal catalysts and precursors
US9809758B2 (en) * 2014-07-24 2017-11-07 Exxonmobil Chemical Patents Inc. Production of xylenes from syngas
CN109794283B (zh) * 2017-11-15 2022-01-14 中国科学院大连化学物理研究所 一种由合成气直接制取芳烃的方法
CN110496639B (zh) * 2018-05-17 2022-05-27 中国科学院大连化学物理研究所 一种芳烃合成用催化剂及其制备方法和应用
US11426708B2 (en) * 2020-03-02 2022-08-30 King Abdullah University Of Science And Technology Potassium-promoted red mud as a catalyst for forming hydrocarbons from carbon dioxide
JP7731195B2 (ja) * 2020-12-25 2025-08-29 Ｅｎｅｏｓ株式会社 反応装置
CN114011423B (zh) * 2021-12-14 2023-10-20 上海兖矿能源科技研发有限公司 一种合成气制低碳烯烃的熔铁催化剂及其制备方法与应用
US12018392B2 (en) 2022-01-03 2024-06-25 Saudi Arabian Oil Company Methods for producing syngas from H2S and CO2 in an electrochemical cell

Citations (3)

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US4304871A (en) * 1976-10-15 1981-12-08 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing a dual catalyst bed
US4361503A (en) * 1978-07-21 1982-11-30 Mobil Oil Corporation Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha
WO2001097968A2 (en) * 2000-06-20 2001-12-27 Sasol Technology (Pty) Ltd Hydrocarbon synthesis catalyst and process

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US4086262A (en) * 1976-09-20 1978-04-25 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures
US4269783A (en) * 1977-03-07 1981-05-26 Mobil Oil Corporation Conversion of syngas to high octane olefinic naphtha
US4279830A (en) 1977-08-22 1981-07-21 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors
US4172843A (en) 1978-07-21 1979-10-30 Mobil Oil Corporation Conversion of synthesis gas to high octane predominantly olefinic naphtha
US4289695A (en) 1978-11-13 1981-09-15 Eli Lilly And Company Process for preparing 2-chlorosulfinylazetidinones
US4298695A (en) 1978-12-18 1981-11-03 Mobil Oil Corporation Conversion of synthesis gas with iron-containing catalyst
US4463101A (en) * 1980-12-29 1984-07-31 Mobil Oil Corporation Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha
US4652538A (en) 1983-11-01 1987-03-24 Union Carbide Corporation Catalysts for conversion of syngas to liquid motor fuels
US4556645A (en) * 1984-06-27 1985-12-03 Union Carbide Corporation Enhanced catalyst for conversion of syngas to liquid motor fuels
US4994428A (en) * 1989-03-17 1991-02-19 Mobil Oil Corp. Method for preparing a promoted iron catalyst and catalyst prepared by the method for conversion of synthesis gas to liquid hydrocarbons
US4978689A (en) * 1989-03-17 1990-12-18 Mobil Oil Corp. Conversion of synthesis gas to liquid hydrocarbons
GB2247412A (en) * 1989-03-17 1992-03-04 Mobil Oil Corp Regeneration of Fischer-Tropsch catalysts
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Patent Citations (3)

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US4304871A (en) * 1976-10-15 1981-12-08 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing a dual catalyst bed
US4361503A (en) * 1978-07-21 1982-11-30 Mobil Oil Corporation Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha
WO2001097968A2 (en) * 2000-06-20 2001-12-27 Sasol Technology (Pty) Ltd Hydrocarbon synthesis catalyst and process

Also Published As

Publication number Publication date
CN1653158A (zh) 2005-08-10
US20050203194A1 (en) 2005-09-15
JP2005522566A (ja) 2005-07-28
CN1653159A (zh) 2005-08-10
WO2003087265A1 (en) 2003-10-23
US7655704B2 (en) 2010-02-02
US20050227851A1 (en) 2005-10-13
CN1281711C (zh) 2006-10-25
WO2003087266A1 (en) 2003-10-23
US7459485B2 (en) 2008-12-02
AU2003262193A1 (en) 2003-10-27
AU2003262194A1 (en) 2003-10-27
AU2003262193B2 (en) 2007-12-20

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Granted publication date: 20070516

Termination date: 20210415