CN1212999C - Long-acting humic acid phosphate fertilizer and process for preparing same - Google Patents
Long-acting humic acid phosphate fertilizer and process for preparing same Download PDFInfo
- Publication number
- CN1212999C CN1212999C CN 02102185 CN02102185A CN1212999C CN 1212999 C CN1212999 C CN 1212999C CN 02102185 CN02102185 CN 02102185 CN 02102185 A CN02102185 A CN 02102185A CN 1212999 C CN1212999 C CN 1212999C
- Authority
- CN
- China
- Prior art keywords
- acting
- phosphate fertilizer
- humic acid
- long
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Fertilizers (AREA)
Abstract
The present invention provides a long-acting humic acid phosphate fertilizer and a preparation method thereof. Cheap coal humic acids and general quick-acting phosphate fertilizers are used for making a long-acting phosphate fertilizer through chemical reactions under the action of accelerators and complexing agents. The method uses special chemical reactions to make an HA-P compound generated by the reactions effectively inhibit the fixation of effective phosphorus and reduce the soil fixation of the phosphorus by 16%. Under the condition that fertilizer application is the same or reduced, compared with corresponding common phosphate fertilizers, the HA-P can increase the yield by about 10%, and the utilization rate of P is increased by 10 %.
Description
Technical field:
The invention belongs to slow release fertilizer, relate in particular to a kind of preparation method of long-acting humic acid phosphate fertilizer.
Background technology:
Phosphorus (P) is one of necessary element of crop growthing development, and rationally using of phosphate fertilizer becomes the important factor of guaranteeing crop yield and improving agriculture production benefit.But because soil is to phosphorus fixation, cause crop extremely low to the utilization ratio of phosphate fertilizer, its quick-acting (water-soluble) phosphorus major part that is manured into soil in general seven days of the back changes into invalid phosphorus and also has part phosphorus to be dissolved in water body in addition, causes body eutrophication, worsens the mankind and habitable environment.Therefore, reduce phosphorus fixation and loss, improve phosphate fertilizer utilization efficiency and fertilizer efficiency, become focus and difficult point that current chemical fertilizer and agronomy circle are competitively studied.The long-acting slowization of phosphate fertilizer is the key measure that solves this difficult problem.
Studies show that in a large number that both at home and abroad coal-based humic acids (HA) is the effective fertilizer synergistic agent of a kind of cheapness, for the loss that reduces nitrogen and potassium, inhibition phosphorus fixation obvious effect is arranged, and the effect of phosphate fertilizer is especially caused people's common concern.Early fifties, Japanese scholar has found that HA has the effect of the phosphate fertilizer of inhibition fixed, Chinese scholar has also been done great deal of experimental, proves that adding various HA salt in the soil has all reduced soil to phosphorus fixation.
At present, the patent documentation and the report of relevant long-acting humic acid phosphate fertilizer preparation are a lot, mainly adopt following two kinds of methods: (1) HA or its esters and quick-acting phosphate fertilizer mixing granulation, make granulated fertilizer.Tian Sanlang herds in Japan, and (day special permission communique 49-123849) was once used nitro xanthohumic acid (NFA) and calcium superphosphate mixing granulation, thought that NFA has stoped the effect of water-soluble phosphorus and metal ion, made the phosphate fertilizer stay in grade, the fertilizer efficiency raising.15～17% ammonium humate (HA-NH was also once used in Uzbekistan (USSR 359247)
4) mix with general calcium or coarse whiting and to make granulated fertilizer.China produces HA-P's in this way.USSR (Union of Soviet Socialist Republics) (SU 139328) was once being carried out granulation behind the rotten sodium solution of spray on the general calcium powder.Japanese Patent (day special permission communique) discloses: slow-acting type HA-NP composite fertilizer is made in HA and the reaction of phosphorus ammonium heating and pressurizing, but does not see industrialized report; (2) HA-NPK and multi-element particle composite fertilizer.China and Japanese publication are crossed this type of patent in recent years, prove use the said products after, can reduce phosphorus fixation, improve utilization ratio and the crop yield of P.But the simple substance of the simple and mechanical mixed type of this class and compound fertilizer still are in extensive state so far, and technology falls behind, and effect is stable inadequately, does not also reach a standard fully economically.About HA and phosphate fertilizer chemical reaction prepare the technology of composite organic phosphate fertilizer, do not appear in the newspapers so far.
Summary of the invention:
The invention provides a kind of low cost, the preparation method of the long-acting humic acid phosphate fertilizer that effect is stable.
Long-acting humic acid phosphate fertilizer of the present invention, its main component weight percent is:
Moisture 3-5% ash content 34-63%
Humic acids content 7-54% available phosphorus content 9-25%.
The preparation of long-acting humic acid phosphate fertilizer of the present invention is carried out as follows:
(1) will be crushed to 40 order to 80 purposes and contain humic acid material coal, promotor, complexing agent, quick-acting phosphate fertilizer and mix, 50-120 ℃ of reaction 0.5-5 hour with the part by weight of water with 10-90: 0.5-10: 0.1-2: 10-90: 50-200;
(2) above-mentioned reactant through be concentrated into moisture less than 50% after, drying is made the long-acting humic acid phosphate fertilizer product.
The aforesaid humic acid material that contains is peat, brown coal, weathered coal etc., and its humic acids content will reach 40% (butt) at least, is preferably more than 60%.
Aforesaid promotor is that weight percent concentration is a kind of or its mixture of the mixture of carbon ammonium aqueous solution of ammoniacal liquor, 2-20% of 5-10% or potassium hydroxide, sodium hydroxide, ironic hydroxide.
Aforesaid complexing agent can be a kind of or its mixture of ferrous sulfate, Tai-Ace S 150, zinc sulfate, manganous sulfate.
Aforesaid quick-acting phosphate fertilizer can be calcium superphosphate, primary ammonium phosphate or Secondary ammonium phosphate.
Compare with technology is arranged mutually, the present invention has following advantage:
1. adopt low-grade coal (peat, brown coal and weathered coal) humic acids and quick-acting phosphate fertilizer to carry out the operational path of chemical reaction, its technology is simple, and is with low cost.
Since in the humic acids active oxygen-containing functional group and phosphate fertilizer effective combine and formed the HA-P mixture, make quite a few water-soluble phosphorus be converted into the molten phosphorus of Chinese holly, and increased the total available phosphorus content in the reaction product, having overcome common quick-acting phosphate fertilizer is easy to fundamentally realized long-actingization of phosphate fertilizer by soil fixing, shortcoming that phosphorus utilization is low.
3. the molten phosphorus of more Chinese holly is arranged in the product of the present invention, and owing to the molten phosphorus of Chinese holly is not easy by soil fixing, thereby therefore prolongation has greatly improved the utilization ratio of phosphate fertilizer to the time of plant phosphorus supply.
4. the present invention has also overcome the drawback of easy moisture absorption of common phosphate fertilizer and caking owing to the adding of humic acids.
5. under or the situation about reducing identical in rate of fertilizer application, HA-P is than corresponding common phosphate fertilizer volume increase about 10%, and the P utilization ratio improves 10 percentage points.
6. because the synergistic effect of humic acids, make this product also have indissoluble phosphorus in the activating soil, the physico-chemical property of improving the soil, improve crop quality, strengthen advantage such as crop anti-adversity energy.
7. product of the present invention also can be used as the main ingredient of high-concentration multi-element compound and bulk blended fertilizer except that using as long-acting phosphate fertilizer separately.
Embodiment:
Embodiment 1
Get weathered coal 20g, mix stirring evenly with mixed solution 3ml, ferrous sulfate 0.2g, calcium superphosphate 180g, the water 400ml of the carbon ammonium aqueous solution of 5% ammoniacal liquor and 2%, 50 ℃ of reactions 5 hours, concentrate drying was made the long-acting humic acid phosphate fertilizer product.Its effective constituent (weight percent) is moisture 4.5, ash content 67.8, humic acids 7, available phosphorus content 20.7.
Embodiment 2
Get peat 50g, mix with mixture (weight ratio 1: 1) 5g, ferrous sulfate, Tai-Ace S 150, mixture (weight ratio 1: 1: the 2) 0.3g of zinc sulfate, primary ammonium phosphate ammonium 50g, the water 200ml of sodium hydroxide and ironic hydroxide and to stir evenly, 100 ℃ of reactions 2 hours, concentrate drying is made the long-acting humic acid phosphate fertilizer product.Its effective constituent (weight percent) is moisture 3.5, ash content 34.7, humic acids 36.3, available phosphorus content 25.5.
Embodiment 3
Get brown coal 70g, stir evenly with mixing with mixture (weight ratio 1: 1) 7g, manganous sulfate 2g, Secondary ammonium phosphate 30g, the water 400ml of sodium hydroxide and potassium hydroxide, 80 ℃ of reactions 2 hours, concentrate drying was made the long-acting humic acid phosphate fertilizer product.Its effective constituent (weight percent) is moisture 3.2, ash content 36.8, humic acids 42.4, available phosphorus content 17.6.
Embodiment 4
Get peat 80g, mix stirring evenly with mixed solution 5ml, sodium hydroxide 7g, zinc sulfate 0.8g, primary ammonium phosphate 20g, the water 500ml of the carbon ammonium aqueous solution of 5% ammoniacal liquor and 2%, 120 ℃ of reactions 1 hour, concentrate drying was made the long-acting humic acid phosphate fertilizer product.Its effective constituent (weight percent) is moisture 3.8, ash content 29.6, humic acids 53.4, available phosphorus content 13.2.
Embodiment 5
Get brown coal 30g, (weight ratio 1: 1: 1: 1) 0.3g, calcium superphosphate 70g, water 200ml mix and stir evenly with the mixture of potassium hydroxide 1.5g, ferrous sulfate, Tai-Ace S 150, zinc sulfate, manganous sulfate, 100 ℃ of reactions 5 hours, concentrate drying was made the long-acting humic acid phosphate fertilizer product.Its effective constituent (weight percent) is moisture 4.3, ash content 58.9, humic acids 18.6, available phosphorus content 18.2.
Embodiment 6
Get weathered coal 90g, mix stirring evenly with ironic hydroxide 7%, Tai-Ace S 150 1.2g, Secondary ammonium phosphate 10g, water 300ml, 90 ℃ of reactions 1.5 hours, concentrate drying was made the long-acting humic acid phosphate fertilizer product.Its effective constituent (weight percent) is moisture 3.8, ash content 33.6, humic acids 53.4, available phosphorus content 9.2.
Embodiment 7
Get weathered coal 40g, mixture 2g, the calcium superphosphate 60g of the mixture of potassium hydroxide and ironic hydroxide (weight ratio 1: 1) 3g, manganous sulfate and zinc sulfate, water 250ml mixing stirs evenly, and 80 ℃ of reactions 4 hours, concentrate drying was made the long-acting humic acid phosphate fertilizer product.Its effective constituent (weight percent) is moisture 4.2, ash content 48.6, humic acids 24.6, available phosphorus content 22.6.
Embodiment 8
Get peat 30g, potassium hydroxide 3g, ferrous sulfate 1g, calcium superphosphate 70g, water 300ml mixing stir evenly, and 120 ℃ of reactions 5 hours, concentrate drying was made the long-acting humic acid phosphate fertilizer product.Its effective constituent (weight percent) is moisture 3.6, ash content 53.1, humic acids 18.4, available phosphorus content 24.9.
Get the product of embodiment 1,2,3,4,5,6,7,8 preparations, contrast with normal superphosphate.In 400g soil, press and wait phosphorus amount (500mg P
2O
5/ kg soil) sneak into and place the glass beaker of 500ml respectively, stirred in per 5 days and the equivalent trickle once, make moisture content in the soil near the field state, cultivated 60 days under the room temperature, measure the effective P in the soil
2O
5Content and various phosphate fertilizer suppress soil to the phosphorus fixation effect.Test-results sees Table 1.
The various phosphate fertilizer of table 1 are cultivated the measurement result of available phosphorus after 60 days and fixed rate thereof in soil
Phosphate fertilizer variety available phosphorus phosphorus fixed rate (%) suppresses fixed rate (%)
(mg/kg)
Calcium superphosphate 279.4 41.00-
Embodiment 1 207.0 32.36 21.07
Embodiment 2 255.0 29.28 28.58
Embodiment 3 176.0 36.88 16.60
Embodiment 4 132.0 25.91 36.80
Embodiment 5 182.0 31.98 22.00
Embodiment 6 92.0 26.86 34.50
Embodiment 7 226.0 30.01 26.80
Embodiment 8 249.0 32.10 21.70
Claims (4)
1. the preparation method of a long-acting humic acid phosphate fertilizer is characterized in that the preparation method carries out as follows:
(1) will be crushed to 40 order to 80 purposes and contain humic acid material coal, promotor, complexing agent, quick-acting phosphate fertilizer and mix, 50-120 ℃ of reaction 0.5-5 hour with the part by weight of water with 10-90: 0.5-10: 0.1-2: 10-90: 50-200;
(2) above-mentioned reactant through be concentrated into moisture less than 50% after, drying is made the long-acting humic acid phosphate fertilizer product;
Described promotor is that weight percent concentration is a kind of or its mixture of the mixture of carbon ammonium aqueous solution of ammoniacal liquor, 2-20% of 5-10% or potassium hydroxide, sodium hydroxide, ironic hydroxide.
Described complexing agent is a kind of of ferrous sulfate, Tai-Ace S 150, zinc sulfate or manganous sulfate or its mixture.
3. the preparation method of a kind of long-acting humic acid phosphate fertilizer as claimed in claim 1 is characterized in that the described humic acid material that contains is that humic acids content reaches 40% peat, brown coal or weathered coal.
4. the preparation method of a kind of long-acting humic acid phosphate fertilizer as claimed in claim 1 or 2 is characterized in that the described humic acid material that contains is that humic acids content reaches 60% peat, brown coal or weathered coal.
5. the preparation method of a kind of long-acting humic acid phosphate fertilizer as claimed in claim 1 is characterized in that described quick-acting phosphate fertilizer is calcium superphosphate, primary ammonium phosphate or Secondary ammonium phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02102185 CN1212999C (en) | 2002-01-21 | 2002-01-21 | Long-acting humic acid phosphate fertilizer and process for preparing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02102185 CN1212999C (en) | 2002-01-21 | 2002-01-21 | Long-acting humic acid phosphate fertilizer and process for preparing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1434006A CN1434006A (en) | 2003-08-06 |
| CN1212999C true CN1212999C (en) | 2005-08-03 |
Family
ID=27627486
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02102185 Expired - Lifetime CN1212999C (en) | 2002-01-21 | 2002-01-21 | Long-acting humic acid phosphate fertilizer and process for preparing same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1212999C (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101293666B (en) * | 2007-04-29 | 2011-04-20 | 兰州大学 | Calcium magnesium phosphor potassium fertilizer particle balling preparation technique |
| CN102408257B (en) * | 2011-08-08 | 2013-04-10 | 山东省农业科学院农业资源与环境研究所 | Microelement-introducing weathered coal activating agent as well as activation method and application |
| CN103274798B (en) * | 2013-06-17 | 2015-09-23 | 中国农业科学院农业资源与农业区划研究所 | A kind of Humic acid synergistic ammonium phosphate and preparation method thereof |
| CN103739375A (en) * | 2013-12-19 | 2014-04-23 | 山西惠亿农生物科技有限公司 | Microbial fermentation humic acid biological fertilizer and application and preparation method thereof |
| CN104402597B (en) * | 2014-11-07 | 2017-02-15 | 成都新柯力化工科技有限公司 | Stable phosphor-oxygen amide fertilizer and preparation method thereof |
| CN105084985A (en) * | 2015-09-17 | 2015-11-25 | 青岛漾花湖农业科技有限公司 | Special humic acid water-soluble fertilizer for horseradish trees and preparation method of special humic acid water-soluble fertilizer |
| CN106083332A (en) * | 2016-06-15 | 2016-11-09 | 云南省化工研究院 | The production method of organic composite humic fertilizer produced by a kind of potassium dihydrogen phosphate by-product citric acid soluble phosphorus potash fertilizer |
| CN109438029A (en) * | 2018-11-09 | 2019-03-08 | 中国农业科学院农业资源与农业区划研究所 | A kind of phosphorus ammonium preparation method containing Humic acid synergistic carrier suitable for basic soil |
| CN110790945B (en) * | 2019-11-26 | 2021-06-18 | 陕西科技大学 | Cationized humic acid and preparation method and application thereof |
| CN111675569A (en) * | 2020-06-23 | 2020-09-18 | 瑞安市味乐食品厂 | Efficient flower-promoting and fruit-promoting compound foliar fertilizer for fruit trees and preparation method thereof |
| CN115073241A (en) * | 2022-07-08 | 2022-09-20 | 安徽农业大学 | Preparation method and application of humic acid phosphate fertilizer for improving phosphorus effectiveness |
-
2002
- 2002-01-21 CN CN 02102185 patent/CN1212999C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1434006A (en) | 2003-08-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1212999C (en) | Long-acting humic acid phosphate fertilizer and process for preparing same | |
| CN102476972A (en) | Corn base fertilizer for saline alkali land, preparation method and application thereof | |
| CN100413816C (en) | Nitrogen fertilizer solidifying method by active soil, flocculant, adsorbent composite material and fertilizer | |
| CN1990432A (en) | Processing method for humic acidic ammonium complex blending fertilizer | |
| CN1793072A (en) | Process for preparing organic fertilizer by biological mud and grass refuse of papermaking plant | |
| CN1255361C (en) | Humic acid solid fertilizer | |
| CN103755490A (en) | Fermented fertilizer containing pyroligneous liquor, and preparation method thereof | |
| CN1060147C (en) | High concentrative non-flocculant humic acids complexed nutrient liquid and preparation thereof | |
| CN1062545C (en) | Efficient organic fertilizer and producing method thereof | |
| CN1491924A (en) | Humic acid long-acting compound fertilizer and its preparing method | |
| CN101041605A (en) | Soil phosphorus element activating agent and application thereof | |
| CN1683287A (en) | Instant soluble flushing and spreading fertilizer containing agricultural rare-earth and synergistic agent | |
| CN102260124B (en) | Method for preparing humic acid coated urea | |
| CN1203213A (en) | Compound fertilizer and producing method thereof | |
| CN1522993A (en) | Water preserving nitrogenous fertilizer synergist and preparation method thereof | |
| CN100491500C (en) | Environment friendly composite material for controlling loss of nitrogen fertilizer and applications | |
| CN1288880A (en) | Multielement marine organism fertilizer and its preparation | |
| CN101033156A (en) | Multielement high nutrient synthetic organic fertilizer product and application thereof | |
| CN101525261B (en) | Calcareous-soil nitrogen-phosphorus synergist and preparation method thereof | |
| CN1248987C (en) | Long lasting composite fertilizer | |
| CN1246262C (en) | Process for preparing efficient ammonium phosphate | |
| CN101063037A (en) | Organic macromolecular soil phosphor element activator and preparation method thereof | |
| CN1220656C (en) | Slow releasing fertilizer specially for Chinese goldthread and its production process | |
| CN1120823C (en) | Seedling-strengthening agent for growing rice seedlings | |
| CN1059885C (en) | Soil improvement all-elements micro-fertilizer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20050803 |
|
| CX01 | Expiry of patent term |