CN1247260A - Colouring wall decorative material with/or without patterns and spots, and prepn. method - Google Patents
Colouring wall decorative material with/or without patterns and spots, and prepn. method Download PDFInfo
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- CN1247260A CN1247260A CN 99110969 CN99110969A CN1247260A CN 1247260 A CN1247260 A CN 1247260A CN 99110969 CN99110969 CN 99110969 CN 99110969 A CN99110969 A CN 99110969A CN 1247260 A CN1247260 A CN 1247260A
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Abstract
To reveal a clear single color tone by fixing two or more colors of respective color parts constituting a pattern of a colored wall face material with a pattern in a transparent binder in a state of mutually mixing/dispersing few kinds of colored coarse grains having the grain size being almost uniform in a specific range. Because of a single color tone of respective color parts constituting a pattern of a colored wall face material with a pattern, colored coarse grains are used by combining few kinds of optional colors, and three primary colors of colors or a combination of these three primary colors and a white color and/or a black color are particularly desirable. The grain size of the colored coarse grains of the respective colors is almost uniform, the central grain size is set in a range of 10 to 1000 m, and the respective color parts are fixed in a transparent binder in a mutually mixed/dispersed state. The same effect as a sketch in a picture can be obtained by mixing and dispersing the colored coarse grains of several colors having the almost uniform specific grain size, a clear single color tone can be revealed in the respective color parts of the wall face material, and contrast of the colors between the respective color parts becomes very clear.
Description
The present invention relates to pattern-free or have pattern the colouring wall material, contain the pattern-free of spot or have the colouring wall material of pattern and their manufacture method.
Always, with the planar spraying material of sand (original text リ Bing シ, English translated name lithin-applicant note) or ジ コ ラ ケ (japonic a kind of wall material, the no suitable Chinese is translated with the English translated name and is claimed-applicant's note) and other wall material when being processed into specific single tone, be in aqueous matrix coating such as synthetic resin emulsion, with other complex, simultaneously will be for example the pigment powder of the millimicron size particle diameter of 10～100nm degree monochromatic or cooperate more than two looks, to show tone.
On the other hand, have in the wall material of pattern at the wall material of the pattern of natural stone such as imitation so-called granite etc. etc., used coloured natural stone particle, the colored particles of the big particle diameter of artificial painted particle, painted mm sizes such as resin sheet on natural stone particle.
But, in the prior art of the pattern-free colouring wall material of above-mentioned use pigment, because toning is to use the micro pigment of 10～100nm degree to mix, so the occasion principle of mixing colours with the drawing pigment more than mixing 2 looks identical, color usually becomes muddy because of the mixing of pigment, and it is difficult showing distinct dark tone.
In addition, sesamoid spot appearance such as performance black or white when containing the pattern-free colouring wall material of spot with formation, can not present distinct dark tone because background color is easily muddy on the background color of such tone, and institute is so that the spot appearance is unshowy.
On the other hand, the colored particles of using in the colored pattern wall material of the above-mentioned patterns such as " driving shadow stone " of imitation is because of constituting the particle that pattern uses the quite big particle diameter of 0.1～10mm degree.Thereby, each colored particles all be can naked eyes the big particle diameter of identification degree, can not expect said function of the colored particles more than 2 looks being mixed the single tone of performance.
; what is called point in drawing is retouched mode (method of forming background colour with many little color dots); the set of the choice refreshments of several colors by having the certain limit particle diameter is during with the performance tone, and is then different with the situation that drawing pigment is mixed, and can show distinct tone.Therefore, the point of these colors, requiring has roughly homogeneous particle diameter, and can not be to resemble the pigment excessive smallly, can not be the big particle diameter that naked eyes can be discerned.
The present invention is exactly that several colored particles of homogeneous particle diameter that will be by will having certain limit are mixed, and realizes that in the colouring wall material point of drawing is retouched the effect of mode, and by these colored particles are fixed in the transparent adhesives, realizes dark tone.
The formation of the 1st invention
The 1st invention of the application (invention of record in the claim 1) is, the colored particles of the homogeneous particle diameter and a few species color that possess the particle diameter that is in 10～1000 mu m ranges roughly is fixed in the transparent adhesives with the state that mutual mixing disperses, takes this to show the pattern-free colouring wall material of single tone.
The formation of the 2nd invention
The 2nd invention of the application (invention of record in the claim 2) is, make following 1) and 2) colored particles mix and to be dispersed in the transparent aqueous matrix coating, take this by 1) make by 2 on the background color of the single tone of performance) the pattern-free colouring wall material that contains spot that manifested of the sesamoid spot appearance of performance.
1) roughly the homogeneous particle diameter and colored particles that possess a few species color that is in the particle diameter in 10～1000 mu m ranges.
2) possess above-mentioned relatively 1) 2～10 times of particle diameters of colored particles, have with by 1) colored particles of the color that the color of single tone xenogenesis of performance or concentration of the same race but look are different.
The formation of the 3rd invention
The 3rd invention of the application (invention of record in the claim 3) is, the colouring wall material that has pattern of the pattern that formation partly is made of the color more than two looks, be in constituting each color part of this pattern, the colored particles of the homogeneous particle diameter and a few species color that possess the particle diameter that is in 10～1000 mu m ranges roughly is fixed in the transparent adhesives with the state that mutual mixing disperses, takes this to show the colouring wall material that has pattern of single tone.
The formation of the 4th invention
The 4th invention of the application (invention of record in the claim 4) is, make aforesaid right requirement 2 described 1) and 2) colored particles mix and to be dispersed in the transparent aqueous matrix coating, take this by 1) make by 2 on the background color of the single tone of performance) the sesamoid spot appearance of the performance colouring wall material that has pattern that contains spot that manifested, partly constitute pattern by the color more than two looks.
The formation of the 5th invention
The 5th invention of the application (invention of record in the claim 5) is, in any one of～the 4 invention of the 1st invention, the color scheme of the colored particles that above-mentioned mutual mixing disperses is the combination of three primary colors or this three primary colors and the white and/or the black of look.
The formation of the 6th invention
The application's the 6th invention (in the claim 6 record invention) be ,～the 5 invention of the 1st invention each pattern-free colouring wall material or the colouring wall material that has a pattern be the surface layer material of stipulating among the JIS A6909.
The formation of the 7th invention
The 7th invention of the application (in the claim 7 record invention) be, in the 2nd invention or the 4th invention, will be by above-mentioned 2) the spot appearance of performance is taken as the spot appearance of white or dense colour.
The formation of the 8th invention
The 8th invention of the application (invention of record in the claim 8) is, make necessary other cooperate material, make simultaneously homogeneous particle diameter roughly and possess the colored particles that is in a few species color of particle diameter in 10～1000 mu m ranges and mix the coating material that is dispersed in the transparent aqueous matrix coating.
The formation of the 9th invention
The 9th invention of the application (claim 9 record invention) be, makes necessary other cooperate material, make simultaneously the 2nd invention 1) and 2) colored particles mix the coating material that is dispersed in the transparent aqueous matrix coating.
The formation of the 10th invention
The 10th invention of the application (in the claim 10 record invention) be, uses the monochromatic color coating material of the 8th invention to make the pattern-free colouring wall material of the 1st invention or make the manufacture method of colouring wall material of the colouring wall material that has pattern of the 3rd invention with the coating material more than 2 colors of the 8th invention.
The formation of the 11st invention
The 11st invention of the application (in the claim 11 record invention) be, uses the monochromatic color coating material of the 9th invention to make the pattern-free colouring wall material that contains spot of the 2nd invention or use the above coating material of 2 colors of the 9th invention to make the manufacture method of colouring wall material of the colouring wall material that has pattern that contains spot of the 4th invention.
Effect, the effect of the 1st invention
In the 1st invention, make to have in 10～1000 mu m ranges roughly the colored particles of several colors of the regulation particle diameter of homogeneous and mix and disperse, take this to have obtained with drawing in point retouch same effect, present the tone of single distinctness.
During the roughly homogeneous particle diameter less than 10 μ m of colored particles, and colored particles is when having wide size distribution, and the effect that point is retouched dies down, and the vividness of tone descends, the tone of the general easy muddiness that becomes history.When the roughly homogeneous particle diameter of colored particles surpassed 1000 μ m, each colored particles became the situation that vision can identification, has lost the function that said mixing by the colored particles more than 2 looks shows single tone.
Because these colored particles are fixed, therefore invested dark tone in the clear binder as parent.
Effect, the effect of the 2nd invention
In the pattern-free colouring wall material that contains spot of the 2nd invention, by 1) the distinct dark background color of colored particles performance of a few species color, simultaneously will be by 2) the sesamoid spot appearance of colored particles performance present, so this spot situation is very especially showy.
Effect, the effect of the 3rd invention
In the 3rd invention,, be to present and the single tone of the dark distinctness that the 1st invention is same about the tone of each color part of the formation pattern in the colouring wall material that has pattern.Thereby the color contrast between each color part is also very distinct.
During the roughly homogeneous particle diameter less than 10 μ m of colored particles or when surpassing 1000 μ m, and colored particles is when having wide size distribution since with the 1st reason that invention is identical, can not guarantee above-mentioned effect.
Effect, the effect of the 4th invention
In the colouring wall material that has pattern that contains spot of the 4th invention, in each color part of formation pattern in having the colouring wall material of pattern, by 1) the background color of the distinct dark single tone of the colored particles performance of a few species color, and will be by 2) the sesamoid spot appearance of colored particles performance display, therefore, the contrast of the color between each color part becomes distinct, and these spot appearance in each color part are especially showy simultaneously.
The effect of the 5th invention
In the 5th invention, be to make the trichromatic colored particles of color mix dispersion, or adding therein to mix after the colored particles of white and/or black disperses, and makes that therefore the well balanced tone attractive in appearance of performance becomes possibility in the various colouring wall materials of～the 4 invention of the 1st invention.
Effect, the effect of the 6th invention
Because the 6th invention, the painted surface layer material of pattern-free of the dark tone that makes it possible to provide distinct or have the painted surface layer material of pattern perhaps contains the painted surface layer material of pattern-free of spot or has the painted surface layer material of pattern.
Effect, the effect of the 7th invention
In the 7th invention, with above-mentioned the 2nd invention or the pattern-free colouring wall material that contains spot of the 4th invention or have the spot appearance of the colouring wall material of pattern, make black, white or have the spot appearance of dense colour, take this to realize spot appearance attractive in appearance.
Effect, the effect of the 8th invention and the 9th invention
Owing to use the monochromatic color coating material of the 8th invention, can make the pattern-free colouring wall material of the 1st invention, owing to use the above coating material of 2 colors of the 8th invention, can make the colouring wall material that has pattern of the 3rd invention.
In addition, owing to use the monochromatic color coating material of the 9th invention, the pattern-free colouring wall material that contains spot of the 2nd invention can be made,, the colouring wall material that has pattern that contains spot of the 4th invention can be made owing to use the above coating material of 2 colors of the 9th invention.
Effect, the effect of the 10th invention and the 11st invention
According to the manufacture method of the 10th invention and the colouring wall material of the 11st invention, can make the pattern-free colouring wall material that contains spot of the colouring wall material that has pattern of the pattern-free colouring wall material of the 1st invention, the 3rd invention, the 2nd invention or the colouring wall material that has pattern that contains spot of the 4th invention.
Below to the 1st the invention～the 11 working of an invention mode describe.When placing an order title " the present invention ", refer to the blanket of～the 11 invention of the 1st invention.
The kind of colouring wall material
The pattern-free colouring wall material of～the 4 invention of the 1st invention, contain spot pattern-free colouring wall material, have the colouring wall material of pattern and contain the kind of the colouring wall material that has pattern of spot, in building etc., do not limit in the scope of used wall material.It is as follows to go out 2,3 routine wall materials by the kind example: a kind of surface layer material of the planar spraying material of synthetic resin emulsion sand or epidermis are that the coating material is processed in ジ コ ラ ケ wall, the thickening of using the painted main material of aggregate, in addition also can enumerate various plates, sheet, watt etc. forming board, by using the position example to go out 2,3 routine wall materials, can enumerate: use at ceiling portion, above ground portion, vertical plane wall wall part.
Colored particles
Colored particles is that silica sand, gypsum rubrum (originate in Japan, broken thing-applicant's note of pure white calcite set tissue) nature stone particle such as, ware matter crushed material, glass grain, aggregates such as resin sheet, can use had the same specific color or be coloured to specific color.Preferred especially water resistance and weatherability good, non-fading.
Colored particles is used in combination the arbitrary hue of a few species.Here said " a few species ", preferred 2 looks～5 look degree, but also can be on request by 6 looks～10 look degree or constitute more than it.Particularly preferred color scheme is 3 primary colors of look, or one or the two combination of these 3 primary colors and white and black.In the toning of achromatic color system, only the combination of white and black also can.Except the combination of these basic colors, also can make primary colors color arbitrarily in addition combined.
As on aggregate with the means of above-mentioned specific colour coloring, for example can utilize the yellow, the blue or green blue blue look of phthalein of redness, the ochre of black, the iron oxide of carbon black etc.Colorize method is arbitrarily, for example can freely utilize methods such as the sintering that applies air dry, usefulness glaze is painted, calcining.
The particle diameter of the colored particles of each color is a homogeneous roughly, and its medium particle diameter is in the scope of 10～1000 μ m.Particularly be in the scope of 80～300 μ m, this is realizing that in the distinct toning be preferred.
About above-mentioned particle diameter all once, so long as retouching effect to the point that can obtain requiring, just can satisfy homogeneous, but an one preferred benchmark is, the colored particles of minimum grain size is 1/2 with respect to the size ratio of the colored particles of maximum particle diameter, another preferred benchmark is, colored particles all more than 80% with respect to medium particle diameter be included in ± 30% scope in.
The mixing of colored particles disperses
The colored particles of a few species color is fixed in the transparent adhesives with the state that mutual mixing disperses.Wish these colored particles with the distribution proportion mixing of homogeneous separately, even but the inhomogenous part of distribution proportion is partly arranged, so long as do not destroy as the degree of all toning balances just passable.
The number ratio of the colored particles of each color that is combined because of different as the color order of toning pattern, does not limit.That is, for example the colored particles of red/orchid/Huang Sanse is being mixed when disperseing the desirable numerical value arbitrarily of X, Y, Z among its number ratio X/Y/Z.
Colored particles is with respect to the cooperation ratio of clear binder, for example be necessary to set out and adjust according to the granularity of colored particles or the viscosity/viscosity of adhesive by the viewpoint in the construction, also be necessary to change, therefore can not do same qualification according to degree as the depth perception of the toning of target.
Adhesive
As adhesive, can use known various adhesive arbitrarily, for example the synthetic resin solution of acetic acid esters, acrylate etc. or emulsion, silicate base solution, silicate base dispersion etc.These adhesives in order to invest the dark sensation of pattern-free colouring wall material, use transparent.Even its transparency with some muddinesses, but so long as invests the degree of transparent feel in fact and just can satisfy.And use water white adhesive better, but the adhesive that also can use colored transparent is to invest the substrate effect in the toning.
Pattern-free or have used coating material in the manufacturing of colouring wall material of pattern
Used coating material in the manufacturing of pattern-free colouring wall material is in transparent aqueous matrix coating, makes necessary other cooperate material, simultaneously the colored particles of above-mentioned a few species color is mixed to disperse, thereby mix colours into single tone.In the manufacturing of the colouring wall material that has pattern, use the above toning of 2 kinds of colors to become the coating material of above-mentioned specific single tone.
As transparent aqueous matrix coating, can use the synthetic resin solution, emulsion, dispersion of various water white transparencies described in above-mentioned " adhesive " or colored transparent etc.Preferred especially synthetic resin emulsion.
Other cooperation material as cooperating in the coating material can make known various additives such as water, tackifier, anticorrisive agent, activating agent arbitrarily.
For the toning effect that makes pattern-free or have a colouring wall material of pattern is more effectively brought into play, it is good not cooperating the solid-state aggregate beyond the colored particles in the coating material, but if is necessary also can cooperate.The aggregate that for example also can cooperate the big particle diameter of minority except that colored particles again by the appearance of the aggregate of these big particle diameters performance pin mark, is then mixed colours by colored particles to the part of the background color beyond it.
Contain the pattern-free colouring wall material of spot or have the colouring wall material of pattern
Contain the pattern-free colouring wall material of spot or have the colouring wall material of pattern, be for above-mentioned pattern-free colouring wall material or have the additional sesamoid spot appearance of colouring wall material of pattern.
Specifically, be in transparent aqueous matrix, make other necessary compounding ingredient, make 1 simultaneously) be the colored particles and 2 that constitutes the minority kind color of pattern-free colouring wall material) be that the colored particles that constitutes sesamoid spot appearance is mixed the coating material that single tone is mixed colours in dispersion, this is coated with material in containing the pattern-free colouring wall material of spot, uses single color, containing in the colouring wall material that has pattern of spot and using more than 2 colors, take this to modulate.
As above-mentioned 2) colored particles, should have with by above-mentioned 1) the tone color not of the same race of background color of a few species colored particles toning, even perhaps of the same race but be the different color of color depth that can with the naked eye discern degree at least.Particularly by above-mentioned 2) the spot appearance of performance is that the situation of black, white or the spot appearance with dense colour is preferable.Background color is the occasion of black for white or light achromatic color (gray tone etc.), spot appearance, and perhaps background color be that the occasion etc. of the dense colour that light slightly yellowish green tone, blood orange tone etc. are colored, the spot appearance is or xenogenesis of the same race with it is also preferable.
In addition, above-mentioned 2) colored particles possesses with respect to above-mentioned 1) the particle diameter of 2～10 times of colored particles the time, form on the good spot appearance preferable.Particularly preferably be, 1) the medium particle diameter of colored particles be in the occasion of the scope of 10～1000 μ m, 2) colored particles be in the scope of 20～5000 μ m and possess 1) the particle diameter of colored particles more than 2 times.
In addition, to above-mentioned 2) the cooperation ratio of colored particles do not do special qualification, but 1) and 2) all 100 parts of weight of colored particles in, the degree that accounts for 1～30 part of weight is better.
Pattern-free colouring wall material or contain the manufacture method of the pattern-free colouring wall material of spot
Pattern-free colouring wall material or contain the pattern-free colouring wall material of spot is by making on the base material (sheet, plate body etc.) that above-mentioned this corresponding coating material is useful in the wall material.Can adopt known the whole bag of tricks as the method that is suitable for.For example can adopt spraying, roller coating, scraper to be coated with or the mode of flow coat, the method for screen printing adopts then that air dry or temperature are air-dry dryly to wait processing to handle, but the mode that especially preferably sprays.
In addition, above-mentioned make the dry sclerosis of coating material like that after, also painting synthetic resin solution or synthetic resin emulsion form transparent coating thereon, perhaps lamination is made the lucite film.
Have the colouring wall material of pattern or contain the manufacture method of the colouring wall material that has pattern of spot
Having the colouring wall material of pattern or contain the colouring wall material that has pattern of spot, is by making mixing colours separately the above-mentioned coating material of single tone to be applicable to that the base material (sheet, plate body etc.) of wall material is gone up with the pattern that forms regulation more than two kinds.
Concrete usability methods is not done special qualification, can adopt known the whole bag of tricks arbitrarily, for example has to use the bull spray gun, the coating material more than two looks is packed in other jar of branch by separately nozzle application, formed method of patterning through a spray-coating.
In addition, also can use single nozzle spray gun application or with the application of trowel, take this coating material difference application of each color is formed pattern, perhaps after the comprehensive application of coating material with a color, again at the coating material of other color of specific part recoat (the part of recoat is not the pattern of initial color).
In addition, also can shown in Fig. 1 (a), have like that on the finishing die 1 of arbitrary graphic pattern male and fomale(M﹠F), such shown in Fig. 1 (b), the coating material 2 of coating single color is concavo-convex all to cover it, the base material 3 of overlapping sheet again, such shown in Fig. 1 (c) then, with it by extracting counter-rotating on the finishing die 1, such shown in Fig. 1 (d) then, the coating material 4 that is coated with other color after the drying, grinds the layer of coating 4 to cover the concavo-convex all of coating material 2 with suitable method, to expose the protuberance of coating material 2, take this partly to constitute pattern arbitrarily by the color part of coating material 2 and the color of coating material 4.
And after formation had the colouring wall material of pattern, also painting synthetic resin solution or synthetic resin emulsion were to form transparent coating thereon, and perhaps lamination is made the lucite film.
The pattern kind that has on the colouring wall material of pattern does not limit, and the artificial pattern (globule pattern, band pattern etc.) that both can be random pattern also can be the pattern of the natural various rocks of imitation.
Embodiment
The Production Example of the pattern-free colouring wall material of the yellowish green tone of embodiment 1-
Preparation is by 100 parts of weight of acrylic acid ester emulsion (solid state component 50%), 100 parts of weight of water and contain 100 parts of the transparent aqueous complexs that 4 parts of weight of additive of tackifier, anticorrisive agent, activating agent etc. constitute, to wherein adding colored particles for 400 parts, abundant hybrid modulation coating material with weight ratio.
This colored particles, be with medium particle diameter be 100 μ m and size distribution be the silica sand of roughly homogeneous particle diameter of 50～210 μ m as raw material, with thereon in order to ochre as the emulsion coatings of pigment composition be coloured to yellow 2 parts of weight of particle, thereon in order to phthalein blue or green blue as the emulsion coatings of pigment composition be coloured to blue look 1 part of weight of particle, gypsum rubrum is pulverized the medium particle diameter that obtains is that the distribute ratio of 7 parts of weight of cold water sand of being in 50～300 μ m of 260 μ m and material footpath is disperseed to mix and obtained.
Then, the above-mentioned coating material is sprayed on the thickness of 2mm on the flat substrates of polyester nonwoven, carries out application.Solidify 100 ℃ of warm air-dry dry making it of carrying out 20 minutes, manufacture the pattern-free colouring wall material of the yellowish green tone of embodiment 1.
The photo of this pattern-free colouring wall material is shown in Fig. 3, presents the distinct yellowish green tone of dark pattern-free.
The Production Example of the pattern-free colouring wall material of embodiment 2-blood orange tone
Preparation is by 100 parts of weight of acrylic acid ester emulsion (solid state component 50%), 100 parts of weight of water and contain 100 parts of the transparent aqueous complexs that 4 parts of weight of additive of tackifier, anticorrisive agent, activating agent etc. constitute, to wherein adding colored particles for 400 parts with weight ratio, fully hybrid modulation becomes the coating material.
This colored particles is that 100 μ m and size distribution are that the silica sand of the roughly homogeneous particle diameter of 50～210 μ m is that the ratio of 260 μ m and size distribution 3.5 parts of weight of cold water sand of being in 50～300 μ m is disperseed to mix and obtained as raw material, to be coloured to 0.5 part of weight of particle of black, to be coloured to red 3.5 parts of weight of particle, gypsum rubrum is pulverized the medium particle diameter that obtains as the emulsion coatings of pigment composition in order to iron oxide thereon as the emulsion coatings of pigment composition in order to carbon black thereon with medium particle diameter.
Then, the above-mentioned coating material is sprayed to the thickness of 2mm on the flat substrates of polyester nonwoven, carry out application, solidify 100 ℃ of warm air-dry dry making it again, produce the pattern-free colouring wall material of the blood orange tone of embodiment 2 through 20 minutes.
This pattern-free colouring wall material, its photo is shown in Fig. 4, presents distinct dark pattern-free blood orange tone.
The Production Example of the pattern-free colouring wall material of embodiment 3-gray tone
Preparation is by 100 parts of weight of acrylic acid ester emulsion (solid state component 50%), 100 parts of weight of water and contain 100 parts of the transparent aqueous complexs that 4 parts of weight of additive of tackifier, anticorrisive agent, activating agent etc. constitute, to wherein adding colored particles for 400 parts with weight ratio, fully hybrid modulation becomes the coating material.
This colored particles, be with medium particle diameter be 100 μ m and size distribution be the silica sand of roughly homogeneous particle diameter of 50～210 μ m as raw material, being coloured to 1 part of weight of particle of black, being coloured to yellow 0.5 part of weight of particle, gypsum rubrum is ground into medium particle diameter as the emulsion coatings of pigment composition in order to ochre thereon as the emulsion coatings of pigment composition in order to carbon black thereon is that the ratio of 200 μ m and size distribution 8.5 parts of weight of cold water sand of being in 30～300 μ m is disperseed to mix and obtained.
Then, the above-mentioned coating material is sprayed to the thickness of 2mm on the flat substrates of polyester nonwoven, carry out application, solidify, produce the pattern-free colouring wall material of the gray tone of embodiment 3 100 ℃ of warm air-dry dry making it of carrying out 20 minutes.
This pattern-free colouring wall material, its photo is shown in Fig. 5, presents distinct dark pattern-free gray tone.
Embodiment 4-has the Production Example of the colouring wall material of pattern
Respectively the coating material with yellowish green tone of modulation and the occasion same composition of embodiment 1, with the coating material with blood orange tone of the occasion same composition of embodiment 2 and with the coating material with gray tone of the occasion same composition of embodiment 3.
Then, the coating material of these 3 kinds of tones is sprayed to 2mm thickness on the flat substrates of nonwoven of polyester, carry out application, make it to form mutually the pattern of regulation, carry out 20 minutes warm air-dry dry at 100 ℃ again and make it to solidify, the color part that produces the color part of color part, blood orange tone of yellowish green tone and gray tone is mixed mutually and is deposited and form the colouring wall material that has pattern of predetermined pattern.
This has the colouring wall material of pattern, and each above-mentioned color partly presents the single tone of distinct dark yellowish green tone, blood orange tone and gray tone, so each color part is with distinct contrast.
The simple declaration of accompanying drawing
Fig. 1 is the figure of manufacturing process that expression has the colouring wall material of pattern.
Fig. 2 is the figure of embodiment example that expression has the colouring wall material of pattern.
Fig. 3 is the photo that shows the pattern-free colouring wall material of embodiment 1.
Fig. 4 is the photo that shows the pattern-free colouring wall material of embodiment 2.
Fig. 5 is the photo that shows the pattern-free colouring wall material of embodiment 3.
The explanation of symbol
1 finishing die
2,4 coating materials
Claims (11)
1, pattern-free colouring wall material, it is characterized in that, the colored particles of the homogeneous particle diameter and a few species color that possess the particle diameter that is in 10～1000 mu m ranges roughly is fixed in the transparent adhesives with the state that mutual mixing disperses, takes this to show single tone.
2, the pattern-free colouring wall material that contains spot, it is characterized in that, make following 1) and 2) colored particles mix and to be dispersed in the transparent aqueous matrix coating, take this by 1) make by 2 on the background color of the single tone of performance) the sesamoid spot appearance of performance manifested
1) roughly the homogeneous particle diameter and colored particles that possess a few species color of the particle diameter in the scope that is in 10～1000 μ m;
2) possess with respect to above-mentioned 1) 2～10 times of colored particles particle diameter, have with by 1) colored particles of the color that the color of the single tone xenogenesis of performance or concentration of the same race but look are different.
3, the colouring wall material that has pattern, it is characterized in that, it is the colouring wall material that has pattern that forms the pattern that partly constitutes by the color more than two looks, be in constituting each color part of this pattern, the state that the mutual mixing of the colored particles of the homogeneous particle diameter and a few species color that possess the particle diameter that is in 10～1000 mu m ranges is roughly disperseed is fixed in the transparent adhesives, takes this to show single tone.
4, the colouring wall material that has pattern that contains spot, it is characterized in that, make aforesaid right requirement 2 described 1) and 2) colored particles mix and to be dispersed in the transparent aqueous matrix coating, take this by 1) make by 2 on the background color of the single tone of performance) the sesamoid spot appearance of performance manifested, partly constituted pattern by the color more than two looks.
5, claim 1-claim 4 is in each, and the color scheme of the colored particles that above-mentioned mutual mixing disperses is the combination of three primary colors or this three primary colors and the white and/or the black of look.
6, each described pattern-free colouring wall material of claim 1-claim 5 or the colouring wall material that has a pattern are the surface layer materials of stipulating among JIS (Japanese Industrial Standards) A6909.
7, in claim 2 or the claim 4, by above-mentioned 2) performance the spot appearance be the spot appearance of black, white or dense colour.
8, the coating material is characterized in that, makes necessary other cooperate material, make simultaneously homogeneous particle diameter roughly and possess the colored particles that is in a few species color of particle diameter in 10～1000 mu m ranges and mix and be dispersed in the transparent aqueous matrix coating and obtain.
9, the coating material is characterized in that, makes necessary other cooperate material, makes claim 2 described 1 simultaneously) and 2) colored particles mix and be dispersed in the transparent aqueous matrix coating and obtain.
10, the manufacture method of colouring wall material, it is characterized in that, use the described monochromatic color coating material of claim 8 to make claim 1 described pattern-free colouring wall material or make the described colouring wall material that has pattern of claim 3 with the above coating material of described 2 colors of claim 8.
11, the manufacture method of colouring wall material, it is characterized in that, use the described monochromatic color coating material of claim 9 to make the described pattern-free colouring wall material that contains spot of claim 2, or make the described colouring wall material that has pattern that contains spot of claim 4 with the above coating material of described 2 colors of claim 9.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10201317A JP3047291B2 (en) | 1998-06-30 | 1998-06-30 | Patternless colored wall material, its manufacturing method, and spotted colored wall material |
| JP201317/1998 | 1998-06-30 | ||
| JP153593/1999 | 1999-06-01 | ||
| JP15359399A JP3509632B2 (en) | 1999-06-01 | 1999-06-01 | Pattern-attached color wall material, spotted pattern-attached color wall material, and methods for producing them |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1247260A true CN1247260A (en) | 2000-03-15 |
| CN1113000C CN1113000C (en) | 2003-07-02 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99110969 Expired - Fee Related CN1113000C (en) | 1998-06-30 | 1999-06-30 | Colouring wall decorative material with/or without patterns and spots, and prepn. method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1113000C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102259086A (en) * | 2010-05-26 | 2011-11-30 | 四国化研(上海)有限公司 | Surface pattern forming method |
| CN103459471A (en) * | 2011-03-31 | 2013-12-18 | 积水化成品工业株式会社 | Colored resin particle, method for producing same, and use thereof |
| CN113232426A (en) * | 2021-04-21 | 2021-08-10 | 佛山市美嘉陶瓷设备有限公司 | Ink jet machine for multicolor printing and printing method thereof |
-
1999
- 1999-06-30 CN CN 99110969 patent/CN1113000C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102259086A (en) * | 2010-05-26 | 2011-11-30 | 四国化研(上海)有限公司 | Surface pattern forming method |
| CN103459471A (en) * | 2011-03-31 | 2013-12-18 | 积水化成品工业株式会社 | Colored resin particle, method for producing same, and use thereof |
| CN103459471B (en) * | 2011-03-31 | 2016-04-27 | 积水化成品工业株式会社 | Pigmentary resin particle, its manufacture method and uses thereof |
| CN113232426A (en) * | 2021-04-21 | 2021-08-10 | 佛山市美嘉陶瓷设备有限公司 | Ink jet machine for multicolor printing and printing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1113000C (en) | 2003-07-02 |
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