CN117279617A - 定妆化妆品组合物 - Google Patents
定妆化妆品组合物 Download PDFInfo
- Publication number
- CN117279617A CN117279617A CN202280032811.2A CN202280032811A CN117279617A CN 117279617 A CN117279617 A CN 117279617A CN 202280032811 A CN202280032811 A CN 202280032811A CN 117279617 A CN117279617 A CN 117279617A
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- Prior art keywords
- composition
- oil
- sio
- soluble film
- cosmetic
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- 239000000203 mixture Substances 0.000 title claims abstract description 64
- 239000002537 cosmetic Substances 0.000 title claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 229920000642 polymer Polymers 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims description 20
- 239000011347 resin Substances 0.000 claims description 20
- 125000003545 alkoxy group Chemical group 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 6
- 229910004283 SiO 4 Inorganic materials 0.000 claims description 6
- 229920006037 cross link polymer Polymers 0.000 claims description 6
- 238000005191 phase separation Methods 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 4
- 229960003237 betaine Drugs 0.000 claims description 4
- 239000003595 mist Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical group C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 claims description 3
- 229910002808 Si–O–Si Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical group C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
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- 239000003921 oil Substances 0.000 description 21
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- 239000012071 phase Substances 0.000 description 12
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- 239000007788 liquid Substances 0.000 description 7
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- 150000002430 hydrocarbons Chemical class 0.000 description 3
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- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
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- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
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- 230000004888 barrier function Effects 0.000 description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
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- 230000000052 comparative effect Effects 0.000 description 2
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- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 235000020673 eicosapentaenoic acid Nutrition 0.000 description 2
- 229960005135 eicosapentaenoic acid Drugs 0.000 description 2
- JAZBEHYOTPTENJ-UHFFFAOYSA-N eicosapentaenoic acid Natural products CCC=CCC=CCC=CCC=CCC=CCCCC(O)=O JAZBEHYOTPTENJ-UHFFFAOYSA-N 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical compound CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
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- 239000002649 leather substitute Substances 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
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- DVSZKTAMJJTWFG-SKCDLICFSA-N (2e,4e,6e,8e,10e,12e)-docosa-2,4,6,8,10,12-hexaenoic acid Chemical compound CCCCCCCCC\C=C\C=C\C=C\C=C\C=C\C=C\C(O)=O DVSZKTAMJJTWFG-SKCDLICFSA-N 0.000 description 1
- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 description 1
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Abstract
[课题]提供能够抑制脱妆的定妆化妆品组合物。[解决手段]使用一种定妆化妆品组合物，其包含油分、作为具有特定结构的聚合物的油溶性成膜剂以及水而成。
Description
技术领域
本发明涉及定妆化妆品组合物及将定妆化妆品组合物填充至分配器型容器而成的化妆品。
背景技术
为了防止脱妆、提高粉底液等上妆化妆品的持妆，开发有从实施了化妆的脸部上方进行涂布使用的定妆化妆品(例如专利文献1)。使用者诉求该定妆化妆品具有吸附皮脂、保护肌肤不受干燥、或保护肌肤不受花粉、灰尘等外部因素的影响、或化妆不易转移到衣服等上的功能。进而，由于新型冠状病毒的感染预防，戴口罩在日常过程中，使用者强烈要求粉底液不易粘附于口罩。
作为直接应用于肌肤的隔离化妆品、通常的彩妆化妆品中使用的成膜剂，提出有有机高分子、有机硅系树脂等(例如专利文献2)。
现有技术文献
专利文献
专利文献1：日本特开2020-026401号公报
专利文献2：日本特开2020-029454号公报
发明内容
本发明人等令人吃惊地发现，通过在化妆之后涂布包含油分、作为具有特定结构的聚合物的油溶性成膜剂以及水而成的定妆化妆品，能够抑制脱妆。
本发明是基于这种见解而完成的，公开了一种化妆品组合物，其包含油分、作为具有特定结构的聚合物的油溶性成膜剂以及水而成。
根据本发明，提供以下发明。
[1]一种定妆化妆品组合物，其包含：
(A)油分；
(B)油溶性成膜剂，其包含树脂结构和线性结构，
前述树脂结构包含由SiO4/2所示的单元或由R1SiO3/2所示的单元，其中R1为C1-6烷基或C1-6烷氧基，
前述线性结构包含由R2SiO2/2所示的单元，其中R2为C1-6烷基或C1-6烷氧基，
前述油溶性成膜剂为前述树脂结构和前述线性结构通过Si-O-Si键连结而成的聚合物；以及
(C)水。
[2]根据[1]所述的组合物，其中，前述树脂结构包含由SiO4/2所示的单元和由(R3)3SiO1/2所示的单元，其中R3为C1-6烷基或C1-6烷氧基。
[3]根据[1]或[2]所述的组合物，其中，前述聚合物具有羟基。
[4]根据[1]或[2]所述的组合物，其中，前述油溶性成膜剂为硅酮树脂胶。
[5]根据[1]或[2]所述的组合物，其中，前述油溶性成膜剂为三甲基硅烷氧基硅酸酯/聚二甲基硅氧烷醇交联聚合物。
[6]根据[1]或[2]所述的组合物，其中，前述油溶性成膜剂的配合量相对于组合物的总量为0.05～5质量％。
[7]根据[1]或[2]所述的组合物，其还包含表面活性剂。
[8]根据[7]所述的组合物，其中，前述表面活性剂为甜菜碱型表面活性剂。
[9]根据[1]或[2]所述的组合物，其在静置时发生相分离。
[10]一种化妆品，其将[1]或[2]所述的组合物填充至分配器型容器而成。
[11]根据[10]所述的化妆品，其中，前述组合物以雾状喷出。
[12]根据[10]或[11]所述的化妆品，其在使用前通过振动使前述组合物乳化。
本发明的定妆化妆品能够抑制脱妆。尤其能够抑制粉底液等上妆化妆品在口罩上的附着。
具体实施方式
本发明涉及定妆化妆品组合物(以下有时称为组合物)，其包含(A)油分、(B)具有特定结构的油溶性成膜剂以及(C)水而成。
此处，本发明中的定妆化妆品组合物的含义是指在化妆之后应用的、对化妆赋予润肤功能的组合物，与直接应用于肌肤的隔离化妆品或通常的彩妆化妆品不同。
具体而言，在实施了粉底液等底妆、眼影、腮红等的上妆之后，应用定妆化妆品。本发明的优选方式中，本发明的定妆化妆品在粉底液之后应用。由此，能够在戴口罩时抑制粉底液在口罩上的附着。
本发明的组合物优选为在静置时发生相分离的化妆品组合物。静置时可以为2相以上，优选为2相，典型地，静置时从上依次成为油相、水相。通过发生相分离，能够稳定地配合与各相相匹配的化妆品成分、尤其是有效成分。
相分离状态的组合物优选在使用前通过振动使其乳化来使用。本发明的一个优选方式中，通过振动，将分离出的油相和水相均匀地分散于整体中，整体成为单相状态，之后通过静置发生再次分离。
(A)油分
本发明的组合物包含(A)油分(以下有时称为(A)成分。(B)以后下同)。作为(A)成分，例如可列举出硅油、烃油、高级脂肪酸、高级醇、合成酯油、液体油脂等，优选为硅油或烃油，更优选为硅油。
作为硅油，例如可列举出链状聚硅氧烷(例如，聚二甲基硅氧烷、聚甲基苯基硅氧烷、聚二苯基硅氧烷等)、环状聚硅氧烷(例如，八甲基环四硅氧烷、十甲基环五硅氧烷、十二甲基环六硅氧烷等)、形成三维网眼结构的硅酮树脂、硅橡胶、各种改性聚硅氧烷(氨基改性聚硅氧烷、聚醚改性聚硅氧烷、烷基改性聚硅氧烷、氟改性聚硅氧烷等)、丙烯酸有机硅类等，优选为链状聚硅氧烷。
作为烃油，例如可列举出异十二烷、异十六烷、异链烷烃、液体石蜡、地蜡、角鲨烷、姥鲛烷、石蜡、纯地蜡、角鲨烯、凡士林、微晶蜡等。
作为高级脂肪酸，例如可列举出月桂酸、肉豆蔻酸、棕榈酸、硬脂酸、山嵛酸、油酸、十一烯酸、妥尔油酸、异硬脂酸、亚油酸、亚麻酸、二十碳五烯酸(EPA)、二十二碳六烯酸(DHA)等。
作为高级醇，例如可列举出直链醇(例如，月桂醇、鲸蜡醇、硬脂醇、山嵛醇、肉豆蔻醇、油醇、十八十六醇等)、支链醇(例如，单硬脂基甘油醚(鲨肝醇)、2-癸基十四碳炔醇、羊毛脂醇、胆甾醇、植物甾醇、己基十二烷醇、异硬脂醇、辛基十二烷醇等)等。
作为合成酯油，例如可列举出辛酸辛酯、壬酸壬酯、鲸蜡醇乙基己酸酯、肉豆蔻酸异丙酯、辛基十二醇肉豆蔻酸酯、棕榈酸异丙酯、棕榈酸乙基己酯、硬脂酸丁酯、月桂酸己酯、肉豆蔻醇肉豆蔻酸酯、油酸癸酯、二甲基辛酸己基癸基酯、鲸蜡醇乳酸酯、肉豆蔻醇乳酸酯、乙酰化羊毛脂、异鲸蜡醇硬脂酸酯、异鲸蜡醇异硬脂酸酯、胆甾醇12-羟基硬脂酸酯、乙二醇二(2-乙基己酸)酯、二季戊四醇脂肪酸酯、单异硬脂酸-N-烷基二醇酯、新戊二醇二癸酸酯、二特戊酸三丙二醇酯、二异硬脂醇苹果酸酯、甘油二-2-庚基十一烷酸酯、甘油二异硬脂酸酯、三羟甲基丙烷三(2-乙基己酸)酯、三羟甲基丙烷三异硬脂酸酯、季戊四醇四(2-乙基己酸)酯、甘油三(2-乙基己酸)酯、三辛酸甘油酯、三异棕榈酸甘油酯、三羟甲基丙烷三异硬脂酸酯、鲸蜡醇2-乙基己酸酯、棕榈酸2-乙基己酯、甘油三肉豆蔻酸酯、甘油三(2-庚基十一烷酸)酯、蓖麻醇酸甲酯、油醇油酸酯、乙酰甘油酯、2-庚基十一烷醇棕榈酸酯、己二酸二异丁酯、N-月桂酰基-L-谷氨酸-2-辛基十二烷基酯、二(2-庚基十一烷醇)己二酸酯、月桂酸乙酯、癸二酸二(2-乙基己酯)、肉豆蔻酸2-己基癸酯、棕榈酸2-己基癸酯、己二酸2-己基癸酯、癸二酸二异丙酯、琥珀酸(2-乙基己酯)、柠檬酸三乙酯、鲸蜡醇乙基己酸酯等。
作为液体油脂，例如可列举出鳄梨油、山茶油、澳洲坚果籽油、玉米油、橄榄油、菜籽油、芝麻油、桃仁油、小麦胚芽油、山茶花油、蓖麻油、亚麻籽油、红花油、棉籽油、紫苏油、大豆油、花生油、茶籽油、榧子油、米糠油、泡桐油、日本桐油、霍霍巴油、胚芽油、三聚甘油等。作为固体油脂，例如可列举出可可脂、椰子油、氢化椰子油、棕榈油、棕榈仁油、日本蜡仁油、氢化油、野漆果蜡、氢化蓖麻油等。
关于(A)成分的配合量，相对于本发明的组合物的总量优选为1～20质量％，更优选为3～15质量％。通过设为该范围，从而能够使相分离变得良好、且能够抑制应用于肌肤时的粘腻、油腻。
(B)油溶性成膜剂
本发明的组合物为包含树脂结构和线性结构的油溶性成膜剂，
树脂结构包含由SiO4/2所示的单元或由R1SiO3/2(R1为C1-6烷基或C1-6烷氧基)所示的单元，线性结构包含由R2SiO2/2(R2为C1-6烷基或C1-6烷氧基)所示的单元，
所述油溶性成膜剂(以下，有时称为油溶性成膜剂、聚合物或(B)成分)为树脂结构和线性结构通过Si-O-Si键连结而成的聚合物。
本发明中使用的油溶性成膜剂的特征之一是具有树脂结构和线性结构这两个结构。一般而言，聚合物仅由树脂结构构成，源自该结构的成膜性和粘合性优异，但柔软性、追随性有时不充分。然而，在聚合物中组合线性结构时，聚合物变得兼具柔软性和追随性。若应用包含具有这种特征的油溶性成膜剂的化妆品，则能够形成柔软且具有粘合性的覆膜。由此认为，若在化妆后形成这种覆膜，则对于与口罩或衣服等的摩擦、皮脂或汗液等起到保护化妆的层的功能，因此，有效地抑制脱妆。
树脂结构包含由SiO4/2所示的单元(以下有时称为Q单元)或由R1SiO3/2(R1为C1-6烷基或C1-6烷氧基，优选为甲基、乙基、丙基、甲氧基、乙氧基或丙氧基，更优选为甲基)(以下有时称为T单元)所示的单元而成，优选包含Q单元而成。
树脂结构除了上述单元以外，还可以也包含(R3)3SiO1/2(R3为C1-6烷基或C1-6烷氧基，优选为甲基、乙基、丙基、甲氧基、乙氧基或丙氧基，更优选为甲基)所示的单元(以下有时称为M单元)。
优选的一个方式中，树脂结构包含M单元和Q单元而成，更优选为由M单元和Q单元构成的结构(MQ结构)。
线性结构包含由R2SiO2/2(R2为C1-6烷基或C1-6烷氧基，优选为甲基、乙基、丙基、甲氧基、乙氧基或丙氧基，更优选为甲基)所示的单元(以下有时称为D单元)而成。线性结构优选D单元的5个单元以上连结成链状，连续地键合成链状的数量更优选5～1000、进而更优选10～300。换言之，D单元为多个、优选为5以上、连结的部分为线性结构，除此以外的Q单元、T单元、D单元和M单元混合存在的部分为树脂结构。
线性结构优选在分子链的末端具有羟基(硅烷醇基)。
树脂结构和线性结构的连结部通过Si-O-Si键连结，通过该Si-O-Si键连结的结构在分子内可以为多个。优选的一个方式中，键合于树脂结构的Si原子为T单元。
聚合物1分子中所含的树脂结构与线性结构的质量比优选为50：50～95：5，更优选为60：40～90：10。
(B)成分优选为有机硅系成膜剂，更优选为硅酮树脂胶。具体而言，可列举出三甲基硅烷氧基硅酸酯/聚二甲基硅氧烷醇交联聚合物。
对于(B)成分的质均分子量，从作为成膜剂的功能和溶解性的观点出发，优选为5000～100000，更优选为10000～50000。此处，质均分子量是基于凝胶渗透色谱法的聚苯乙烯换算的值。
(B)成分可以配合1种或2种以上。(B)成分的配合量相对于本发明的组合物的总量优选为0.05～5质量％，更优选为1～5质量％。
(C)水
本发明的组合物包含(C)水。作为水，可以使用化妆品、准药物等中使用的水，例如，可以使用纯化水、离子交换水、自来水等。
水的配合量相对于本发明的组合物的总量优选为40～95质量％，更优选为60～95质量％。
本发明的组合物优选还包含表面活性剂。作为表面活性剂，可列举出阴离子性表面活性剂、阳离子性表面活性剂、两性表面活性剂、非离子性表面活性剂，优选为非离子性表面活性剂或两性表面活性剂，更优选为两性表面活性剂。
作为两性表面活性剂，可列举出例如咪唑啉系两性表面活性剂(例如，2-十一烷基-N,N,N-(羟乙基羧甲基)-2-咪唑啉钠、2-椰油酰基-2-咪唑鎓氢氧化-1-羧基乙氧基二钠盐等)；甜菜碱型表面活性剂(例如，月桂基甜菜碱、椰油酰胺丙基甜菜碱、氨基甜菜碱、磺基甜菜碱等)等，优选为甜菜碱型表面活性剂。
表面活性剂可以配合1种或2种以上。
表面活性剂的配合量相对于本发明的组合物的总量优选为0.01～0.2质量％，更优选为0.02～0.1质量％。
本发明的组合物可以包含氯化钠。通过包含氯化钠，在发生相分离的化妆品组合物的情况下，可以清除相界面，并且可以调整分离速度。
氯化钠的配合量相对于本发明的组合物的总量优选为0.01～0.5质量％，更优选为0.05～0.3质量％。通过设为该范围，从而能够抑制由氯化钠所致的粘腻，且可以清除相界面、调整分离速度。
本发明的组合物可以包含低级醇。通过配合低级醇，可以减轻组合物的比重。另外，能够赋予清爽的使用感。作为低级醇，例如可以举出乙醇、丙醇、异丙醇、异丁醇、叔丁醇等。
低级醇的配合量相对于本发明的组合物的总量优选为1～45质量％，更优选为5～30质量％。
作为上述以外的任意成分，可列举出化妆品中通常使用的成分，例如保湿剂、增稠剂、杀菌剂、防腐剂、pH调节剂、紫外线吸收剂、抗氧化剂、有机和无机粉体、香料、颜料、染料、美白剂、维生素类、各种氨基酸等。
本发明的组合物可以按照常规方法制造。
本发明的化妆品是将本发明的组合物填充到分配器型容器中而成的化妆品。本发明的组合物优选从该容器以雾状喷出本发明的组合物。由于本发明的组合物被喷成雾状，能够不直接接触皮肤，并且均匀地涂布，所以不会破坏化妆，能够在化妆上形成薄、均匀、不易模糊的膜。
实施例
基于以下例对本发明进行具体说明，但本发明并不限定于这些例子。含量除非另有说明，以相对于总量的质量％表示。
[实施例1～6和比较例1～3]
以表1所示配比制备实施例1～6和比较例1～3的组合物。将制备好的组合物在静置状态下观察外观时，全部发生了2相分离。
[表1]
表中，三甲基硅烷氧基硅酸酯/聚二甲基硅氧烷醇交联聚合物使用了“DOWSIL FC-5004DM(1.5cSt Silicone Resin Gum)”(Dow Toray Co.,Ltd.)。需要说明的是，“DOWSILFC-5004DM(1.5cSt Silicone Resin Gum)”为包含溶解于低粘度聚二甲基硅氧烷液中的三甲基硅烷氧基硅酸酯/聚二甲基硅氧烷醇交联聚合物的制品，而表中所述的质量％仅是指三甲基硅烷氧基硅酸酯/聚二甲基硅氧烷醇交联聚合物，不包含商品中所含的溶剂等。
[口罩上的彩妆附着容易度评价]
将上述制备的组合物收纳于分配器型的喷雾容器中。
在人工皮革上涂布规定量的液体粉底液，使其干燥30分钟。然后，从离人工皮革为15cm的距离处，喷三次喷雾容器以涂布组合物。然后，用喷雾容器将离子交换水离从离15cm的距离处喷三次，然后涂布油酸(0.5mg/cm2)，使其干燥30分钟，使用安装了非织造布的轻敲试验机，进行10次轻敲。通过目视观察向非织造布上的颜色转移，基于以下基准进行评价。得到的结果如表1所示。
A：未确认到向非织造布上的颜色转移。
B：稍有确认到向非织造布上的颜色转移。
C：确认到向非织造布上的颜色转移比B多。
将实施例1～6的组合物收纳于分配器型的喷雾容器中，通过喷雾向彩妆后的脸部涂布。经过8小时之后确认，结果未确认到脱妆、模糊，而且彩妆也没有变淡。
Claims (12)
1.一种定妆化妆品组合物，其包含：
(A)油分；
(B)包含树脂结构和线性结构的油溶性成膜剂，
所述树脂结构包含由SiO4/2所示的单元或由R1SiO3/2所示的单元，其中R1为C1-6烷基或C1-6烷氧基，
所述线性结构包含由R2SiO2/2所示的单元，其中R2为C1-6烷基或C1-6烷氧基，
所述油溶性成膜剂为所述树脂结构和所述线性结构通过Si-O-Si键连结而成的聚合物；以及
(C)水。
2.根据权利要求1所述的组合物，其中，所述树脂结构包含由SiO4/2所示的单元和由(R3)3SiO1/2所示的单元，其中R3为C1-6烷基或C1-6烷氧基。
3.根据权利要求1或2所述的组合物，其中，所述聚合物具有羟基。
4.根据权利要求1或2所述的组合物，其中，所述油溶性成膜剂为硅酮树脂胶。
5.根据权利要求1或2所述的组合物，其中，所述油溶性成膜剂为三甲基硅烷氧基硅酸酯/聚二甲基硅氧烷醇交联聚合物。
6.根据权利要求1或2所述的组合物，其中，所述油溶性成膜剂的配合量相对于组合物的总量为0.05～5质量％。
7.根据权利要求1或2所述的组合物，其还包含表面活性剂。
8.根据权利要求7所述的组合物，其中，所述表面活性剂为甜菜碱型表面活性剂。
9.根据权利要求1或2所述的组合物，其在静置时发生相分离。
10.一种化妆品，其将权利要求1或2所述的组合物填充至分配器型容器而成。
11.根据权利要求10所述的化妆品，其中，所述组合物以雾状喷出。
12.根据权利要求10或11所述的化妆品，其在使用前通过振动使所述组合物乳化。
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