CN1261394C - 制备枯烯的方法 - Google Patents

制备枯烯的方法 Download PDF

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Publication number
CN1261394C
CN1261394C CNB028138449A CN02813844A CN1261394C CN 1261394 C CN1261394 C CN 1261394C CN B028138449 A CNB028138449 A CN B028138449A CN 02813844 A CN02813844 A CN 02813844A CN 1261394 C CN1261394 C CN 1261394C
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CN
China
Prior art keywords
benzene
alkylation
mcm
catalyst
volume ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB028138449A
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English (en)
Chinese (zh)
Other versions
CN1529687A (zh
Inventor
A·B·丹德卡
D·L·斯特恩
M·赫尼斯扎克
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ExxonMobil Chemical Patents Inc
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ExxonMobil Chemical Patents Inc
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Publication date
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Publication of CN1529687A publication Critical patent/CN1529687A/zh
Application granted granted Critical
Publication of CN1261394C publication Critical patent/CN1261394C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/085—Isopropylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB028138449A 2001-07-11 2002-05-20 制备枯烯的方法 Expired - Fee Related CN1261394C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/902,957 US20020042548A1 (en) 2001-07-11 2001-07-11 Process for producing cumene
US09/902,957 2001-07-11

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CNA200610077774XA Division CN1840514A (zh) 2001-07-11 2002-05-20 制备枯烯的方法

Publications (2)

Publication Number Publication Date
CN1529687A CN1529687A (zh) 2004-09-15
CN1261394C true CN1261394C (zh) 2006-06-28

Family

ID=25416685

Family Applications (2)

Application Number Title Priority Date Filing Date
CNB028138449A Expired - Fee Related CN1261394C (zh) 2001-07-11 2002-05-20 制备枯烯的方法
CNA200610077774XA Pending CN1840514A (zh) 2001-07-11 2002-05-20 制备枯烯的方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNA200610077774XA Pending CN1840514A (zh) 2001-07-11 2002-05-20 制备枯烯的方法

Country Status (12)

Country Link
US (5) US20020042548A1 (enExample)
EP (1) EP1404634B1 (enExample)
JP (1) JP4554201B2 (enExample)
KR (1) KR100894388B1 (enExample)
CN (2) CN1261394C (enExample)
CA (1) CA2451646C (enExample)
ES (1) ES2559077T3 (enExample)
FI (1) FI125517B (enExample)
SG (1) SG180016A1 (enExample)
TW (2) TWI245754B (enExample)
WO (1) WO2003006405A1 (enExample)
ZA (1) ZA200309896B (enExample)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020042548A1 (en) * 2001-07-11 2002-04-11 Dandekar Ajit B. Process for producing cumene
US6815570B1 (en) * 2002-05-07 2004-11-09 Uop Llc Shaped catalysts for transalkylation of aromatics for enhanced xylenes production
JP4325335B2 (ja) * 2003-09-18 2009-09-02 住友化学株式会社 クメンの製造方法
JP4732510B2 (ja) * 2005-03-31 2011-07-27 エクソンモービル・ケミカル・パテンツ・インク 芳香族化合物のトランスアルキル化の製造方法および触媒
BRPI0607647B1 (pt) * 2005-03-31 2015-07-07 Badger Licensing Llc Processo para produzir etil-benzeno ou cumeno, método para readaptar uma planta existente de etil-benzeno ou cumeno para produzir etil-benzeno ou cumeno, e métodos para selecionar um catalisador de alquilação e de transalquilação para o referido processo
US20080043334A1 (en) * 2006-08-18 2008-02-21 Mirage Innovations Ltd. Diffractive optical relay and method for manufacturing the same
KR100978980B1 (ko) 2006-02-14 2010-08-30 엑손모빌 케미칼 패턴츠 인코포레이티드 엠씨엠-22계 분자체의 제조 방법
EP1996328B1 (en) 2006-02-14 2016-07-13 ExxonMobil Chemical Patents Inc. Method of preparing a molecular sieve composition
WO2007143239A2 (en) * 2006-02-14 2007-12-13 Exxonmobil Chemical Patents Inc. Process for producing sec-butylbenzene
GB0608582D0 (en) * 2006-05-02 2006-06-07 Univ Sheffield Hallam High power impulse magnetron sputtering vapour deposition
WO2007128842A1 (es) * 2006-05-08 2007-11-15 Petroquímica Española, S.A. (Petresa) Transalquilación catalítica de dialquilbencenos
EP2041242B1 (en) 2006-05-24 2017-03-29 ExxonMobil Chemical Patents Inc. Monoalkylated aromatic compound production
US20080058566A1 (en) * 2006-09-05 2008-03-06 Fina Technology, Inc. Processes for reduction of alkylation catalyst deactivation utilizing low silica to alumina ratio catalyst
US7919421B2 (en) * 2006-12-21 2011-04-05 Exxonmobil Chemical Patents Inc. Catalyst composition, the method of manufacturing and the process of use thereof in aromatics alkylation
US7420098B2 (en) * 2007-01-12 2008-09-02 Uop Llc Dual zone aromatic alkylation process
US7381676B1 (en) * 2007-01-16 2008-06-03 Exxonmobil Chemical Patents Inc. Catalyst composition and its use thereof in aromatics alkylation
US7645913B2 (en) 2007-01-19 2010-01-12 Exxonmobil Chemical Patents Inc. Liquid phase alkylation with multiple catalysts
WO2008097737A1 (en) * 2007-02-09 2008-08-14 Exxonmobil Chemical Patents Inc. A Corporation Of The State Of Delaware Improved alkylaromatic production process
US7683228B2 (en) * 2007-02-12 2010-03-23 Exxonmobil Chemical Patents Inc. Production of high purity cumene from non-extracted feed and hydrocarbon composition useful therein
US8816145B2 (en) 2007-06-21 2014-08-26 Exxonmobil Chemical Patents Inc. Liquid phase alkylation process
US7790940B2 (en) * 2007-06-21 2010-09-07 Exxonmobil Chemical Patents Inc. Liquid phase alkylation process
US20100312033A1 (en) * 2009-03-13 2010-12-09 Exxonmobil Research And Engineering Company Olefin feed purification process
US20110118522A1 (en) 2009-11-13 2011-05-19 Exxonmobil Research And Engineering Company Olefin feed purification process
JP5757996B2 (ja) * 2010-05-20 2015-08-05 エクソンモービル ケミカル パテンツ インコーポレイテッド 改善されたアルキル化プロセス
RU2563461C2 (ru) * 2010-08-30 2015-09-20 Эксонмобил Кемикэл Пейтентс Инк. Улучшенный способ алкилирования
CN103180042B (zh) * 2010-10-15 2015-07-22 埃克森美孚化学专利公司 选择改进的催化剂组合物和使用所述催化剂组合物的烃转化方法
ITMI20111144A1 (it) * 2011-06-23 2012-12-24 Polimeri Europa Spa Procedimento per l'alchilazione di idrocarburi aromatici con olefine
WO2014018752A1 (en) 2012-07-26 2014-01-30 Badger Licensing Llc Aromatics alkylation process
RU2654699C2 (ru) * 2012-12-11 2018-05-22 Эксонмобил Кемикэл Пейтентс Инк. Способ получения кумола с рециклом продуктов алкилирования
WO2016205878A1 (en) * 2015-06-22 2016-12-29 Patrick James Cadenhouse-Beaty Process for producing transport fuel blendstock
US10503176B2 (en) 2016-12-30 2019-12-10 Bendix Commercial Vehicle Systems Llc Self-ordering of fleet vehicles in a platoon
JP6914362B2 (ja) * 2017-01-25 2021-08-04 エクソンモービル・ケミカル・パテンツ・インク トランスアルキル化プロセスおよびそれに使用される触媒組成物
EP3600654B1 (en) 2017-03-29 2024-05-01 ExxonMobil Chemical Patents Inc. Methods for removing impurities from a hydrocarbon stream and their use in aromatic alkylation processes
WO2018183009A1 (en) * 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes
BR112019020215B1 (pt) 2017-03-29 2023-10-10 Exxonmobil Chemical Patents Inc Composição de catalisador para uso em processos de alquilação aromática e processo para produzir um composto aromático monoalquilado
WO2018183012A1 (en) * 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Methods for removing impurities from a hydrocarbon stream and their use in aromatic alkylation processes
TWI665012B (zh) * 2017-03-29 2019-07-11 美商艾克頌美孚化學專利股份有限公司 自烴流移除雜質之方法及其於芳族烷基化製程之用途
IT201900015066A1 (it) * 2019-08-27 2021-02-27 Versalis Spa Procedimento per il trattamento di idrocarburi polialchilaromatici.
WO2023196729A1 (en) 2022-04-05 2023-10-12 Exxonmobil Chemical Patents Inc. Mww zeolite precursor nanoparticles having an uncondensed layer structure and methods for production thereof

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB896390A (en) 1957-09-16 1962-05-16 Robert Sancier Aries Alkylation of benzene
US3308069A (en) * 1964-05-01 1967-03-07 Mobil Oil Corp Catalytic composition of a crystalline zeolite
US3966644A (en) * 1973-08-03 1976-06-29 American Cyanamid Company Shaped catalyst particles
US4185040A (en) * 1977-12-16 1980-01-22 Union Oil Company Of California Alkylation of aromatic hydrocarbons
EP0007126A1 (en) 1978-07-06 1980-01-23 Union Carbide Corporation Cumene synthesis process
US4486616A (en) 1979-12-13 1984-12-04 Mobil Oil Corporation Rejuvenation of deselectivated alkylation catalyst
US4328130A (en) * 1980-10-22 1982-05-04 Chevron Research Company Shaped channeled catalyst
US4387260A (en) 1981-04-20 1983-06-07 Cosden Technology, Inc. Alkylation of aromatic compounds with silicalite catalysts in the presence of steam
DE3117135A1 (de) * 1981-04-30 1982-11-18 Bayer Ag, 5090 Leverkusen Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe
US4441990A (en) * 1982-05-28 1984-04-10 Mobil Oil Corporation Hollow shaped catalytic extrudates
US5149894A (en) 1986-01-29 1992-09-22 Chevron Research And Technology Company Alkylation using zeolite SSZ-25
US4826667A (en) * 1986-01-29 1989-05-02 Chevron Research Company Zeolite SSZ-25
US4954325A (en) * 1986-07-29 1990-09-04 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis and use
US4798816A (en) * 1986-12-19 1989-01-17 Union Oil Company Of California Process for increasing the selectivity of an alkylation catalyst for monoalkylation
US5081323A (en) * 1987-12-17 1992-01-14 Chevron Research And Technology Company Liquid phase alkylation or transalkylation process using zeolite beta
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
US4992606A (en) * 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
FR2638157B1 (fr) 1988-10-26 1991-04-19 Inst Francais Du Petrole Procede de production d'alkylbenzenes utilisant un catalyseur a base de mordenite modifiee
RU1839668C (ru) 1988-11-28 1993-12-30 МИЦУИ ПЕТРОКЕМИКАЛ ИНДАСТРИЗ, Лтд (JP) Способ получени фенола
US5536895A (en) 1990-12-17 1996-07-16 Uop Isomerization process using modified zeolite Omega
US5250277A (en) * 1991-01-11 1993-10-05 Mobil Oil Corp. Crystalline oxide material
US5545788A (en) 1991-06-19 1996-08-13 Mobil Oil Corporation Process for the alkylation of benzene-rich reformate using MCM-49
US5236575A (en) * 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
EP0538518A1 (en) 1991-10-16 1993-04-28 Council of Scientific and Industrial Research An improved process for the production of cumene
EP0537389A1 (en) 1991-10-16 1993-04-21 Council of Scientific and Industrial Research An improved process for the production of cumene
US5362687A (en) * 1992-02-04 1994-11-08 Narumi China Corporation Lead-free frit glaze
US5258565A (en) * 1992-05-04 1993-11-02 Mobil Oil Corp. Process for preparing short chain alkylaromatic compounds
US5362697A (en) * 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
WO1996011175A1 (en) 1994-10-06 1996-04-18 Exxon Chemical Patents Inc. Process for manufacturing ethylbenzene or cumene
US5600048A (en) 1994-12-27 1997-02-04 Mobil Oil Corporation Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
US5723710A (en) * 1996-07-12 1998-03-03 Uop Zeolite beta and its use in aromatic alkylation
DE19649944A1 (de) 1996-12-03 1998-06-04 Basf Ag Verfahren zur Herstellung von Aminen aus Olefinen an Zeolithen des Typs MCM-49 oder MCM-56
TW416938B (en) 1997-01-22 2001-01-01 Chinese Petroleum Corp Process for the production of cumene and its catalyst preparation
US6028238A (en) 1998-04-14 2000-02-22 Mobil Oil Corporation Xylene isomerization
US6051521A (en) 1998-08-25 2000-04-18 Mobil Oil Corporation Method of producing an aromatics alkylation catalyst
US6984764B1 (en) * 1999-05-04 2006-01-10 Exxonmobil Oil Corporation Alkylaromatics production
US6897346B1 (en) * 1999-06-10 2005-05-24 Fina Technology, Inc. Aromatic conversion process employing low surface area zeolite Y
FR2795403B1 (fr) 1999-06-22 2002-11-29 Inst Francais Du Petrole Alkylation de benzene par des olefines en presence d'un catalyseur comprenant une zeolithe euo, en vue de la synthese du cumene
FR2795404B1 (fr) 1999-06-22 2002-11-29 Inst Francais Du Petrole Alkylation du benzene par un agent d'alkylation c2 ou c3, en presence d'un catalyseur a base de zeolithe euo, en vue de la synthese du cumene et de l'ethylbenzene
US20020042548A1 (en) * 2001-07-11 2002-04-11 Dandekar Ajit B. Process for producing cumene
US6781025B2 (en) * 2001-07-11 2004-08-24 Exxonmobil Chemical Patents Inc. Reactivation of aromatics alkylation catalysts
CN2812449Y (zh) 2005-08-15 2006-08-30 华为技术有限公司 分布式基站模块

Also Published As

Publication number Publication date
SG180016A1 (en) 2012-05-30
TW200613247A (en) 2006-05-01
US7638668B2 (en) 2009-12-29
FI20040030L (fi) 2004-01-12
ES2559077T3 (es) 2016-02-10
JP4554201B2 (ja) 2010-09-29
TWI245754B (en) 2005-12-21
CA2451646A1 (en) 2003-01-23
US20080045765A1 (en) 2008-02-21
CN1529687A (zh) 2004-09-15
US7399894B2 (en) 2008-07-15
FI125517B (fi) 2015-11-13
KR20040030797A (ko) 2004-04-09
ZA200309896B (en) 2004-06-09
US7868215B2 (en) 2011-01-11
EP1404634A1 (en) 2004-04-07
KR100894388B1 (ko) 2009-04-20
WO2003006405A1 (en) 2003-01-23
CN1840514A (zh) 2006-10-04
EP1404634B1 (en) 2015-11-11
US20020042548A1 (en) 2002-04-11
US20050187416A1 (en) 2005-08-25
CA2451646C (en) 2010-06-29
JP2004534845A (ja) 2004-11-18
US6888037B2 (en) 2005-05-03
US20100056835A1 (en) 2010-03-04
TWI268917B (en) 2006-12-21
US20030092949A1 (en) 2003-05-15

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