CN1199332A - Hair treatment composition - Google Patents

Hair treatment composition Download PDF

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Publication number
CN1199332A
CN1199332A CN 96196810 CN96196810A CN1199332A CN 1199332 A CN1199332 A CN 1199332A CN 96196810 CN96196810 CN 96196810 CN 96196810 A CN96196810 A CN 96196810A CN 1199332 A CN1199332 A CN 1199332A
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CN
China
Prior art keywords
acid
hair
treatment composition
composition
total composition
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Pending
Application number
CN 96196810
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Chinese (zh)
Inventor
B·菲丝
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Kao Corp
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Kao Corp
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Publication date
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Application filed by Kao Corp filed Critical Kao Corp
Publication of CN1199332A publication Critical patent/CN1199332A/en
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

A hair treatment composition based on water or a water/alcohol mixture comprising (a) at least 0.01 wt.% of lactic acid, (b) at least 0.01 wt.% of citric acid, and (c) at least 0.01 wt.% of pyrrolidonecarboxylic acid. This composition gives gloss, capability of combing, and softness to the hair.

Description

Hair-treatment composition
Invention field
The present invention relates to aqueous hair-treatment composition, more particularly, the present invention relates to Wo 2008069000, they make hair have gloss and bulk (volume) and smooth cardability, and give hair light, flexibility and pliability during especially for impaired dry hair.
Background of invention
In recent years, people have used various Wo 2008069000s, and these compositionss normally are used for making the situation such as the gloss, bulk of hair, and smooth cardability and pliability are improved.
In these conventional compositions some are in one of following type: a class is that its component is remained on compositions on the hair, and another kind of is to use the rinse-off compositions in back.
Yet the compositions of these types is renderd a service in conditioning and is still had deficiency, and this problem is particularly outstanding on being used for impaired dry hair the time.
Therefore, the invention provides hair-treatment composition, they make hair have gloss and bulk, and smooth cardability, and give hair with flexibility and pliability.
Disclosure of the Invention
In view of such circumstances, the inventor has carried out broad research, in order that a kind of solution to the problems referred to above is provided, found that the moisture hair-treatment composition that the part by weight with qualification respectively of the present invention contains lactic acid, citric acid and pyrrolidone carboxylic acid mixture demonstrates significantly improved hair conditioning effectiveness.Finished the present invention thus.
More particularly, the invention provides hair-treatment composition, they are that following component (a) and (b) that percetage by weight limits respectively and mixture (c) are contained in the basis with moisture or moisture-pure medium: (a) lactic acid 0.01wt% (b) citric acid 0.01wt% (c) 2-pyrrolidone-5-carboxylic acid 0.01wt% detailed description of the preferred embodiments at least at least at least
Hair-treatment composition of the present invention is designed to be applied to hair as the final processing after hair washing, perming, the hair dyeing etc.All above-mentioned percents are based on the total composition meter.
In the present composition, the 0.01wt% of component (a)-lactic acid-at least, preferred 0.05-2wt%, more preferably the ratio of 0.1-1wt% contains, and is benchmark in the total composition.
Component (b)-citric acid-also is 0.01wt% at least, preferred 0.05-1wt%, and more preferably the ratio of 0.1-0.5wt% contains, and is benchmark in the total composition.
Component (c)-2-pyrrolidone-5-carboxylic acid (be 5-oxo-pyrrolidine-2-carboxylic acid, often claim pyroglutamic acid)-at least 0.01wt%, preferred 0.5-2wt%, more preferably the ratio of 0.1-1wt% contains, and is benchmark in the total composition.
The hair conditioning effect of the present composition can further be improved by adding one or more organic acid that are selected from glycolic, malic acid, glyoxalic acid, tartaric acid, mandelic acid and acetone acid.Preferably with 0.01wt% at least, particularly the ratio of 0.05wt% contains described organic acid at least, is benchmark in the total composition.
Unimportant and the main required pH value decision of these organic acid upper limits by the present composition.Preferred pH value is 2-7, particularly 4-5.5.Usually, above-mentioned organic acid toatl proportion is about 5wt%, and preferably about 2.5wt% is a benchmark in the total composition.On the other hand, lower limit is preferably about 0.05wt%, particularly 0.25wt%, is benchmark in the total composition.These organic acid can obtain from plant and fruit juice or its extracting solution.
Other preferred additives comprise glycerol, and preferably its minimum flow is the 0.5wt% of compositions, particularly 1-10wt%.
Term used herein " hair-treatment composition " is meant that the preparation that imposes on the hair is (for this definition after hair washing, hair-waving (permanentwaving) or hair dyeing, referring to K.Schrader, " Grundlagen und Rezepturen der Kosmetika ", second edition, (1989, Hutig Bucbverlag, Heidelberg), pp.722-724).They make moisture or moisture-alcoholic solution usually, emulsion or dispersion liquid, but and arbitrariness ground with aerosol, particularly aerosol foam is used.
The present composition preferably contains at least a cationic surfactant, and its ratio especially is the 0.1-7.5wt% of total composition, particularly 0.25-5wt%.
Above-mentioned suitable cationic surfactants comprises long chain quaternary ammonium compound, instantiation is as follows: hexadecyltrimethylammonium chloride, dimethyl two (cetyl) ammonium chloride, trimethyl ammonium chloride, dimethyl two (cetyl) ammonium chloride, trimethyl cetyl ammonium bromide, stearyl trimethyl ammonium chloride, dimethyl stearyl benzyl ammonium chloride, benzyl myristyl alkyl dimethyl ammonium chloride, dimethyl dehydration Adeps Bovis seu Bubali ammonium chloride, lauryl chloride pyridine, lauryl dimethyl benzyl ammonium chloride, lauryl trimethyl ammonium chloride, three (low polyoxy ethyl) alkyl phosphoric acid ammonium, hexadecylpyridinium chloride etc., they can use or mix use separately.
Specially suitable is the mixture of two (cetyl) alkyl dimethyl ammonium chlorides and stearyl trimethyl ammonium chloride, and preferably its weight ratio is 1: 5-5: 1.
European Patent Application No. 472,107 disclosed quaternary ammonium salts also are useful.
Say that in principle all list in " CTFA cosmetic composition dictionary (CTFA CosmeticIngredient Dictionary ", the 4th edition (1991)) quaternary ammonium compound under " quaternary salt (quaternium) " generic name all can use.
Certainly, said composition also can comprise all known compositions in this class care composition own; For avoiding repetition, please refer again to K.Schrader, " Grundlagen undRezepturen der Kosmetika ", second edition (1989, Huting BuchverlagHeidelberg), pp.722-771.
Also can use non-ionic surface active agent, particularly use with cationic surfactant, for example be the about 0.25-5wt% of benchmark, the preferably amine oxide of about 0.5-3.5wt% in the total composition.
These amine oxides are known already in this area, for example C 12-C 18Alkyl dimethyl amine oxide, as lauryl dimethyl amine oxide, C 12-C 18Alkyl acyl aminopropyl or ethyl amine oxide, C 12-C 18Alkyl two (ethoxy) or (hydroxypropyl) amine oxide, or in the alkyl chain band ethylene oxide and (or) amine oxide of propylene oxide group.These amine oxide markets are on sale, and for example trade mark is called " Ammonyx ", or " Genaminox ".
Condensation degree is about the C of 1.2-2.5 8-C 18Alkyl androstanediol also is a preferred nonionic.
Compositions of the present invention also can contain both sexes or zwitterionic surfactant, preferably mixes with cationic surfactant, and its ratio is the about 0.1-5wt% in basis in the total composition, particularly about 0.5-3wt%.To this, can use various known betaines, as fatty acid acyl aminoalkyl betaine and sulfo group betaine, lauryl hydroxyl sulfo group betaine for example.
The representative instance of the dispensable additive of arbitrariness is a complexant, dyestuff, antiseptic, pH regulator agent, viscosity modifier such as inorganic salt, spice, pearling agent, thickening agent, wetting agent, vegetable and animals oils such as simmondsia wet goods.Specially suitable additive also has the hair conditioning active matter, cationic polymer especially, and preferably its ratio is the 0.05-2.5wt% of total composition, particularly 0.2-1.5wt%.European patent number 337,354 discloses the use of cationic polymer and alkyl polyglucoside surfactant; Wherein listed cationic polymer also is the suitable conditioning additive of the present composition on the 3-7 page or leaf; Known product is useful too down for listed generic name in " CTFA cosmetic composition dictionary, the 4th edition (1991) " " poly-quaternary salt ".
Other conditioning additives are protein hydrolysates, and for example its amount is the 0.25-5wt% of total composition, preferred 0.5-2.5wt%, or water solublity collagen or collagen derivant.
Various polysiloxanes also can be used as the conditioning additive in Wo 2008069000 of the present invention.Its preferred proportion is about 0.25-5wt%, particularly 0.5-2.5wt% of total composition.Suitable is the ring-type or the linear polysiloxane of high volatile volatile and low volatility, i.e. silicone oil, for example generic name " dimethicone " or " phenyl dimethicone " and " SILIBIONE OIL 70047 V20 DC-21330 DC21330 ".Polyorganosiloxane ramification also can use described in the european patent number 398,177, and this derivant is used with alkyl polyglucoside in described patent.
The preparation of the present composition is undertaken by mix each one-component in water or water-alcohol, thereby also can use the pre-composition of different component.
Embodiment
The present invention is illustrated by the following example, but is not limited to these embodiment.
Preparation has the hair-treatment composition of the present invention of filling a prescription shown in the following embodiment 1-5 respectively.
Embodiment 1 hair care washing lotion (hair care lotion) cetyl stearyl alcohol 5.00 (wt%) two (cetyl) alkyl dimethyl ammonium chloride 1.60 radix bardanaes oil (Burdock root oil) extract 1.00 hydroxypropyl guar gum hydroxypropyl-trimethyl ammonium chlorides 0.40 (Hydroxypropyl Guar hydroxypropyltrimonium chloride) isopropyl alcohol 1.50 isopropyl myristates 1.20 panthenols 0.50 spices 0.40 lactic acid 0.55 citric acid 0.05 2-pyrrolidone-5-carboxylic acid 0.02 tartaric acid 0.02 malic acid 0.01 anticorrisive agent suitable quantity of water surplus amounts to 100.00
Embodiment 2 hair care reinforcing agent (hair care tonic) radix bardanae oil extract 0.50 (wt%) phytantriol (phytantriol) 0.10 panthenol, 0.20 INCROQUAT TMC-80 (Behentrimonium 0.10chloride) hydroxypropyl guar gum hydroxypropyl-trimethyl ammonium chlorides 0.03 iso stearyl glyceryl pentaerythrite ether 0.10 quaternary (Quaternary) polysiloxanes 0.15 lactic acid 0.25 2-pyrrolidone-5-carboxylic acid 0.05 citric acid 0.15 malic acid 0.05 pyruvic acid 0.05 spices 0.40 ethanol 35.00 water surplus amount to 100.00
Embodiment 3 loose and dry hair conditioner cetyl stearyl alcohols 5.50, (wt%) two, (cetyl) alkyl dimethyl ammonium chloride 0.50 stearyl trimethyl ammonium chloride 0.40 iso stearyl glyceryl pentaerythrite ether 0.20 wheat bran oil 0.10 hydrolyzed wheat protein product 0.50 isopropyl myristate 0.50 panthenol 0.20 lactic acid 0.15 citric acid 0.15 2-pyrrolidone-5-carboxylic acid 0.05 malic acid 0.05 glycolic 0.02 pyruvic acid 0.02 tartaric acid 0.06 spices 0.35 anticorrisive agent suitable quantity of water surplus amounts to 100.00
Compare other half side the test with using the compositions that does not contain hydroxy carboxylic acid mixture of the present invention, the hair of washing with the compositions-treated of embodiment 1-3 makes hair have the wet cardability of doing of obvious improvement, sagging and soft hand feeling, and the light that increases.
The conditioner cetyl stearyl alcohol 5.00 of embodiment 4 colored hairs, (wt%) two, (cetyl) alkyl dimethyl ammonium chloride 1.00 isopropyl myristates 0.40 isopropyl alcohol 0.50 iso stearyl glyceryl pentaerythrite ether 0.20 Lu Yun leaf, (Aloe vera leaves) extract 0.50 lecithin 0.50 panthenol 0.20 lactic acid 0.15 citric acid 0.15 2-pyrrolidone-5-carboxylic acid 0.10 malic acid 0.03 pyruvic acid 0.02 tartaric acid 0.05 glycolic 0.05 spices 0.45 anticorrisive agent suitable quantity of water surplus amounts to 100.00
Except the conditioning effect that the compositions with embodiment 1-3 reaches, embodiment 4 has also recovered the colored gloss of hair.
Embodiment 5 hair-wavings amount to 100.00 with conditioner cetyl stearyl alcohol 5.00 (wt%) two (cetyl) alkyl dimethyl ammonium chlorides 1.20 apricot kernel oils 0.50 lecithin 0.50 almond protein hydrolysate 0.50 panthenol 0.20 glycerine 0.50 lactic acid 0.20 2-pyrrolidone-5-carboxylic acid 0.03 citric acid 0.03 malic acid 0.02 pyruvic acid 0.01 tartaric acid 0.01 spices 0.40 anticorrisive agent suitable quantity of water surplus
Industrial applicability of the present invention
According to the present invention, hair-treatment composition is provided, it is excellent novel product, Have significantly improved performance, particularly gloss and bulk, and give light, flexibility And pliability.

Claims (4)

1. hair-treatment composition that is used for Crinis Carbonisatus is the mixture that following ingredients is contained on the basis with moisture or moisture-pure medium:
A) lactic acid of 0.01wt% at least;
B) citric acid of 0.01wt% at least; With
C) 2-pyrrolidone-5-carboxylic acid of 0.01wt% at least,
All percents are benchmark in the total composition.
2. according to the hair-treatment composition of claim 1, also contain the glycerol of 0.5wt% at least.
3. according to the hair-treatment composition of claim 1 or 2, also contain at least a glycolic that is selected from, malic acid, glyoxalic acid, tartaric acid, the organic acid of mandelic acid and acetone acid.
4. according to claim 1,2 or 3 hair-treatment composition, contain the cationic surfactant of counting 0.1-5wt% with total composition.
CN 96196810 1995-09-08 1996-09-09 Hair treatment composition Pending CN1199332A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19533211.3 1995-09-08
DE1995133211 DE19533211B4 (en) 1995-09-08 1995-09-08 Hair aftertreatment preparations

Publications (1)

Publication Number Publication Date
CN1199332A true CN1199332A (en) 1998-11-18

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ID=7771605

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 96196810 Pending CN1199332A (en) 1995-09-08 1996-09-09 Hair treatment composition

Country Status (6)

Country Link
JP (1) JPH09110650A (en)
CN (1) CN1199332A (en)
DE (1) DE19533211B4 (en)
GB (1) GB2321595B (en)
TW (1) TW427910B (en)
WO (1) WO1997009029A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100444821C (en) * 2003-08-01 2008-12-24 花王株式会社 Hair grooming preparation
CN108403554A (en) * 2018-04-27 2018-08-17 北京杼宸医学研究院 A kind of hair nourishing shampoo and preparation method thereof
CN109475490A (en) * 2016-05-23 2019-03-15 西姆莱斯股份公司 Hair treating mixtures containing Testa Tritici extract
CN114712267A (en) * 2022-04-06 2022-07-08 王洪伟 Hair waving buffering agent

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9704050D0 (en) * 1997-02-27 1997-04-16 Unilever Plc Hair treatment composition
DE19720366A1 (en) * 1997-05-15 1998-11-19 Wella Ag Hair cleanser with gloss-enhancing properties
EP0978272A1 (en) * 1998-08-07 2000-02-09 Kao Corporation Medulla care preparation
JP3208381B2 (en) * 1998-12-28 2001-09-10 花王株式会社 Hair cosmetics
DE10009438A1 (en) * 2000-02-29 2001-08-30 Schwarzkopf Gmbh Hans Use of combination of pyrrolidinone carboxylic acid derivative and cationic or amphoteric polymer to improve wash-fastness of dyed fibers, especially human hair
DE10009439A1 (en) * 2000-02-29 2001-08-30 Schwarzkopf Gmbh Hans Use of cationic protein hydrolyzates as agents for improving the wash-fastness of dyed fibers, especially human hair
US7871599B2 (en) 2002-07-05 2011-01-18 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Hair treatment compositions containing xanthine and alpha hydroxy acid
DE60332386D1 (en) * 2002-11-26 2010-06-10 Kao Corp COSMETIC HAIR PREPARATION
JP4926371B2 (en) * 2002-11-26 2012-05-09 花王株式会社 Hair cosmetics
JP4473820B2 (en) * 2003-08-01 2010-06-02 花王株式会社 Hair cosmetics
JP2006193461A (en) * 2005-01-13 2006-07-27 Pola Chem Ind Inc Hair detergent
JP5168996B2 (en) 2007-04-13 2013-03-27 味の素株式会社 Preserved aqueous solution with high amino acid content
JP5496456B2 (en) * 2007-12-28 2014-05-21 花王株式会社 Hair cosmetics
EP2090291B1 (en) * 2008-02-14 2011-09-14 KPSS-Kao Professional Salon Services GmbH Composition for hair comprising PCA and PCA ester
JP2010065022A (en) * 2008-08-12 2010-03-25 Kao Corp Hair treatment composition
WO2011124560A2 (en) * 2010-04-09 2011-10-13 Dsm Ip Assets B.V. Hair care compositions
US20210275418A1 (en) * 2020-03-09 2021-09-09 Colgate-Palmolive Company Personal Care Compositions

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3492738B2 (en) * 1993-10-13 2004-02-03 サンスター株式会社 Hair cosmetics
DE19504914C1 (en) * 1995-02-15 1995-11-16 Goldwell Gmbh Hair washing agent giving gloss and body, and easy combing

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100444821C (en) * 2003-08-01 2008-12-24 花王株式会社 Hair grooming preparation
CN109475490A (en) * 2016-05-23 2019-03-15 西姆莱斯股份公司 Hair treating mixtures containing Testa Tritici extract
CN108403554A (en) * 2018-04-27 2018-08-17 北京杼宸医学研究院 A kind of hair nourishing shampoo and preparation method thereof
CN108403554B (en) * 2018-04-27 2021-03-05 北京杼宸医学研究院 Hair nourishing shampoo and preparation method thereof
CN114712267A (en) * 2022-04-06 2022-07-08 王洪伟 Hair waving buffering agent

Also Published As

Publication number Publication date
WO1997009029A1 (en) 1997-03-13
GB9803642D0 (en) 1998-04-15
JPH09110650A (en) 1997-04-28
DE19533211B4 (en) 2005-12-01
TW427910B (en) 2001-04-01
GB2321595B (en) 2000-01-26
GB2321595A (en) 1998-08-05
DE19533211A1 (en) 1996-02-08

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