CN117887511A - Super-lubricating titanium alloy total-synthesis processing liquid and preparation method thereof - Google Patents
Super-lubricating titanium alloy total-synthesis processing liquid and preparation method thereof Download PDFInfo
- Publication number
- CN117887511A CN117887511A CN202311790344.2A CN202311790344A CN117887511A CN 117887511 A CN117887511 A CN 117887511A CN 202311790344 A CN202311790344 A CN 202311790344A CN 117887511 A CN117887511 A CN 117887511A
- Authority
- CN
- China
- Prior art keywords
- percent
- titanium alloy
- super
- antirust agent
- processing liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000012545 processing Methods 0.000 title claims abstract description 34
- 239000007788 liquid Substances 0.000 title claims abstract description 28
- 229910001069 Ti alloy Inorganic materials 0.000 title claims abstract description 25
- 238000006257 total synthesis reaction Methods 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000005260 corrosion Methods 0.000 claims abstract description 20
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 20
- 230000007797 corrosion Effects 0.000 claims abstract description 19
- 239000013556 antirust agent Substances 0.000 claims abstract description 18
- 229920000570 polyether Polymers 0.000 claims abstract description 13
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 12
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 11
- -1 alcohol amine Chemical class 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 150000001413 amino acids Chemical class 0.000 claims abstract description 9
- 239000012964 benzotriazole Substances 0.000 claims abstract description 9
- 239000002131 composite material Substances 0.000 claims abstract description 9
- 150000003628 tricarboxylic acids Chemical class 0.000 claims abstract description 9
- 239000012530 fluid Substances 0.000 claims description 18
- 239000003112 inhibitor Substances 0.000 claims description 16
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical group CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 5
- 238000003754 machining Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 12
- 239000000839 emulsion Substances 0.000 abstract description 10
- 238000005461 lubrication Methods 0.000 abstract description 6
- 239000003595 mist Substances 0.000 abstract description 5
- 238000003912 environmental pollution Methods 0.000 abstract description 4
- 239000000779 smoke Substances 0.000 abstract description 3
- KNOYHJOPRUTPSQ-QHCPKHFHSA-N (4s)-5-amino-5-oxo-4-[3-[4-(4-phenylphenyl)phenyl]propanoylamino]pentanoic acid Chemical compound C1=CC(CCC(=O)N[C@@H](CCC(O)=O)C(=O)N)=CC=C1C1=CC=C(C=2C=CC=CC=2)C=C1 KNOYHJOPRUTPSQ-QHCPKHFHSA-N 0.000 abstract 1
- 239000002173 cutting fluid Substances 0.000 description 23
- 229910052751 metal Inorganic materials 0.000 description 20
- 239000002184 metal Substances 0.000 description 20
- 239000003921 oil Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 9
- 239000008233 hard water Substances 0.000 description 9
- 238000005555 metalworking Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 6
- 235000011181 potassium carbonates Nutrition 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 239000003085 diluting agent Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 230000001050 lubricating effect Effects 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 238000010079 rubber tapping Methods 0.000 description 4
- 229910000838 Al alloy Inorganic materials 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- UUFQTNFCRMXOAE-UHFFFAOYSA-N 1-methylmethylene Chemical compound C[CH] UUFQTNFCRMXOAE-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000002199 base oil Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000003670 easy-to-clean Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010669 acid-base reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- CAMJPMYWRKKZNK-UHFFFAOYSA-N nitroformaldehyde Chemical compound [O-][N+](=O)C=O CAMJPMYWRKKZNK-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses a super-lubrication titanium alloy total synthesis processing liquid which comprises the following components in percentage by weight: 3 to 5 percent of amino acid antirust agent, 2 to 4 percent of tricarboxylic acid antirust agent, 1 to 2 percent of benzotriazole, 0.5 to 1.5 percent of composite corrosion inhibitor, 18 to 28 percent of polyether, 1.8 to 3.2 percent of Guerbet alcohol, 353 to 6 percent of Craien PN, 0.5 to 2 percent of potassium hydroxide, 18 to 25 percent of alcohol amine, 0.5 to 1.5 percent of potassium carbonate and the balance of water. The invention also provides a preparation method of the super-lubrication titanium alloy total-synthesis processing liquid. Compared with the prior art, the invention can solve the problems that most of the processing media used in the existing titanium alloy processing are processed by pure oil or emulsion with higher oil content, and the pure oil processing has the hidden trouble of large oil mist, difficult cleaning and easy ignition safety; the emulsion product has the problems of large smoke, easy environmental pollution, difficult management on the use site, poor stability and large dosage.
Description
Technical Field
The invention relates to the technical field of machining fluids, in particular to a super-lubrication titanium alloy total-synthesis machining fluid and a preparation method thereof.
Background
The synthetic cutting fluid is a water-based cutting fluid, is prepared from chemicals, does not contain mineral oil, and has the characteristics of long storage period, safety, no toxicity, high work efficiency and high finish; it has no physiological toxicity and environmental pollution; it is an environment-friendly metal cutting fluid. The cutting fluid is an industrial fluid used for cooling and lubricating a cutter and a machined part in the metal cutting, cutting and grinding processes, is formed by compounding and matching a plurality of auxiliary agents, and has good cooling performance, lubricating performance, rust-preventing performance and cleaning performance.
The cutting fluid is an industrial liquid used in the metal cutting and grinding process and used for cooling and lubricating a cutter and a workpiece, is formed by scientifically compounding and matching a plurality of super functional auxiliary agents, and has the characteristics of good cooling performance, lubricating performance, rust resistance, oil removal and cleaning functions, corrosion prevention and easy dilution. Cutting fluids are divided into emulsion, semisynthetic and fully synthetic. The fully-synthesized cutting fluid has strong stability and good cooling performance.
Most of the processing media used in the current titanium alloy processing are processed by pure oil or emulsion with higher oil content, and the pure oil processing has the problems of large oil mist, difficult cleaning and easy ignition and hidden danger; the emulsion product has the problems of large smoke, easy environmental pollution, difficult management on the use site, poor stability, large dosage and the like.
Disclosure of Invention
The invention aims at: in order to solve the problems that most of the processing media used in the current titanium alloy processing are processed by pure oil or emulsion with higher oil content, the pure oil processing has the hidden trouble of large oil mist, difficult cleaning and easy ignition safety; the emulsion product has the problems of large smoke, easy environmental pollution, difficult use site management, poor stability and large dosage, and the super-lubricating titanium alloy total synthesis processing liquid and the preparation method thereof are provided.
For this purpose, in one aspect, the invention provides a super-lubricated titanium alloy total synthesis processing liquid, which comprises the following components in percentage by weight:
as a further description of the above technical solution:
the super-lubricating titanium alloy total-synthesis processing liquid comprises the following components in percentage by weight: 3.4 to 4.5 percent of amino acid antirust agent, 2.4 to 3.6 percent of tricarboxylic acid antirust agent, 1.2 to 1.8 percent of benzotriazole, 0.8 to 1.2 percent of composite corrosion inhibitor, 20 to 26 percent of polyether, 2.0 to 3.0 percent of Guerbet alcohol, 353.4 to 5.6 percent of Crain PN, 0.8 to 1.6 percent of potassium hydroxide, 21 to 23 percent of alcohol amine, 0.8 to 1.2 percent of potassium carbonate and the balance of water.
As a further description of the above technical solution:
the super-lubricating titanium alloy total-synthesis processing liquid comprises the following components in percentage by weight: 4% of amino acid antirust agent, 3% of tricarboxylic acid antirust agent, 1.6% of benzotriazole, 1% of composite corrosion inhibitor, 24% of polyether, 2.5% of Guerbet alcohol, 354% of Craien PN, 1.2% of potassium hydroxide, 22% of alcohol amine, 1% of potassium carbonate and the balance of water.
As a further description of the above technical solution:
the alcohol amine is triisopropanolamine. In order to improve the rust-proof effect, polyether amine is added, the polyether amine is uniformly attached to the metal surface, the corrosion inhibition effect of the organic carboxylic acid is enhanced, and the rust-proof and corrosion inhibition protection effects of the cutting fluid on processed workpieces are improved.
On the other hand, the invention also provides a preparation method of the super-lubrication titanium alloy total-synthesis processing liquid, which comprises the following steps:
1) Preparing each material according to the proportion;
2) Adding water, an amino acid antirust agent, a tricarboxylic acid antirust agent, benzotriazole, potassium hydroxide, triisopropanolamine and potassium carbonate into a beaker according to the proportion, and stirring at normal temperature until the mixture is uniform and transparent;
3) And adding the composite corrosion inhibitor, polyether, guerbet alcohol and Craien PN35 into the uniform transparent liquid, and stirring at 30-50 ℃ until the liquid is uniform and transparent.
As a further description of the above technical solution:
the stirring temperature in step 3) was 40 ℃.
In summary, due to the adoption of the technical scheme, the beneficial effects of the invention are as follows:
1. the titanium alloy has good tapping torque, the service life of the cutter is longer than that of the prior proposal, the lubricity is greatly improved, and the 'water' is changed into 'milk'.
2. Does not contain base oil, does not generate oil mist, and has little pollution and harm.
3. The cleaning performance is good, the residue on the surface of the workpiece is less, and the use of cleaning agents is reduced.
4. The hard water resistance is strong, the stability is good, the diluent is stable and uniform after long-time use, frequent liquid replacement is not needed, and the cost is saved.
5. The use solution is stable and transparent for a long time, the use solution does not need to be changed, the service life is long, the recycling rate of the waste liquid is 100%, and the consumption is reduced.
Detailed Description
Exemplary embodiments of the present disclosure will be described in more detail below. While exemplary embodiments of the present disclosure are shown, it should be understood that the present disclosure may be embodied in various forms and should not be limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the disclosure to those skilled in the art.
Basic information of the chemical additives involved:
"Water": water-based products, chemically synthesized, free of mineral oil;
"milk": the content of mineral oil in the emulsified product is 40-50%;
"super lubrication": ultra-high lubricity, exceeding oil-containing emulsion products;
amino acid rust inhibitor: is an antirust agent applied to aqueous solution, has good antirust performance on cast iron and other ferrous metals, and does not cause aluminum and titanium to change color;
tricarboxylic acid antirust agent: has the advantages of good rust resistance, extreme low foaming property, good hard water stability, no irritation to skin and mucous membrane when in a concentration range of common use, and the like. The metal corrosion inhibitor is mainly used as a metal corrosion inhibitor additive in water-based products such as semisynthetic cutting fluid, total synthetic grinding fluid, water-based quenching fluid, water-based cleaning agent, automobile antifreezing agent, antirust water and the like;
composite corrosion inhibitor (Chinese patent: CN20171011012698. X): the sustained-release coating has a sustained-release effect, is wide in application range, and has a good protective effect on magnesium alloy, aluminum alloy and titanium alloy;
benzotriazole: mainly used as water treatment agent, metal rust inhibitor and corrosion inhibitor. The catalyst is widely applied to the circulating water treatment agent, rust-proof oil and lipid products, and also applied to the vapor phase corrosion inhibitors of copper and copper alloy and lubricating oil additives. The silver, copper and zinc are used for surface purification in electroplating, and the anti-discoloration effect is achieved. BTA and copper atoms form covalent bonds and coordination bonds, and are mutually replaced by chain polymers, and a multi-layer protective film is formed on the surface of copper, so that oxidation-reduction reaction and hydrogen gas are not generated on the surface of copper, and the corrosion resistance is realized. The same effect is also achieved for metallic materials such as lead, cast iron, nickel, zinc, titanium, etc. BTA can be matched with various corrosion inhibitors, so that the corrosion inhibition effect is improved;
guerbet alcohol: guerbet alcohols are a generic term for a class of fatty alcohols having a branched chain attached to the second carbon, also known as 2-alkyl-1-alkanols, which are a class of saturated primary alcohols. The following properties are possessed by the special structure having two 100% linear alkyl chains: 1) Low volatility; 2) Low irritation; 3) Low freezing point; 4) Excellent lubricity; 5) Excellent oxidation stability; 6) Good solubility and dissolution ability; 7) Low viscosity; 8) Good biodegradability;
polyether: is a synthetic oil with the largest sales amount. It is a linear polymer prepared by taking ethylene oxide, propylene oxide, butylene oxide and the like as raw materials and carrying out ring-opening homopolymerization or copolymerization under the action of a catalyst. Based on the polarity of the polyether, and the low viscosity coefficient, the lubricant film with high adsorption capacity and bearing capacity can be formed stably in almost all lubrication states, and the lubricant film has low friction coefficient and high shearing resistance. Polyethers are better in lubricity than mineral oils, polyalphaolefins and diesters, but not as good as polyol esters and phosphate esters;
craien PN35: craien ClariantGenapol PN35 lubricity improvers, low foaming surfactants for synthetic metal working fluids and cleaners, genapol PN35 is an EO/PO block copolymer, useful as a low foaming surfactant and lubricity improver in metal working fluids and metal cleaners. It is stable to hard water. Meanwhile, the anti-corrosion and lubricating properties are good;
potassium hydroxide: the reactivity is improved, and the reactivity of fatty acid and alcohol amine in the cutting fluid can be improved by adding potassium hydroxide because the metal processing fluid is mostly organic acid-base reaction and has weaker reactivity and needs to be catalyzed and activated, so that the utilization efficiency is improved. Can increase the base number and reduce the use amount of the base. Activating hard water, wherein hydroxyl groups are combined with calcium and magnesium in water to form fine particle precipitation, so that fatty acid is prevented from being combined with calcium and magnesium to form flocculent precipitation;
triisopropanolamine (85%): triisopropanolamine is an organic compound with the structural formula of [ CH3CH (0H) CH2]3N. Because the triisopropanolamine and the salt generated by the long-chain fatty acid have good coloring stability, the triisopropanolamine is used as an emulsifier to prepare zincate additives, ferrous metal rust inhibitors, cutting coolants, cement reinforcing agents, printing and dyeing softeners, gas absorbers and antioxidants, and is used as auxiliary agents such as soaps, detergents, cosmetics and the like, and the triisopropanolamine mainly plays roles of rust prevention in metal processing liquid, metal corrosion inhibition and provides effective base number and pH;
potassium carbonate: potassium carbonate is an inorganic substance, has a chemical formula of K2C03, has a molecular weight of 138.206, is white crystal powder, has strong hygroscopicity, can absorb carbon dioxide and moisture when being exposed to air, and can be converted into potassium bicarbonate, so that the pH and the cleaning capacity can be well improved.
Embodiment one:
adding water, 4% of an amino acid antirust agent, 3% of a tricarboxylic acid antirust agent, 1.6% of benzotriazole, 1.2% of potassium hydroxide, 22% of triisopropanolamine and 1% of potassium carbonate into a 250ml beaker, stirring at normal temperature until the mixture is uniform and transparent, adding 1% of a composite corrosion inhibitor, 24% of polyether, 2.5% of Guerbet alcohol and 354% of Craien PN into the transparent liquid, and stirring at 40 ℃ until the mixture is uniform and transparent, thereby obtaining the cutting fluid.
And (3) performing a comparison experiment between the two types of common metal processing liquid microemulsified A type and emulsified B type on the market and the metal processing liquid. The factors such as pure water, nitrous oxide, formaldehyde, tapping torque meter, cleaning workpiece, experimental environment and the like used in the comparative test are kept consistent, and only variable is that the model of the metal working fluid is different.
The three metal working fluids are respectively prepared into 500ppm hard water with the concentration of 5% and 1000ppm for observing the hard water resistance, and then 5% tap water diluent is prepared for testing the formaldehyde and the nitrite content.
Comparison results: according to the same environment and the same test method, experiments of hard water stability and test of harmful substances made of three types of cutting fluids show that the patent cutting fluid has the best hard water resistance and does not contain harmful substances such as nitroformaldehyde, and the A type metal processing fluid and the B type metal processing fluid have soap separation and contain harmful substances. Experimental results show that the cutting fluid is stable and environment-friendly.
Embodiment two:
three metal working fluids were each prepared as a 10% strength tap water dilution, and then tested for lubricity using a titanium alloy tapping torque meter.
Metal working fluid model | Lubricity of the bearing |
Cutting fluid of the invention | 153.2Ncm |
Microemulsion A model | 240.4Ncm |
Emulsion B type | 212.6Ncm |
Comparison results: in the same environment and in the same test method, the lubricity experiments of the cutting fluids of three different types show that the patent cutting fluid has optimal lubricity, the type B metal working fluid has the next lowest lubricity, and the type A metal working fluid has the worst lubricity. The result shows that the patent cutting fluid has good lubricity, can meet the harsh processing technology, and can achieve good processing effect with lower concentration.
Embodiment III:
and respectively preparing tap water diluent with the concentration of 5% for the three metal processing liquids, and then testing the protectiveness of each product on aluminum alloy and titanium alloy in a 40 ℃ constant-temperature water bath test tank.
Note that: the A-grade protection performance is best, which means that the metal material is free from color change and oxidation before and after soaking; and C, the worst grade represents blackening, discoloration and oxidization of the soaked metal material.
Comparison results: in the same environment and the same test method, the metal soaking experiments of three cutting fluids with different types show that the patent cutting fluids have the best protection property for aluminum and titanium alloys.
Experiment IV:
and respectively preparing 10% concentration diluent for the three metal processing liquids, processing a workpiece, and testing the cleaning performance.
Cutting fluid model | Cleaning performance |
Cutting fluid of the invention | Easy to clean |
Microemulsion A model | Is difficult to clean |
Emulsion B type | Is not cleaned cleanly |
Comparison results: under the same experimental conditions, the patent cutting fluid is most easy to clean, the model A is difficult to clean, the model B has residues after cleaning, and the effect is worst.
In summary, due to the adoption of the technical scheme, the beneficial effects of the invention are as follows:
1. the titanium alloy has good tapping torque, the service life of the cutter is longer than that of the prior proposal, the lubricity is greatly improved, and the 'water' is changed into 'milk'.
2. Does not contain base oil, does not generate oil mist, and has little pollution and harm.
3. The cleaning performance is good, the residue on the surface of the workpiece is less, and the use of cleaning agents is reduced.
4. The hard water resistance is strong, the stability is good, the diluent is stable and uniform after long-time use, frequent liquid replacement is not needed, and the cost is saved.
5. The use solution is stable and transparent for a long time, the use solution does not need to be changed, the service life is long, the recycling rate of the waste liquid is 100%, and the consumption is reduced.
The foregoing is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art, who is within the scope of the present invention, should make equivalent substitutions or modifications according to the technical scheme of the present invention and the inventive concept thereof, and should be covered by the scope of the present invention.
Claims (6)
1. The super-lubricating titanium alloy total-synthesis processing liquid is characterized by comprising the following components in percentage by weight:
2. the super-lubricated titanium alloy total-synthesis processing liquid according to claim 1, which is characterized by comprising the following components in percentage by weight: 3.4 to 4.5 percent of amino acid antirust agent, 2.4 to 3.6 percent of tricarboxylic acid antirust agent, 1.2 to 1.8 percent of benzotriazole, 0.8 to 1.2 percent of composite corrosion inhibitor, 20 to 26 percent of polyether, 2.0 to 3.0 percent of Guerbet alcohol, 353.4 to 5.6 percent of Crain PN, 0.8 to 1.6 percent of potassium hydroxide, 21 to 23 percent of alcohol amine, 0.8 to 1.2 percent of potassium carbonate and the balance of water.
3. The super-lubricated titanium alloy total-synthesis processing liquid according to claim 1, which is characterized by comprising the following components in percentage by weight: 4% of amino acid antirust agent, 3% of tricarboxylic acid antirust agent, 1.6% of benzotriazole, 1% of composite corrosion inhibitor, 24% of polyether, 2.5% of Guerbet alcohol, 354% of Craien PN, 1.2% of potassium hydroxide, 22% of alcohol amine, 1% of potassium carbonate and the balance of water.
4. A super-lubricated titanium alloy full-synthetic processing fluid according to any one of claims 1 to 3, wherein said alcohol amine is triisopropanolamine.
5. The preparation method of the super-lubricated titanium alloy total-synthesis processing liquid is characterized by comprising the following steps of:
1) The formulation according to any one of claims 1-4, preparing each material;
2) Adding water, an amino acid antirust agent, a tricarboxylic acid antirust agent, benzotriazole, potassium hydroxide, triisopropanolamine and potassium carbonate into a beaker according to the proportion, and stirring at normal temperature until the mixture is uniform and transparent;
3) And adding the composite corrosion inhibitor, polyether, guerbet alcohol and Craien PN35 into the uniform transparent liquid, and stirring at 30-50 ℃ until the liquid is uniform and transparent.
6. The method for preparing a total synthetic machining fluid for super lubricated titanium alloy according to claim 5, wherein the stirring temperature in step 3) is 40 ℃.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202311790344.2A CN117887511A (en) | 2023-12-25 | 2023-12-25 | Super-lubricating titanium alloy total-synthesis processing liquid and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202311790344.2A CN117887511A (en) | 2023-12-25 | 2023-12-25 | Super-lubricating titanium alloy total-synthesis processing liquid and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN117887511A true CN117887511A (en) | 2024-04-16 |
Family
ID=90647925
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202311790344.2A Pending CN117887511A (en) | 2023-12-25 | 2023-12-25 | Super-lubricating titanium alloy total-synthesis processing liquid and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN117887511A (en) |
-
2023
- 2023-12-25 CN CN202311790344.2A patent/CN117887511A/en active Pending
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101323813A (en) | Multiple-effect type water-based synthesized cutting solution and preparation thereof | |
CN102533418A (en) | Environmental-friendly micro emulsion cutting fluid | |
CN101104831A (en) | Micro-emulsification stainless steel cutting liquid | |
CN106635369A (en) | Fully synthetic cutting fluid and production method thereof | |
CN109054973A (en) | A kind of micro-emulsion cutting fluid, Preparation method and use | |
CN111909770A (en) | Fully-synthetic high-lubrication metal working fluid, and preparation method and application thereof | |
CN114350432A (en) | Easy-to-clean environment-friendly cutting fluid for machining aluminum wheel hub and preparation method thereof | |
US4670168A (en) | Aqueous metal removal fluid | |
US5985804A (en) | Bioresistant surfactants and cutting oil formulations | |
CN106675736A (en) | Multifunctional cutting solution composition | |
JPH03229631A (en) | Novel biodegradation resisting surfactant and cutting oil compound using same | |
US20120177938A1 (en) | Metalworking fluid, metal working method and metal work product | |
CN1238480C (en) | Method for preparing metal cutting fluid and grinding fluid with low surface tension | |
CN103849451A (en) | Smooth liquid with efficient cleaning capability for secondary cold rolling unit | |
CN104312705A (en) | Environment-friendly cutting fluid and preparation method thereof | |
CN106566625B (en) | One vegetable oil base titanium alloy emulsifies working fluid | |
CN117887511A (en) | Super-lubricating titanium alloy total-synthesis processing liquid and preparation method thereof | |
CN102465053A (en) | Environment-friendly cutting solution | |
CN111234909A (en) | Water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining | |
CN104357201A (en) | Microemulsified cutting fluid applicable to magnesium alloy material machining and preparation method thereof | |
CN114317088A (en) | Organic amine-free biological stable water-based emulsified cutting fluid and preparation method thereof | |
KR100761557B1 (en) | Water soluble metal working fluids using soybean oil and metal working fluids thereof | |
CN101418248B (en) | Method for manufacturing multipurpose metal working lubricant | |
CN101126048B (en) | Water-base type line cutting working liquid | |
CN107739651A (en) | A kind of magnesium alloy cutting fluid |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |