CN1243802C - 溶剂型凹印、柔印特种调金油 - Google Patents
溶剂型凹印、柔印特种调金油 Download PDFInfo
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- CN1243802C CN1243802C CN 03112266 CN03112266A CN1243802C CN 1243802 C CN1243802 C CN 1243802C CN 03112266 CN03112266 CN 03112266 CN 03112266 A CN03112266 A CN 03112266A CN 1243802 C CN1243802 C CN 1243802C
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- 239000002904 solvent Substances 0.000 title claims description 8
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000010931 gold Substances 0.000 claims abstract description 40
- 229910052737 gold Inorganic materials 0.000 claims abstract description 40
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920006026 co-polymeric resin Polymers 0.000 claims abstract description 14
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims abstract description 12
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 11
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 239000000049 pigment Substances 0.000 claims abstract description 9
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 8
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 8
- 239000002966 varnish Substances 0.000 claims abstract description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 6
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 229920006122 polyamide resin Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 239000003960 organic solvent Substances 0.000 abstract description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 abstract 2
- 239000011111 cardboard Substances 0.000 abstract 2
- 235000019439 ethyl acetate Nutrition 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 16
- 229910000906 Bronze Inorganic materials 0.000 description 9
- 239000010974 bronze Substances 0.000 description 9
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 210000000981 epithelium Anatomy 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
本发明涉及一种由具有优质保金效果的树脂、有机溶剂、增塑剂以及颜料预制体溶解混合而成的应用于凹版、柔版印刷中溶剂型金墨调配的特种调金油。它的组份、含量如下：热塑性甲基丙烯酸甲酯/甲基丙烯酸丁酯共聚树脂 10-50%、乙酸乙酯 30-80%、丙二醇甲醚乙酸酯 1-25%、邻苯二甲酸二辛酯 1-15%、颜料预制体 1-10%。
Description
一、技术领域：
本发明属于一种凹版、柔版印刷中所用溶剂型金墨，具体涉及一种溶剂型凹印、柔印特种调金油。
二、背景技术
在所有金墨印刷的场合，以凹印、柔印溶剂型金墨的印刷品金属质感为最好。凹印、柔印溶剂型金墨的制备方法为：将金粉(条、浆)用溶剂浸润后混合于调金油中搅拌均匀而成。为了保证必要的金属质感，使用普通调金油所制得的传统金墨必须维持高的金粉含量，故其印刷品在基材(或承印物)上的附着力极差，因此传统金墨大多只能印刷一些线条和小面积图案，从而使金在印刷品中的表现受到极大限制，大面积的印金、金上再印、金上烫金等工艺很难完成，同时近年来顺应环保要求而设想采用在白卡纸上印金以替代无法回收的金卡纸的方案也无法实施。
三、发明内容
本发明所要解决的技术问题是降低金墨中的金粉含量，解决传统金墨在基材上附着力差的缺陷，但又可确保由其调制的金墨和传统金墨之印刷品的金属质感相当，同时可降低成本，从而使凹印、柔印金墨可以实现大面积(包括整版)印刷、金上再印、金上烫金的工艺以及白卡纸上印金替代金卡纸的环保设计也有了切实的技术支持。
一种溶剂型凹印、柔印特种调金油，它是由下述配比的组份制成的，用量为重量：
热塑性甲基丙烯酸甲酯/甲基丙烯酸丁酯共聚树脂 10-50％
乙酸乙酯 30-80％
丙二醇甲醚乙酸酯 1-25％
邻苯二甲酸二辛酯 1-15％
颜料预制体 1-10％
共聚树脂还可选用如下树脂来代替：热塑性丙烯酸树脂、乙烯/醋酸乙烯共聚树脂、氯乙烯/醋酸乙烯共聚树脂、氯乙烯/乙烯基醚共聚树脂、纤维素及其衍生物类树脂、聚酰胺树脂、聚氨酯树脂、聚乙烯醇树脂、改性松香树脂。有机溶剂选用低沸点的酯、酮、醇、醚、芳香族、醚酯。将树脂和颜料预制体分别用乙酸乙酯、丙二醇甲醚乙酸酯预溶解，加入剩余各组分搅拌均匀，操作过程中的温度不可超过60℃。
通过加入颜料预制体提高金墨的着色力，进而减少金粉的用量，达到附着力的提高，仍维持印刷品金属质感而且与普通金墨印刷品的质量相当。
发明的效果通过对比实验加以说明
金墨A 金墨B 金墨C
普通调金油 60
实施例1 85
实施例2 80ECKART700011金 40 15 20实验结果如下：
其中：印刷机为BOBST820型六色机，印刷基材为230克白卡纸，印刷时各金墨粘相同；
附着力测试样品为直接在基材上整版印金印刷样；
层间附着力测试样品为首先在基材整版印金，之后再在金上整版印透明红的印刷样；
附着力的测试按QB/140000-JH001-2000方法进行，5级最好：油墨皮膜几乎没有剥离；1级最差：油墨皮膜几乎完全剥离。
烫金牢度，良好为图案均匀完整、边缘齐整，差为图案有漏缺、边缘发毛；
模压抗折强度，良好为图案均匀完整、边缘齐整，差为图案有漏缺、边缘发毛。
综上实验可得：本发明和传统调金油相比在金墨印刷中具有：相当的金属质感，在各种基材上优良的附着力及烫金、模压牢度，显著的成本降低优势。
四、具体实施方式
实施例1
热塑性甲基丙烯酸甲酯/甲基丙烯酸丁酯共聚树脂 22％
乙酸乙酯 67％
丙二醇甲醚乙酸酯 5％
邻苯二甲酸二辛酯 2％
颜料预制体 4％
实施例2
热塑性甲基丙烯酸甲酯/甲基丙烯酸丁酯共聚树脂 18％
乙酸乙酯 59％
丙二醇甲醚乙酸酯 10％
邻苯二甲酸二辛酯 12％
颜料预制体 1％
实施例3
热塑性甲基丙烯酸甲酯/甲基丙烯酸丁酯共聚树脂 30％
乙酸乙酯 41％
丙二醇甲醚乙酸酯 15％
邻苯二甲酸二辛酯 6％
颜料预制体 8％
Claims (2)
1、一种溶剂型凹印、柔印特种调金油，其特征是：它是由下述配比的组份制成的，用量为重量：
热塑性甲基丙烯酸甲酯/甲基丙烯酸丁酯共聚树脂 10-50％
乙酸乙酯 30-80％
丙二醇甲醚乙酸酯 1-25％
邻苯二甲酸二辛酯 1-15％
颜料预制体 1-10％
2、根据权利要求书1所述的溶剂型凹印、柔印特种调金油，其特征是：共聚树脂还可选用如下树脂来代替：热塑性丙烯酸树脂、乙烯/醋酸乙烯共聚树脂、氯乙烯/醋酸乙烯共聚树脂、氯乙烯/乙烯基醚共聚树脂、纤维素及其衍生物类树脂、聚酰胺树脂、聚氨酯树脂、聚乙烯醇树脂、改性松香树脂。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 03112266 CN1243802C (zh) | 2003-05-27 | 2003-05-27 | 溶剂型凹印、柔印特种调金油 |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 03112266 CN1243802C (zh) | 2003-05-27 | 2003-05-27 | 溶剂型凹印、柔印特种调金油 |
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| Publication Number | Publication Date |
|---|---|
| CN1482185A CN1482185A (zh) | 2004-03-17 |
| CN1243802C true CN1243802C (zh) | 2006-03-01 |
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| CN 03112266 Expired - Fee Related CN1243802C (zh) | 2003-05-27 | 2003-05-27 | 溶剂型凹印、柔印特种调金油 |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1300269C (zh) * | 2004-09-18 | 2007-02-14 | 王尔健 | 醇溶型凹版纸箱预印罩光油 |
| CN100460473C (zh) * | 2006-01-27 | 2009-02-11 | 杨青青 | 无苯调金油 |
| CN100528985C (zh) * | 2006-08-30 | 2009-08-19 | 西安理工大学 | 复配表面改性剂包覆铜锌粉末配制的金油墨及制备方法 |
| CN102485813A (zh) * | 2010-12-01 | 2012-06-06 | 成都市新津托展油墨有限公司 | 一种醇水性塑料凹版调金油的制备方法 |
| CN102382503A (zh) * | 2011-09-16 | 2012-03-21 | 广西真龙彩印包装有限公司 | 凹印无苯油墨及其制造方法 |
| CN106752360A (zh) * | 2017-01-19 | 2017-05-31 | 长春吉星印务有限责任公司 | 一种特殊溶剂型凹印金墨及其制备方法 |
| CN109440506A (zh) * | 2019-01-12 | 2019-03-08 | 绍兴市正阳家纺有限公司 | 一种烫金工艺 |
-
2003
- 2003-05-27 CN CN 03112266 patent/CN1243802C/zh not_active Expired - Fee Related
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| Publication number | Publication date |
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| CN1482185A (zh) | 2004-03-17 |
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