CN1263880C - High strength stainless steel wire excellent in ductility-toughness and modulus of rigidity and method for production thereof - Google Patents
High strength stainless steel wire excellent in ductility-toughness and modulus of rigidity and method for production thereof Download PDFInfo
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- CN1263880C CN1263880C CNB02813737XA CN02813737A CN1263880C CN 1263880 C CN1263880 C CN 1263880C CN B02813737X A CNB02813737X A CN B02813737XA CN 02813737 A CN02813737 A CN 02813737A CN 1263880 C CN1263880 C CN 1263880C
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- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 238000012545 processing Methods 0.000 claims abstract description 55
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 14
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 8
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 7
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 6
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 87
- 239000010959 steel Substances 0.000 claims description 87
- 239000001257 hydrogen Substances 0.000 claims description 36
- 229910052739 hydrogen Inorganic materials 0.000 claims description 36
- 239000012298 atmosphere Substances 0.000 claims description 31
- 239000013078 crystal Substances 0.000 claims description 29
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 23
- 239000010935 stainless steel Substances 0.000 claims description 21
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- 229910052758 niobium Inorganic materials 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 229910052715 tantalum Inorganic materials 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 238000005098 hot rolling Methods 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 27
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 4
- 239000001301 oxygen Substances 0.000 abstract description 4
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 239000000306 component Substances 0.000 abstract 1
- 238000007670 refining Methods 0.000 abstract 1
- 238000005728 strengthening Methods 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 230000000930 thermomechanical effect Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 34
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 26
- 229910000734 martensite Inorganic materials 0.000 description 23
- 230000000052 comparative effect Effects 0.000 description 22
- 239000007789 gas Substances 0.000 description 19
- 229910052786 argon Inorganic materials 0.000 description 13
- 239000000463 material Substances 0.000 description 9
- 238000000137 annealing Methods 0.000 description 8
- 150000002431 hydrogen Chemical class 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 230000009975 flexible effect Effects 0.000 description 6
- 238000005096 rolling process Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 238000011835 investigation Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- 238000007669 thermal treatment Methods 0.000 description 3
- 229910000639 Spring steel Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 206010050031 Muscle strain Diseases 0.000 description 1
- PWKWDCOTNGQLID-UHFFFAOYSA-N [N].[Ar] Chemical compound [N].[Ar] PWKWDCOTNGQLID-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/26—Selection of soldering or welding materials proper with the principal constituent melting at less than 400 degrees C
- B23K35/262—Sn as the principal constituent
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D7/00—Modifying the physical properties of iron or steel by deformation
- C21D7/02—Modifying the physical properties of iron or steel by deformation by cold working
- C21D7/10—Modifying the physical properties of iron or steel by deformation by cold working of the whole cross-section, e.g. of concrete reinforcing bars
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
- C21D8/065—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/525—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length for wire, for rods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2101/00—Articles made by soldering, welding or cutting
- B23K2101/36—Electric or electronic devices
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
Abstract
Description
No. | Steel grade | Chemical ingredients (quality %) | 2C+N (%) | Ni equivalent (%) | GI (%) | Hydrogen amount (ppm) | Average crystal grain diameter (μ m) | Strain causes living horse for the scale of construction (volume %) | Tensile strength (N/mm 2) | Number of torsions (inferior) | Rigidity modulus (GPa) | |||||||||||
C | Si | Mn | P | S | Ni | Cr | Mo | Cu | O | N | ||||||||||||
Example of the present invention | 1 | A | 0.1 | 0.8 | 1.6 | 0.03 | 0.0033 | 7 | 17 | 0.1 | 0.2 | 0.005 | 0.06 | 0.26 | 22.0 | 18.5 | 2.2 | 40 | 51 | 1990 | 17 | 67 |
2 | B | 0.04 | 0.8 | 1.5 | 0.02 | 0.0045 | 7 | 16.9 | 0.1 | 0.1 | 0.006 | 0.1 | 0.18 | 21.6 | 18.2 | 2 | 30 | 70 | 1910 | 14 | 68 | |
3 | C | 0.13 | 0.8 | 1.5 | 0.04 | 0.0052 | 7 | 17.1 | 0.2 | 0.1 | 0.004 | 0.02 | 0.28 | 22.0 | 18.7 | 1.8 | 30 | 58 | 2050 | 13 | 69 | |
4 | D | 0.03 | 0.8 | 1.5 | 0.03 | 0.0023 | 6.9 | 17 | 0.1 | 0.2 | 0.004 | 0.17 | 0.23 | 22.4 | 17.9 | 2.3 | 40 | 31 | 1850 | 40 | 66 | |
5 | E | 0.1 | 0.2 | 1.6 | 0.03 | 0.0008 | 7 | 17.1 | 0.3 | 0.2 | 0.005 | 0.06 | 0.26 | 22.1 | 19.8 | 3 | 50 | 51 | 1990 | 32 | 66 | |
6 | F | 0.1 | 2 | 1.5 | 0.02 | 0.0038 | 7 | 17 | 0.1 | 0.1 | 0.005 | 0.06 | 0.26 | 22.4 | 18.3 | 2.8 | 30 | 41 | 1950 | 35 | 66 | |
7 | G | 0.1 | 3.5 | 1.5 | 0.03 | 0.0003 | 6.9 | 16.9 | 0.1 | 0.2 | 0.002 | 0.06 | 0.26 | 22.7 | 17.7 | 2.1 | 40 | 24 | 1880 | 40 | 65 | |
8 | H | 0.08 | 0.8 | 0.3 | 0.03 | 0.0020 | 8.5 | 17 | 0.1 | 0.2 | 0.006 | 0.05 | 0.21 | 21.9 | 28.9 | 1.8 | 30 | 25 | 1790 | 43 | 63 | |
9 | I | 0.1 | 0.7 | 3 | 0.02 | 0.0063 | 7 | 17 | 0.2 | 0.1 | 0.005 | 0.06 | 0.26 | 23.5 | 22.1 | 1.5 | 40 | 38 | 1940 | 36 | 65 | |
10 | J | 0.11 | 0.8 | 4.5 | 0.03 | 0.0072 | 5.6 | 17 | 0.1 | 0.2 | 0.003 | 0.07 | 0.29 | 23.8 | 12.0 | 1.8 | 50 | 61 | 2080 | 12 | 69 | |
11 | K | 0.1 | 0.8 | 0.5 | 0.03 | 0.0023 | 6.8 | 17.2 | 0.1 | 0.2 | 0.005 | 0.06 | 0.26 | 20.9 | 13.9 | 2.3 | 30 | 67 | 2050 | 13 | 70 | |
12 | L | 0.11 | 0.8 | 1.6 | 0.04 | 0.0046 | 7.3 | 14.5 | 0.1 | 0.3 | 0.005 | 0.06 | 0.28 | 20.8 | 28.9 | 3.1 | 40 | 75 | 2120 | 11 | 67 | |
13 | M | 0.09 | 0.8 | 1.3 | 0.03 | 0.0028 | 7.2 | 18.5 | 0.1 | 0.2 | 0.005 | 0.05 | 0.23 | 22.7 | 14.9 | 3.2 | 50 | 31 | 1850 | 25 | 65 | |
14 | N | 0.09 | 0.8 | 1.4 | 0.04 | 0.0015 | 7.2 | 17 | 0.8 | 0.2 | 0.004 | 0.06 | 0.24 | 22.6 | 25.3 | 1.8 | 40 | 34 | 1880 | 38 | 65 | |
15 | O | 0.08 | 0.8 | 1.3 | 0.03 | 0.0064 | 7 | 17.1 | 1.7 | 0.1 | 0.005 | 0.04 | 0.23 | 23.4 | 29.8 | 2.5 | 40 | 23 | 1820 | 46 | 64 | |
16 | P | 0.07 | 0.8 | 1.3 | 0.03 | 0.0039 | 6.8 | 17.6 | 2.1 | 0.05 | 0.003 | 0.04 | 0.18 | 23.3 | 29.5 | 2.1 | 30 | 22 | 1820 | 40 | 63 | |
17 | Q | 0.09 | 0.7 | 1.6 | 0.03 | 0.0088 | 7 | 17.1 | 0.1 | 0.2 | 0.003 | 0.06 | 0.24 | 22.0 | 18.0 | 2.7 | 50 | 56 | 1970 | 18 | 67 | |
18 | R | 0.1 | 0.6 | 1.6 | 0.03 | 0.0012 | 6.9 | 17 | 0.1 | 0.2 | 0.009 | 0.05 | 0.25 | 21.8 | 17.5 | 2.2 | 40 | 63 | 2020 | 13 | 67 | |
19 | R | 0.09 | 0.6 | 1.6 | 0.01 | 0.0007 | 7.1 | 17.1 | 0.1 | 0.2 | 0.009 | 0.06 | 0.24 | 22.0 | 18.9 | 2.2 | 40 | 54 | 1960 | 30 | 67 | |
Comparative example | 20 | S | 0.02* | 0.8 | 1.6 | 0.03 | 0.003 | 7.2 | 17.1 | 0.1 | 0.2 | 0.005 | 0.06 | 0.1* | 21.3 | 18.7 | 2.8 | 30 | 90* | 1650 | 18 | 65 |
21 | T | 0.15* | 0.6 | 1.6 | 0.03 | 0.003 | 6.9 | 17 | 0.1 | 0.1 | 0.005 | 0.04 | 0.34* | 22.3 | 18.1 | 2.1 | 30 | 42 | 2100 | 2* | 67 | |
22 | U | 0.04 | 0.8 | 1.6 | 0.03 | 0.003 | 6.9 | 17 | 0.1 | 0.1 | 0.005 | 0.22* | 0.3 | 23.2 | 19.0 | 1.9 | 40 | 0* | 1850 | 3* | 63 | |
23 | V | 0.1 | 4.5* | 1.4 | 0.03 | 0.003 | 6.8 | 16.8 | 0.1 | 0.2 | 0.005 | 0.05 | 0.25 | 22.7 | 16.8 | 2 | 40 | 25 | 1870 | 7* | 65 | |
24 | W | 0.08 | 0.8 | 6* | 0.03 | 0.003 | 6.5 | 17.1 | 0.1 | 0.2 | 0.005 | 0.05 | 0.21 | 25.6 | 22.0 | 1.8 | 30 | 40 | 1850 | 8* | 63 | |
25 | X | 0.09 | 0.7 | 0.6 | 0.03 | 0.003 | 9.5* | 17 | 0.1 | 0.2 | 0.005 | 0.05 | 0.23 | 23.3 | 38.7* | 1.7 | 50 | 0* | 1700 | 55 | 60* | |
26 | Y | 0.1 | 0.8 | 3.8 | 0.03 | 0.003 | 4.5* | 17 | 0.1 | 0.2 | 0.005 | 0.05 | 0.25 | 21.6 | 0.3 | 2.2 | 40 | 95* | 2280 | 1* | 70 | |
27 | Z | 0.09 | 0.7 | 1.5 | 0.03 | 0.003 | 7.2 | 13.8* | 0.1 | 0.2 | 0.005 | 0.05 | 0.23 | 19.8* | 29.4 | 2.3 | 30 | 95* | 2180 | 2* | 66 | |
28 | AA | 0.09 | 0.8 | 1.4 | 0.03 | 0.003 | 7 | 19.6* | 0.1 | 0.2 | 0.005 | 0.05 | 0.23 | 23.3 | 10.0 | 2.2 | 30 | 15* | 1800 | 8* | 62* | |
29 | AB | 0.08 | 0.7 | 1.3 | 0.03 | 0.003 | 6.8 | 16.8 | 3.5* | 0.2 | 0.005 | 0.05 | 0.21 | 24.4* | 43.4* | 2.4 | 50 | 3* | 1720 | 15 | 59* | |
30 | AC | 0.1 | 0.7 | 1.6 | 0.03 | 0.003 | 7.1 | 17 | 0.1 | 1.5* | 0.005 | 0.06 | 0.26 | 22.1 | 19.4 | 2.5 | 40 | 1* | 1660* | 40 | 60* | |
31 | AD | 0.1 | 0.8 | 1.6 | 0.03 | 0.0082 | 6.9 | 17 | 0.1 | 0.2 | 0.014* | 0.05 | 0.25 | 21.8 | 17.5 | 3.1 | 40 | 62 | 2010 | 5* | 67 | |
32 | AE | 0.09 | 0.6 | 1.6 | 0.03 | 0.015* | 6.9 | 17 | 0.1 | 0.2 | 0.07 | 0.06 | 0.24 | 21.8 | 17.4 | 1.9 | 30 | 64 | 2000 | 7* | 67 |
No. | Steel grade | Chemical ingredients (quality %) | 2C+N (%) | Ni equivalent (%) | GI (%) | Hydrogen amount (ppm) | Average crystal grain diameter (μ m) | Strain causes living horse for the scale of construction (volume %) | Tensile strength (N/mm 2) | Number of torsions (inferior) | Rigidity modulus (GPa) | ||||||||||||
C | Si | Mn | P | S | Ni | Cr | Mo | Cu | O | N | (other) | ||||||||||||
Example of the present invention | 33 | AF | 0.1 | 0.7 | 1.7 | 0.03 | 0.0033 | 6.9 | 17 | 0.1 | 0.2 | 0.005 | 0.06 | 0.26 | 22.0 | 17.8 | 3.1 | 50 | 55.0 | 2000 | 18 | 67 | |
34 | AG | 0.09 | 0.8 | 1.6 | 0.02 | 0.0043 | 7.1 | 16.9 | 0.2 | 0.1 | 0.002 | 0.05 | Al;0.02 | 0.23 | 21.9 | 20.2 | 2.1 | 10 | 63.0 | 1980 | 34 | 67 | |
35 | AH | 0.11 | 0.6 | 1.5 | 0.03 | 0.0008 | 7.1 | 17.1 | 0.3 | 0.1 | 0.004 | 0.04 | Al;0.06 | 0.26 | 22.1 | 20.4 | 2.5 | 10 | 54.0 | 2000 | 29 | 68 | |
36 | AI | 0.1 | 0.8 | 1.4 | 0.02 | 0.0029 | 7 | 17 | 0.1 | 0.2 | 0.002 | 0.06 | Al;0.18 | 0.26 | 21.8 | 18.1 | 1.9 | 10 | 53.0 | 2000 | 25 | 68 | |
37 | AJ | 0.1 | 0.8 | 1.4 | 0.02 | 0.0029 | 7 | 17 | 0.1 | 0.2 | 0.005 | 0.06 | Nb;0.08 | 0.26 | 21.8 | 18.1 | 2.2 | 20 | 52.0 | 1990 | 31 | 67 | |
38 | AK | 0.09 | 0.7 | 1.5 | 0.03 | 0.0035 | 6.9 | 17.1 | 0.2 | 0.1 | 0.006 | 0.05 | Nb;0.25 | 0.23 | 21.7 | 17.6 | 3 | 10 | 70.0 | 2000 | 32 | 68 | |
39 | AL | 0.1 | 0.8 | 1.6 | 0.03 | 0.0044 | 7 | 17 | 0.3 | 0.1 | 0.003 | 0.05 | Ti;0.07 | 0.25 | 22.1 | 20.0 | 1.8 | 10 | 56.0 | 1980 | 24 | 67 | |
40 | AM | 0.09 | 0.8 | 1.5 | 0.02 | 0.0008 | 7.2 | 17 | 0.2 | 0.1 | 0.003 | 0.05 | Zr;0.22 | 0. 23 | 22.0 | 20.6 | 2.2 | l0 | 58.0 | 1950 | 25 | 66 | |
4l | AN | 0.09 | 0.8 | 1.5 | 0.02 | 0.0008 | 7.2 | 17 | 0.2 | 0.1 | 0.003 | 0.05 | Ta;0.15 | 0.23 | 22.0 | 20.6 | 2.2 | 10 | 60.0 | 1950 | 23 | 67 | |
42 | AO | 0.1 | 0.7 | 1.6 | 0.03 | 0.0016 | 7.1 | 16.9 | 0.1 | 0.2 | 0.004 | 0.06 | W;0.17 | 0.26 | 22.0 | 19.7 | 2.2 | 20 | 50.0 | 1980 | 24 | 66 | |
43 | AP | 0.09 | 0.8 | 1.5 | 0.02 | 0.0021 | 7 | 17 | 0.1 | 0.2 | 0.004 | 0.05 | Al;0.03,Nb;0.1 | 0.23 | 21.7 | 18.0 | 2.2 | 10 | 54.0 | 1980 | 33 | 68 | |
44 | AO | 0.1 | 0.7 | 1.5 | 0.02 | 0.0034 | 7.1 | 17.1 | 0.1 | 0.1 | 0.005 | 0.05 | V;0.3 | 0.25 | 22.0 | 18.8 | 2.2 | 10 | 58.0 | 2010 | 25 | 87 | |
Relatively | 45 | AR | 0.09 | 0.7 | 1.6 | 0.03 | 0.0005 | 7.1 | 17.1 | 0.1 | 0.1 | 0.002 | 0.06 | Al;0.38* | 0.24 | 22.1 | 18.9 | 2.2 | 10 | 57.0 | 1970 | 5 | 57 |
46 | AS | 0.1 | 0.8 | 1.5 | 0.03 | 0.0011 | 7.1 | 17.1 | 0.1 | 0.1 | 0.005 | 0.06 | Nb;0.50* | 0.26 | 22.1 | 18.9 | 2.2 | 10 | 50.0 | 2000 | 6 | 66 |
No. | Steel grade | Dehydrogenation is handled | The gas of many continuous annealing atmosphere | Hydrogen amount (ppm) | Average crystal grain diameter (μ m) | Strain causes living martensite volume (volume %) | Tensile strength (N/mm 2) | Number of torsions (inferior) | Rigidity modulus (GPa) | |
Example of the present invention | 47 | A | Be untreated | Argon gas | 2.2 | 10 | 60 | 2000 | 17 | 67 |
48 | A | Be untreated | Nitrogen | 2.5 | 10 | 63 | 1980 | 17 | 67 | |
49 | A | Be untreated | Atmosphere | 2.1 | 10 | 61 | 2050 | 16 | 68 | |
50 | A | 300 ℃-24h, atmosphere | Argon gas | 0.8 | 10 | 58 | 2040 | 22 | 67 | |
51 | A | 300 ℃-24h, nitrogen | Argon gas | 0.9 | 10 | 62 | 2030 | 21 | 68 | |
52 | A | 250 ℃-24h, atmosphere | Argon gas | 1.2 | 10 | 63 | 2000 | 20 | 67 | |
53 | A | 150 ℃-24h, atmosphere | Argon gas | 2 | 10 | 65 | 1990 | 18 | 67 | |
54 | A | 450 ℃-24h, atmosphere | Argon gas | 0.7 | 10 | 59 | 2020 | 25 | 68 | |
55 | A | 550 ℃-24h, atmosphere | Argon gas | 1.1 | 10 | 60 | 2030 | 22 | 68 | |
Relatively | 56 | A | Be untreated | Hydrogen-containing gas * | 6.3* | 10 | 61 | 2050 | 7* | 66 |
57 | A | 300 ℃-24h, atmosphere | Hydrogen-containing gas * | 5.3* | 10 | 62 | 2100 | 5* | 65 |
No. | Steel grade | Ni equivalent (%) | The hand-drawn wire amount of finish, the ε optimum range | Actual hand-drawn wire amount of finish; ε | Hydrogen amount (ppm) | Average crystal grain diameter (μ m) | Strain causes living martensite volume (volume %) | Tensile strength (N/mm 2) | Number of torsions (inferior) | Rigidity modulus (GPa) | |
Example of the present invention | 58 | AH | 22.1 | 1.035~2.435 | 1.51 | 2.4 | 10 | 55 | 2000 | 29 | 68 |
59 | AH | 22.1 | 1.035~2.435 | 1.1 6 | 2.3 | 10 | 30 | 1860 | 43 | 65 | |
60 | AH | 22.1 | 1.035~2.435 | 2.08 | 2.1 | 10 | 75 | 2210 | 12 | 68 | |
61 | I | 23.5 | 1.245~2.645 | 1.51 | 1.8 | 40 | 40 | 1950 | 34 | 65 | |
62 | I | 23.5 | 1.245~2.645 | 1.27 | 2 | 40 | 25 | 1820 | 48 | 64 | |
63 | I | 23.5 | 1.245~2.645 | 2.45 | 2.1 | 40 | 76 | 2080 | 20 | 66 | |
64 | L | 20.8 | 0.84~2.24 | 1.51 | 2.8 | 30 | 70 | 2100 | 12 | 67 | |
65 | L | 20.8 | 0.84~2.24 | 0.87 | 2.5 | 30 | 30 | 1830 | 19 | 64 | |
66 | L | 20.8 | 0.84~2.24 | 2.00 | 2.4 | 30 | 78 | 2200 | 10 | 68 | |
Comparative example | 67 | AH | 22.1 | 1.035~2.435 | 0.96* | 2.5 | 10 | 18* | 1650 | 45 | 62* |
68 | AH | 22.1 | 1.035~2.435 | 2.45* | 2.3 | 10 | 83* | 2200 | 5* | 68 | |
69 | I | 23.5 | 1.245~2.645 | 1.06* | 1.9 | 40 | 10* | 1640 | 50 | 62* | |
70 | I | 23.5 | 1.245~2.645 | 2.89* | 2.3 | 40 | 84* | 2240 | 5* | 66 | |
71 | L | 20.8 | 0.84~2.24 | 0.78* | 2.8 | 30 | 18* | 1680 | 23 | 62* | |
72 | L | 20.8 | 0.84~2.24 | 2.45* | 3 | 30 | 90* | 2240 | 2* | 68 |
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PCT/JP2002/004493 WO2003095693A1 (en) | 2002-05-08 | 2002-05-08 | High strength stainless steel wire excellent in ductility-toughness and modulus of rigidity and method for production thereof |
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CN1263880C true CN1263880C (en) | 2006-07-12 |
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JP (1) | JP4212553B2 (en) |
KR (1) | KR100566142B1 (en) |
CN (1) | CN1263880C (en) |
HK (1) | HK1069190A1 (en) |
WO (1) | WO2003095693A1 (en) |
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JPWO2003095693A1 (en) | 2005-09-15 |
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KR20040013124A (en) | 2004-02-11 |
JP4212553B2 (en) | 2009-01-21 |
KR100566142B1 (en) | 2006-03-30 |
HK1069190A1 (en) | 2005-05-13 |
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