CN1311749C - Method for preparing strong anti-biosis, multi-functional agricultural chemical prepn. used for ocean living things - Google Patents
Method for preparing strong anti-biosis, multi-functional agricultural chemical prepn. used for ocean living things Download PDFInfo
- Publication number
- CN1311749C CN1311749C CNB2005100453996A CN200510045399A CN1311749C CN 1311749 C CN1311749 C CN 1311749C CN B2005100453996 A CNB2005100453996 A CN B2005100453996A CN 200510045399 A CN200510045399 A CN 200510045399A CN 1311749 C CN1311749 C CN 1311749C
- Authority
- CN
- China
- Prior art keywords
- salt
- chlorine dioxide
- preparation
- derivative
- plants
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The present invention relates to a preparing method for a high antibacterial multifunctional oceanic biologic agricultural preparation prepared from chitin modified by an antibacterial intensifying factor from an oceanic crustaceous organism, a derivative of the chitin and a universal plant nutrient substance as an auxiliary component for disinfecting plants. The agricultural preparation is prepared from the main components of chitosan, a derivative thereof, chlorine dioxide and a plant nutrient substance as an auxiliary component. The preparing method comprises: firstly preparing the chitosan and the derivative thereof into a 1% to 10% weakly acidic solution or a 1% to 10% neutral solution; slowly adding the chlorine dioxide component during stir, processing the mixture through reaction for 20 to 90 minutes; then adding the plant nutrient substance, and uniformly stirring the mixture to obtain the oceanic biologic agricultural preparation of which the solid content is from 0.0001% to 100%. The present invention has the advantages of simple implementing technology and abundant and easily obtained raw material. The oceanic biologic agricultural preparation prepared by the preparing method of the present invention has the advantages of wide application range, high antibacterial effect, high disinfecting effect, fertilizing action and yield increasing action, and can be widely used for spraying on the leaf surface of the plants or irrigating the rhizome of the plants.
Description
Technical field:
The present invention relates to chitin and derivative thereof that the antibiotic intensifier modification of a kind of usefulness comes from ocean crust biology, be aided with the preparation method that the general nutrient component preparation of plant is used for the strong antibiotic multifunction marine organisms Agrotechnical formulation of plant sterilization again.This preparation not only has strong killing power to bacillus, coccus, and fungi and virus are also had stronger killing action.Can not only controlling plant diseases, be beneficial to natural environmental-protective, also can make the usefulness of daily sterilization, prophylactic cross-infection.Patent classificating number A01N65/00.
Technical background:
At present, crops are being used various liquid fertile, and as foliage fertilizer, ammino acid liquid fertilizer, micro-liquid fertilizer etc., some aspect of these fertilizer is better than traditional fertilizer and single chemical fertilizer.But because the negative effect that long-term a large amount of applying pesticides and chemical fertilizer bring can't be eliminated for the moment.(as soil compaction, the decline of the single salt murder by poisoning of plant, crop yield and quality.) the particularly serious influence that is agricultural chemicals, chemical fertilizer to ecotope, causing the insect mortality, the chitin of the short long required insect secretion of plant growing reduces in a large number, has directly influenced the healthy growth and development of plant.Chitin is described as the 6th human biological element by American-European scientist.Modern's eaten food is too meticulous, original few chitin, and agricultural product lose part again in process, and people have generally reduced the picked-up to chitin like this.Health has also been caused influence in various degree.Though the negative effect of existing liquid fertile no chemical fertilizer.But lack the chitin to plant growing, for this reason, people press for a kind of Agrotechnical formulation that had not only had the negative effect of agriculture chemical but also made the crops healthy growth.
In existing or disclosed technology, more by the Agrotechnical formulation that plant leaf surface uses, as trace element fertilizer, composite amino acid fertilizer, plant growth promoter, bactericide or the like.JP 2000-212013A has described a kind of inhibitor with antifungic action that contains aqueous solution shitosan, salicylic acid, acetyl magnesium and saleratus: JP 2000-128711A has described a kind of agricultural and gardening disease inhibitor that comprises water soluble chitosan, salicylic acid and salicylic acid analog; US 5,374, and 627 to have described a kind of molecular weight be 10,000-50,000 the chitosan hydrolyzate thing and the composition that is used to prevent and treat some crop pest of acetate; RU214768A has described a kind of composition of preventing and treating rice blast, and it contains molecular weight is 800-50,000 and degree of deacetylation be shitosan, lactic acid, succinic acid, potassium metasilicate, dimethyl sulfoxide (DMSO) and the water of 70-90%; EP878129 has described the composition of a kind of increase to the plant disease resistance, and it comprises molecular weight is that 800-15000 and degree of deacetylation are shitosan, lactic acid and the succinic acid etc. of 65-97%; Chinese patent application CN01122696.X discloses " a kind of preparation of shitosan health plant growth promoter and technology ", it is base-material with the shitosan, with the mineralized water is carrier, be equipped with acetic acid, lecithin, composite aminophenol powder, rapeseed oil, steviol glycoside etc. are to have the foliage fertilizer that promotes the plant growth effect; CN01123508.X discloses " a kind of agriculturally useful compositions that contains water soluble chitosan "; said composition contains low-molecular-weight and degree of deacetylation greater than 75% shitosan and non-toxic organic acid, Choline Chloride, betain, light rare earth, amino acids, vitamins, monoethanolamine, trace element etc., also has the effect that promotes crop growth.There is following defective in these Agrotechnical formulations: (1) function singleness; (2) functional effect a little less than; (3) contain the friendly organic synthesis composition of non-ambient.Also have multinomial Chinese patent to relate to the preparation method of green disinfectant chlorine dioxide, be used for the sterilizing prevent disease of crops, though environmental protection, function singleness, use cost height.
Summary of the invention:
The objective of the invention is to overcome the shortcoming that exists in the prior art, aim to provide chitin and derivative thereof that the modification of the antibiotic intensifier chlorine dioxide of a kind of usefulness comes from ocean crust biology, be aided with the manufacture method that the general nutrient component preparation of plant is used for the strong antibiotic multifunction marine organisms Agrotechnical formulation of plant sterilization again.
Chitin and derivative thereof are described as the 6th vital principle, and this marine organisms cellulose is very easy of plant absorbing, has strengthened physiology, the biochemical function of plant.Plant vigor strengthens, and helps promoting the plant health growth, and for there not being insects secretion chitins such as honeybee, butterfly, the greenhouse growing plants, as booth vegetable etc., it is important to seem more, and it not only has resistant effect, the effect of increasing production of applying fertilizer in addition.
It is generally acknowledged that when plant was subjected to extraneous infringement and pathogen and infects, chitin and derivative thereof can inducing plant produce a series of defense responses to be protected and self avoid further injury, and the generation disease resistance.Can excite the material of the defense response of plant to be called exciton.Its effect is just as our usually said vaccine.The exciton of denier just can excite strong disease resistance response takes place in plant or the cell, produces and accumulation disease resistance material (also claiming protective plant protecting agent).Chitin and deacetyl chitin are the main components of the shell of crustacean, also are the constituents of multiple fungal cell wall.Crust oligosaccharides (oligochitin) and chitosan oligosaccharide (oligochitosan) are exactly the plant exciton.Though chitin oligo saccharide and chitosan oligosaccharide inducing plant produce the machine-processed not clear of resistance.But the effect that its inducing action makes plant produce antibody enemy disease resistance has obtained the confirmation of many scientific researches.This becomes chitin derivative and is used for the theoretical foundation of marine organisms with agent.
But regrettably, though chitin and derivative thereof have certain antibacterial action, but it is subjected to the influence of environment very big, antibacterial effect does not far reach sterilization effects, this make it at present Agrotechnical formulation under the trend of multifunction, high efficiency, environmental friendliness development, seeming, major function is not enough, thereby has influenced applying of it.Chlorine dioxide is the environmentally friendly sterilized disinfectant that is called as 21 century.Have wide spectrum, efficient, green advantage.Many aspects such as agricultural have been begun to be used for.But exist independent function of use very single, labour intensity is big, and defective such as effective drug duration is short.
In order to realize the foregoing invention purpose, the main component of the inventive method prepared preparation comprises deacetyl chitin and derivative thereof, chlorine dioxide, auxiliary element nutrient for plants; Elder generation is mixed with deacetyl chitin and derivative thereof 1%～10% weakly acidic solution or neutral solution, under stirring condition, slowly add chlorine dioxide component reaction 20～90 minutes, add nutrient for plants again and stir and promptly make the marine organisms Agrotechnical formulation, deacetyl chitin and derivative thereof account for 0.0001%～30% in its preparation; Chlorine dioxide accounts for 0.001%～30%; General nutrient for plants accounts for 0.1%～40%; Surplus is other solvents such as water, is weight ratio; Total solids content is 0.0001%～100%.Wherein employed deacetyl chitin and derivative thereof comprise deacetylation be 10%～100% take off acetyl crust quaternary ammonium salt shitosan, shitosan carboxylate; And quaternary ammonium salt shitosan and shitosan carboxylate can be selected sodium salt, sylvite, ammonium salt, magnesium salts, calcium salt, zinc salt, mantoquita, molysite, molybdenum inflammation, silver salt etc.; Employed chlorine dioxide component comprises chlorine dioxide, aqueous solution of chlorine dioxide, solid-state stabilizing chlorine dioxide, the recessive body of chlorine dioxide etc.; And the recessive body of chlorine dioxide comprises chlorite and chlorate, and salt refers to sodium salt, sylvite, ammonium salt, magnesium salts, calcium salt, zinc salt, mantoquita, molysite, molybdenum salt, silver salt etc.Employed auxiliary element nutrient for plants can be selected chemical fertilizer commonly used, comprise nitrogenous fertilizer, potash fertilizer, phosphate fertilizer, amino acid and its esters, humus and its esters, also comprise trace elements such as sodium, potassium, ammonium, magnesium, calcium, zinc, copper, iron, molybdenum, boron, selenium, rare earth.Prepared strong antibiotic multifunction marine organisms Agrotechnical formulation can be by the sterilizing disease-preventing and the fertilising volume increase that plant leaf surface are sprayed, form such as root pouring is used for each plant species.Its auxiliary element nutrient for plants can use for multiple simultaneously for single the kind also.
Chitin and derivative thereof and chlorine dioxide reaction can make chitin and derivative thereof degrade gradually, and biologically active significantly improves; Chitin and derivative thereof are the natural marine organism macromolecular materials, and its special structure has stronger absorption stability effect to chlorine dioxide, have overcome the disadvantage of the volatile inefficacy of chlorine dioxide on largely.So the reactant of chitin and derivative thereof and chlorine dioxide has the effect of the other side's function of mutually promoting, and promptly has synergistic effect.On this basis, needs according to the nutrition of crop classification, comprise the general nutrients of plants such as trace element such as nitrogenous fertilizer, potash fertilizer, phosphate fertilizer, amino acid and its esters, humus and its esters, sodium, potassium, magnesium, calcium, zinc, copper, iron, molybdenum, boron, selenium, rare earth element on composite, make the biological Agrotechnical formulation of this novel sea have the killing action very strong to fungi, virus and common pathogen, better to the control efficiency of plant disease.On the other hand, because chitin and derivatives active thereof significantly improve, the easier absorption of plant, " protective plant protecting agent " effect is better, and the fertilising effect of increasing production improves.
Embodiment:
The present invention is further elaborated to enumerate five formulation examples below.
Example 1:
Deacetyl chitin is made into 3% weakly acidic solution, under stirring condition, slowly adds 2% chlorine dioxide (ClO
2) solution, reacted 30 minutes, add 1% urea and 0.5% potassium phosphate thereafter, stir and promptly get the biological Agrotechnical formulation of novel sea.
It is sprayed in cucumber and Chinese cabbage blade face 10 days cycles by diluting 200 times.Cucumber production promoting 23% as a result.Chinese cabbage volume increase 37%.Serious plant disease does not take place in growing period.
Example 2:
Shitosan is made into 1% the aqueous solution.Under agitation feed chlorine dioxide (ClO
2) gas, reacted 60 minutes, make the ClO of absorption
2Content reaches 2%-3%, adds 1% urea and 0.5% potassium phosphate thereafter again, 2% compound amino acid, and the trace element of total amount 1% stirs and promptly gets the biological Agrotechnical formulation of novel sea.
It is sprayed in plant leaf surface 10 days cycles by diluting 300 times.Cucumber production promoting 28% as a result, Chinese cabbage volume increase 32%, eggplant volume increase 18%, radish volume increase 22%, peach volume increase 14%.Serious plant disease does not take place in growing period.
Example 3:
At first deacetyl chitin is made into 5% weakly acidic solution.After again sodium chlorite and citric acid being mixed by 1: 3 weight ratio, under agitation slowly add in the weakly acidic solution of deacetyl chitin again, sustained response 30 minutes adds general nutrient for plants thereafter again, stirs and promptly gets the biological Agrotechnical formulation of novel sea.
It is sprayed in plant leaf surface 10 days cycles by diluting 300 times.Cucumber production promoting 31% as a result.Chinese cabbage volume increase 40%, eggplant volume increase 19%, green pepper volume increase 20%, radish volume increase 24%, peach volume increase 17%.Serious plant disease does not take place in growing period.
Example 4:
The shitosan carboxylate is made into 10% the aqueous solution.Under agitation slowly add 4%ClO
2The aqueous solution reacted 50 minutes, added 2% urea and 1.5% diammonium phosphate thereafter, 3% potassium humate, and the trace element of total amount 1% stirs and promptly gets the biological Agrotechnical formulation of novel sea.
It is sprayed in plant leaf surface 10 days cycles by diluting 1000 times.Cucumber production promoting 20% as a result.Chinese cabbage volume increase 25%, eggplant volume increase 12%, green pepper volume increase 10%, radish volume increase 19%, peach volume increase 20%.Serious plant disease does not take place in growing period.
Example 5:
Deacetyl chitin is made into 2% weakly acidic solution.Under agitation slowly add 5%ClO
2The aqueous solution, confined reaction 90 minutes adds 2% glycerine thereafter, and 5% ethanol and 0.001% essence and an amount of pigment stir and promptly get strong bactericidal properties marine organisms shin moisturizer.The usefulness that can be used for daily skin care diseases prevention and textile disinfecting.
Claims (5)
1, a kind of preparation method of strong antibiotic multifunction marine organisms Agrotechnical formulation, it is characterized in that earlier deacetyl chitin and derivative thereof being mixed with weakly acidic solution or neutral solution, under stirring condition, slowly add chlorine dioxide component reaction 20～90 minutes, add nutrient for plants again and stir and promptly make the marine organisms Agrotechnical formulation, solid content is 0.0001%～100% in its preparation; The composition of preparation comprises that deacetyl chitin and derivative thereof account for 0.0001%～30%, chlorine dioxide accounts for 0.001%～30%, and auxiliary element is that general nutrient for plants accounts for 0.1%～40%; All be weight percentage.
2, the preparation method of strong antibiotic multifunction marine organisms Agrotechnical formulation according to claim 1 is characterized in that deacetyl chitin and derivative thereof comprise that deacetylation is deacetyl chitin, quaternary ammonium salt shitosan, the shitosan carboxylate of 10%-100%; And quaternary ammonium salt shitosan and shitosan carboxylate comprise sodium salt, sylvite, ammonium salt, magnesium salts, calcium salt, zinc salt, mantoquita, molysite, molybdenum salt, silver salt.
3, the preparation method of strong antibiotic multifunction marine organisms Agrotechnical formulation according to claim 1 is characterized in that chlorine dioxide comprises chlorine dioxide, aqueous solution of chlorine dioxide, solid-state stabilizing chlorine dioxide, the recessive body of chlorine dioxide; And the recessive body of chlorine dioxide comprises chlorite and chlorate, and salt comprises sodium salt, sylvite, ammonium salt, magnesium salts, calcium salt, zinc salt, mantoquita, molysite, molybdenum salt, silver salt.
4, the preparation method of strong antibiotic multifunction marine organisms Agrotechnical formulation according to claim 1, it is characterized in that auxiliary element is a nutrient for plants, comprises nitrogenous fertilizer, potash fertilizer, phosphate fertilizer, amino acid and its esters, humus and its esters, sodium, potassium, magnesium, calcium, zinc, copper, iron, molybdenum, boron, selenium, rare earth element.
5, the preparation method of strong antibiotic multifunction marine organisms Agrotechnical formulation according to claim 1 is characterized in that being used for by the form that plant leaf surface is sprayed or root waters sterilizing disease-preventing and the fertilising volume increase of plant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100453996A CN1311749C (en) | 2005-12-22 | 2005-12-22 | Method for preparing strong anti-biosis, multi-functional agricultural chemical prepn. used for ocean living things |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100453996A CN1311749C (en) | 2005-12-22 | 2005-12-22 | Method for preparing strong anti-biosis, multi-functional agricultural chemical prepn. used for ocean living things |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1784963A CN1784963A (en) | 2006-06-14 |
| CN1311749C true CN1311749C (en) | 2007-04-25 |
Family
ID=36782641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100453996A Expired - Fee Related CN1311749C (en) | 2005-12-22 | 2005-12-22 | Method for preparing strong anti-biosis, multi-functional agricultural chemical prepn. used for ocean living things |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1311749C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102816649B (en) * | 2012-08-16 | 2015-01-07 | 江苏兴达文具集团有限公司 | Screen cleaning agent |
| CN106135263B (en) * | 2016-05-14 | 2019-07-30 | 海南正业中农高科股份有限公司 | Composition and application thereof containing organic zinc |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000212013A (en) * | 1999-01-20 | 2000-08-02 | Okayama Oyo Kagaku:Kk | Inhibitor against infection of cross-breeding for agriculture and horticulture |
| CN1480043A (en) * | 2002-09-05 | 2004-03-10 | 张天德 | Compound bactericide for treating water and its preparing method |
-
2005
- 2005-12-22 CN CNB2005100453996A patent/CN1311749C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000212013A (en) * | 1999-01-20 | 2000-08-02 | Okayama Oyo Kagaku:Kk | Inhibitor against infection of cross-breeding for agriculture and horticulture |
| CN1480043A (en) * | 2002-09-05 | 2004-03-10 | 张天德 | Compound bactericide for treating water and its preparing method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1784963A (en) | 2006-06-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103265366B (en) | Seed dressing agent | |
| CN100354236C (en) | Aqueous solution of non-colloidal silicic acid and boric acid | |
| CN103864512B (en) | A kind of nano biological environment protection multifunctional organic bamboo vinegar medicine is fertile | |
| CN103265376B (en) | The nuisanceless bactericidal and herbicidal Chemical Mixed Fertilizer of one kind of plant | |
| CN103242107A (en) | Straw rotten organic sterilizing/weeding compound fertilizer | |
| CN105230661A (en) | Functional auxiliary agent for crops and preparation method thereof | |
| CN101973822A (en) | Pollution-free medicinal fertilizer capable of trapping and killing pests and promoting plant growth and preparation method thereof | |
| CN101637156B (en) | Composite of fatty acids and derivatives thereof | |
| CN102701878A (en) | Pomacea canaliculata molluscicide fertilizer mixture and production method thereof | |
| CN103283725A (en) | Sterilization composition containing amino-oligosaccharin and validamycin and application of pesticide composition | |
| CN105660698A (en) | Application of plant immune resistance inducer in prevention and control of damping-off and blight of cucumbers | |
| KR101132712B1 (en) | Environment-friendly organic agricultural products for soil insect pest control | |
| CN103641576A (en) | Traditional Chinese medicine fertilizer and preparation method thereof | |
| CN106748248A (en) | A kind of efficiently volume increase water soluble fertilizer | |
| CN102992901A (en) | Insecticide-fertilizer composition containing organic heterocyclic insecticides | |
| CN103819274B (en) | Preparation method for phosphite- chitosan oligosaccharide composite biological medical fertilizer | |
| CN101020766A (en) | Degradable mulching product and its production process | |
| JP2009167177A (en) | Plant protecting and activating agent | |
| CN108552231A (en) | A kind of diseases prevention insect prevention cold-resistant dressing agent for rice | |
| CN1311749C (en) | Method for preparing strong anti-biosis, multi-functional agricultural chemical prepn. used for ocean living things | |
| CN101423440B (en) | Iodine alginate aqua medical fertilizer and preparation method thereof | |
| CN104671953A (en) | Preparation method of agricultural sterilizing and disinfecting agent | |
| KR19990030815A (en) | Liquid composite fertilizer containing chitin, chitosan and wood vinegar | |
| CN103553811A (en) | Corncob-decomposed organic nanometer fertilizer | |
| RU2600711C2 (en) | Method of lupine white yield increasing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Yiyuan Xinquan Chemical Co., Ltd. Assignor: Qingdao University Contract fulfillment period: 2007.8.5 to 2014.8.4 contract change Contract record no.: 2009370000085 Denomination of invention: Method for preparing strong anti-biosis, multi-functional agricultural chemical prepn. used for ocean living things Granted publication date: 20070425 License type: Exclusive license Record date: 2009.6.5 |
|
| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.8.5 TO 2014.8.4; CHANGE OF CONTRACT Name of requester: YIYUAN XINQUAN CHEMICAL CO., LTD. Effective date: 20090605 |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070425 Termination date: 20121222 |