CN1200265A - Hair cosmetic composition - Google Patents
Hair cosmetic composition Download PDFInfo
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- CN1200265A CN1200265A CN 98115141 CN98115141A CN1200265A CN 1200265 A CN1200265 A CN 1200265A CN 98115141 CN98115141 CN 98115141 CN 98115141 A CN98115141 A CN 98115141A CN 1200265 A CN1200265 A CN 1200265A
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Abstract
The present invention relates to a hair cosmetic composition comprising (A) an [alpha]-hydroxycarboxylic acid or salt thereof; and (B) a plant selected from the group consisting of sesame, rosemary, sage, chamomile, clove, thyme, turmeric, green onion, celery, licorice, blueberry, scutellatia root, mulberry bark, phellodendron bark, Japanese captis, rose fruit, henna, paeonia or witch hazel, or an extracted or pressed-product thereof. The hair cosmetic composition according to the present invention can prevent hair from damages such as dry hair or changes in color and impart glass and flexibility to the hair.
Description
The present invention relates to a kind of hair dressing composition, it can prevent that hair is impaired, as because of being exposed to the heat that daylight or ultraviolet radiation, hair washing, combing, drying machine send, the perhaps hair that causes of hair dye or the bleach hair drying or the change color equivalent damage of degenerating and causing; And said composition can make hair have gloss and flexibility.
Hair often is in the various environmental conditions.When being exposed to ultraviolet radiation, low humidity air or when hot, hair can be impaired, and can become dry or become bronzing.At this moment, think that hair surface is by the active oxygen oxidation.Found that in various environmental factorss ultraviolet radiation is the key factor that produces active oxygen.
Impaired for preventing hair, a kind of hair dressing composition (Japan Patent is openly speciallyyed permit the flat 4-224508 of communique) has been proposed, the benzophenone that it comprises highly polymeric dimethyl polysiloxane and is used as the ultraviolet radiation inhibitor; With a kind of hair dressing composition (Japan Patent is openly speciallyyed permit the flat 1-211515 of communique), it comprises the polysiloxanes and the antioxidant of high component.
Above-mentioned hair dressing composition is preventing that hair can not be satisfactory aspect impaired, and they can prevent the hair drying, but adopt them to nurse gloss and the flexibility that can not improve hair, effect even than also poor before impaired.
Therefore the purpose of this invention is to provide a kind of hair dressing composition, it can prevent that the hair that causes because of ultraviolet radiation etc. is impaired, and can improve the gloss and the flexibility of hair.
At above situation, the inventor has carried out broad research.Found that a kind of hair dressing composition, it can suppress the hair damage such as the hair variable color that cause because of active oxygen, and it can improve the gloss and the flexibility of hair, and it is that alpha-hydroxy carboxylic acid compounds and specific plant or its extract or squeezing product are adopted in combination, thereby has finished the present invention.
Therefore one aspect of the present invention provides a kind of hair dressing composition, and said composition comprises following composition (A) and (B):
(A) at least a chemical compound that is selected from alpha-hydroxy carboxylic acid compounds and inorganic salt and organic salt; With
(B) kind of plant is selected from Semen Sesami, Herba Rosmarini Officinalis, Salvia japonica Thunb. (sage), Chamomile, Flos Caryophylli, Herba thymi vulgaris, Rhizoma Curcumae Longae, the leaf Herba Alii fistulosi, Herba Apii graveolentis, Radix Glycyrrhizae, Pericarpium Citri tangerinae, scutellariae,radix, Cortex Mori, phellodendron bark, Japanesecaptis, rose fruit, mignonettetree, Radix Paeoniae and witch hazel, or their extract or squeezing product.
Hair dressing composition of the present invention can prevent that hair is impaired, as dehydration, surface oxidation or change color, and can make hair have gloss and flexibility.
Being suitable for the alpha-hydroxy carboxylic acid compounds of making component of the present invention (A) is monocarboxylic acid or the polybasic carboxylic acid with one or more hydroxyl-functional bases.Go up at least one hydroxyl-functional base of introducing at this sour alpha-position (the adjacent carbon atom of carboxyl-functional base).This examples for compounds comprises citric acid, lactic acid, methyllactic acid, phenyl-lactic acid, malic acid, mandelic acid, glycolic, hydroxymalonic acid, tartaric acid and gluconic acid.Their inorganic salt or organic salt also are suitable for.Wherein optimization citric acid, lactic acid, tartaric acid, glycolic and their inorganic salt and organic salt, wherein preferred especially lactic acid and glycolic and inorganic salt and organic salt are because of it can improve the flexibility of hair.Containing L-lactic acid is preferred more than the lactic acid of D-lactic acid and inorganic salt thereof and organic salt.Preferred especially L-lactic acid content accounts for lactic acid and inorganic salt and the organic salt of the 60-100% of lactic acid total amount, because of it more can improve the flexibility of hair.Preferred L-lactic acid content is the 85-100% that accounts for the lactic acid total amount, preferred especially 100%.Among the present invention, the content of L-lactic acid is 100% in the most preferred lactic acid.Pure L-lactic acid can be passed in time and gradually by racemization, become the equilibrium mixture that contains about 85% L-lactic acid and about 15% D-lactic acid.This mixture also is applicable to hair dressing composition of the present invention.
The form that lactic acid is suitable for is to contain 10-90% D-approximately, the aqueous solution of the lactic acid of L-or racemic form.If the L-lactic acid content is higher than the content of D-lactic acid, then this solution is best suited for hair dressing composition of the present invention.Known L-lactic acid can be from specific tunning and plant extract.The aqueous solution of the L-lactic acid that is obtained by vegetable material fermentation also contains other 'alpha '-hydroxy acids sometimes.
By the way, can measure specific rotatory power by own known method in the prior art and determine the content that L-lactic acid accounts for the lactic acid total amount.The L-lactic acid content is that 60% o'clock corresponding optical purity is 20%ee.
Inorganic salt or organic salt to alpha-hydroxy carboxylic acid compounds there is no particular determination, as long as it is the salt that is formed by alpha-hydroxy carboxylic acid compounds and inorganic base and organic base.The example of salifiable inorganic base comprises hydroxide, oxide, carbonate and the bicarbonate of alkali metal or alkaline-earth metal such as sodium, potassium, lithium, calcium or magnesium.In addition, ammonium salt, particularly ammonium hydroxide or trialkyl ammonium hydroxide also are the inorganic bases that is suitable for.The example of organic base has nitrogenous base, as primary, the second month in a season or tertiary amine; The chemical compound of imido-, guanidine radicals, imidazolinyl, imidazole radicals or pyridine radicals; And aminoacid, peptide and protein.
Can use separately or shared as the alpha-hydroxy carboxylic acid compounds of composition (A) or its inorganic salt or organic salt.Content be there is no particular determination, but preferable amount is 0.05-30wt% (after this simplifies and make %).Preferred especially 0.1-10% has gloss and flexibility because of they can make hair.
The chemical compound that is suitable for work (B) composition in the present invention is for being selected from Semen Sesami, Herba Rosmarini Officinalis, Salvia japonica Thunb., Chamomile, Flos Caryophylli, Herba thymi vulgaris, Rhizoma Curcumae Longae, the leaf Herba Alii fistulosi, Herba Apii graveolentis, Radix Glycyrrhizae, Pericarpium Citri tangerinae, scutellariae,radix, Cortex Mori, phellodendron bark, Japanese captis, rose fruit, mignonettetree, the plant of Radix Paeoniae and witch hazel, or their extract or squeezing product.
When adopting the above-mentioned plant of enumerating, its leaf, root, stem, flower etc. can be cut into slices dry also fragmentation or grind.
The example of the preparation method of each plant extract comprises the method that makes extraction solution through extraction, and for example, water or hydrophilic organic solvent extract leaf, root, stem and the flower of plant, comprises that also the dry extraction solution that so obtains is to obtain the method for extract powder.The example of hydrophilic organic solvent comprises methanol, ethanol, 1,3 butylene glycol and propylene glycol.These solvents can use separately or be shared, can mix with water before using.
Adopt organic solvent such as hexane extraction Semen Sesami, or obtain Oleum sesami through squeezing, the latter can be used as component (B).
In the component that makes through said method (B), preferably through the squeezing Semen Sesami, Herba Rosmarini Officinalis extract, Radix Paeoniae Alba extract and witch hazel extract.
Component (B) can be used separately or be shared.For consideration to final products stability, when component utilized (B) when being plant, be preferably based on total composition, its dried solids content is 0.001-20%, particularly 0.01-10%, more preferably 0.05-5%.When adopt be plant extract the time, be preferably based on total composition, its dried solids content is 0.005-20%, particularly 0.01-10%, more preferably 0.05-5%.When adopt be plant component through squeezing the time, be preferably based on total composition, its dried solids content is 0.005-20%, particularly 0.01-10%, more preferably 0.05-5%.Preferred above-mentioned consumption is because can reach the fabulous impaired effect of anti-hair, the stability that can also promote plant component in the product in addition thus.
Among the present invention, but former state adopts plant extract or squeezing plant.In addition, they can be used as one-component and use, or plant extract or squeezing plant are further extracted or use with at least two kinds of mixture of ingredients behind acid or alkali classification and purification through organic solvent (for example dichloromethane, normal hexane or ethanol).These compositions be there is no particular determination, as long as can obtain by above-mentioned plant extract or squeezing plant.The example comprises purification Oleum sesami, sesamol, sesamin, carnosol, carnosic acid (carnodic acid), Herba Rosmarini Officinalis phenol (rosmanol), acetaminol, thymol (phenols essential oil composition), curcumin, Tricetin, glycyrrhizic acid, monoammonium glycyrrhizinate, glycyrrhizic acid list potassium, glycyrrhizic acid dipotassium, 18 β-glycyrrhetinic acid, glycyrrhetinic acid stearyl, carbenoxolone sodium, the anthocyanin that is shown below:
R wherein
1Be hydroxyl or methoxyl group, R
2Be H or hydroxyl or methoxyl group, and Glyc. is arabinose, glucose, galactose, flavonoid glycosides such as ougonin, baikarin or baicalein, triterpenoid such as alpha-amyrin, alkaloid such as berberine, and flavonol glucosides such as multiflorin.
In the above-mentioned composition of enumerating, preferred especially purification Oleum sesami, sesamol, sesamin, carnosol, carnosic acid and Herba Rosmarini Officinalis phenol.
These compositions can use separately or be shared, and preferably its consumption accounts for the 0.05-10% of total composition, particularly 0.1-3%.
Component in the hair dressing composition of the present invention (B) especially preferably adopts the purification Oleum sesami, Herba Rosmarini Officinalis extract, and Radix Paeoniae Alba extract and witch hazel extract are because they have the excellence effect that prevents that active oxygen from forming.
In addition, preferably in hair dressing composition of the present invention, add UV absorbent, can promote inhibitory action, improve its defence capability, and can improve hair care effect and stability active oxygen to ultraviolet radiation because of it.These UV absorbent be there is no particular determination, as long as it is the composition that is usually used in cosmetic composition.Example comprises octyl methoxycinnamate, benzophenone, benzophenone derivative, para-amino benzoic acid and benzoyl methane.Its commercially available product has: octyl methoxycinnamate " ParsolMCS " (trade (brand) name, Givaudan produces); Benzophenone derivative has 2-hydroxyl-4-methoxyl group benzophenone " Uvinul M-40 " (trade (brand) name, BASF produces), benzophenone sulfonic acid " Uvinul MS-40 " (trade (brand) name, BASF produces), benzophenone sodium sulfonate, the sodium salt of " Uvinul MS-40 "; ESCAROL 507 " Escarol 507 " (trade (brand) name, Dan Dyk produces) is arranged in the para-amino benzoic acid, and octyl triazone " Uvinul T-150 " (trade (brand) name, BASF produces); Butyl methoxydibenzoylmethise " Parsol 1789 " (trade (brand) name, Givaudan produces) is arranged in the benzoyl methane.
For reaching sufficient ultra-violet absorption effect, the consumption of UV absorbent preferably accounts for total composition 0.1-20%, preferred especially 0.2-10%.
In addition, preferably add non-volatile polysiloxanes, because of it has further improvement effect to preventing ultraviolet radiation to the damage of hair.Non-volatile polysiloxanes be there is no particular determination, as long as it is nonvolatile.The example comprises dimethyl polysiloxane, methyl phenyl silicone, polyether-modified polysiloxanes, amino modified polysiloxane, alkyl-modified polysiloxanes and alkoxy-modified polysiloxanes.
Wherein, be 1000 centistokes (cs) or dimethyl polysiloxane more than 1000 centistokes or methyl phenyl silicone, particularly 100000 centistokes or more than 100000 centistokes preferably 25 ℃ of following viscosity, the back is difficult for removing on the hair because of it sticks to.The dimethyl polysiloxane of the available before use low viscosity of this full-bodied polysiloxanes (500 centistokes or 500 centistokes are following), volatile cyclic polysiloxanes, volatility isoparaffin etc. dilute, to reduce its viscosity.
For amino modified polysiloxane, can be listed below shown in formula (5) and (6) those.
R wherein
6Be methyl or hydroxyl, R
7Be methyl or H, R
8Be alkyl amino or alkenyl amino, R
9Be hydroxyl, hydroxyalkyl, oxyalkylene group or polyoxyalkylenes, according to the difference of molecular weight, t, u and v represent integer respectively.
In the above-mentioned amino modified polysiloxane, be preferably as follows shown in the formula (7) those especially.
R wherein
8, u and v definition are as above.
The representative instance of these amino modified polysiloxanes is as shown in the formula the polymer shown in (8):
Wherein according to the molecular weight of 3000-100000, w and x represent certain integer respectively, and the mean molecule quantity of this amino modified polysiloxane is about 3000-100000.The clauses and subclauses of Amodimethikone have been described this amino modified polysiloxane in the CTFA handbook (cosmetic composition handbook/U.S.) the 3rd edition.
In the non-volatile polysiloxanes, preferred especially dimethyl polysiloxane and amino modified polysiloxane.
These non-volatile polysiloxanes can use separately or be shared.Though the consumption to non-volatile polysiloxanes there is no particular determination, preferably its consumption accounts for the 0.5-50% of total composition.Preferred especially its consumption is 1-30%, more preferably 2-10%, and this polysiloxanes has fabulous film property on hair like this, thereby can improve the defense reaction to active oxygen, and can prevent the hair drying.
The potent antioxidant vitamin that is selected from vitamin A, B, C and E and analog thereof is mixed hair dressing composition of the present invention can suppress the hair damage that active oxygen causes.The example of vitamin A comprises alpha-carotene and beta-carotene; The example of vitamin B comprises nicotinic acid, pantothenic acid and panthenol; Ascorbic example comprises ascorbic acid; The example of vitamin E comprises various tocopherols.Wherein special preferably beta-carotene, nicotinic acid, panthenol and alpha-tocopherol are because they have high antioxidant effect.Based on the consideration to its effect and stability, its suitable consumption accounts for the 0.0005-10% (weight) of total composition, more preferably 0.01-3%.
Except that mentioned component, also can add the composition that other is used for conventional hair dressing composition as required, as long as its consumption can not influence effect of the present invention.The example comprises surfactant, as cationic surfactant, and anion surfactant and non-ionic surface active agent; The higher alcohol that contains straight or branched alkyl or alkenyl; Hydrocarbon such as liquid paraffin and vaseline; Lanolin derivative such as liquid lanolin and lanolin fatty acid; Phospholipid such as lecithin; Sterol such as cholesterol and derivant thereof; The peptide derivant that collagen protein decomposes; PFPE; The ester that oils and fats such as high fatty alcohol and higher fatty acids form, higher fatty acids and contain alkyl or the long-chain amidoamines of alkenyl; Animal and plant fat such as ermine oil and olive oil; Make hair have the polymer of easy arrangement; Solvent such as alcohol, for example propylene glycol; Medicinal ingredient such as antidandruff agent and antibacterial; Antiseptic such as hydroxy benzoate class; Thickening agent such as water-soluble polymer; Coloring agent such as dyestuff and pigment; And other additive, as astringent, essence, colorant, pH regulator agent and aerosol volatilizer.
Mentioned component can be mixed, prepare hair dressing composition of the present invention according to conventional method then.For example, can be made into non-bath preparation,, and bathe with preparation such as shampoo, purificant, nursing agent and hair conditioner as hair mousse, hair oil or setting agent.
Below will further specify the present invention by embodiment.But it should be understood that following embodiment does not constitute any qualification to the present invention.In addition, among the present invention the consumption of plant extract or analogous components with dried solid content meter.Embodiment 1-6 and comparative example 1-3
Preparation has shown in the table 1 hair oil of forming, and the extent of damage, gloss and the flexibility of the hair that applies this hair oil are estimated.The results are shown in Table 1.(evaluation methodology)
Japanese experimenter's hair color (1g/5cm) is handled with each hair oil of 0.25g respectively, adopted solar simulator then through ultraviolet radiation 20 hours.Adopt the ESCA surface analysis that the degree of oxidation of treated and untreated hair surface S-S key is measured.Estimate according to following standard.Also the gloss and the flexibility of hair are carried out sensory evaluation in addition according to following standard.Evaluation criterion: the extent of damage A of (1) hair: the hair after the processing is compared with untreated hair, does not find oxidized S radix purpose difference.B: the hair after the processing is compared with untreated hair, and oxidation S radix purpose increases＜10%.C: the hair after the processing is compared with untreated hair, and oxidation S radix purpose increases 〉=10%.(2) the gloss A of hair: treated hair is more glossy than untreated hair.B: the treated hair and the gloss of untreated hair are similar.C: treated hair is poorer than untreated hair gloss.D: treated hair is compared with untreated hair, obviously tarnishes.(3) the flexibility A of hair: treated hair is stronger than the flexibility of untreated hair.B: the treated hair and the flexibility of untreated hair are similar.C: treated hair is obviously poorer than the flexibility of untreated hair.
Table 1
| Composition | Product of the present invention | Reference product | |||||||
| ????1 | ???2 | ??3 | ??4 | ????5 | ????6 | ????1 | ????2 | ??3 | |
| Glycolic | ????5 | ???5 | ??5 | ??- | ????- | ????5 | ????- | ????5 | ??- |
| L-lactic acid | ????- | ???- | ??- | ??6 | ????6 | ????6 | ????- | ????- | ??- |
| Purification Oleum sesami (the Tahaku Oleum sesami that Takemoto Oils ﹠Fats Co. produces) | ????0.5 | ???0.5 | ??0.5 | ??0.5 | ????0.5 | ????0.5 | ????0.5 | ????- | ??- |
| Methoxy cinnamic acid octyl group ester (" Parsol MCS; The Givaudan product) | ????- | ???0.5 | ??- | ??- | ????- | ????0.5 | ????- | ????- | ??0.5 |
| Amino modified polysiloxane (SM8702C; Toray Industries) | ????- | ???- | ??3 | ??- | ????3 | ????- | ????- | ????1 | ??1 |
| Dimethyl polysiloxane (viscosity 10000000 centistokes) | ????- | ???- | ??- | ??- | ????- | ????5 | ????5 | ????- | ??5 |
| Liquid paraffin,light | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus |
| The hair extent of damage | ???A | ???A | ???A | ???A | ???A | ???A | ???A | ???C | ??B |
| Gloss | ???B | ???B | ???A | ???B | ???A | ???A | ???C | ???C | ??C |
| Flexibility | ???B | ???B | ???B | ???A | ???A | ???A | ???D | ???B | ??D |
Result in the table 1 shows that hair oil of the present invention all can suppress the damage of ultraviolet radiation to hair; (%) (1) polyoxyethylene lauryl ether sodium sulphate (2EO) 12 (2) lauric acid diethyl amides 3 (3) dimethyl polysiloxanes (20000000 centistokes/100 centistokes (1/10)) 3 (4) cranberry extracts (Tokiwa Shokubutsu Kagaku Kenkyujo product) 0.2 (5) Pfansteihls (Wako Pure Chemical Indusrtries product) 5 (6) oxybenzones 0.1 (" Unvinul M-40 ", trade (brand) name of and has gloss and flexibility preferably through the hair of its nursing. embodiment 7 (shampoo composite) (composition); BASF produces), (7) diglycol stearate 2, (8) sodium hydroxide is an amount of, (9) essence is an amount of, (10) antiseptic is an amount of, (11) purified water surplus, (preparation method)
With said components (1)-(11) uniform mixing, 75 ℃ of cool off then under, the shampoo composite of gained has pearlescent appearance.Embodiment 8 (conditioner composition) are is (1) cetyl stearyl trimethyl ammonium chloride 2 (cetostearyltrimethylammonium chloride) (2) hexadecanol 2 (3) witch hazel extracts (Ichimaru Pharcos Co. (%) (composition), Ltd. (4) octyl triazone (" Unvinul T-150 ", trade (brand) name " the U.S. 0.2 continent Radix Hamamelidis Mollis liquid " of Chu Pining); BASF produces) an amount of (10) the purified water surplus (preparation method) of an amount of (8) colouring agent of 0.2 (5) glycolic, 5 (6) butylated hydroxytoluenes, 0.1 (7) hydroxyethylcellulose (C.I. edible green 3) an amount of (9) anticorrisive agent
With said components (1)-(11) uniform mixing, cool off then under 80 ℃, the hair conditioner composition of gained is a paste.Embodiment 9 (hair mousse) (composition) is (1) dimethyl polysiloxane (1000000 centistoke) 3 (2) octamethylcy-clotetrasiloxanes 10 (3) scutellariae,radix extracts (Iwase Cosfa Co, " the scutellariae,radix extract " that .Ltd produces) 10 (4) ESCAROL 507 (" Escarol 507 " (%); Dan Dyk produces) 0.1 (5) tartaric acid 5 (6) glycerol, 2 (7) non-ionic surface active agents (" Emanone CH80 "; KAO. Corp. SA produces) an amount of (10) purified water surplus (11) normal butane 7 (preparation methoies) of 2 (8) ethanol, 15 (9) essence
Said components (1)-(10) are mixed.In the emulsified body fill gas colloidal sol bottle with gained, install valve then additional.Then component (11) is added in the bottle, obtain hair mousse. (%) (1) dimethyl polysiloxane (2000000 centistokes/100 centistokes (1/10)) 10 (2) glycerol 1 (3) purification Oleum sesami (" Tahaku Oleum sesami ", trade (brand) name of embodiment 10 (hair spray (hair mist)) is (composition); 5Takemoto Oils ﹠ amp; Fats produces) an amount of (10) the purified water surplus (preparation method) of an amount of (9) anticorrisive agent of an amount of (8) essence of (4) cetyl stearyl trimethyl ammonium chloride 0.5 (5) malic acid 5 (6) ethanol 5 (7) NaOH (pH adjusting agent)
Said components (1)-(10) are mixed.The emulsified body of gained is charged in the hair spray container, obtain hair spray. embodiment 11 (shampoo composite) (composition) is (1) polyoxyethylene lauryl ether sodium sulphate (2EO) 8 (2) polyoxyethylene lauryl ether sulfuric acid triethanolamines 3 (3) lauric acid diethyl amides 4 (4) dimethyl polysiloxanes (20000000 centistokes/100 centistokes 1/10) (%)) 3 (5) amino modified polysiloxane (" SM8702C ", trade (brand) names; Toray Industries goes out 0.2 product) an amount of (13) the purified water surplus (preparation method) of (6) Rosmarinus officinalis extract an amount of (12) anticorrisive agent of an amount of (11) essence of (Iwase Cosfa Co., " Rosmarinus officinalis extract " that Ltd. produces) 0.2 (7) Pfansteihl (Wako Pure Chemical Indusrtries product), 5 (8) panthenols (BASF product), 0.1 (9) diglycol stearate, 2 (10) NaOH
With said components (1)-(13) uniform mixing, cool off then under 75 ℃, the shampoo composite of gained has pearlescent appearance.Embodiment 12 (hair rinse agent compositions) (composition) is (1) cetyl stearyl trimethyl ammonium chloride 2 (2) hexadecanols 2.5 (3) propylene glycol 3 (4) witch hazel extracts (Ichimaru Falcos Co. (%), " the America gold thread 0.2 prunus mume (sieb.) sieb.et zucc. liquid " of Ltd. producing) (5) octyl triazone (" Uvinul T-150 ", trade (brand) name; BASF produces) 0.2 (6) AHA
* 1(COSMETOCHEM AG product) 10, (7) dimethyl polysiloxane, (20000000 centistokes/100 centistokes, (1/10)) 0.5, (8) vaseline 0.5, (9) essence is an amount of, (10) purified water surplus, (preparation method)
With said components (1)-(10) uniform mixing, cool off then under 80 ℃, the hair rinse agent compositions of gained is a paste.* 1: contain 23.5% lactic acid, 2.5% glycolic and 0.1% tartaric acid.
Each hair dressing composition of finding embodiment 7-12 gained all can prevent the hair damage that causes because of ultraviolet radiation, and can make hair have good gloss and flexibility.
Claims (8)
1. hair dressing composition comprises following composition (A) and (B):
(A) at least a chemical compound that is selected from alpha-hydroxy carboxylic acid compounds and inorganic salt and organic salt; With
(B) kind of plant, be selected from Semen Sesami, Herba Rosmarini Officinalis, Salvia japonica Thunb., Chamomile, Flos Caryophylli, Herba thymi vulgaris, Rhizoma Curcumae Longae, leaf Herba Alii fistulosi, Herba Apii graveolentis, Radix Glycyrrhizae, Pericarpium Citri tangerinae, scutellariae,radix, Cortex Mori, phellodendron bark, Japanese captis, rose fruit, mignonettetree, Radix Paeoniae and witch hazel, or their extract or squeezing product.
2. the hair dressing composition of claim 1, wherein component (B) is to be selected from Semen Sesami, Herba Rosmarini Officinalis, the plant of Radix Paeoniae and witch hazel, or their extract or squeezing product.
3. claim 1 or 2 hair dressing composition, wherein component (A) is for being selected from citric acid, lactic acid, one or more materials in glycolic and tartaric acid and inorganic salt thereof and the organic salt.
4. claim 1 or 2 hair dressing composition, wherein component (A) is for being selected from one or more materials in lactic acid and glycolic and inorganic salt and the organic salt.
5. claim 1 or 2 hair dressing composition, wherein component (A) is lactic acid or its inorganic salt or organic salt, L-lactic acid is more than D-lactic acid in the lactic acid.
6. the hair dressing composition of claim 5, wherein the content of L-lactic acid accounts for the 60-100% of lactic acid total amount.
7. each hair dressing composition among the claim 1-6 wherein also contains the UV absorbent that is selected from methoxy cinnamic acid octyl group ester, benzophenone, benzophenone derivative, para-amino benzoic acid and benzoyl methane.
8. each hair dressing composition among the claim 1-7 wherein also contains non-volatile polysiloxanes.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP109276/97 | 1997-04-25 | ||
| JP109276/1997 | 1997-04-25 | ||
| JP10927697 | 1997-04-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1200265A true CN1200265A (en) | 1998-12-02 |
| CN1124838C CN1124838C (en) | 2003-10-22 |
Family
ID=14506072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 98115141 Expired - Fee Related CN1124838C (en) | 1997-04-25 | 1998-04-24 | Hair cosmetic composition |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN1124838C (en) |
| TW (1) | TW520991B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100446751C (en) * | 2005-05-18 | 2008-12-31 | 天津医科大学总医院 | Protective agent and hair dye of anti irritability from hair dye, and method |
| CN104434624A (en) * | 2014-11-08 | 2015-03-25 | 安徽富泰发饰文化股份有限公司 | Efficient shampoo |
| CN105813694A (en) * | 2013-10-16 | 2016-07-27 | 传统医疗保健有限公司 | Use of a composition for the pigmentation of hair and hairs |
-
1998
- 1998-04-10 TW TW87105455A patent/TW520991B/en not_active IP Right Cessation
- 1998-04-24 CN CN 98115141 patent/CN1124838C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100446751C (en) * | 2005-05-18 | 2008-12-31 | 天津医科大学总医院 | Protective agent and hair dye of anti irritability from hair dye, and method |
| CN105813694A (en) * | 2013-10-16 | 2016-07-27 | 传统医疗保健有限公司 | Use of a composition for the pigmentation of hair and hairs |
| CN104434624A (en) * | 2014-11-08 | 2015-03-25 | 安徽富泰发饰文化股份有限公司 | Efficient shampoo |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1124838C (en) | 2003-10-22 |
| TW520991B (en) | 2003-02-21 |
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