CN1304976A - Process for preparing fuel gas by gasifying biomass and its gasifying reactor - Google Patents
Process for preparing fuel gas by gasifying biomass and its gasifying reactor Download PDFInfo
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- CN1304976A CN1304976A CN 00130716 CN00130716A CN1304976A CN 1304976 A CN1304976 A CN 1304976A CN 00130716 CN00130716 CN 00130716 CN 00130716 A CN00130716 A CN 00130716A CN 1304976 A CN1304976 A CN 1304976A
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Abstract
A process for preparing fuel gas from biomass includes loading said biomass to gasifier, cracking at 700-800 deg.C to obtain tar-containing gas, and cracking tar at 850-950 deg.C to obtain pure gas. Its advantages are no secondary pollution and high gasifying efficiency.
Description
The present invention relates to a kind of is the method and the gasification reactor apparatus of clean fuel gas with Wood Adhesives from Biomass.
Biomass are as renewable energy source, be except that coal, oil, Sweet natural gas and nuclear energy, to have one of energy of DEVELOPMENT PROSPECT, available biomass comprise surplus, the animals and plants processing waste material in the animals and plants kitchen in the domestic refuse, as sawdust, bark, wood chip, pericarp, stalk, ight soil and slaughter-house refuse, other comprises that also it is wood grass of the special plantation of purpose or the like that mud reaches with the energy utilization.As renewable energy source, participate in the biosphere carbon cycle, so it utilizes the CO that discharges in the process
2Can not produce Greenhouse effect; The sulfur and the ash of biomass are generally lower simultaneously, the processing burden of sulphur, ash discharging is light, therefore exhausted day by day at the oil reserves, and coal utilization exists under the influence of high pollution and factor such as non-renewable, countries in the world recognize that progressively biomass energy quantizes importance and the various reasonable approach of utilizing, and the vegetation of the U.S. even the short growth cycle of plan plantation high yield is with the energizing quantity utilization.China's biomass resource is very abundant, and only the annual production of agricultural crop straw promptly reaches more than 700,000,000 tons, be roughly equal to more than 300,000,000 ton of standard coal, and the main component in China's municipal wastes also is biomass.
The method of conventional process biomass comprises landfill, goes back field or on-site incineration, causes the destruction of the wasting of resources, soil and contaminated water source, land structures and high-temperature chamber effect methane gas to generate, and grows germ simultaneously, harm humans health.At present special incineration technology is comparatively fast developed owing to subtracting big, the recyclable heat energy of appearance, but the secondary pollution problem is more thorny.When the outstanding advantage of emerging biomass gasification technology was that biomass material transform to obtain chemical energy, environmental-protecting performance was superior, so evaporating method is the new direction that current biomass energy utilizes, and was mainly reflected in the following aspects:
(1) under the high-temperature reductibility atmosphere, the high-molecular hydrocarbons that produces in the pyrolytic gasification process can effectively be decomposed, and prevents the carrying out of reverse building-up reactions simultaneously; Have the chlorine element as some biomass material, then the chlorine element exists with the form of hydrogenchloride rather than free chlorine, do not have free oxygen yet and exist, therefore high temperature can fine control Dioxins than operation under the long residence time generation.And existing studies show that, the burning of chloride waste material can produce more Dioxins;
(2) heavy metal of part oxidation state is present in the lime-ash of discharge and is regarded as hazardous material in the burning process, and the heavy metal in the gasification biomass is enriched in the lime-ash of eliminating with the heavy metal form of going back ortho states basically, is regarded as non-hazardous material;
(3) the no acidic gas of evaporating method generates, and coal gas tolerance is 1/3 of incineration flue gas amount only, and dust, HCL wait for treated substance concentration height in the atmosphere, and the small scale of follow-up pollution control equipment is invested little.
But conventional gasification process is when handling the thermal viscosity biomass waste material that energy density is low, volatile content is high, and the interior gas-solid of the feed mechanism of system and bed is flowed and the temperature field all need be rearranged and be constructed.The more important thing is more, the promptly usually said tar of macromolecule carbon oxyhydroxide deposits yields, when not taking any tar cracking measure, biomass such as gasifying stalk produce tar content and reach 20g/NM
3The difficulty that the generation of tar causes back system jams and following process to handle easily, promoting the use of of restriction biomass gasifying furnace, gas yield and calorific value are descended, system's cold gas efficiency descends, and therefore resolving the coal-tar middle oil cracking problem of biomass pyrogenation gasification process is successfully to develop the key of biomass gasification device and technology.Tar can adopt catalytic cracking method or keep certain residence time effectively to decompose under hot conditions.Report from pertinent literature, a kind of method before the present more employing, mainly used for reference the method for hydro carbons processing industry, adopt various catalyst for cracking heavy oil or have the cheap Wingdale of coke tar cracking effect, but all have the catalyst carbon deposit problem, influence work-ing life, therefore need manipulation of regeneration, increased the complicacy of equipment, technology, and coke tar cracking is not thorough, the utilization of coal gas is restricted, and (being suitable for combustion gas as internal combustion turbine requires tar content less than 0.1g/NM
3), these problems are more apparent outstanding in middle-size and small-size biogas metallization processes.Other has and is reported in condensed tar in the biomass gasification process and reclaims the technology of returning the stove internal consumption, but needs to increase oil-water separation system, and problems such as obstruction easily take place in reflux pump and the return line, has increased the complicacy of technology equally.USDOE organization development recently biomass gasification technology, for improving calorific value of fuel gas, on technology, take the pattern of twin furnace operation, biomass are finished pyrolysis output high heating value gas with husky mixing of heat in pyrolytic gasification stove, carbon containing flying dust and sand are mixed into the heating that the roasting kiln internal combustion is finished sand simultaneously, hot sand returns again finishes circulation in the pyrolytic gasification stove, but also has the handling problem of tar in the process.
The purpose of this invention is to provide a kind of do not have tar generation and the method for the simple preparing fuel gas by gasifying biomass of technology and the isolated plant of gasification reaction.
The object of the present invention is achieved like this: biomass need not sort and purify, be crushed to less than 5mm, add vapourizing furnace and under 700～800 ℃, carry out pyrolytic gasification, generation contains the air gas of tar again by the top high-temperature area, make tar cracking at high temperature, do not contained the clean gas of tar.
The method of preparing fuel gas by gasifying biomass of the present invention comprises the steps:
(1) biomass is crushed to granularity less than 5mm;
(2) the sand material is placed in the vapourizing furnace, is heated to 700～800 ℃, the biomass of granularity less than 5mm are joined in the vapourizing furnace, and with the sand material under whipped state, bubbling air, going into stove air total amount and biomass material proportioning is 2.0-3.5NM
3/ Kg, keeping the interior temperature of vapourizing furnace is 700～800 ℃, generates the air gas that contains tar;
(3) air gas that contains tar by 850～950 ℃ the high-temperature zone and stop 1-3 cracking second, generate the clean gas that does not contain tar;
(4) part that will not contain the clean gas of tar turns back to (3) step high-temperature zone, is equipped with the perfect combustion required air, makes the high-temperature zone temperature remain on 850～950 ℃, makes the coke tar cracking in the air gas that contains tar.
Go into the stove air and enter two part sums of air bottom the air total amount is meant as mentioned above by top jet nozzle.
In order to realize foregoing invention, designed a kind of special-purpose gasification reactor apparatus.
This device is made up of body of heater, opening for feed, temperature-measuring port, gas distribution grid, gas exit, fuel oil atomizer, it is characterized in that an opening for feed is positioned on the gas distribution grid of body of heater bottom, another opening for feed is positioned at the body of heater top, at the body of heater middle part one group of fuel oil atomizer is installed radially, another group fuel oil atomizer radially is installed under the gas exit of upper of furnace body, inlet air plenum and blast inlet are arranged under the gas distribution grid of body of heater bottom, agitator is housed in body of heater.
Aforesaid gas distribution grid is taper.
The present invention compared with prior art has following advantage:
(1) the present invention is because based on gasification technology, and the generation of dioxin-like chemical is inhibited, and is simultaneously pending narrow-minded, makes follow-up pollution control equipment small scale, invests for a short time, and environmental-protecting performance is superior.
(2) reaction unit of the present invention is simple in structure, and is easy to operate.
(3) method for preparing combustion gas of the present invention does not have the tar generation, and technology is simple.
(4) calorific value of institute's producing coal gas is at 1200-1500Kcal/Nm
3
Below in conjunction with embodiment and accompanying drawing thereof the present invention is described in further detail.
Fig. 1 is a schema of the present invention.
Fig. 2 is the structural representation of the special-purpose gasification reactor apparatus of the present invention.
As shown in the figure, the 1st, body of heater, the 2nd, be positioned at the fuel oil atomizer at body of heater 1 middle part, the 3rd, be positioned at body of heater 1 top and be positioned at fuel oil atomizer under the gas exit 4, the 5th, be positioned at body of heater 1 bottom and be positioned at opening for feed on the gas distribution grid 8, the 6th, be positioned at the opening for feed of furnace roof, therefore raw material can select the feeding mouth of different positions to go into stove as the case may be, the 7th, the feed(raw material)inlet valve, the 9th, be positioned at body of heater 1 bottom and be positioned at blast inlet under the gas distribution grid 6, the 10th, the sediment outflow ash discharging hole that is connected and is connected with gas distribution grid 8 with body of heater 1 bottom, under connect blow-off valve 11, the 12nd, be installed on the agitator in the body of heater 1, this agitator 12 drives by the motor 13 that is positioned at body of heater 1 top, 14,15, the 16th, be positioned at the temperature-measuring port at body of heater 1 upper, middle and lower three places, the 17th, the temperature instrumentation of connection thermopair, the 18th, enter sand material or biomass in the body of heater 1, the 19th, gas blower, the 20th, air manometer, the 21st, motor, the 22nd, by the feeding screw of motor 21 drives, 23, the 24th, the storage bin of connection feeding screw 22, the 25th, fuel source, the 26th, the cyclonic separator that links to each other with gas exit 4, the 27th, ash-storing bin, the 28th, lime-ash, the 29th, water cooling heat exchanger, the 30th, water pump, the 31st, water coolant, the 32nd, the hot water of discharging, the 33rd, from the water of condensation of water cooling heat exchanger 29 discharges, the 34th, pure coal gas, the 35th, vacuum pump, this vacuum pump turns back to fuel source 25,36th with clean gas 34 parts, is positioned at the inlet air plenum under the gas distribution grid 8.
Embodiment 1:
With the wood chip is that gasified raw material need not sort, purify, and is crushed to granularity less than 5mm, and the storage bin 23,24 of packing into is stand-by.The sand material of the back homogeneous grain diameter of sieving is placed gasifying reactor 1, open Root's blower 19 and town gas source of the gas or liquefied gas source 25 air outlet valves, being equipped with the perfect combustion required air with liquefied gas or town gas under normal pressure enters the stove internal combustion by upper of furnace body nozzle 3 and body of heater middle part nozzle 2 and carries out baker, in temperature-measuring port 14,15,16, insert thermopair, connect temperature controller 17 by thermopair and carry out thermometric.Throat temperature is elevated to 860 ℃, body of heater bottom and middle part temperature are elevated to 750 ℃, open motor 13 drive agitators 12 and begin to stir, open motor 21 feeding screw 22 is sent to storage bin 23 or 24 li ready biomass in the stove, be pressed into stove air wood chip than being 2.325Nm
3The metering air of/Kg (going into stove air total amount meter), air is entered in the stove from admission port 9, and stop nozzle 2 air inlets, and air is gone into stove through gas distribution grid 8 and is contacted with biomass, and the temperature that makes stove bottom and middle part is 750 ℃, and the flow of adjustment nozzle 3, making throat temperature is 860 ℃, treat bed temperature and tolerance regulate stable after, open cooling-water pump 31, biomass and the air of going into stove from grid distributor 8 burn under 750 ℃ temperature and the pyrolytic gasification reaction, generate the air gas that contains tar.This air gas rise to 860 ℃ in furnace roof portion the high-temperature zone, stop after 1 second, tar is decomposed.Coal gas enters cyclonic separator 26 from exporting 4, and dust is separated with coal gas; Dust enters ash-storing bin 27, discharges dust 28 from ash-storing bin 27; The coal gas that comes out from cyclonic separator 26 obtains clean gas 34 after through water cooling heat exchanger 29 coolings.Open vacuum pump 35, make the part clean gas turn back to fuel gas source 25 places, go into furnace roof by nozzle 3 again, stop the supply of alternative fuel such as town gas or liquefied gas this moment, adjust the amount of returning coal gas, make the temperature of furnace roof remain on 860 ℃.Water of condensation 33 dischargings that coal gas condenses through water cooling heat exchanger 29, the index of institute's producing coal gas sees Table 1.
Regulate throat temperature and reach 870 ℃, body of heater bottom and middle part temperature are become 750 ℃, air wood chip ratio becomes 2.07Nm
3/ Kg, the air gas that contains tar rises to the high-temperature zone of 870 ℃ in furnace roof portion, stops 2 seconds, and all the other are with embodiment 1.
Embodiment 3
Regulate throat temperature and reach 870 ℃, body of heater bottom and middle part temperature are become 730 ℃, air wood chip ratio becomes 2.557Nm
3/ Kg, the air gas that contains tar rises to the high-temperature zone of 870 ℃ in furnace roof portion, stops 1 second, and all the other are with embodiment 1.
Regulate throat temperature and reach 935 ℃, body of heater bottom and middle part temperature are become 780 ℃, air wood chip ratio becomes 2.493Nm
3/ Kg, the air gas that contains tar rises to the high-temperature zone of 935 ℃ in furnace roof portion, stops 2.5 seconds, and all the other are with embodiment 1.
Regulate throat temperature and reach 940 ℃, body of heater bottom and middle part temperature are become 800 ℃, air wood chip ratio becomes 2.455Nm
3/ Kg, the air gas that contains tar rises to the high-temperature zone of 940 ℃ in furnace roof portion, stops 2 seconds, and all the other are with embodiment 1.Table 1
Claims (3)
1. the method for preparing fuel gas by gasifying biomass is characterized in that comprising the steps:
(1) biomass is crushed to granularity less than 5mm;
(2) the sand material is placed in the vapourizing furnace, is heated to 700～800 ℃, the biomass of granularity less than 5mm are joined in the vapourizing furnace, and with the sand material under whipped state, bubbling air, going into stove air total amount and biomass material proportioning is 2.0-3.5NM
3/ Kg, keeping the interior temperature of vapourizing furnace is 700～800 ℃, generates the air gas that contains tar;
(3) air gas that contains tar by 850～950 ℃ at top the high-temperature zone and stop 1-3 cracking second, generate the clean gas that does not contain tar;
(4) part that will not contain the clean gas of tar turns back to (3) step high-temperature zone, is equipped with the perfect combustion required air, makes the high-temperature zone temperature remain on 850～950 ℃, makes the coke tar cracking in the air gas that contains tar.
2. the gasification reactor apparatus of a preparing fuel gas by gasifying biomass, be by body of heater (1), opening for feed (5) and (6), temperature-measuring port (14,15,16), gas distribution grid (8), gas exit (4), fuel oil atomizer (2,3) form, it is characterized in that opening for feed (5) is positioned on the gas distribution grid (8) of body of heater (1) bottom, another opening for feed (6) is positioned at the top of body of heater (1), at body of heater (1) middle part fuel oil atomizer (2) is installed, under the gas exit (4) on body of heater (1) top, fuel oil atomizer (3) is installed, inlet air plenum (36) and blast inlet (9) are arranged under the gas distribution grid (8) of body of heater (1) bottom, agitator (12) is housed in body of heater (1).
3. the gasification reactor apparatus of a kind of preparing fuel gas by gasifying biomass according to claim 2, it is taper that its feature is stored in described gas distribution grid (8).
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| CNB001307169A CN1136291C (en) | 2000-10-11 | 2000-10-11 | Process for preparing fuel gas by gasifying biomass and its gasifying reactor |
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| CN1136291C CN1136291C (en) | 2004-01-28 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100363461C (en) * | 2005-11-25 | 2008-01-23 | 清华大学 | Method and device for preparing fuel gas from biomass/domestic garbage double bed type heat decomposition |
| CN101824338A (en) * | 2010-03-29 | 2010-09-08 | 许敬轩 | Method for eliminating tar and waste water in gasification furnace and improving gas producing efficiency |
| CN101915424A (en) * | 2010-09-25 | 2010-12-15 | 中国烟草总公司郑州烟草研究院 | Method for utilizing industrial solid tobacco waste |
| CN101063039B (en) * | 2006-04-26 | 2011-03-23 | 董久明 | Powder coal grading clean grading utilization technology using thermal dissociation as the first stage |
| CN102417830A (en) * | 2011-09-28 | 2012-04-18 | 合肥德博生物能源科技有限公司 | Method and device for gasifying low tar biomass |
| CN102719265A (en) * | 2012-06-18 | 2012-10-10 | 天津大学 | Solid waste or biomass high-efficiency pyrolysis oil-producing system |
| CN101440291B (en) * | 2008-12-24 | 2013-01-02 | 张建超 | Biomass gasification equipment and process |
-
2000
- 2000-10-11 CN CNB001307169A patent/CN1136291C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100363461C (en) * | 2005-11-25 | 2008-01-23 | 清华大学 | Method and device for preparing fuel gas from biomass/domestic garbage double bed type heat decomposition |
| CN101063039B (en) * | 2006-04-26 | 2011-03-23 | 董久明 | Powder coal grading clean grading utilization technology using thermal dissociation as the first stage |
| CN101440291B (en) * | 2008-12-24 | 2013-01-02 | 张建超 | Biomass gasification equipment and process |
| CN101824338A (en) * | 2010-03-29 | 2010-09-08 | 许敬轩 | Method for eliminating tar and waste water in gasification furnace and improving gas producing efficiency |
| CN101915424A (en) * | 2010-09-25 | 2010-12-15 | 中国烟草总公司郑州烟草研究院 | Method for utilizing industrial solid tobacco waste |
| CN102417830A (en) * | 2011-09-28 | 2012-04-18 | 合肥德博生物能源科技有限公司 | Method and device for gasifying low tar biomass |
| CN102719265A (en) * | 2012-06-18 | 2012-10-10 | 天津大学 | Solid waste or biomass high-efficiency pyrolysis oil-producing system |
| CN102719265B (en) * | 2012-06-18 | 2014-06-25 | 天津大学 | Solid waste or biomass high-efficiency pyrolysis oil-producing system |
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| CN1136291C (en) | 2004-01-28 |
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Granted publication date: 20040128 Termination date: 20131011 |