CN117858908A - 具有窄粒径分布的烯烃的聚合工艺 - Google Patents

具有窄粒径分布的烯烃的聚合工艺 Download PDF

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Publication number
CN117858908A
CN117858908A CN202280057854.6A CN202280057854A CN117858908A CN 117858908 A CN117858908 A CN 117858908A CN 202280057854 A CN202280057854 A CN 202280057854A CN 117858908 A CN117858908 A CN 117858908A
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CN
China
Prior art keywords
alkyl
group
catalyst
mol
polymer
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Pending
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CN202280057854.6A
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English (en)
Chinese (zh)
Inventor
P·卡斯特罗
V·卡内洛普洛斯
V·苏梅林
J·阿霍
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Borealis GmbH
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Borealis GmbH
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Publication of CN117858908A publication Critical patent/CN117858908A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/07—Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/24—Polymer with special particle form or size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN202280057854.6A 2021-06-24 2022-06-23 具有窄粒径分布的烯烃的聚合工艺 Pending CN117858908A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP21181478 2021-06-24
EP21181478.5 2021-06-24
PCT/EP2022/067185 WO2022268961A2 (en) 2021-06-24 2022-06-23 Process for polymerising olefins having narrow particle size distribution

Publications (1)

Publication Number Publication Date
CN117858908A true CN117858908A (zh) 2024-04-09

Family

ID=76971619

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202280057854.6A Pending CN117858908A (zh) 2021-06-24 2022-06-23 具有窄粒径分布的烯烃的聚合工艺

Country Status (8)

Country Link
US (1) US20240287217A1 (https=)
EP (1) EP4359453A2 (https=)
JP (1) JP2024525008A (https=)
KR (1) KR20240024252A (https=)
CN (1) CN117858908A (https=)
BR (1) BR112023026990A2 (https=)
CA (1) CA3223004A1 (https=)
WO (1) WO2022268961A2 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4185622A1 (en) 2020-07-23 2023-05-31 Borealis AG Metallocene complexes and catalysts made therefrom
EP4703426A1 (en) 2024-08-27 2026-03-04 Borealis GmbH Method for controlling polymer material formation

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6787616B2 (en) * 2002-07-12 2004-09-07 Maruzen Petrochemical Co., Ltd. Catalyst for olefin polymerization and process for polymerizing olefin by means thereof
CN103582669A (zh) * 2011-03-30 2014-02-12 日本聚乙烯株式会社 乙烯类聚合物、聚乙烯类树脂组合物及其用途、烯烃聚合用催化剂成分、包含所述成分的烯烃聚合用催化剂以及使用所述催化剂生产乙烯类聚合物的方法
JP2016183334A (ja) * 2015-03-25 2016-10-20 日本ポリエチレン株式会社 ポリエチレン系樹脂組成物
WO2018032745A1 (zh) * 2016-08-19 2018-02-22 中国科学院化学研究所 超高分子量超细粒径丙烯聚合物及其制备方法和应用
WO2020179650A1 (ja) * 2019-03-01 2020-09-10 旭化成株式会社 ポリエチレンパウダー、並びにこれを成形してなる成形体
JP6791662B2 (ja) * 2016-06-27 2020-11-25 旭化成株式会社 ポリエチレン系パウダー、ポリエチレン系パウダーの製造方法、ポリエチレン系樹脂組成物、及び架橋ポリエチレン管の製造方法

Family Cites Families (18)

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Publication number Priority date Publication date Assignee Title
US3242150A (en) 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3405109A (en) 1960-10-03 1968-10-08 Phillips Petroleum Co Polymerization process
US3324093A (en) 1963-10-21 1967-06-06 Phillips Petroleum Co Loop reactor
US3374211A (en) 1964-07-27 1968-03-19 Phillips Petroleum Co Solids recovery from a flowing stream
US4582816A (en) 1985-02-21 1986-04-15 Phillips Petroleum Company Catalysts, method of preparation and polymerization processes therewith
US5565175A (en) 1990-10-01 1996-10-15 Phillips Petroleum Company Apparatus and method for producing ethylene polymer
FI89929C (fi) 1990-12-28 1993-12-10 Neste Oy Foerfarande foer homo- eller sampolymerisering av eten
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
FI96866C (fi) 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
US6239235B1 (en) 1997-07-15 2001-05-29 Phillips Petroleum Company High solids slurry polymerization
DE60129444T2 (de) 2001-10-30 2007-10-31 Borealis Technology Oy Polymerisationsreaktor
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
EP1415999B1 (en) 2002-10-30 2007-12-05 Borealis Technology Oy Process and apparatus for producing olefin polymers
ATE329941T1 (de) 2004-04-29 2006-07-15 Borealis Tech Oy Verfahren zur herstellung von polyethylen
US7169864B2 (en) 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
RU2410388C2 (ru) 2005-03-18 2011-01-27 Базелль Полиолефине Гмбх Металлоценовые соединения
CN1923861B (zh) 2005-09-02 2012-01-18 北方技术股份有限公司 在烯烃聚合催化剂存在下的烯烃聚合方法
EP3178853B1 (en) 2015-12-07 2018-07-25 Borealis AG Process for polymerising alpha-olefin monomers

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6787616B2 (en) * 2002-07-12 2004-09-07 Maruzen Petrochemical Co., Ltd. Catalyst for olefin polymerization and process for polymerizing olefin by means thereof
CN103582669A (zh) * 2011-03-30 2014-02-12 日本聚乙烯株式会社 乙烯类聚合物、聚乙烯类树脂组合物及其用途、烯烃聚合用催化剂成分、包含所述成分的烯烃聚合用催化剂以及使用所述催化剂生产乙烯类聚合物的方法
US20140194277A1 (en) * 2011-03-30 2014-07-10 Japan Polyethylene Corporation Ethylene-based polymer, polyethylene-based resin composition and use thereof, catalyst component for olefin polymerization, olefin polymerization catalyst containing the component, and method for producing ethylene-based polymer by using the catalyst
JP2016183334A (ja) * 2015-03-25 2016-10-20 日本ポリエチレン株式会社 ポリエチレン系樹脂組成物
JP6791662B2 (ja) * 2016-06-27 2020-11-25 旭化成株式会社 ポリエチレン系パウダー、ポリエチレン系パウダーの製造方法、ポリエチレン系樹脂組成物、及び架橋ポリエチレン管の製造方法
WO2018032745A1 (zh) * 2016-08-19 2018-02-22 中国科学院化学研究所 超高分子量超细粒径丙烯聚合物及其制备方法和应用
WO2020179650A1 (ja) * 2019-03-01 2020-09-10 旭化成株式会社 ポリエチレンパウダー、並びにこれを成形してなる成形体

Also Published As

Publication number Publication date
WO2022268961A2 (en) 2022-12-29
EP4359453A2 (en) 2024-05-01
WO2022268961A3 (en) 2023-02-02
JP2024525008A (ja) 2024-07-09
BR112023026990A2 (pt) 2024-03-12
US20240287217A1 (en) 2024-08-29
CA3223004A1 (en) 2022-12-29
KR20240024252A (ko) 2024-02-23

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