TW520991B - Hair cosmetic composition containing plant ingredient - Google Patents

Abstract

The present invention relates to a hair cosmetic composition comprising (A) an Α-hydroxycarboxylic acid or salt thereof; and (B) a plant selected from the group consisting of sesame, rosemary, sage, chamomile, clove, thyme, turmeric, green onion, celery, licorice, blueberry, scutellatia root, mulberry bark, phellodendron bark, Japanese captis, rose fruit, henna, paeonia or witch hazel, or an extracted or pressed-product thereof. The hair cosmetic composition according to the present invention can prevent hair from damages such as dry hair or changes in color and impart glass and flexibility to the hair.

Description

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 520991 V. Description of the Invention (1. Invention Funeral The present invention relates to a hair pellet composition that protects hair from bruising, such as exposure to sunlight or ultraviolet radiation Under the conditions of shampooing, combing, high temperature of hair dryer, or dry hair or color change caused by hair dye or bleach; and can make hair shiny and elastic. 2. Relevant technical description of hair often exposed to various environmental conditions Down. When exposed to ultraviolet light, low humidity air or high temperature, the hair tends to be damaged, and becomes dry or reddish brown. At this time, the surface of the hair is considered to be oxidized by active oxygen. It has been found Among various environmental factors, ultraviolet radiation is an important factor that generates active oxygen. To prevent such hair damage, for example, a hair cosmetic composition containing highly polymerizable monomethyl polysiloxane and benzophenone (Japan Patent Laid-open Application No. HEI 4-224508) as an ultraviolet radiation inhibitor; and contains high molecular weight silicone and antioxidants Chemical cosmetics for hair (Japanese Patent Laid-Open Application No. HEI 1-211515). However, from the viewpoint of preventing damage, the above-mentioned hair cosmetic compositions are not satisfactory, although they can prevent The hair is dry, but the luster or elasticity of the hair is not improved by the treatment, and it is even worse than the luster or elasticity of the hair before the damage. Therefore, one of the items of the present invention is to provide protection for hair from A cosmetic composition for hair that is damaged by ultraviolet rays or the like, and can improve the gloss and elasticity of the hair. -4-This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm)

(Please read the notes on the back before filling in this page. J «I clothing, 3 520991 V. Description of the invention (3 acids, tartaric acid and ethylene glycol _ 'and its inorganic and 4 salts, t particularly preferred is lactic acid and China Acetic acid, and its inorganic and organic salts, because it can improve the elasticity of hair. The best is lactic acid containing more L-lactic acid than 0_ lactic acid, and its inorganic and organic salts. More particularly, the content of L_lactic acid is the total The amount of lactic acid is between 100% and lactic acid of its inorganic and organic salts, because it can improve the elasticity of hair. A better content of L-lactic acid is 85 to 100% of the total lactic acid, and 'Grand Temar 100 % Content. In the present invention, the optimal lactic acid has 100% L _ lactic acid content content: pure L-lactic acid will gradually racemize with time and become about 85% L-lactic acid with about 15 % D _ Balanced mixture of lactic acid. This mixture can also be used in the hair granulation product combination 2 of the present invention, and lactic acid can be obtained by containing about 10 to 90% of D, L or racemic form of lactic acid in water. If the L-lactic acid content is greater than the D_lactic acid content, the solution is most suitable for use in the present invention In hair cosmetic composition. It is known that lactic acid can be obtained from specific fermentation and plant extracts. Aqueous L_lactic acid can be obtained from the fermentation of plant materials that sometimes contain other carboxylic acids. Printed ------ r --- I clothes! C Please read the notes on the back JI before filling out this page. J Incidentally, the content of L-lactic acid in the total lactic acid content can be used in nature. It is known by measuring the optical rotation rate. 60% content is equivalent to 20% ee of L lactic acid (optical rotation yield). There is no specific limit imposed on the inorganic or organic salt of the α-hydroxycarboxylic acid, as long as it is The salt formed by the reaction of α-hydroxycarboxylic acid with an inorganic or organic base is sufficient. Examples of the inorganic base forming the salt include hydroxides, oxides of alkali metals or alkaline earth metals (such as sodium, potassium, lithium, calcium or magnesium), Carbonate and -6- This paper size applies to Chinese National Standard (CNS) mm) 520991 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (5) In the ingredient (B) obtained by the above method To suppress sesame Rosemary extract, peony extract and witch hazel extract are preferred. Ingredient (B) can be used alone or in combination. When using plants as ingredient (B), according to the stability of the ingredient (B) in the final product, The dry solids are preferably incorporated in an amount of 0.001 to 20%, more preferably 0.01 to 10%, and more particularly 0.05 to 5% of the total composition. When using plant extracts, it is preferable to use total The dry solid content is 0.005 to 20% of the composition, more preferably 0.01 to 10%, and even more preferably 0.05 to 5%. When using pressed plant material, it is preferable to use 0.005 to 20 of the total composition. %, More preferably from 0.001 to 10%, more preferably from 0.05 to 5%, as the dry solid component. The addition amount in the above range is better because it can produce excellent anti-damage effect. In addition, the stability of the plant material in the product can be increased. In the present invention, existing extracted or pressed plants can be used. Alternatively, after further extracting the extracted or pressed plant with an organic solvent (such as dichloromethane, n-hexane or ethanol), it can be used as a single component or a mixture of at least two components, or subjected to acid or alkali fractionation, Then purified. There are no specific restrictions imposed on such ingredients from the aforementioned extracted or compressed products. Examples include purified sesame oil, sesanol, sesame, camozole, canodic acid, rosman〇1, eugenol, thymol (phenol-based essential oil component), curcumin, quercetin, glycyrrhizic acid, monoammonium glycyrrhizinate, glycyrrhizin Monopotassium, dipotassium glycyrrhizinate, 18β-glycyrrhizinic acid, stearyl glycyrrhizinate vinegar, raw gastric ketone ketone, anthocyanin with the following formula: glycosides: -8-This paper size applies to Chinese National Standard (CNS) A4 Specifications (210X 297 mm) „;-(Please read the notes on the back before filling this page), -srai 520991 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 5. Invention Description (7) BASF products ), "Divinyl sulfonate and sulfonic acid" Uvind MS-4〇, (product name: βα ^ products) 'Sodium benzophenone sulfonate "Uvinul MS-4〇, sodium salt; in p-aminobenzoic acid "Escarol 507" (product name; product of Dan Dyk) and "Uvinul τ · 15〇" (product of "basf product") of p-dimethylaminobenzoic acid; and benzamidine methane Of butylmethoxydibenzoylmethane

Parsol 1789 (Product name: Givaudan product). In order to obtain a sufficient ultraviolet absorbing effect, the preferred amount of the ultraviolet absorber added is from 0.1 to 20%, more preferably from 0.2 to 10%, of the total composition. Moreover, the addition of non-volatile silicone is preferred because it has a better improvement in avoiding damage from ultraviolet radiation. There is no specific restriction imposed on the nonvolatile silicone 'as long as it is nonvolatile. Examples include dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, amine-modified silicone, alkyl-modified silicone, and alkoxy-modified silicone. Among them, at 25 C, the viscosity is 1000 cs or higher, more preferably 100,000 cs or higher, dimethylpolysiloxane or methylphenylpolysiloxane is preferred because After adhesion, it will not easily separate from the hair. It can be diluted with low viscosity (500 cs or lower) monomethylpoly; acetone, volatile cyclic lithone, volatile isoparaffin or the like to reduce the viscosity and then use this high viscosity silicone 0 As the amine-modified crushed ketone, an example is one having the following formula ⑶ or ⑹ 0 -10- This paper size applies the Chinese National Standard (CNS) A4 specification (21 Ox 297 mm) ----- Γ- -^-I-- (Please read the notes on the back before filling out this page} • 订 I order 520991 A7 B7 V. Description of the invention (8 R6 R6. Ch3 -SiOI CH, C »3 -SinI C [l3

Sin I R9

ClhI Sin · I, Sin- (Please read the notes on the back before filling out this page) where R6 represents methyl or hydroxyl, R7 represents methyl or fluorene atom, R8 represents amine or enamine, and R9 represents hydroxyl, Hydroxyalkyl, oxyalkylene, or polyoxyalkylene, and t, u, and v each represent an integer that depends on the molecular weight. Among the above-mentioned amine-modified zhenones, those having the following general formula are more preferable. H0 ch3 -SiOI CH,

OilI SiO (7) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ¥ water where R8, u and v have the same meaning as defined above. A general example of such an amine-modified silicone is a polymer having the following formula: 11-This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 520991 A7 B7 V. Description of the invention (9 H0 ch3 • Sit) I CH,

(III

Sin (CH ^ I NilI m? (8); Member of the Ministry of Economic Affairs Standards Bureau, M Consumer Cooperative, where W and X are independent representations that depend on integers ranging from 3,000 to 100,000 molecular weight, and the average molecular weight is about 3,000 to 100,000. This amine-modified silicone is described in the CTFA Dictionary (USA) 3rd Edition under the name Amodimethikone. As a non-volatile silicone, dimethylpolysiloxane and amine-modified silicone are used. Ketones are more preferred. This non-volatile silicone can be used alone or in combination. Although there is no specific limit imposed on the amount of non-volatile silicone to be used, the preferred addition amount is 0.5 to 50% of the total composition In particular, by adding 1 to 30% I, more preferably 2 to 10%, the silicone exhibits excellent film-forming properties on the hair, thus improving the protection of the hair from active oxygen and preventing dry hair When strong antioxidant vitamins are selected from vitamins A, b, c, and E, and their analogs are incorporated into the hair cosmetic composition of the present invention, it is possible to inhibit 2 active oxygen-induced hair damage. Vitamin Eight True Examples include α_ = lutein and β-carotene; examples of vitamin B include nicotinic acid, pantothenic acid, and pan-12. · This paper size applies Chinese national standard ~ (CNS) A4 specification (210X 297) (please first Read the notes on the reverse side and fill out this page) Order '__ 520991 A7 _______ B7 V. Description of the invention (10) Alcohol; Examples of vitamin c include ascorbic acid; Examples of vitamin E include various; tocopherol. Among them, it is more preferred It is carotene, nicotinic acid, panthenol and α-tocopherol because it has a high antioxidant effect. From the standpoint of its effect and stability, it is preferred to add the amount of 0.0005 of the total composition To 10% by weight, and more preferably 0.01 to 3%. Printed by the Consumer Cooperatives of the Central Bureau of quasi-Ministry of Economic Affairs (please read the precautions on the back before filling this page) In addition to the above ingredients, if necessary, you can To the extent that the benefits of the present invention are not compromised, the ingredients used in conventional hair cosmetic compositions are incorporated. Examples include surfactants, such as cationic surfactants, anionic surfactants, and non-ionic surfaces Alkyl or alkenyl containing high carbon number alcohols; hydrocarbons, such as liquid paraffins and petrolatum; lanolin derivatives, such as liquid lanolin and lanolin fatty acids; phospholipids, such as lecithin; solids, such as cholesterol And its derivatives; collagen-degraded peptide derivatives; perfluoropolyethers, oils and fats, such as high carbon number alcohols and high carbon number fatty acids, high carbon number fatty acids M 3 alkyl or alkenyl amidoamines Acting esters; animal or vegetable oils and fats, such as mink oil and olive oil; polymerizing and dissolving hair that makes the hair treatable, such as alcohol (for example, propylene glycol); drugs, such as anti-dandruff and antiseptics; disinfectants , Such as parabens; thickeners, such as water-soluble polymer 2, coloring substances, such as dyes and pigments; and other additives, such as astringency training, perfumes, colorants, pH regulators and aerosol propellants. The cosmetic composition for hair according to the present invention can be prepared by mixing the above-mentioned ingredients according to a conventional method. For example, it can be used in external baths (secret b, agent (= Shuofa foam latex or styling agent) and internal baths (Huaqizhan tincture (such as shampoos, tinctures, essences, treatment fluids, and hair conditioners) This model is obtained in more detail through the following examples. However, it should be kept in mind that --- --- -13-Ben's scale is applicable to the Chinese National Standard (cns). Printed by the Central Bureau of Standards of the People ’s Consumer Cooperatives t A7 _______ B7 ....... ........——————- V. Description of the Invention (11) The present invention is not limited to the following examples. Incidentally, the amount of the plant extract of the present invention or the like is expressed in terms of dry solid content. Examples 1 to 6 and Comparative Examples 1 to 3 A hair oil having the composition shown in Table 1 was prepared and evaluated for application After this hair oil, the degree of stubbornness, luster and elasticity of the hair are shown in Table 1. (Evaluation method), A Japanese black hair (丨 g) cm was treated with 0.25 g of various hair oils ), And then exposed to the ultraviolet rays of the solar simulator for 20 hours. The treated and untreated heads The degree of oxidation of the s_s bond on the surface is determined by the ESCA surface analysis method. 评估 The evaluation is performed according to the following standards. In addition, the functional evaluation of the gloss and elasticity of the hair is performed according to the following standards. Evaluation criteria: (1) Hair damage degree A · There is no difference between the oxidized s base of treated hair and untreated hair. B: Compared with untreated hair, the "oxidized" number of the treated hair shows < 10% increase. C: Compared with untreated hair, the treated The base of hair oxidation 8 base increase> 10% increase. '/, (2) Hair gloss: A: Treated hair is more lustrous than untreated hair. B · The luster of treated hair is similar to untreated hair. c: The luster of treated hair is lower than that of untreated hair. D: Compared with untreated hair, treated hair clearly loses its luster. -14-This paper is a national standard (财-一 --- (please first Read the notes on the back and fill in this page) -1¾. —Order '-. 520991 A7 B7 2 15 qs Difference 7 10 1 V. Description of the invention (15) (6) Glycerin 2 ⑺Nonionic surfactant (,,, Eman〇ne CH8〇 "; Kao

Products of Corporation) (8) Ethanol (9) Perfume (10) Pure water (11) n-butane (manufacturing method) Mix the above ingredients (1) to (10). The thus-obtained emulsion was packed in an aerosol bottle, followed by a valve. Then, the ingredient (11) was packed in a bottle, whereby a hair foam latex was obtained. Example 10 (Aerosol) (ingredients) (1) dimethyl polysiloxane [2 million cs / 100 cs (1/10)] ⑺ glycerin ⑶ pure sesame oil (" Tahaku sesame oil ,,, product name; ( (Please read the precautions on the back before filling out this page) • Suspected clothing _ Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

Product of Takemoto Oil Co., Ltd.) 5 ⑷Ceto stearyl 醯 trimethylammonium chloride 0.5 ⑶malic acid 5 (6) ethanol 5 钠 sodium hydroxide (pH adjuster) qs ⑻perfume qs ⑼disinfectant qs -18- This paper standard Applicable to China National Standard (CNS) A4 specification (210X 297mm) 520991 A7 B7 V. Description of the invention (16) (10) Pure water is poor (manufacturing method X mixes the above ingredients ⑴ to (10). The emulsion thus obtained is packed in An aerosol was obtained in a mist container. Example 11 (Shampoo Composition) (ingredients) (1) Poly (ethylene oxide) sodium lauryl sulfate (2EO) (%) (2) Poly (ethylene oxide) lauryl ether Triethanolamine sulfate 8 (3) Diethanolamine laurate 3 Dimethylpolysiloxane 4 [20 million cs / 100cs (l / 10)] 3 (5) Amine-modified silicone (`` SM8702C , ', Product name; TorayIndustries products) 0.2 (Please read the notes on the back before filling out this page) Order. Printed by the Consumer Standards Cooperative of the Ministry of Standards (6) Rosemary Extract (`` Rosemary Extract ''; Product of Iwase Cosfa Co., Ltd.) 0.2 (7) L-lactic acid (Wako Pure Chemical Indu Product of Stries Co., Ltd.) 5 (8) Panthenol (product of BASF) 0.1 (9) Ethylene glycol distearate 2 (10) Sodium hydroxide qs (11) Perfume qs · (12) Disinfectant qs ( 13) Pure water balance (manufacturing method) -19- This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) Notice 1 象 ii Application date 87. 4. 10 ～ Case number 87105455 The category palm is filled by this bureau ） Chinese manual revision page every year 丨 丨 month) A4 C4 520991 Invention

Ministry of Economic Affairs ^ 2: 4 ^ only 'Gongnafei Cooperative Co., Ltd. Printed Invention I. New Name Chinese Plant-Based Hair Cosmetic Composition with English Names 1, fHAIR COSMETIC COMPOSITION CONTAINING PLANT INGREDIENT " Name Sakamoto Yuichi Invention, One 、 People create nationality Japan 'Residence, residence ^ * ^ · --- Name (name) in Kao Co., Ltd., 2-2-3 Bunka, Sumida-ku, Tokyo, Japan ——---- ~~ --- -------- ^ * Nissho Kao Co., Ltd. Nationality Japanese Version III. Applicant's residence and residence (office) Japanese nationality, Tokyo, Chuo-ku, Chuo-ku, Tokyo, Japan Applicable 1 Representative name Goto Takuya -1-Factory Two ..._______, nn: C ^ X ----—____ IT equipment 520991

Replacement page for Chinese specification of Patent Application No. 087105455 (December 91) a? -------------- B7 V. Description of the invention (2) Summary of the invention: The invention of this invention Authors have conducted extensive research. Therefore, it has been found that by using α_ # 基 可 with a specific plant or a combination of extracts or compression products thereof, the present invention can be used to suppress hair damage (such as color change caused by active oxygen) and improve hair gloss or elasticity. Granulated hair composition. Therefore, one aspect of the present invention is to provide a granulated hair product composition containing the following ingredients (A) and (B): () the soil species is selected from the group consisting of compounds containing kicidic acid, and inorganic and organic salts thereof; and (B ) —Species selected from the group consisting of sesame, rosemary, sage, chamomile, lilac tree's thyme, coriander, green syringa, sprouts, licorice, blueberry, yellow tea root, vermilion bark, male bark, Japanese Captis, rose fruit, henna, peony or witch hazel, or a plant derived from it or pressed. The cosmetic composition for hair according to the present invention can protect the hair from damage such as loss of water, surface oxidation or color change, and make the hair shiny and elastic. Preferred specific example f_Heart In the present invention, the heart hydroxycarboxylic acid as component (eight) has! A single or multiple carboxylic acids of one or more hydroxypeptyl groups. At least one hydroxyl functional group has been introduced at the alpha position of the acid (the carbon is adjacent to the carboxyl functional group). Examples of such compounds <Examples include citric acid, lactic acid, methyl lactic acid, phenyl lactic acid, malic acid, mandelic acid, glycolic acid, propionic acid, tartaric acid, and gluconic acid. It is also possible to use its inorganic or organic salts. Among them, citric acid and milk are preferred.

520991 Patent Application No. 087105455 Patent Replacement Page of Chinese Manual (December 91) A?

Bicarbonates. In addition, ammonium salts, especially amines, ammonium can be used as "free". Can provide ^^^ or tertiary hydroxide tertiary amine), containing imine group, venyl group, == and f 'secondary amines or stubborn ... * Not the main combination of forest or imidazolyl, human amine Peptides and proteins are examples of organic bases. The α-light citrin can be used singly or in combination with an inorganic or organic salt thereof as a saccharine. Although there is no specific limitation imposed on the use amount, it is preferred (addition amount is 0.05 to 30% by weight (hereinafter simply referred to as%). The addition amount of 2 to 1G% is more preferable because such an addition amount can Makes hair shiny and elastic. Compounds that can be used as ingredients in the present invention are selected from the group consisting of sesame, rosemary, timothy, chamomile, lilac, thyme, turmeric, green onion, cattail, licorice, M, yellow Tea root, mulberry bark, sassafras bark, Japanese captis' rosehip tree, henna, peony or witch hazel, or extracted or pressed product. When using the above example plant, its leaves, rhizomes , Flowers and the like are cut into pieces, dried, and then split into pieces or mashed. Examples of processing to obtain various plant extracts include extraction using water or hydrophilic: organic solvents, for example. Plant leaves, roots, stems and flowers A method for obtaining an extract / cereal, and a method for drying the extract solution to obtain an extract powder. Examples of the hydrophilic organic solvent include methanol, ethanol, 3, butanediol, and propylene Alcohol. These solvents can be used alone or in combination. These solvents can be used after mixing with water. Sesame is extracted with an organic solvent (such as hexane) or pressed to obtain sesame oil 'which can be used as ingredient (B). 520991 No. 087105455 Replacement page of Chinese specification of patent application (December 91) V. Description of invention (6)

Wherein R1 represents a hydroxyl group or a methoxy group, R2 represents a hydrogen atom or a hydroxyl group or a methoxy group, and Glyc represents arabinose, glucose or galactose, a flavonoid glycocalyx (e.g., ougonin, begaring, or berberin), a triterpene Compounds (such as α-Elemantine. Essence), alkaloids (such as berberine) and flavanol glycosides (such as polyflorin). Among the above-mentioned example ingredients, purified sesame oil, sesame alcohol, zemamine, camozole, camodilic acid, and rosmanol are particularly preferred. These ingredients can be used alone or in combination, and the preferred addition amount is 0.05 to 10%, more preferably 0.1 to 3% of the total composition. As the component (B) in the hair cosmetic composition of the present invention, purified sesame oil, rosemary extract, peony extract, and witch hazel are particularly preferable because they can produce an excellent effect of preventing the formation of active oxygen. In addition, it is preferable to add an ultraviolet absorbent to the hair cosmetic composition of the present invention because it can increase the effect of suppressing ultraviolet radiation, improve the ability to prevent active oxygen, and bring improvements in hair care effect and stability. There are no specific restrictions imposed on such an ultraviolet absorber, as long as it can usually be used in a cosmetic composition. Examples include octyl methoxycinnamate, benzophenone, benzophenone derivatives, p-aminobenzoic acid, and benzoylmethane. Its commercially available products are as follows: nPai * sol MCSn (octyl methoxycinnamate) (product name; product of Givaudan) · 2-hydroxy-4-methoxybenzophenone in benzophenone derivatives Ketone "Uvinul Μ-40π (Product name: -9-This paper size applies to China National Standard (CNS) Α4 specification (210 X 297 mm)

Outfit-玎

520991 Patent Application No. 087105455 Patent Replacement Page of Chinese Manual (December 91) A7 B7 V. Description of Invention (12) (3) Hair elasticity A: Treated hair is more elastic than untreated hair. B: The elasticity of treated hair is similar to that of untreated hair. C: The elasticity of treated hair is clearly inferior to that of untreated hair. Table 1

Ingredient invention product comparison product 1 2 3 4 5 6 1 2 3 Hydroxyhexanoic acid 5 5 5? 5 5 L-lactic acid • 6 6 6 1 pure sesame oil (Tahaku sesame oil; product of Takemoto Oil Co., Ltd.) 0.5 0.5 0.5 0.5 0.5 0.5 0.5--Octyl methoxycinnamate (Parsol MCS; Givaudan product)-0.5---0.5--0.5 Amine modified silicone (SM8702C; Toray Industries)--3-3--1 1 Dimethyl Polysiloxane (viscosity: 100,000 CS)-----5 5-5 Light liquid paraffin balance difference balance difference balance difference hair damage degree AAAAAAA c B gloss BBABAAC c C elastic BBBAAADBD -15- this The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 520991, IL ·? ^ Patent Application No. 087105455 丨 Replacement page of the Chinese manual (December 91) A7…, 5. Description of the invention (13 From the results in Table 1, it can be found that the hair oils according to the present invention can each protect the hair from damage caused by ultraviolet radiation, and the hair treated with it has good gloss and elasticity. Example 7 (shampoo composition) (ingredients) (%) (1) polyoxyethylene lauryl ether sodium sulfate (2EO) 12 (2) diethanolammonium laurate (3) dimethyl polysiloxane 3 [20 million cs / 100 cs cl / 10)] (4) Blueberry extract (product of Tokiwa Shokubutsu Kagaku 3 Kenkyujo) 0.2 (5) L lactic acid (product of Wako Pure Chemical Indusrtries) (6) 2 -hydroxy- 4-Methoxybenzophenone 5 ('' UnvinulM-40 &quot;, trade name; product of BASF) 0.1 (7) ethylene glycol distearate 2 (8) sodium hydroxide qs (9) perfume qs ( 10) Disinfectant qs (11) Pure water (manufacturing method) The balance of the above ingredients (1) to (11) is uniformly mixed at 75 ° C, so a shampoo composition is obtained in a bead form. Example 8 (Adjuster composition) (ingredients) -16-combined, and then the paper size of the cold paper applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 520991 Patent Application No. 087105455 Chinese Specification Replacement Page (91 December, 2014 g. Description of the invention (14) (1) Cetylstearate trimethylammonium chloride 2 Cetyl alcohol 2 (3) Witch hazel extract (π witch hazel liquid); Ichimaru Pharcos Ltd. products) 0.2 (4) Octyltriazinone ('TJvinul T-150 ", trade name; product of BASF) 0.2 (5) glycolic acid 5 (6) butylhydroxytoluene 0.1 (7) hydroxyhexyl cellulose qs (8) Colorant (CI · Food Green 3) qs (9) Disinfectant qs CIO) Pure water balance (manufacturing method) At 80 ° C, uniformly mix the above ingredients ⑴ to (11), and then cool, so, A hair conditioner was obtained in a creamy form. Example 9 (hair foam latex) (ingredients) (%) (1) dimethyl polysiloxane (1 million cs) 3 (2) octamethylcyclotetrasiloxane 10 (3) yellow tea extract ( &quot; Scutellaria extract "; product of Iwase Cosfa Co., Ltd.) 10 (4) p-dimethylaminobenzoic acid (" Escarol 507 "; product of Dan Dyk) 0.1 (5) tartaric acid 5 -17-this paper Applicable to China National Standard (CNS) A4 (210X 297mm)

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k 520991 Patent Application No. 087105455 Patent Replacement Page (December 91) V. Description of the invention (17) At 75 ° C, the above ingredients (1) to (13) are uniformly mixed, and then cooled, so the obtained Bead-type shampoo composition. Example 12 (Conditioner composition) (ingredient) (%) (1) Cetostearyl trimethylammonium chloride 2 (2) Cetyl alcohol 2.5 (3) Propylene glycol 3 (4) Witch hazel extract ( '' Witch hazel extract '': Product of Ichimaru Falcos Co., Ltd.) 0.2 (5) Octyl Uvinul T-150 ”; Product of BASF) 0.2 (6) AHA + 1 (Product of COSMETOCHEM AG) 10 (7) Dimethylpolysiloxane [20 million cs / 100cs (l / 10)] 0.5 (8) Vaseline 0.5 (9) Perfume qs (10) Pure water balance (manufacturing method) At 80 ° C, uniformly mix the above ingredients ⑴ to (10), and then cooled, so that a cream conditioner composition was obtained) | 0 * 1: Contains 23.5% lactic acid, 2.5% glycolic acid and 0.1% tartaric acid. Examples 7 to 12 were found. Each of the obtained hair cosmetic compositions can protect the hair from damage caused by ultraviolet rays, and make the hair have good gloss and elasticity. -20- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) )

Claims (1)

520991 Drama η Patent application No. 087105455 g _ Chinese application for replacement of the patent scope (December 1991, patent application scope 1. A hair cosmetic composition containing plant ingredients, which contains the following ingredients (A) and (B ): (A) 0.5 to 30% by weight of one or two or more selected from light acetic acid, lactic acid, mineral fruit acid, inorganic salts and organic salts thereof; and (B) 0. 〇〇1〜 20% by weight of a plant selected from the group consisting of sesame, rosemary, sage, chamomile, thyme, blueberry, Poria cocos, peony and witch hazel, and its extracted or pressed product. 2. According to item 1 of the scope of patent application The cosmetic composition for hair containing plant-based ingredients, wherein the component (A) is lactic acid, or an inorganic or organic salt thereof, and the lactic acid contains more L-lactic acid than D-lactic acid. 3. According to the second item of the scope of the patent application Plant-containing hair cosmetic composition, wherein the content of the L-lactic acid ranges from 60 to 100% of the total lactic acid. 04. The plant-containing hair cosmetic composition according to item 1 of the patent application scope, which further contains Selected from octyl methoxycinnamate, diphenyl It is the same as the benzophenone derivative, p-aminobenzoic acid and benzamyl methane ultraviolet absorber. 5. The cosmetic composition for hair containing plant-based ingredients according to item 1 of the patent application scope, which still contains Non-volatile syringone. This paper size it s $ material (CNS) A4 secret (⑽χ 297 公 澄): ----------