CN1266874A - Ethylene-butadiene-styrene type flame-retarding fire-extinguishing universal adhesive without benzene toxin - Google Patents
Ethylene-butadiene-styrene type flame-retarding fire-extinguishing universal adhesive without benzene toxin Download PDFInfo
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- CN1266874A CN1266874A CN 99112745 CN99112745A CN1266874A CN 1266874 A CN1266874 A CN 1266874A CN 99112745 CN99112745 CN 99112745 CN 99112745 A CN99112745 A CN 99112745A CN 1266874 A CN1266874 A CN 1266874A
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Abstract
A flame-retarding and fire-extinguishing universal adhesive without benzene toxin for building decoration is prepared from 12 chemical substances including styrene-butadiene-styrene (SBS) block copolymer, terpene resin, cross-linking agent, flame-retarding agent, etc through proportional mixing and stirring. Its advantages are no benzene toxin, high flame retarding effect, not freezing at -23--30 deg.C, less odour, high adhesion and low cost.
Description
The present invention is the multi-purpose adhesive of a kind of new-type performance of using in the architectural decoration, say definitely be a kind of be the flame-retarding fire-extinguishing universal adhesive without benzene toxin of main composition raw material with the styrene-butadiene-styrene ternary block polymer.
At present, along with The development in society and economy, urban and rural residents' housing condition has also obtained very big improvement, and the finishing in room has become a currently marketed large focal spot.But because finishing is accidentally, the continuous generation that has thereupon brought fire, and then adopted great loss for people's lives and properties band.On the other hand, in the component owing to building glue (tackiness agent) used in the present decorating house, substantially all contain the benzene poison, this material constantly discharges in finishing, thereby make the people in the room peppery eyes usually occur, uncomfortable phenomenon such as dizziness, this in fact phenomenon promptly is the benzolism phenomenon, if untimely taking measures, it will cause prestige association to the life of human body.Therefore, the nontoxic fire retardant glue of research and extension is the big problem that people craved for and inquired into always, but the result of great majority research fails to achieve one's goal all the time, be that people fail chemical property at this glue always, have breakthrough on the physicals, thereby can't further in building trade, use and promote.Main drawback according to the problems referred to above, sea, Haicheng reef Industrial Co., Ltd. worked out a kind of chlorobutyl benzene-free fire-retarded universal glue in 1997, and declared national patent (application number: 97115057.5), this patented technology ratio nontoxic flame-retarded technology in the past, very big breakthrough has been arranged, but the basic raw material neoprene latex can't be taken away, and change a kind of new-type raw material SBS promptly is the flame-retarding fire-extinguishing universal adhesive without benzene toxin of main raw material with the styrene-butadiene-styrene ternary block polymer, with the quality and the stability of further raising product.
Purpose of the present invention exactly according to the new problem that is proposed in the problems referred to above, is the prescription and the producing and manufacturing technique of the flame-retarding fire-extinguishing universal adhesive without benzene toxin produced of basic raw material with the styrene-butadiene-styrene ternary block polymer for people work out a kind of.
Implementation method of the present invention is as follows: (part is a weight unit) at first claims following material (industrial one-level) 5-10 part; Linking agent (industry): 0.1-0.3 part; Chlorinated paraffin-70: 5-20 part; TCEP fire retardant (industry) 5-10 part; Methylene dichloride (industry) 100-200 part; Cyclohexane (industry) 80-100 part; Trieline (industry) 60-120 part; Tetracol phenixin (industry) 60-120 part; 1.1-dichloro hexane (industry) 320-520 part; Afterwards by following method operation:
At first load weighted linking agent, clorafin, fire retardant, methylene dichloride, cyclohexane, trieline, tetracol phenixin, 1.1-ethylene dichloride are put into reactor, under 5-30 ℃ temperature, stirred 1-2 hour, again SBS (being the styrene-butadiene-styrene ternary block polymer) is added in the reaction bar afterwards and continue to stir 1-2 hour, adding terpine resin, petroleum resin, rosin afterwards again stirred 6-12 hour, setting-out is afterwards observed, when whole material dissolutions are thorough, blowing packing warehouse-in.
After the present invention realizes, can be widely used in the construction and decoration industry, as: can be applicable to indoor and outdoor decoration, fitting-out work, also can bonding PLASTIC LAMINATED, oak floor, Manchurian ash board, glued board, flax board, density board, also bonding applicable to concrete, irony, aluminium matter, fabric case and bag, calcium-plastic board, biochip leather rubber, foam, continuous goods, pottery etc.Compared with the prior art it have following advantage: 1. flame retardant effect is obvious, and glue is met a naked light carbonization, does not burn; 2. winter-23--30 ℃ of glue do not freeze; 3. smell is little, and cohesive force is strong; 4. contain three benzene solvents (being benzene,toluene,xylene) in the glue anything but; 5. cost is not higher than former chlorobutyl benzene-free fire-retarded universal glue.
The present invention is further described below in conjunction with drawings and Examples:
Fig. 1 is technological process of production figure of the present invention.
Embodiment: at first with linking agent 0.2kg, clorafin 12kg, fire retardant 12kg, methylene dichloride 150kg, cyclohexane 90kg, trieline 90kg, tetracol phenixin 90kg, 1.1-ethylene dichloride 400kg puts into reactor, stirs 2 hours under 5-30 ℃ temperature, again SBS (being the styrene-butadiene-styrene ternary block polymer) 120kg is added in the reaction bar afterwards and continued to mix 2 hours, add terpine resin 120kg afterwards again, petroleum resin 60kg, rosin 8kg, stirred 6-12 hour, setting-out is afterwards observed, when whole material dissolutions are thorough, and blowing packing warehouse-in.
Claims (1)
1, a kind of is the producing and manufacturing technique of the SBS type flame-retarding fire-extinguishing universal adhesive without benzene toxin of body material with the styrene-butadiene-styrene ternary block polymer, and it is characterized in that: it is with following component: (part is a weight unit).
SBS (792,791,801): 110-135 part, terpine resin (low softening point) 125-135 part, petroleum resin (industry): 50-80 part; Rosin (industrial one-level) 5-10 part; Linking agent (industry) 0.1-0.2 part; Chlorinated paraffin-70: 5-20 part; TCEP fire retardant (industry) 5-10 part; Methylene dichloride (industry) 100-200 part; Cyclohexane (industry) 80-100kg; Trieline (industry) 60-120 part; Tetracol phenixin (industry) 60-120 part; 1.1-ethylene dichloride (industry) 320-520 part, afterwards by following method operation:
At first with load weighted linking agent, clorafin, fire retardant, methylene dichloride, cyclohexane, trichlorine alkene, tetracol phenixin, 1.1-ethylene dichloride are put into reactor, under 5-30 ℃ of condition, stirred 1-2 hour, afterwards, again SBS (being the styrene-butadiene-styrene ternary block polymer) is added in the reactor, continue to stir 1-2 hour, add terpine resin afterwards again, petroleum resin, rosin stirred 6-12 hour, setting-out is afterwards observed, when whole material dissolutions are thorough, blowing packing warehouse-in.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99112745 CN1266874A (en) | 1999-03-16 | 1999-03-16 | Ethylene-butadiene-styrene type flame-retarding fire-extinguishing universal adhesive without benzene toxin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99112745 CN1266874A (en) | 1999-03-16 | 1999-03-16 | Ethylene-butadiene-styrene type flame-retarding fire-extinguishing universal adhesive without benzene toxin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1266874A true CN1266874A (en) | 2000-09-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99112745 Pending CN1266874A (en) | 1999-03-16 | 1999-03-16 | Ethylene-butadiene-styrene type flame-retarding fire-extinguishing universal adhesive without benzene toxin |
Country Status (1)
| Country | Link |
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| CN (1) | CN1266874A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504734A (en) * | 2011-11-08 | 2012-06-20 | 李保忠 | Flame-retarding environment-friendly all-purpose adhesive and preparation method thereof |
| CN105255394A (en) * | 2015-10-15 | 2016-01-20 | 中国林业科学研究院林产化学工业研究所 | Flame-retardant adhesive for genuine gold plate and preparation method and application thereof |
| CN109628015A (en) * | 2018-12-06 | 2019-04-16 | 广东莱尔新材料科技股份有限公司 | Polyolefin hot-melt and preparation method thereof and the composite insulating material for using it |
-
1999
- 1999-03-16 CN CN 99112745 patent/CN1266874A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504734A (en) * | 2011-11-08 | 2012-06-20 | 李保忠 | Flame-retarding environment-friendly all-purpose adhesive and preparation method thereof |
| CN105255394A (en) * | 2015-10-15 | 2016-01-20 | 中国林业科学研究院林产化学工业研究所 | Flame-retardant adhesive for genuine gold plate and preparation method and application thereof |
| CN109628015A (en) * | 2018-12-06 | 2019-04-16 | 广东莱尔新材料科技股份有限公司 | Polyolefin hot-melt and preparation method thereof and the composite insulating material for using it |
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