CN1228918A - Diethofencarb and chlorothalonil compound agent - Google Patents
Diethofencarb and chlorothalonil compound agent Download PDFInfo
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- CN1228918A CN1228918A CN 98121719 CN98121719A CN1228918A CN 1228918 A CN1228918 A CN 1228918A CN 98121719 CN98121719 CN 98121719 CN 98121719 A CN98121719 A CN 98121719A CN 1228918 A CN1228918 A CN 1228918A
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Abstract
A mixture of diethofercarb and chlorothalonil, as an agricultural chemical, in the form of smoking agent, wettable powder, particles and powder for treating the gray mold of vegetables such as tomato with high effect and no toxic damage features that the weight ratio of diethofencarb and chlorothalonil in the mixture is 1-85% and the weight ratio of diethofencarb to chlorothalonil is (1-10) : (1-10).
Description
The invention belongs to technical field of pesticide, mould prestige of particularly a kind of second and chlorothalonil compound agent.
Eliminating vegetable botrytis is one of important disease that influences yield of vegetables, and the chemical control of relevant gray mold is subjected to domestic and international agricultural chemicals circle attention always.From latter stage in the sixties is that to succeed in developing middle nineteen seventies be that the dicarboximide fungicide of representative is succeeded in developing with the Sukeling for the benzimidazole germicide of representative with the carbendazim, improve gray mold greatly and prevented and treated level, but these bactericide pathogen after use has all produced pesticide resistance to some extent, thereby its control efficiency to gray mold is obviously weakened.
The object of the present invention is to provide a kind of mould prestige of second and the chlorothalonil compound agent that can effectively prevent and treat diseases such as eliminating vegetable botrytis, its further purpose is to provide a kind of mould prestige of second and the chlorothalonil compound wetting powder that can effectively prevent and treat diseases such as eliminating vegetable botrytis.
For reaching above-mentioned purpose, the present invention adopts following technical scheme: mould prestige of second and chlorothalonil compound agent, contain mould prestige of the second that accounts for gross weight 1-85% and tpn, and mould prestige of second and tpn weight ratio are 1-10: 1-10.
The mould prestige of second: tpn=1: 1-5.
This composite dose is fumicants, contains mould prestige of the second that accounts for gross weight 1-40% and tpn, also contains oxidant, combustion adjuvant, cooling agent and stabilizing agent.
Oxidant is nitrate such as ammonium nitrate, accounts for gross weight 10-35%; Combustion adjuvant is a wood powder etc., accounts for gross weight 10-35%; Stabilizing agent is an ammonium chloride etc., accounts for gross weight 1-8%; Cooling agent is potter's clay, land plaster etc., the polishing surplus.
This composite dose is dust agent, contains mould prestige of the second that accounts for gross weight 1-10% and tpn, also contains fillers such as potter's clay, the polishing surplus.
This composite dose is wetting powder, contains mould prestige of the second that accounts for gross weight 10-75% and tpn, also contains wetting agent, dispersant and filler.
Wetting agent is a neopelex, and dispersant is lignosulfonates, and the two accounts for the 5-20% of gross weight; Filler is a precipitated calcium carbonate, the polishing surplus.
This composite dose is granule, contains mould prestige of the second that accounts for gross weight 1-5% and tpn, also contains binding agent and carrier.
Binding agent is paraffin, polyvinyl alcohol etc., accounts for gross weight 1-5%; Carrier is sand, cinder etc., the polishing surplus.
Wherein the mould prestige ISO adopted name of second is diethofencarb, and chemical name is 3,4-diethoxy phenyl amido isopropyl formate, and structural formula is:
Empirical formula C
14H
21NO
4, 100.3 ℃ of fusing points, 25 ℃ of vapour pressures 1.46 * 10
-2Pa, the biological property sterilization; Tpn ISO general term chlorothalonil, chemical name 2,4,5,6-tetrachloro-1,3-dinitrile benzene, structural formula
Empirical formula C
8Cl
4N
2, fusing point 250-251 ℃, 25 ℃ of vapour pressures 5.72 * 10
-7Pa, the biological property sterilization.
Product preparation method of the present invention is that agricultural chemicals prepares universal method, wherein mould prestige of second and tpn wetting powder preparation method are: open mixer, successively former medicine, auxiliary agent (comprising wetting agent and dispersant), filler being added mixer fully mixes, open airslide disintegrating mill, the said mixture material is pulverized; Pack and get final product.
The present invention is mainly used in eliminating vegetable botrytis such as control tomato, when its wetting powder uses, earlier medicament is poured in the sprayer, converts water then to stir, and the blade face evenly sprays.Using dosage is by 500-700 times of former medicine 10-20 gram/mu dilution, and dispenser in 7-10 days once.This product should be avoided and skin and eye contact, cleans as contacting immediately; Should be stored in shady and cool dry place, keep fire away, thermal source; Must not mix with food, feed and put.
The mould prestige of contained second belongs to systemic fungicide in the product of the present invention, and tpn belongs to the broad spectrum type protective fungicide, and the two composite use has obvious control efficiency to diseases such as eliminating vegetable botrytis.
Utilizing built wettable powder of the present invention to carry out the graw mold of tomato field control effectiveness test shows, mould prestige of 20% second and chlorothalonil compound wetting powder control graw mold of tomato, press mu dose dilution 500-700 doubly in morbidity phase beginning, spray in 7 days once at interval, connect and spray 3 times, preventive effect reaches 95.53%, and control obviously;
Adopt the former medicine of the mould prestige of 80% second (Xinyi insecticide factory product), the former medicine of 92% tpn (produce in favorable to the people chemical plant, Xinyi) and the present invention's 20% wetting powder to botrytis cinerea---Botrytis cinerea bacterium (cultivate at Shenyang Chemical Engineering Inst pesticide bioassay center) carries out the toxicity test test.Mould prestige of second and tpn are respectively 1.225mg/L, 13.266mg/L to the EC50 of Botrytis cinerea bacterium, and the former the antibacterial latter of being higher than is described.Wetting powder co-toxicity coefficient of the present invention is up to 246.76, and illustrating that two medicines are composite has a remarkable synergistic effect.
According to GB-15670-1995 " agriculture chemical registration toxicology test method " be: acute oral toxicity, male, female rats LD to the The acute toxicity tests of the present invention's 20% wetting powder
50(median lethal dose, down together)>4640mg/kg; Acute dermal toxicity, male, female rats LD
50>2150mg/kg; Acute skin irritation test, slight excitant; Eye stimulates, mild to moderate excitant.Unite acute toxicity evaluation criterion in " the chemistry security toxicological evaluation program " of promulgation by the Ministry of Public Health, the Ministry of Agriculture, belong to the lower toxicity agricultural chemicals.
Adopt the mould prestige content of second lower and prescription that tpn content is higher both can satisfy the preventive effect requirement among composite dose of the present invention, can reduce cost again, economical and practical.
Embodiment 1,2, and 3 is mould prestige of second and chlorothalonil compound fumicants, and prescription sees Table 1.Method for making is: with NH
4NO
3, potter's clay is crushed to by 100 mesh standard sieves with cracker respectively; Get above-mentioned material of formula ratio and wood powder and former medicine, pulverize again after thick the mixing, go into the abundant mixing of mixer then; The above-mentioned material forming machine hopper of packing into, open the tablet press machine compressing tablet packing fumicants that gets product.
Embodiment 4,5, and 6 is mould prestige of second and chlorothalonil compound wetting powder, and prescription sees Table 2.Method for making is: open mixer, add former medicine, neopelex, sodium lignin sulfonate, precipitated calcium carbonate successively, fully mix (20-30 minute) to even; To mix the back material pulverizes; Pack and get final product.
Embodiment 7,8, and 9 is mould prestige of second and chlorothalonil compound granule, and prescription sees Table 3.Method for making is: carrier is made 20-60 order particle, more former medicine is poured into and added the abundant mixing of adhesive packing and get final product.
Claims (9)
1, mould prestige of second and chlorothalonil compound agent, the present invention is characterised in that, contains mould prestige of the second that accounts for gross weight 1-85% and tpn, mould prestige of second and tpn weight ratio are 1-10: 1-10.
2, composite dose as claimed in claim 1, it is characterized in that the mould prestige of second: tpn=1: 1-5.
3, composite dose as claimed in claim 1 or 2, it is characterized in that this composite dose is fumicants, contain mould prestige of the second that accounts for gross weight 1-40% and tpn, also contain oxidant, combustion adjuvant, cooling agent and stabilizing agent.
4, composite dose as claimed in claim 4, it is characterized in that oxidant is nitrate such as ammonium nitrate, accounts for gross weight 10-35%; Combustion adjuvant is a wood powder etc., accounts for gross weight 10-35%; Stabilizing agent is an ammonium chloride etc., accounts for gross weight 1-8%; Cooling agent is potter's clay, land plaster etc., the polishing surplus.
5, composite dose as claimed in claim 1 or 2, it is characterized in that this composite dose is dust agent, contain mould prestige of the second that accounts for gross weight 1-10% and tpn, also contain fillers such as potter's clay, the polishing surplus.
6, composite as claimed in claim 1 or 2 dose, it is characterized in that this composite dose is wetting powder, contain mould prestige of the second that accounts for gross weight 10-75% and tpn, also contain wetting agent, dispersant and filler.
7, composite dose as claimed in claim 6, it is characterized in that wetting agent is a neopelex, dispersant is lignosulfonates, the two accounts for the 5-20% of gross weight; Filler is a precipitated calcium carbonate, the polishing surplus.
8, composite dose as claimed in claim 1 or 2, it is characterized in that this composite dose is granule, contain mould prestige of the second that accounts for gross weight 1-5% and tpn, also contain binding agent and carrier.
9, composite dose as claimed in claim 8, it is characterized in that binding agent is paraffin, polyvinyl alcohol etc., accounts for gross weight 1-5%; Carrier is sand, cinder etc., the polishing surplus.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB981217192A CN1171531C (en) | 1998-12-16 | 1998-12-16 | Diethofencarb and chlorothalonil compound agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB981217192A CN1171531C (en) | 1998-12-16 | 1998-12-16 | Diethofencarb and chlorothalonil compound agent |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1228918A true CN1228918A (en) | 1999-09-22 |
CN1171531C CN1171531C (en) | 2004-10-20 |
Family
ID=5227274
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB981217192A Expired - Fee Related CN1171531C (en) | 1998-12-16 | 1998-12-16 | Diethofencarb and chlorothalonil compound agent |
Country Status (1)
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CN (1) | CN1171531C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100376157C (en) * | 2005-09-15 | 2008-03-26 | 南京第一农药有限公司 | Germicide composition containing kresoxim-methyl and chlorothalonil and its application |
CN101755800A (en) * | 2009-11-23 | 2010-06-30 | 陈章艳 | Bactericide composition containing iprovalicarb |
-
1998
- 1998-12-16 CN CNB981217192A patent/CN1171531C/en not_active Expired - Fee Related
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100376157C (en) * | 2005-09-15 | 2008-03-26 | 南京第一农药有限公司 | Germicide composition containing kresoxim-methyl and chlorothalonil and its application |
CN101755800A (en) * | 2009-11-23 | 2010-06-30 | 陈章艳 | Bactericide composition containing iprovalicarb |
CN101755800B (en) * | 2009-11-23 | 2013-01-09 | 福建新农大正生物工程有限公司 | Bactericide composition containing iprovalicarb |
Also Published As
Publication number | Publication date |
---|---|
CN1171531C (en) | 2004-10-20 |
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