CN1230503C - 一种厕盆保洁剂 - Google Patents
一种厕盆保洁剂 Download PDFInfo
- Publication number
- CN1230503C CN1230503C CN 00127486 CN00127486A CN1230503C CN 1230503 C CN1230503 C CN 1230503C CN 00127486 CN00127486 CN 00127486 CN 00127486 A CN00127486 A CN 00127486A CN 1230503 C CN1230503 C CN 1230503C
- Authority
- CN
- China
- Prior art keywords
- agent
- acid
- amide
- compound
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 10
- -1 fatty acid salt Chemical class 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 4
- 239000000194 fatty acid Substances 0.000 claims abstract description 4
- 229930195729 fatty acid Natural products 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 9
- 150000001408 amides Chemical class 0.000 claims description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 6
- 238000004090 dissolution Methods 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 230000003750 conditioning effect Effects 0.000 claims description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 239000002304 perfume Substances 0.000 claims description 3
- 239000003352 sequestering agent Substances 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- ANBZTKMYPDMODS-YPKPFQOOSA-N (z)-n,n-diethyloctadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CC)CC ANBZTKMYPDMODS-YPKPFQOOSA-N 0.000 claims description 2
- RZEWIYUUNKCGKA-UHFFFAOYSA-N 2-(2-hydroxyethylamino)ethanol;octadecanoic acid Chemical compound OCCNCCO.CCCCCCCCCCCCCCCCCC(O)=O RZEWIYUUNKCGKA-UHFFFAOYSA-N 0.000 claims description 2
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 2
- 244000060011 Cocos nucifera Species 0.000 claims description 2
- 239000005639 Lauric acid Substances 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 235000021360 Myristic acid Nutrition 0.000 claims description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims description 2
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 claims description 2
- OTGQIQQTPXJQRG-UHFFFAOYSA-N N-(octadecanoyl)ethanolamine Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCO OTGQIQQTPXJQRG-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 150000002193 fatty amides Chemical class 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N isopropyl alcohol Natural products CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 23
- 238000000034 method Methods 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 230000001954 sterilising effect Effects 0.000 abstract description 6
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 6
- 238000001125 extrusion Methods 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract description 4
- 239000004094 surface-active agent Substances 0.000 abstract 3
- 229910019142 PO4 Inorganic materials 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 2
- 239000010452 phosphate Substances 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 239000002738 chelating agent Substances 0.000 abstract 1
- 230000001276 controlling effect Effects 0.000 abstract 1
- 238000004332 deodorization Methods 0.000 abstract 1
- 239000000645 desinfectant Substances 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 14
- 230000002262 irrigation Effects 0.000 description 5
- 238000003973 irrigation Methods 0.000 description 5
- 230000001877 deodorizing effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- DTGKSKDOIYIVQL-MRTMQBJTSA-N (-)-isoborneol Chemical compound C1C[C@@]2(C)[C@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-MRTMQBJTSA-N 0.000 description 1
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229940125810 compound 20 Drugs 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- JAXFJECJQZDFJS-XHEPKHHKSA-N gtpl8555 Chemical compound OC(=O)C[C@H](N)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](C(C)C)C(=O)N1CCC[C@@H]1C(=O)N[C@H](B1O[C@@]2(C)[C@H]3C[C@H](C3(C)C)C[C@H]2O1)CCC1=CC=C(F)C=C1 JAXFJECJQZDFJS-XHEPKHHKSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
本发明涉及化工产品领域尤其是一种厕盆保洁剂，其特征在于采用挤压工艺生产，选用含有强去污能力的表面活性剂、螯合剂、显示剂、填充剂、杀菌剂、芳香剂、粘合剂的混合物中再加入大于0至小于或等于50%的脂肪酸盐类、大于0至小于或等于40%的烷基醇酰胺类表面活性剂和大于0至小于或等于30%的一种或多种较低环氧乙烷数的聚氧乙烯类非离子表面活性剂混合物作为溶解速度调节剂，使几种物质混合产生较好的协同作用，很好的控制本发明产品的溶解速度。该产品中不含磷酸盐，避免了磷酸盐对生态环境存在的潜在危害性，有利于生态环境的保护。本发明产品具有制造方法简单、去污力强、溶解速度均匀、使用时间长、浸入水中不塌陷、不变形，能自动粘附于水箱底部，并且具有防垢、除臭、杀菌、清洗一次完成的作用。
Description
本发明涉及日用化学产品的生产领域，尤其是一种日用化学保洁剂即厕盆专用保洁剂。
在国内外，专用于抽水马桶的清洁剂目前市场上有多种，可分为二大类，一类是去垢型洁厕剂，如洁厕粉、洁厕液等，它们直接作用于污垢上，对污垢起去除的作用。由于抽水马桶内污垢吸附顽固，化学成分特殊，故这类清洁剂一般都做成强酸性，但强酸对陶瓷表面腐蚀性强，易破坏瓷表面及下水管，且使用时对人体很不安全，又不能经常对厕盆进行清洗、消毒，为此国外许多公司，如Jeyes group LTD、Henkel、Kiwi Brourds Inc等研究出另一类固态自动冲洗剂，它可每次使用后自动对抽水马桶进行冲洗，可防污垢沉积，且具有清洁、除臭、杀菌、消毒等多种功能，可直接放入水箱内，使用时间长达一个月或更久。这类产品也有三种形式，一种为将固体冲洗剂装入瓶中，通过丝线挂于水箱内使用，另一种将固体冲洗剂装在空心篮中挂于厕盆边使用，第三种则是直接投入水箱内使用。但前两种产品不但使用后废弃物增加，成本上升，而且使用也不方便，而市场上有的第三种形式的产品存在冲洗剂性能不稳定，如冲洗剂溶解速度太快或完全不溶解，产品浸入水中后塌陷变形，块状物在使用过程中位置移动、浮起，被冲洗水冲走以及外表较软、生产运输不便、易于变形等缺点。
本发明的目的是提供一种将块状保洁剂直接浸入水箱中，在较长时间内在水中能均匀释放，将其所含的有效物溶于水中，对厕盆及水箱等起到清洁、杀菌、除臭一次完成的一种厕盆保洁剂及其制造方法。
本发明的技术方案是：以表面活性剂如脂肪醇聚氧乙烯醚(9EO)、烷基酚聚氧乙烯醚(10EO)、脂肪醇聚氧乙烯醚硫酸钠、十二烷基苯磺酸钠、十二烷基硫酸钠、烷基磺酸钠、烷醇酰胺、烯基磺酸盐、脂肪酸甲酯磺酸盐等为主要去污剂，再加入螯合剂、显示剂、填充剂、杀菌剂、芳香剂、粘合剂等原料，在采用挤压工艺生产过程中，在上述混合物中再添加如下重量百分比组分的溶解速度调节剂：
a、脂肪酸盐类不大于50％，其分子式为R-COOM，R是碳原子数为8-24的烷基，M可以是钾、钠、钙、镁、铝、锌金属盐或三乙醇胺盐；
b、烷基醇酰胺类表面活性剂不大于40％，其选自椰子油酸二乙醇酰胺，椰子油酸甲脂二乙醇酰胺，椰子油酸单乙醇酰胺，月桂酸单异丙醇酰胺，硬脂酸二乙醇酰胺，硬脂酸甲脂二乙醇酰胺，硬脂酸单乙醇酰胺，油酸二乙醇酰胺，油酸甲脂二乙醇酰胺，或豆蔻酸单乙醇酰胺等；
c.一种或多种较低环氧乙烷数的聚氧乙烯类非离子表面活性剂混合物，不大于30％，其选自脂肪胺聚氧乙烯化合物，脂肪酰胺聚氧乙烯化合物，脂肪酸聚氧乙烯化合物，脂肪醇聚氧乙烯化合物，烷基酚聚氧乙烯化合物或聚氧乙烯聚氧丙烯嵌段聚合物，其烷基含8-24个碳原子，环氧乙烷数可为1-6Mol。
由以上组分混合制造的产品中不含磷酸盐，因而避免了磷酸盐对生态环境存在的潜在危害，有利于生态环境的保护。
本技术方案的产品采用以下方法进行生产：将上述组分材料混合均匀后，进行碾磨，再送入普通的螺旋式挤压机进行挤压成型，再进行切割即可包装出厂。
由于本发明产品中采用了上述表面活性剂、螯合剂、显示剂、填充剂、杀菌剂、芳香剂、粘合剂及溶解速度调节剂等材料，使本发明产品可以直接投入水箱中，在溶解速度调节剂的作用下，使本品能缓慢均匀溶解于水中，通过观察显示剂的颜色变化，判断该物是否可以继续使用，由于本发明产品直接投入水箱使用，使有效物质溶于水中，使冲水清洗、杀菌、除臭一次完成，起到保持抽水马桶清洁的作用，同时散发清香，净化空气，使冲洗水呈有色，对卫生间环境起到美化的作用。此外，由于采用挤压成型工艺，使本发明产品的生产速度快，可以通过流水线进行生产，取代了传统的采用铸模、压模生产工艺，省却了加热、脱模等过程，因挤压工艺使本发明产品可做成不同的形状，产品表面光滑、均匀、内部结构紧密，且外表较硬，便于运输包装。
下面阐述本发明最佳实施例：配方实施例：
脂肪酸三乙醇胺 25％
硬脂酸甲酯二乙醇酰胺 12％
2EO的脂肪酸聚氧乙烯化合物 20％
异龙脑 5％
十二烷基硫酸钠 14％
芒硝 17％
EDTA二钠 0.5％
蓝色染料 5％
香精 1.5％
将上述九种成份按比例混合，碾磨，送入压条机挤压成条，然后切块，包装即可。
Claims (1)
1.一种厕盆保洁剂，包括表面活性剂、螯合剂、显示剂、填充剂、杀菌剂、芳香剂、粘合剂，其特征在于在上述混合物中再添加如下重量百分比组份的溶解速度调节剂：
a、脂肪酸盐类大于0至小于50％，其分子式为R-COOM，R是碳原子数为8-24的烷基，M可以是钾、钠、钙、镁、铝、锌金属盐或三乙醇胺盐；
b、烷基醇酰胺类表面活性剂大于0至小于40％，其选自椰子油酸二乙醇酰胺，椰子油酸甲脂二乙醇酰胺，椰子油酸单乙醇酰胺，月桂酸单异丙醇酰胺，硬脂酸二乙醇酰胺，硬脂酸甲脂二乙醇酰胺，硬脂酸单乙醇酰胺，油酸二乙醇酰胺，油酸甲脂二乙醇酰胺或豆蔻酸单乙醇酰胺；
c、一种或多种较低环氧乙烷数的聚氧乙烯类非离子表面活性剂混合物，大于0至小于30％，其选自脂肪胺聚氧乙烯化合物，脂肪酰胺聚氧乙烯化合物，脂肪酸聚氧乙烯化合物，脂肪醇聚氧乙烯化合物，烷基酚聚氧乙烯化合物或聚氧乙烯聚氧丙烯嵌段聚合物，其烷基含8-24个碳原子，环氧乙烷数为1-6Mol。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00127486 CN1230503C (zh) | 2000-11-22 | 2000-11-22 | 一种厕盆保洁剂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00127486 CN1230503C (zh) | 2000-11-22 | 2000-11-22 | 一种厕盆保洁剂 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1354241A CN1354241A (zh) | 2002-06-19 |
| CN1230503C true CN1230503C (zh) | 2005-12-07 |
Family
ID=4592501
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00127486 Expired - Lifetime CN1230503C (zh) | 2000-11-22 | 2000-11-22 | 一种厕盆保洁剂 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1230503C (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101239194B (zh) * | 2008-03-17 | 2012-11-28 | 张博 | 厕所除臭杀菌泡沫液 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| UA97967C2 (ru) * | 2006-11-16 | 2012-04-10 | Юнилевер Н.В. | Клеящийся блок чистки для твердых поверхностей и способы его применения |
| CN102051274B (zh) * | 2009-11-10 | 2012-12-05 | 上海卫安生物科技有限公司 | 一种固体节水洁厕剂 |
| WO2012148005A1 (ja) * | 2011-04-28 | 2012-11-01 | 上野製薬株式会社 | 殺菌剤組成物および殺菌洗浄剤組成物 |
| CN105505623A (zh) * | 2016-01-12 | 2016-04-20 | 洛阳和梦科技有限公司 | 环保杀菌型洁厕剂 |
| CN106753861A (zh) * | 2016-11-24 | 2017-05-31 | 嘉兴德扬生物科技有限公司 | 一种抑菌留香的马桶清洁剂及其制备方法 |
| CN107338136A (zh) * | 2017-05-26 | 2017-11-10 | 安徽肤彩生物科技有限公司 | 一种天然植物制洁厕剂 |
| CN107158917A (zh) * | 2017-07-06 | 2017-09-15 | 梁山菱花生物科技有限公司 | 一种用于发酵车间除臭的方法 |
-
2000
- 2000-11-22 CN CN 00127486 patent/CN1230503C/zh not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101239194B (zh) * | 2008-03-17 | 2012-11-28 | 张博 | 厕所除臭杀菌泡沫液 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1354241A (zh) | 2002-06-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9926519B2 (en) | Self-adhesive detergent compositions with color-changing systems | |
| US8247362B2 (en) | Light duty liquid cleaning compositions and methods of manufacture and use thereof | |
| US7196046B2 (en) | Hard surface cleaner comprising a suspension of alginate beads | |
| CA2227803C (en) | Toilet bowl detergent system | |
| JP2622949B2 (ja) | 便器用清浄剤 | |
| BRPI1012851A2 (pt) | blocos limpadores de vaso sanitário esféricos, método para a sua produção, e portador de limpeza compreendendo blocos limpadores de vaso sanitário esféricos | |
| US7119055B2 (en) | Hard surface cleaners comprising a thickening gum mixture | |
| KR20130119446A (ko) | 음이온 계면활성제 유래의 구형 변기 블록 | |
| CA2726517A1 (en) | Light duty liquid cleaning compositions and methods of manufacture and use thereof | |
| GB2398571A (en) | Acidic hard surface cleaning and/or disinfecting composition | |
| CA2726639A1 (en) | Light duty liquid cleaning compositions and methods of manufacture and use thereof | |
| US7291586B2 (en) | Hard surface cleaning compositions comprising suspended alginate inclusions | |
| CN105339565A (zh) | 用于将活性成分制剂分配到抽水马桶便池中的装置 | |
| CN101463293A (zh) | 一种加香的粘稠型酸性厕盆清洁剂 | |
| CN103305353A (zh) | 一种含有蠕虫状胶束微观结构的厨房重垢油污清洁剂及其制备方法 | |
| WO1996021721A1 (en) | Concentrated, aqueous, surfactant-containing compositions | |
| CN1230503C (zh) | 一种厕盆保洁剂 | |
| CN114250120A (zh) | 衣物杀菌清洁剂和衣物杀菌清洁慕斯及制备方法 | |
| CA2228758C (en) | Acidic cleaning compositions | |
| CN1138628A (zh) | 卫生间用固体清洁块 | |
| CN1077596C (zh) | 块状抽水马桶自动冲洗剂及制造方法 | |
| US3925228A (en) | Carbonate built detergents | |
| AU9411998A (en) | Detergents, cleaning compositions and disinfectants comprising chlorine-active substances and fattyacid alkyl ester ethoxylates | |
| EP1781765B1 (de) | Verwendung eines reinigers mit fäkalschmutz-abweisenden eigenschaften | |
| EP3399011B1 (en) | Compositions suitable for lavatory cleaning comprising non-hydraulic binders |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address |
Address after: 200231 No. 1800, Wu Long Road, Shanghai, Xuhui District Patentee after: Shanghai Whitecat Shareholding Co., Ltd. Address before: 200000 No. 1800 Wu Long Road, Shanghai Patentee before: Shanghai White Cat Co., Ltd. |
|
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20051207 |