CN1215063A - 聚氨酯泡沫塑料 - Google Patents
聚氨酯泡沫塑料 Download PDFInfo
- Publication number
- CN1215063A CN1215063A CN98114782A CN98114782A CN1215063A CN 1215063 A CN1215063 A CN 1215063A CN 98114782 A CN98114782 A CN 98114782A CN 98114782 A CN98114782 A CN 98114782A CN 1215063 A CN1215063 A CN 1215063A
- Authority
- CN
- China
- Prior art keywords
- weight
- ethylene oxide
- prepolymer
- polyvalent alcohol
- average
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/409—Dispersions of polymers of C08G in organic compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2350/00—Acoustic or vibration damping material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S521/914—Polyurethane cellular product formed from a polyol which has been derived from at least two 1,2 epoxides as reactants
Abstract
在发泡剂存在下,将4,4′-MDI含量较多的聚异氰酸酯与EO含量较高的多元醇反应以制备软泡沫塑料的方法。
Description
将有机聚异氰酸酯如甲本二异氰酸酯(TDI)或二苯基甲烷二异氰酸酯(MDI)与聚醚多元醇以及发泡剂一起反应制备聚氨酯软泡沫塑料的方法已相当成熟。聚醚通常是由氧化丙烯得出的聚氧化丙烯多元醇或是由氧化丙烯和氧化乙烯的各种组合得出的聚(氧化丙烯一氧化乙烯)多元醇。氧化乙烯封端的聚氧化丙烯多元醇类中,氧化烯基只占总氧化烯残余物的极小部分,由于它们对异氰酸酯有较高的反应性,从而特别重要。
氧化乙烯含量较高的多元醇,例如含50%(重量)或更多氧化己烯的多元醇通常作为微量添加物使用,以确保泡沫塑料具有开孔结构。不能将非常高浓度的上述聚醚与通常的异氰酸酯共同使用,这是因为那样便不产生开孔效应,而导致闭孔泡沫塑料。
现在发现,如果采用基本上纯的4,4′-MDI或其衍生物作为聚异氰酸酯,便可从含高浓度具有高氧化乙烯含量的多元醇的配方成功地制得具有有价值性能的软泡沫塑料。
因而,本发明提供一种制备软聚氨酯泡沫塑料的方法,即,在发泡剂存在下,将聚异氰酸酯与多元醇组合物反应。该聚异氰酸酯含至少85重量%,含至少90重量%较好,含至少95重量%更好的4,4′-二苯基甲烷或其变体。该多元醇组合物包含至少一种聚(氧化乙烯-氧化烯)多元醇,其平均标称羟基官能度为2-6,平均羟基当量为1000-3000,平均氧化乙烯含量为50-85,最好为60-85重量%,任何还可加入的多元醇中氧化乙烯含量最好为500当量或者至少占50重量%。
本发明方法所用的聚异氰酸酯组分可主要包含纯4,4′-二苯基甲烷二异氰酸酯或二异氰酸酯与一种或多种其它有机聚异氰酸酯尤其是其它二苯基甲烷二异氰酸酯异构体(例如2,4′-异构体,还可含2,2′-异构体)的混合物。该聚异氰酸酯组分也可以是由含有至少85重量%,4,4′-二苯基甲烷二异氰酸酯的聚异氰酸酯组合物衍生而来的MDI变体。MDI变体是本领域公知的,就本发明用途而言,尤其包括通过将uretonimine和/或碳化二亚胺基团引入上述聚异氰酸酯组合物和/或将该组合物与一种或多种多元醇反应得到的液体产物。
多元醇组合物可包含具有所需官能度、当量和氧化乙烯含量的单一聚氧化烯多元醇,最好是聚(氧化乙烯-氧化丙烯)多元醇,这样的多元醇是本领域公知的,可用常规方法制得,即,同时和/或以任何顺序将氧化乙烯和氧化丙烯与引发剂反应。所述引发剂的例子有:水、多元醇、多元胺和其它具有2至6个活性氢原子的物质。
或者,多元酯组合物可包含两种或多种聚氧化烯多元醇的混合物,使得总组成具有所需的平均官能度、当量和氧化乙烯含量。该混合物中的聚氧化烯多元醇最好是聚(氧化乙烯-氧化丙烯)多元醇,但还可以有一种或多种聚氧化乙烯多元醇和/或聚氧化丙烯多元醇。
优选的多元醇组合物包括:
(a)85-100重量%的含氧化乙烯残基的聚氧化烯多元醇,所述多元醇组分的平均标称羟基官能度为2-6,平均羟基当量为1000-3000且平均氧化乙烯含量为50-85重量%,和
(b)15-0重量%的一种或多种其它多元醇。
多元醇(b)以平均官能度为2-6,平均当量为1000-3000为宜,例如,可以是聚氧化丙烯多元醇、聚氧化乙烯多元醇或含有50重量%以下或85重量%以上氧化乙烯残基的聚(氧化乙烯-氧化丙烯)多元醇。
具有500或更高当量的各多元醇最好含至少50重量%的氧化乙烯。此混合物中的聚氧化烯最好是聚(氧化乙烯-氧化丙烯)多元醇,但还可以含有一种或多种聚氧化乙烯多元醇。
此处“平均标称羟基官能度”是指在假设聚氧化烯多元醇的平均官能度与制备过程中所用的引发剂的平均官能度(每个分子中活性氢的数目)相同--尽管实际上由于终端不饱和常常较少——的条件下,多元醇组合物的平均官能度(每个分子中羟基的数目)。多元醇组合物的平均标称羟基官能度最好为2-4,最优选的聚氧化烯多元醇是三元醇。
必要时,聚氧化烯多元醇(或当使用其混合物时,一种或多种聚氧化烯多元醇)可含有分散的聚合物颗粒。这样的聚合物改性多元醇在先有技术中已有详尽描述,它还包括在聚氧化烯多元醇中,一种或多种乙烯基单体(例如乙腈和苯乙烯)原位聚合得到的产物,或在聚氧化烯多元醇中,聚异氰酸酯与氨基或羟基官能化合物(例如:三乙胺)原位反应得到的产物。
本发明方法优选的发泡剂是水,还可同时使用物理发泡剂,例如低沸点有机氟化合物。发泡剂的用量可按已知的方式变化,以达到预期的泡沫密度,例如:水的适当用量以多元醇组合物重量为基准计是0.25-20重量%,优选0.25-8重量%,最佳是0.25重量%至5重量%以下。最好只用水作发泡剂。考虑到多元醇组合物、水和任何其它异氰酸酯反应性物质(例如:链扩展剂或交联剂),反应体系的异氨酸酯指数可低至10或高至120。
发泡反应混合物可包含一种或多种该反应混合物常用的添加剂。所述添加剂包括催化剂,例如叔胺和锡化合物;表面活性剂和泡沫稳定剂,例如硅氧烷一氧化烯共聚物;链扩展剂,例如低分子量二元醇或二元胺;交联剂,例如三乙醇胺;阻燃剂;有机和无机填料;颜料;抑制所谓沸腾发泡效应(boiling-foam effect)的物质,例如聚二甲基硅氧烷;和内部脱模剂。
从而,在又一方面,本发明提供的反应体系包括:
(ⅰ)一种含至少85重量%4,4′-二苯基甲烷或其变体的聚异氰酸酯;
(ⅱ)一种多元醇组合物,它包含至少一种含氧化乙烯残基的聚氧化烯多元醇,该多元醇组合物的平均标称羟基官能度为2-6,平均羟基当量为1000-3000,且平均氧化乙烯含量为50-85重量%,多元醇组合物中,当量为500或更高的各多元醇的氧化乙烯含量最好为至少50重量%;
(ⅲ)一种发泡剂,包括水,和可选的
(ⅳ)一种或多种泡沫塑料配方中常用的添加剂。这样的反应体系最好用于制造软泡沫塑料。术语“反应体系”定义为这样的一种体系,其中聚异氰酸酯组分装在一容器中,与异氰酸酯反应性组分分开。
在实施本发明方法时,可采用公知的一步法、半预聚体工艺或全预聚体工艺,同时采用常用的混合设备,泡沫塑料可制成块料或模塑等形式。由上述聚异氰酸酯(过量)和多元醇的反应产物、NCO值为5-50重量%的预聚体地构成了本发明的一部分。所述预聚体的制备是本领域公知的。
本发明方法制得的泡沫塑料具有有价值的能量吸收性质,从而可用于声音振动阻尼以及用作底座。
本发明用下列实施例说明,但并不局限于此。其中全部份数、百分数和比率均以重量计。
下列术语表用来说明实施例中未说明的反应组分。
术语表
A2580是Arcol 2580,一种具有无规氧化乙烯和氧化丙烯残基且氧化乙烯含量为77%的聚醚三元醇,其分子量为4000,可从Arco购得。Arcol是Arco的商标。
Dabco EG是Dabco在乙二醇中的33%溶液,可从Air Products获得。Dabco是Air Products的商标。
Dabco 33LV是从Air Products获得的催化剂。
D80/20是Dabco和二甲基乙醇胺的20/80混合物。
Daltolac C4多元醇是分子量为170的聚氧化丙烯三元醇,可由Imperial Chemical Industries PLC购得。Daltolac是ICI PLC的商标。
Suprasec VM021聚异氰酸酯是NCO含量为23%的4,4′-MDI低官能度变体,可从Imperial Chemical Industries PLC.购得。Suprasec是ICI PLC的商标。
Suprasec VM022聚异氰酸酯是NCO含量为23%的4,4′-MDI低官能度变体,可从Imperial Chemical Industries PLC购得。
Suprasec MPR聚异氰酸酯是纯4,4′-MDI,可以Imperial ChemicalIndustries PLC购得。
Suprasec VM20聚异氰酸酯是uretonimine改性的、NCO含量为29.3%的4,4′-MDI,可从Imperial Chemical Industries PLC购得。
D8154是Dabco 8154,一种催化剂,可从Air Products获得。
DETDA是含约80%3,5-二乙基-2,4-二-氨基甲苯和20%3,5-二乙基-2,6-二氨基甲苯的混合物,可从Ethyl Corporation购得。
DBDTL是二月桂酸二丁基锡
DMDEE是二(2-二甲基氨基乙基)醚
DMEA是二甲基乙醇胺。
A1是Niax A1:一种可从Union Carbide获得的催化剂。
实施例1
采用一步法工艺,将表1给出的配方进行台式混合,制得软泡沫塑料。表1也给出了所得泡沫塑料的性能;
表1
实验 1 2 3 4 5 6 7 8 |
A2580 100 100 100 100 100 100 100 - |
PEG 1000 - - - - - - - 100 |
水 3 3 4 5 3 3 4 3 |
Dabco EG 0.6 0.2 0.1 - - 0.4 0.1 0.4 |
D80/20 0.2 0.9 - 0.13 - - - 0.2 |
Daltolac C4 - 0.7 0.3 - - - - - |
DBTDL - - 0.6 0.87 0.35 0.1 0.6 - |
DMEA - - - - 0.3 - - - |
A1 - - - - - 0.15 - - |
聚异氰酸酯 VM21 VM22 MPR/VM20, VM20 MPR/VM20, MPR/VM20,MPR/VM20,VM20(指数) 1∶1 1∶1 1∶1 1∶1(100) (100) (100) (100) (100) (100) (100) (100) |
起发时间 137 94 42 71 66 35 44 -(sec) |
自由起发密度 39 39 32 26 35 36 31 -(kg/m3) |
压缩载荷挠度1 4.1 2.8 4.6 6.6 4.4 4.2 4.5 -40%(kPa) |
滞后损失 %) 26 24 29 39 21 20 28 - |
回弹率 (%) 33 29 24 35 21 42 22 - |
压缩变形 3 4 4 11 6 6 5 -干燥-50%,(%) |
*对比实施例采用分子量为1000的聚乙二醇,不能得到泡沫塑料,所得产物是“口胶糖状”。
实施例2
采用一步法工艺,将表2给出配方机械混合。表2给出了所得泡沫塑料的性能。
表2
实验 1 2 3 4 5 |
A2580 100 100 100 100 100 |
水 4 4 4 4 5 |
D8154 - 0.1 0.1 0.1 - |
DETDA - 0.4 0.4 0.4 - |
DBTDL 0.15 0.1 0.1 0.1 0.6 |
DMCEE 0.35 0.3 0.3 0.3 0.13 |
异氰酸酯 VM20 VM20 VM20 VM20 VM20 |
指数 100 90 95 100 100 |
起发时间(sec) 67 68 70 60 38 |
自由起发密度 37 33 32 34 23(kg/m2) |
芯部密度,(kg/m3)36 34 34 39 25 |
撕裂强度t,(N/m) 249 266 304 323 279 |
回弹率t,(%) 29 18 21 26 21 |
压缩载荷挠度 40%,(kPa) 2.9 1.9 1.9 2.6 6.0 |
滞后损失(%) 20 27 27 26 34 |
压缩形变干燥 %,(%) - 36 31 30 7 |
实施例3
将60重量份A2580与40重量份MPR反应,制得预聚体,将预聚体与含有2.47pbw水,1.80pbw Daltolac C4和0.4pbw Dabco 33LV的组合物反应制得软泡沫塑料。自由起发密度为32Kg/m3;压缩载荷挠度(40%)为2KPa;滞后损失为17%;回弹率为45%,未观察到凹入部分。
在上述实施例中,密度、撕裂强度、回弹率、压缩载荷挠度和滞后损失分别按ISO1855 ISO8067、ISO8307、ISO3386和ISO3386测定。
Claims (11)
1.一种NCO值为5-30重量%的预聚物,它是由一种含至少85重量%的4,4′-二苯基甲烷二异氰酸酯的过量的聚异酸酯或其变体与一种多元醇组合物反应得到的反应产物,该多元醇组合物包含至少一种聚(氧化乙烯-氧化烯)多元醇,其平均标称羟基官能度为2-6,平均羟基当量为1000-3000,平均氧化乙烯含量为50-85重量%。
2.权利要求1的预聚物,其中所述的多元醇组合物包含:
(a)85-100重量%的含氧化乙烯残基的聚氧化烯多元醇,所述多元醇组分的平均标称羟基官能度为2-6,平均羟基当量为1000-3000且平均氧化乙烯含量为50-85重量%;
(b)15-0重量%的一种或多种其它多元醇。
3.权利要求1或2的预聚物,其中所述的聚(氧化乙烯-氧化烯)多元醇是聚(氧化乙烯-氧化丙烯)多元醇。
4.权利要求1-3的预聚物,其中所述多元醇组合物的平均标称羟基官能度为2-4。
5.权利要求1-4的预聚物,其中所述聚异氰酸酯含有至少90重量%的4,4′-二苯基甲烷二异氰酸酯。
6.权利要求1-5的预聚物,其中所述聚异氰酸酯含有至少95重量%的4,4′-二苯基甲烷二异氰酸酯。
7.权利要求1-6的预聚物,其中所述的聚(氧化乙烯-氧化烯)多元醇的平均标称羟基官能度为3,并且其中所述氧化乙烯部分是任意分布的。
8.权利要求1-7的预聚物,其中当量为500或更高的每一种多元醇的氧化乙烯含量为至少50重量%。
9.权利要求1-8的预聚物,其中所述的具有50-85%氧化乙烯含量的多元醇具有60-85重量%的氧化乙烯含量。
10.制备软聚氨酯泡沫塑料的方法,其特征在于使权利要求1-9的预聚物与一种包括水的发泡剂反应,发泡剂中可任选含有一种物理发泡剂。
11.权利要求10的方法,其中所述发泡剂是水。
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB919126709A GB9126709D0 (en) | 1991-12-17 | 1991-12-17 | Polyurethane foams |
GB919126710A GB9126710D0 (en) | 1991-12-17 | 1991-12-17 | Polyurethane foams |
GB9126709.6 | 1991-12-17 | ||
GB9126710.4 | 1991-12-17 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN92114546A Division CN1042231C (zh) | 1991-12-17 | 1992-12-17 | 聚氨酯泡沫塑料 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1215063A true CN1215063A (zh) | 1999-04-28 |
CN1146607C CN1146607C (zh) | 2004-04-21 |
Family
ID=26300015
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN92114546A Expired - Lifetime CN1042231C (zh) | 1991-12-17 | 1992-12-17 | 聚氨酯泡沫塑料 |
CNB981147828A Expired - Lifetime CN1146607C (zh) | 1991-12-17 | 1998-06-15 | 聚氨酯泡沫塑料 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN92114546A Expired - Lifetime CN1042231C (zh) | 1991-12-17 | 1992-12-17 | 聚氨酯泡沫塑料 |
Country Status (10)
Country | Link |
---|---|
US (1) | US6245825B1 (zh) |
EP (1) | EP0547765B1 (zh) |
JP (1) | JP3242720B2 (zh) |
KR (1) | KR100245236B1 (zh) |
CN (2) | CN1042231C (zh) |
AU (1) | AU651257B2 (zh) |
CA (1) | CA2084807C (zh) |
DE (1) | DE69220338T2 (zh) |
ES (1) | ES2102472T3 (zh) |
HK (1) | HK1004559A1 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1294173C (zh) * | 2001-02-26 | 2007-01-10 | 亨茨曼国际有限公司 | 软质聚氨酯泡沫体的制造方法 |
CN100344333C (zh) * | 2002-10-29 | 2007-10-24 | 株式会社Biopol | 用于伤口填充物的聚氨酯泡沫敷料及其制造方法 |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9311838D0 (en) * | 1993-06-08 | 1993-07-28 | Ici Plc | Process for making flexible foams |
GB9409546D0 (en) * | 1994-05-12 | 1994-06-29 | Ici Plc | Process for removing unwanted material from wanted material |
CN1097066C (zh) * | 1994-11-22 | 2002-12-25 | 亨茨曼Ici化学品有限公司 | 制造软泡沫塑料的方法 |
US5591779A (en) * | 1994-11-22 | 1997-01-07 | Imperial Chemical Industries Plc | Process for making flexible foams |
AU720116B2 (en) * | 1994-11-22 | 2000-05-25 | Huntsman Ici Chemicals Llc | Process for making flexible foams |
UA43899C2 (uk) * | 1995-06-27 | 2002-01-15 | Хантсмен Ай Сі Ай Кемікалз Ллс | Спосіб вилучення забруднення з матеріалу |
EP0865458B2 (en) * | 1995-12-08 | 2005-08-31 | Huntsman International Llc | Polyurethane elastomers |
AU725188B2 (en) * | 1996-06-27 | 2000-10-05 | Huntsman Ici Chemicals Llc | Microcellular elastomeric polyurethane foams |
EP1174454A1 (en) * | 2000-07-20 | 2002-01-23 | Huntsman International Llc | Process for preparing a flexible polyurethane foam |
WO2001060884A1 (en) | 2000-02-14 | 2001-08-23 | Huntsman International Llc | Process for preparing a flexible polyurethane foam |
EP1164153A1 (en) * | 2000-06-13 | 2001-12-19 | Huntsman International Llc | Process for preparing a flexible polyurethane foam |
EP1172387A1 (en) * | 2000-07-14 | 2002-01-16 | Huntsman International Llc | Process for preparing an elastomer |
JP2002155125A (ja) * | 2000-11-20 | 2002-05-28 | Sumika Bayer Urethane Kk | ポリウレタン変性ポリイソシアヌレートフォームの製造方法 |
DE10105559A1 (de) * | 2001-02-06 | 2002-08-08 | Basf Ag | Verfahren zur Herstellung von niedrigdichten hydrophilen Polyurethanweichschaumstoffen |
DE10105560A1 (de) * | 2001-02-06 | 2002-08-08 | Basf Ag | Verfahren zur Herstellung von Polyurethanweichschäumen |
DE10105558A1 (de) * | 2001-02-06 | 2005-04-07 | Basf Ag | Verfahren zur Herstellung von in-situ retikulierten Polyurethanweichschaumstoffen |
US7687548B2 (en) | 2002-07-01 | 2010-03-30 | Huntsman International Llc | Process for preparing a moulded polyurethane material |
DK1592727T3 (da) * | 2003-02-14 | 2012-02-27 | Dow Global Technologies Llc | Hydrofile polyurethanpolymerer afledt fra en MDI-baseret isocyanatafsluttet præpolymer |
US7459488B2 (en) | 2005-03-03 | 2008-12-02 | Polyfoam Products, Inc. | Composition and process for recovery of spilled hydrocarbons from aqueous environments |
JP2006282744A (ja) * | 2005-03-31 | 2006-10-19 | Nippon Polyurethane Ind Co Ltd | 軟質ポリウレタンスラブフォーム用ポリイソシアネート及びそれを用いた軟質ポリウレタンスラブフォームの製造方法 |
US20090012195A1 (en) | 2007-07-05 | 2009-01-08 | Neff Raymond A | Resin composition for use in forming a polyurethane article with increased comfort |
WO2009109600A1 (en) | 2008-03-07 | 2009-09-11 | Huntsman International Llc | Foamed materials comprising a matrix having a high hardblock content and process for preparing them |
US8901187B1 (en) | 2008-12-19 | 2014-12-02 | Hickory Springs Manufacturing Company | High resilience flexible polyurethane foam using MDI |
US8604094B2 (en) | 2008-12-23 | 2013-12-10 | Basf Se | Flexible polyurethane foam and method of producing same |
US8906975B1 (en) | 2009-02-09 | 2014-12-09 | Hickory Springs Manufacturing Company | Conventional flexible polyurethane foam using MDI |
JP4920051B2 (ja) * | 2009-02-25 | 2012-04-18 | 株式会社日立製作所 | 酸素燃焼ボイラプラント及び酸素燃焼ボイラプラントの運転方法 |
EP2881411A1 (de) * | 2013-12-05 | 2015-06-10 | Bayer MaterialScience AG | Verfahren zur Herstellung von viskoelastischen Polyurethanschaumstoffen auf Basis von phasenstabilen Polyolformulierungen |
KR20150116730A (ko) * | 2014-04-08 | 2015-10-16 | 에스케이씨 주식회사 | 소음 및 진동흡수용 초미세 발포 폴리우레탄 탄성체 및 이의 제조방법 |
KR101895981B1 (ko) * | 2017-01-19 | 2018-09-06 | 에스케이씨 주식회사 | 자운스 범퍼용 초미세 발포 폴리우레탄 탄성체 및 이의 제조방법 |
CN115322321B (zh) * | 2022-08-03 | 2024-03-12 | 佳化化学科技发展(上海)有限公司 | 一种亲水性软质泡沫及其制备方法 |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3903232A (en) | 1973-10-09 | 1975-09-02 | Grace W R & Co | Dental and biomedical foams and method |
GB1503732A (en) * | 1974-02-19 | 1978-03-15 | Grace W R & Co | Method for preparing dental and medical foam structures and products |
IT1058454B (it) * | 1976-03-17 | 1982-04-10 | Montedison Spa | Tprcedimento per la produzione di schiume poliuretaniche soffici ed extra supersoffici |
JPS583488B2 (ja) * | 1978-05-15 | 1983-01-21 | 株式会社ブリヂストン | 軟質ポリエ−テルポリウレタンフオ−ムの製造方法 |
JPS5566917A (en) * | 1978-11-14 | 1980-05-20 | Toyo Tire & Rubber Co Ltd | Manufacture of non-yellowing integral polyurethane foam |
DE2945986A1 (de) * | 1978-11-16 | 1980-06-04 | Bridgestone Tire Co Ltd | Sicherheits-tank und verfahren zu dessen herstellung |
DE3069424D1 (en) * | 1979-12-14 | 1984-11-15 | Ici Plc | Process for preparing liquid polyisocyanate compositions, and their use |
US4386032A (en) | 1981-04-13 | 1983-05-31 | Imperial Chemical Industries Limited | Liquid polyisocyanate compositions |
US4384051A (en) * | 1981-10-26 | 1983-05-17 | W. R. Grace & Co. | Flexible polyurethane foam based on MDI |
US4384050A (en) * | 1981-10-26 | 1983-05-17 | W. R. Grace & Co. | Flexible polyurethane foam based on MDI |
US4365025A (en) * | 1981-12-08 | 1982-12-21 | W. R. Grace & Co. | Flexible polyurethane foams from polymethylene polyphenyl isocyanate containing prepolymers |
DE3315596A1 (de) | 1983-04-29 | 1984-10-31 | Basf Ag, 6700 Ludwigshafen | Verwendung von polyurethanpraepolymeren als flockungsmittel |
US4603076A (en) * | 1985-03-04 | 1986-07-29 | Norwood Industries, Inc. | Hydrophilic foam |
DE3806476A1 (de) * | 1988-03-01 | 1989-09-14 | Bayer Ag | Verfahren zur herstellung von kalthaertenden polyurethan-weichformschaumstoffen mit hervorragenden daempfungseigenschaften |
DE3839570A1 (de) | 1988-11-24 | 1990-05-31 | Bayer Ag | Verfahren zur entfernung von flaechig verteilten kohlenwasserstoffen, insbesondere oelrueckstaenden |
DE3903100A1 (de) | 1989-02-02 | 1990-08-23 | Bayer Ag | Verfahren zur herstellung von elastischen und offenzelligen polyurethan-weichformschaumstoffen |
US5001167A (en) * | 1989-03-21 | 1991-03-19 | The Dow Chemical Company | Solvent resistant polyetherpolyurethane products |
DE3927317A1 (de) | 1989-08-18 | 1991-02-21 | Bayer Ag | Verfahren zur aufarbeitung trueber abwaesser |
DE3942330A1 (de) | 1989-12-21 | 1991-06-27 | Basf Ag | Verfahren zur herstellung von flexiblen polyurethan-weichschaumstoffen mit viskoelastischen, koerperschalldaempfenden eigenschaften und hierzu verwendbare polyoxyalkylen-polyol-mischungen |
DE3942329A1 (de) | 1989-12-21 | 1991-06-27 | Basf Ag | Verfahren zur herstellung von polyurethan-weichschaumstoffen mit geringer stauchhaerte und hierfuer verwendbare blockpolyoxypropylen-polyoxyethylen-polyolgemische |
JPH03199223A (ja) * | 1989-12-27 | 1991-08-30 | Achilles Corp | クッション材用ポリウレタンフォーム |
ATE148136T1 (de) * | 1991-05-03 | 1997-02-15 | Ciba Geigy Ag | Polyolkomponente für die herstellung von polyurethanformkörpern |
DE4129666C2 (de) * | 1991-09-06 | 1996-12-12 | Stankiewicz Gmbh | Verfahren zur Herstellung eines viscoelastischen Dämpfungsschaums mit adhäsiver Oberfläche |
GB9126741D0 (en) * | 1991-12-17 | 1992-02-12 | Ici Plc | Polyurethane foams |
US5418261A (en) * | 1993-01-25 | 1995-05-23 | Imperial Chemical Industries Plc | Polyurethane foams |
US5565498A (en) * | 1993-02-02 | 1996-10-15 | Imperial Chemical Industries Plc | Process for making flexible foams |
US5773483A (en) * | 1993-04-13 | 1998-06-30 | Imperial Chemical Industries Plc | Process for preparing a flexible foam |
US5459170A (en) * | 1993-04-13 | 1995-10-17 | Imperial Chemical Industries Plc | Polyurethane foams |
GB9311838D0 (en) * | 1993-06-08 | 1993-07-28 | Ici Plc | Process for making flexible foams |
US5591779A (en) * | 1994-11-22 | 1997-01-07 | Imperial Chemical Industries Plc | Process for making flexible foams |
-
1992
- 1992-11-17 ES ES92310471T patent/ES2102472T3/es not_active Expired - Lifetime
- 1992-11-17 EP EP92310471A patent/EP0547765B1/en not_active Expired - Lifetime
- 1992-11-17 DE DE69220338T patent/DE69220338T2/de not_active Expired - Lifetime
- 1992-11-24 AU AU28569/92A patent/AU651257B2/en not_active Expired
- 1992-12-08 CA CA002084807A patent/CA2084807C/en not_active Expired - Lifetime
- 1992-12-16 KR KR1019920024448A patent/KR100245236B1/ko not_active IP Right Cessation
- 1992-12-17 JP JP33703192A patent/JP3242720B2/ja not_active Expired - Lifetime
- 1992-12-17 CN CN92114546A patent/CN1042231C/zh not_active Expired - Lifetime
-
1996
- 1996-07-02 US US08/678,391 patent/US6245825B1/en not_active Expired - Fee Related
-
1998
- 1998-05-04 HK HK98103792A patent/HK1004559A1/xx not_active IP Right Cessation
- 1998-06-15 CN CNB981147828A patent/CN1146607C/zh not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1294173C (zh) * | 2001-02-26 | 2007-01-10 | 亨茨曼国际有限公司 | 软质聚氨酯泡沫体的制造方法 |
CN100344333C (zh) * | 2002-10-29 | 2007-10-24 | 株式会社Biopol | 用于伤口填充物的聚氨酯泡沫敷料及其制造方法 |
Also Published As
Publication number | Publication date |
---|---|
AU2856992A (en) | 1993-06-24 |
CA2084807C (en) | 2004-11-30 |
CN1088222A (zh) | 1994-06-22 |
JPH05262845A (ja) | 1993-10-12 |
ES2102472T3 (es) | 1997-08-01 |
DE69220338T2 (de) | 1997-11-06 |
CA2084807A1 (en) | 1993-06-18 |
JP3242720B2 (ja) | 2001-12-25 |
HK1004559A1 (en) | 1998-11-27 |
CN1146607C (zh) | 2004-04-21 |
AU651257B2 (en) | 1994-07-14 |
DE69220338D1 (de) | 1997-07-17 |
CN1042231C (zh) | 1999-02-24 |
KR100245236B1 (ko) | 2000-02-15 |
EP0547765A1 (en) | 1993-06-23 |
EP0547765B1 (en) | 1997-06-11 |
US6245825B1 (en) | 2001-06-12 |
KR930012922A (ko) | 1993-07-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1042231C (zh) | 聚氨酯泡沫塑料 | |
CN1043235C (zh) | 聚氨酯泡沫塑料 | |
CN1042232C (zh) | 多元醇组合物 | |
EP0485953B1 (en) | An isocyanate-terminated prepolymer and flexible polyurethane foam prepared therefrom | |
US7022746B2 (en) | Viscoelastic polyurethanes | |
CN1070874C (zh) | 制备柔性泡沫体的方法 | |
CN1772786A (zh) | 具有低堆积密度和压缩强度的软泡沫塑料 | |
CN1038332C (zh) | 聚氨基甲酸乙酯泡沫体 | |
CN1092677C (zh) | 由异氰酸酯封端预聚物制备的很低密度的模塑聚氨酯泡沫塑料 | |
US6133481A (en) | Isocyanate compositions for low density polyurethane foam | |
EP1145209A2 (en) | Low resilience, low frequency molded polyurethane foam | |
CN1047179C (zh) | 聚氨酯泡沫塑料 | |
JP3311746B2 (ja) | 柔軟なポリウレタンフォーム | |
US6376698B1 (en) | Prepolymers | |
KR20000070899A (ko) | 신규한 이소시아네이트-말단 예비중합체 | |
CA2092577C (en) | Process for making flexible foams | |
GB2273939A (en) | Use of formate salts as auxiliary agents for low density rigid foams | |
MXPA99007125A (en) | Isocyanate compositions for low density polyurethane foam |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C06 | Publication | ||
PB01 | Publication | ||
C53 | Correction of patent for invention or patent application | ||
CB02 | Change of applicant information |
Address after: The United States Delaware Applicant after: Hentzman ICI Chemical Product Co., Ltd. Address before: London, England, England Applicant before: Imperial Chemical Industries PLC |
|
COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: IMPERIAL CHEMICAL CORPORATION TO: HENGCIMAN ICI CHEMICALS LTD. |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C17 | Cessation of patent right | ||
CX01 | Expiry of patent term |
Expiration termination date: 20121217 Granted publication date: 20040421 |