CN1202839A - Water removal device - Google Patents
Water removal device Download PDFInfo
- Publication number
- CN1202839A CN1202839A CN96198500A CN96198500A CN1202839A CN 1202839 A CN1202839 A CN 1202839A CN 96198500 A CN96198500 A CN 96198500A CN 96198500 A CN96198500 A CN 96198500A CN 1202839 A CN1202839 A CN 1202839A
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- China
- Prior art keywords
- zeolite membrane
- liquid mixture
- liquid
- supporting substrate
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000007788 liquid Substances 0.000 claims abstract description 43
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 38
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000010457 zeolite Substances 0.000 claims abstract description 38
- 239000012528 membrane Substances 0.000 claims abstract description 32
- 239000000203 mixture Substances 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 10
- 235000012239 silicon dioxide Nutrition 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000002425 crystallisation Methods 0.000 claims description 2
- 230000008025 crystallization Effects 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 description 10
- -1 pottery Substances 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 239000000017 hydrogel Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 229960004592 isopropanol Drugs 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- ZUEKXCXHTXJYAR-UHFFFAOYSA-N tetrapropan-2-yl silicate Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)OC(C)C ZUEKXCXHTXJYAR-UHFFFAOYSA-N 0.000 description 2
- HYUJIYRRLKBBBT-UHFFFAOYSA-N COO[Si](OOC)(OOC)OOC Chemical compound COO[Si](OOC)(OOC)OOC HYUJIYRRLKBBBT-UHFFFAOYSA-N 0.000 description 1
- 208000035126 Facies Diseases 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940088679 drug related substance Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052605 nesosilicate Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000005373 pervaporation Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 125000005624 silicic acid group Chemical class 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
- B01D71/0281—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
- B01D61/362—Pervaporation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
- B01D63/06—Tubular membrane modules
- B01D63/062—Tubular membrane modules with membranes on a surface of a support tube
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
A device for removing water from liquid mixtures which comprises a tubular cylinder closed at one end formed from a support matrix on which is crystallised a zeolite membrane over at least its lower part, in use the cylinder is placed in the liquid mixture with the zeolite membrane in contact with the liquid mixture so that the water passes through the membrane into the cylinder, optionally there can be a reduced pressure inside the cylinder.
Description
The present invention relates to a kind of liquid separating appts, more particularly, relate to a kind of dried up device that can be used for from other liquid, dividing.
It is known to divide dried up from other liquid with zeolite membrane, european patent application 0481660 discloses and has discussed existing zeolite type film, and US3244643,3730910,4578372, Applied Catalysts 49 (1989), 1-25, DE-A-3827049, CA1235684, JP-A-63287504, JP-A-63291809 and EP-A-135069 have been quoted especially as proof.
The routine of film in fluid separation applications used and comprised through-flow method, and wherein the liquid that will separate utilizes pressure reduction or gravity to make a kind of liquid by this film, and stays liquid mixture at the opposite side of film in a side of film.
Another kind method is to use cross-flow to separate, and wherein liquid mixture by the film surface, is removed a kind of liquid with continuous or semicontinuous logistics form from logistics under the effect of both sides differential pressure of membrane.
The device of setting up in these are used may comprise complicated pumping and control system, and liquid is injected in the device.
We have invented a kind of simpler and liquid separating appts more easily, and it is easy to on-the-spot the use.
According to the present invention, a kind of device of separating liquid is provided, it comprises the tube element that one the one end sealing other end opens wide, wherein the part of pipe comprises zeolite membrane.
Tube element can have any shape of cross section, and as circular, avette, oval, rectangle, square etc., circle or oval cross-section are preferred.The length of pipe is unimportant to the ratio of cross-sectional area, and this depends on application, and the shape of pipe can change in big scope, as from elongated tubular to short and thick pipe.
The tube element part that contains zeolite membrane is the zeolite membrane on supporting substrate preferably, and base material has woven wire or sieve, pottery or as the polymeric material of polysulfones or polyether sulfone etc., described in this list of references of mentioning in front.In the present invention, support membrane can be shaped to required shape to constitute the tube element part.
Preferably, the zeolite membrane of tube element part is near blind end, and in case of necessity, its end can be formed by zeolite membrane.
Another part of tube element can comprise the not supporting member of coverlay, or can be made by metal, pottery, plastic or other material.Material is unimportant, but requires to have enough intensity and suitable dimensional stability.It can be porous or atresia, this depends on how it uses.
Zeolite membrane should not have defective basically so that effective separation to be provided, and the zeolite membrane of describing among our the co-pending application PCT/GB95/02221 is preferred, and zeolite membrane is wherein handled with silicic acid.
The method of making silicic acid is described in the GB patent application 2269377, and preferable methods is the acidifying sodium silicate solution, is separated to isolate silicic acid with the organic solvent as oxolane then.Then, can dry organic facies and isolate silicic acid anhydride, for example obtain substantially anhydrous silicate solution by adding n-butanol.The degree of polymerization of silicic acid depends on employed physical condition, as sodium metasilicate before adding organic solvent and sour time of contact, temperature etc.
Be used for silicic acid of the present invention and preferably have 96-10,000 mean molecule quantity further preferably has the mean molecule quantity of 96-3220.
Except that handling with silicic acid, the zeolite type material can also be handled with alkyl ortho-silicate and alkoxyl ortho-silicate, the example of alkyl ortho-silicate has tetraethylorthosilicise (TEOS) and tetra isopropyl ortho-silicate (TIPOT), the example of alkoxyl ortho-silicate has the tetramethoxy ortho-silicate, when it is applied to the zeolite type material, formed poly-silicic acid.These alkyl ortho-silicates and alkoxyl ortho-silicate have formed the mesoporosity silicon oxide compounds, it mainly is made up of a series of poly-silicic acid unit that are linked together, each unit comprises the poly-silicic acid molecule of describing in the GB patent application 2269377, and comprise many three-dimensional materials (species) that are coupled to each other, each three-dimensional material or contain the silicon atom bridge, between each silicon atom oxygen atom is arranged, or on the silicon atom hydroxyl is arranged.
In one embodiment, tube element is to be formed by the base material that can be used as the zeolite membrane supporting member, and zeolite membrane is deposition, growth, crystallization or formation on the part of supporting member, and another part does not deal with.
Apparatus of the present invention can be used in two ways.In first kind of mode, apparatus of the present invention are placed in the container, and liquid mixture is placed in the tube element, and liquid mixture only contacts with the no bore portion of zeolite membrane or tube element like this.Can pass the liquid of zeolite membrane, for example, water passes film and enters container, thereby with fluid separation applications.For the ease of separating, preferably apply a pressure reduction in the both sides of film.
In another kind of mode of operation, liquid mixture is to be contained in the container, and this device is placed in the liquid, and that part that contains zeolite membrane of tube element contacts with liquid mixture.Can pass the liquid of zeolite membrane, for example, water is removed thereby enter tube element.For the ease of separating, preferably apply a pressure reduction in the both sides of film.
This device is particularly suitable for removing from liquid, aqueous mixture and anhydrates, for example, low-level water content is reduced to acceptable, for example, from solvent, diluent and other liquid, biology and the medicine that may be polluted by water and other heat-sensitive substance, remove and anhydrate.In an example, in the liquid, aqueous container that is contained in as beaker or winchester (Winchester) etc., apparatus of the present invention are placed in the liquid, and apply vacuum on tube element.Then, the water in the liquid mixture was suctioned through film.System can continued operation until in liquid mixture, having obtained desired degree of dehydration.Then device is shifted out, cleans and prepare against usefulness again,, then can discard if polluted by biology or drug substance.
Therefore, obtained a kind of easy carrying device that anhydrates that removes from liquid, aqueous mixture, this device adaptability is strong, is easy to use, and can be used for liquid mixture.
A feature of the present invention is can remove to anhydrate from liquid mixture, and does not need high pressure reduction in the film both sides, needs high pressure reduction in the application of disclosed zeolite membrane in the past.
The present invention is described among the following embodiment and accompanying drawing, and embodiment is used to illustrate the preparation of film, and accompanying drawing is used to illustrate the device of using film.The growth of embodiment 1 film
Base materials employed is the porous sintered stainless steel cylinder filter of Pall PSS (trade mark) CP1606 PO5 316L, and as shown in Figure 1, wherein 7 is cylinder filters, the 8th, and screw thread (referring to embodiment 3).
Cylinder is placed in 1 liter the glass container, and container has been used deionized water, acetone, toluene, at last with the acetone washing, and in 90 ℃ baking oven dry 3 hours.
(a) cobalt preliminary treatment
Cylinder is placed in 1 liter the glass container, adds the cobalt nitrate solution of 800ml 0.1M in container, and floods 1 hour, decantation goes out cobalt nitrate solution then, beaker is placed in 90 ℃ the baking oven dryly, from beaker, takes out cylinder, 250 ℃ of following roastings 4 hours.From stove, take out cylinder and cooling.This program repeats more than twice to obtain good cobalt oxide coating.
(b) zeolite preliminary treatment
The base material outside having applied cobalt smears zeolite 4A powder with the finger of being with gloves, in the time zeolite can not being rubbed into its surface, pats unnecessary zeolite.
In two 500ml vials, prepare two kinds of solution A and B by the following method respectively:
Solution A
Machinery shakes 73.47g sodium aluminate, 11.25g NaOH and 445.8g deionized water up to dissolving.The actual sets of sodium aluminate becomes Al
2O
362.48%, Na
2O 35.24%, H
2O 2.28%.
Solution B
151.71g is consisted of Na
2O 14.21%, SiO
235.59% and H
2The sodium metasilicate of O 50.20% is dissolved in the 445.80g deionized water.
Solution A is joined in the solution B lentamente, stir and use hand moving assurance mixing (importantly not forming block hydrogel) fully uniformly simultaneously.The mole of the hydrogel that obtains consists of:
2.01Na
2O：Al
2O
3：2.0SiO
2：120.0H
2O
The 800ml hydrogel is injected growing container lentamente, in this container, be placed vertically the cylinder that zeolite was handled and wiped to cobalt oxide.Growing container and the beaker that fills the surplus water gel solution are placed in the pressure cooker together.Pressure cooker was placed in the baking oven that is preheating to 100 ℃ 5 hours.Then, from baking oven, take out and cooled off 30 minutes.Shift out growing container, and incline and solution.
The careful cylinder that takes out from growing container.Cylinder is placed in the glass container, and with the deionized water of 800ml equivalent washing three times, solution is reverberated guaranteeing to remove fully residue, film was 70 ℃ air drying 2 hours.
Then, with the dry coating surface of wiping lens paper wiping cylinder, remove the friable deposit that may form on the surface.Spend deionised water again, and in 70 ℃ baking oven dry 2 hours.This growth and washing process repeat more than twice.
X-ray analysis shows that this is zeolite 4A.Embodiment 2 prepares TEOS for the post processing of film
120ml TEOS is put in clean, the dry beaker, and adds 540ml deionized water and 540ml ethanol, the preparation post-treatment solution.Mixture stirred 5 minutes under 300rpm.The test of embodiment 3 films
Cylinder is put in 1 liter the glass container, glass container is placed on the hot plate that has heater and agitator, is connected with vacuum pipeline by the end of screw thread with cylinder.Inject isopropanol (IPA/H in the glass container
2O) mixture (90/10wt%).At about 70 ℃ film is tested.
Film away from liquid one side, promptly the pressure of the inboard of cylinder is reduced to 4 millibars (0.4kN), collects penetrating fluid in 8 hours, and weighs, the equivalent that takes a morsel sample is analyzed, and monitors the concentration of water in the charging in whole process.The last handling process of embodiment 4 films
After untreated film is tested with IPA/ water in the equipment of embodiment 3, the turned letter glass container, with the rinsing of 2 * 100ml equivalent ethanol, and then in glass container adding 100ml ethanol, cylinder was placed vacuum following 30 minutes.
From glass container, pour out ethanol, and in glass container, inject the TEOS post-treatment solution of embodiment 2 preparations.Cylinder was handled 24 hours down at 70 ℃, and the inboard of cylinder places under the vacuum simultaneously.After during this, remove mixture, stop heating, remove vacuum, then, make compressed air pass through film 1 hour.Embodiment 5
Film by the preparation of embodiment 1 method is handled under the pervaporation condition of embodiment 3 and in the post processing of embodiment 4, and it the results are shown in table 1.Table 1
Iso-propanol/water mixture, 70 ℃.
Processing time feed water infiltration water infiltration water flux
(hour) wt% wt% (J) Kg/m
2/ day
0.5 7.99 82.18 27.25
1.0 7.60 80.40 23.26
1.5 7.35 78.14 22.39
2.0 6.45 75.38 21.14
2.5 5.84 72.52 19.79
3.0 5.23 69.45 18.36
3.5 4.88 66.14 18.46
4.0 4.41 60.00 16.14
4.5 3.75 57.61 15.05
5.0 3.46 57.32 13.25
5.5 3.16 48.26 13.18
6.0 2.69 45.93 12.30
6.5 2.19 42.16 8.76
7.0 1.90 38.42 8.27
7.5 1.59 33.15 8.44
8.0 1.47 29.51 7.89
8.5 1.18 26.44 6.98
9.0 1.16 25.77 6.44
9.5 1.00 22.02 5.56
100 0.86 21.31 4.87
10.5 0.75 20.34 4.35
110 0.66 18.16 3.91
11.5 0.60 16.06 3.26
12.0 0.52 13.98 2.68
12.5 0.44 10.59 1.89
The example of institute's operative installations wherein fills liquid, aqueous mixture 2 as shown in Figure 2 among the present invention in the container 1.The pipe of being made by woven wire 3 has a bottom 4, has deposited zeolite membrane on it.
In use, pipe is placed in liquid, aqueous in the container, applies vacuum at 5 places.,, shown in 6, can remove from here and anhydrate in the bilge suction pipe by film 4.Therefore liquid 2 remains, and its moisture ratio has descended.
In Another Application, liquid, aqueous being placed in the pipe 3 reduced pressure in the pipe outside.Water is stayed liquid in the pipe by film, and its water content has descended.
Claims (9)
1. the device of a separating liquid, this device comprises a tube element, the end sealing of element, the other end opens wide, and the part of pipe contains zeolite membrane.
2. the device of claim 1, the tube element that wherein contains zeolite membrane is the zeolite membrane that forms on supporting substrate.
3. the device of claim 2, supporting substrate is woven wire or sieve or pottery or polymeric material.
4. claim 3 is installed, and wherein supporting substrate is shaped to required shape, and zeolite membrane is crystallization on supporting substrate
5. the device of any one among the claim 1-4, wherein zeolite membrane is handled by contacting with silicic acid, forms the film of atresia basically.
6. the device of any one among the claim 1-5 is essentially columnar supporting substrate comprising one, deposits zeolite membrane thereon, so that at least in the bottom formation zeolite membrane of close the blind end of device.
7. one kind is removed the method for anhydrating from liquid mixture, comprise and make that the device of any one contacts with liquid mixture among the claim 1-7, so that the water permeable that contacts with liquid mixture of only installing partly contains zeolite membrane basically, so that water is separated by zeolite membrane and from liquid mixture.
8. the method for claim 7, liquid mixture is contained in the container.
9. the method for claim 7, liquid mixture is placed on the inboard of device, so that water flows out by zeolite membrane.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9523854.9 | 1995-11-22 | ||
| GBGB9523854.9A GB9523854D0 (en) | 1995-11-22 | 1995-11-22 | Water removal device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1202839A true CN1202839A (en) | 1998-12-23 |
Family
ID=10784255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96198500A Pending CN1202839A (en) | 1995-11-22 | 1996-11-20 | Water removal device |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0863791A1 (en) |
| JP (1) | JP2000500394A (en) |
| KR (1) | KR19990071526A (en) |
| CN (1) | CN1202839A (en) |
| AU (1) | AU713866B2 (en) |
| CA (1) | CA2237436A1 (en) |
| GB (1) | GB9523854D0 (en) |
| WO (1) | WO1997018886A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102149450A (en) * | 2008-07-10 | 2011-08-10 | 德克萨斯州立大学董事会 | Water purification membranes with improved fouling resistance |
| CN101898089B (en) * | 2009-05-27 | 2013-11-06 | 三菱重工业株式会社 | Dehydration system |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9723253D0 (en) * | 1997-11-04 | 1998-01-07 | Bratton Graham J | Water treatment process |
| GB9821706D0 (en) * | 1998-10-07 | 1998-12-02 | Bratton Graham J | Membrane structure |
| CN103861459A (en) * | 2014-03-25 | 2014-06-18 | 湖州森诺氟材料科技有限公司 | Filtering device with polytetrafluoroethylene membrane |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4995967A (en) * | 1987-11-06 | 1991-02-26 | Akzo N.V. | Separator for cell-containing liquids |
| DE3827049A1 (en) * | 1988-08-10 | 1990-02-15 | Schulten Rudolf Prof Dr | Zeolite molecular sieve for separating fluids |
| GB9022836D0 (en) * | 1990-10-19 | 1990-12-05 | British Petroleum Co Plc | Membranes |
| SE469031B (en) * | 1991-10-31 | 1993-05-03 | Electrolux Ab | DEVICE FOR WATER PURIFICATION MEDIUM REVERSE OSMOS |
| JP3431973B2 (en) * | 1993-12-27 | 2003-07-28 | 三井造船株式会社 | Method for producing liquid mixture separation membrane |
| US5464798A (en) * | 1994-02-24 | 1995-11-07 | Jia; Meng-Dong | Ceramic-zeolite composite membranes and use for separation of vapor/gas mixtures |
-
1995
- 1995-11-22 GB GBGB9523854.9A patent/GB9523854D0/en active Pending
-
1996
- 1996-11-20 AU AU76318/96A patent/AU713866B2/en not_active Ceased
- 1996-11-20 WO PCT/GB1996/002861 patent/WO1997018886A1/en not_active Application Discontinuation
- 1996-11-20 CA CA002237436A patent/CA2237436A1/en not_active Abandoned
- 1996-11-20 EP EP96939178A patent/EP0863791A1/en not_active Withdrawn
- 1996-11-20 CN CN96198500A patent/CN1202839A/en active Pending
- 1996-11-20 JP JP9519502A patent/JP2000500394A/en active Pending
- 1996-11-20 KR KR1019980703799A patent/KR19990071526A/en not_active Application Discontinuation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102149450A (en) * | 2008-07-10 | 2011-08-10 | 德克萨斯州立大学董事会 | Water purification membranes with improved fouling resistance |
| CN101898089B (en) * | 2009-05-27 | 2013-11-06 | 三菱重工业株式会社 | Dehydration system |
Also Published As
| Publication number | Publication date |
|---|---|
| GB9523854D0 (en) | 1996-01-24 |
| AU713866B2 (en) | 1999-12-09 |
| KR19990071526A (en) | 1999-09-27 |
| WO1997018886A1 (en) | 1997-05-29 |
| JP2000500394A (en) | 2000-01-18 |
| EP0863791A1 (en) | 1998-09-16 |
| CA2237436A1 (en) | 1997-05-29 |
| AU7631896A (en) | 1997-06-11 |
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