CN1172100A - Method for producing full-soluble calcium of organic acid using bird's egg shell - Google Patents
Method for producing full-soluble calcium of organic acid using bird's egg shell Download PDFInfo
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- CN1172100A CN1172100A CN 97110498 CN97110498A CN1172100A CN 1172100 A CN1172100 A CN 1172100A CN 97110498 CN97110498 CN 97110498 CN 97110498 A CN97110498 A CN 97110498A CN 1172100 A CN1172100 A CN 1172100A
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Abstract
The present invention relates to a method for producing full-soluble organic acid calcium by using egg shell, and it is characterized by that the egg shell powder or paste and edible organic acid are mixed and diluted by adding water, passed through the process of displacement reaction so as to produce saturated organic acid calcium solution, then the obtained saturated solution can be further heated, concentrated, oven-dried and pulverized so as to obtain the invented powdered organic acid calcium or its crystalline one. Said invention is non-toxic, high in caclium content, good in solubility, easy to be absorbed by human body, low in cost, and its raw material is easily available and its preparation process in simple.
Description
The present invention relates to a kind ofly utilize the production of birds, beasts and eggs shell edible with the full-soluble calcium of organic acid that replenishes the human body calcium deficiency and the method for series product thereof for people.
The great mass of data explanation, calcium is the mineral element that the universe lacks, everybody must mend.The existing following defective of product ubiquity of replenishing the calcium: 1) calcium content is low, 2) solubleness is little, the utilization that is difficult to be absorbed by the body, so effect of supplemented calcium is generally undesirable.
The purpose of this invention is to provide a kind of method of producing full-soluble calcium of organic acid and series product thereof with the birds, beasts and eggs shell.
The object of the present invention is achieved like this: make raw material with the birds, beasts and eggs shell, major ingredient lime carbonate generation replacement(metathesis)reaction by organic acid and eggshell generates water-soluble calcium of organic acid, and the calcium of organic acid of producing full closes liquid liquid or powder, xln and promptly can be used as finished product and sell or make oral liquid or dose in the food seasoning.
Specifically can be divided into two kinds of production methods of dry method and wet method.
(1) dry method:
Raw material: birds, beasts and eggs shell, edible organic acid, water.
The operation step is poly-: i) the birds, beasts and eggs shell cleaned and removed inner membrance, and oven dry, being ground into fineness is the following powder of 100 orders; Ii) put into container and add water and stir evenly in right amount, add edible organic acid slowly, the limit edged stirs, and dilute with water, producing the full calcium of organic acid solution that closes, and crosses 200 order silk sieve, obtains finished product after removing residue.
(2), wet method:
Raw material: birds, beasts and eggs shell, edible organic acid, water
Operation step is poly-: i) the birds, beasts and eggs shell is cleaned and removed inner membrance, add the water mill slurry, make and contain solids more than 40%, fineness is the following birds, beasts and eggs shell cream of 100 orders; Ii) birds, beasts and eggs shell cream adds water and stirs evenly in right amount, adds edible organic acid slowly, and the limit edged stirs, and producing the full calcium of organic acid solution that closes, and crosses 200 order silk sieve, obtains finished product after removing residue.
Above-mentioned dry method or wet production go out fullly closes powder or the xln that calcium of organic acid solution can further make calcium of organic acid, its method is: the calcium of organic acid solution that closes of will satisfying is further heated, discard suspended substance and make it purifying, be condensed into cream, oven dry is pulverized and is obtained calcium of organic acid powder or xln then.
In the method for full calcium of organic acid solution, calcium of organic acid powder or the xln that closes of above-mentioned production, edible organic acid can adopt glacial acetic acid, acetate, thereby the full-soluble calcium of organic acid that obtains is full calcium acetate solution, lime acetate powder or the xln that closes; Thereby also can adopt citric acid to obtain full citrate of lime solution, citrate of lime powder or the xln that closes.
Full calcium acetate solution, lime acetate powder or the xln of closing that utilizes glacial acetic acid, acetate to make can further be produced complete molten high-calsium vinegar; Its method is:
Raw material: make vinegar and satisfy and close calcium acetate solution, lime acetate powder or xln.
Operation steps: i) measure the full calcium content that closes calcium acetate solution, lime acetate powder or xln; Ii) making vinegar by every liter contains the proportion requirement of 1000 to 5000mg calcium, and a considerable amount of full calcium acetate solutions or lime acetate powder or xln of closing are added and make vinegar.
The present invention has following positively effect: i) security is good, has great social value, and eggshell is the outer packaging of life, is the paradise of chick life survival, and is not only nontoxic, and has irreplaceable unique function to preserving life.Eggshell calcium is a high-quality biosynthesizing calcium thereby definitely nontoxic to human body.Produce full-soluble calcium of organic acid with eggshell, will make whole people's calcium deficiency, this social difficult problem of replenishing the calcium, extremely easily solve, thereby have great social value.(2) the full-soluble calcium of organic acid product calcium content height of producing has remarkable economical and is worth.Can produce 1.5 kilograms of calcium acetates through the per 1 kilogram of egg-shell meal of experiment, amount to pure calcium 390g, calculate and to obey 390 days for a people by everyone 1.0g every day.Be equivalent to existing product lid day power 325 boxes of replenishing the calcium, be 4225 yuan at a discount.Only need the 1800ml glacial acetic acid and produce the pure calcium of 390g, have only 14.4 yuan at a discount, ignore as reclaiming eggshell, produce five fens of every gram calcium raw materials cost less than, its economic benefit is appreciable.3) the full-soluble calcium of organic acid product solubility of producing is good, and the utilization that easily is absorbed by the body is soluble in water because of calcium of organic acid acidity is low, so very easily received by the human gastrointestinal tract.
Do detailed explanation below in conjunction with embodiment:
The principles of chemistry: the major ingredient of birds, beasts and eggs shell is a lime carbonate, and replacement(metathesis)reaction takes place behind the ice acetic acid, and its reaction formula is as follows:
Reaction gained lime acetate is the full dissolubility water white transparency aqueous solution.
Raw material: Ovum crusta Gallus domesticus: derive from the factory of raising chickens, food factory.
Glacial acetic acid: the first class product that can select North China Pharmaceutical Factory or the 98--99% of Daqing petrochemical main office for use.
Diluting water: select for use distilled water, deionized water, filtered water or high-quality phreatic water all can.
Operation steps: divide two kinds of dry method and wet methods,, can select dry technology for production for use for guaranteeing planned production such as production and marketing, storage, turnover.Introduce respectively below:
Dry method: Ovum crusta Gallus domesticus → clean and remove interior mantle, baking (solarization) is done, being ground into 100 orders (thin more good more) fine powder → get fine powder, 1000 grams adds water and stirs evenly in right amount, add glacial acetic acid (the limit edged stirs) gradually, and look the feelings thin up, its ratio is as follows: the liquid of former egg-shell meal 1000g/ glacial acetic acid 1800--2000ml/ water inventory 10000--12000ml → reaction termination is crossed and is heated behind 200 order silk sieve → removals residues concentratedly, and purifying (discarding seston) becomes cream → oven drying at low temperature → pulverizing pack → direct encapsulated confession to take orally.
Wet method: Ovum crusta Gallus domesticus → mantle in clean removing → become the to contain eggshell cream of solids 40% with paste mill grinding, adding water with 2500g eggshell cream stirs evenly in right amount, slowly add glacial acetic acid, the limit edged stirs, reaction stops foam and disappears, continue ice acetic acid and water, the two intersects and adds and constantly stirring, generally need glacial acetic acid 1800--2000ml, water 8000--10000ml → drag for supernatant → mistake 200 order silk sieve → removal residues, heat and be condensed into cream (discarding suspended substance, purifying) → oven drying at low temperature → pulverizing and pack → directly incapsulate or make other formulation for oral.
For guaranteeing to work continuously or scale operation, can select big reaction tank, bucket or jar for use, one time capacity adds enough substrates (egg-shell meal), slowly repeatedly adding glacial acetic acid under stirrer stirs reacts, and the full calcium acetate solution that closes proposed repeatedly, look the base consumption situation and constantly replenish, work continuously with maintenance.The length in reaction times and substrate, the ratio of glacial acetic acid and water is relevant.Static again 30 behind the reaction terminating '--60 ' the full liquid that closes on top can be proposed.As being arranged after static, insoluble foam (being protein and pigment) should abandon it.The full calcium acetate solution that closes that proposes can further be made solid lime acetate powder or xln.
Utilize lime acetate that aforesaid method produces fullly to close liquid or powder, xln can further be made complete molten high-calsium vinegar (being calcic vinegar), its method is, at first measure its calcium content, add respectively in the ratio of every liter of 1000mgCa, 2000mgCa, 3000mgCa, 4000mgCa, 5000mgCa then and make complete molten high-calsium vinegar I type, II type, III type, IV type, V-type etc. in making vinegar, directly edible, very favourable to the absorption of calcium.
Claims (7)
1, a kind of method of producing full-soluble calcium of organic acid with the birds, beasts and eggs shell is characterized in that: produce with following raw material and operation steps:
Raw material: birds, beasts and eggs shell, edible organic acid, water
Operation steps: i) with the clean inner membrance that goes of birds, beasts and eggs shell, oven dry, being ground into fineness is the following powder of 100 orders; Ii) put into container and add water and stir evenly in right amount, add edible organic acid slowly, the limit edged stirs, and dilute with water, producing the full calcium of organic acid solution that closes, and crosses 200 order silk sieve, obtains finished product after removing residue.
2, a kind of method of producing full-soluble calcium of organic acid with the birds, beasts and eggs shell is characterized in that: produce with following raw material and operation steps.
Raw material: birds, beasts and eggs shell, edible organic acid, water.
Operation steps: i) the birds, beasts and eggs shell is cleaned removed inner membrance, add the water mill slurry, make and contain solids more than 40%, fineness is the following birds, beasts and eggs shell cream of 100 orders; Ii) birds, beasts and eggs shell cream adds water and stirs evenly in right amount, adds edible organic acid slowly, and the limit edged stirs, and producing the full calcium of organic acid solution that closes, and crosses 200 order silk sieve, obtains finished product after removing residue.
3, method of producing full-soluble calcium of organic acid with the birds, beasts and eggs shell according to claim 1, it is characterized in that: comprise during the operation step is poly-: the calcium of organic acid solution that closes of will satisfying is further heated, discard suspended substance and make it purifying, be condensed into cream, dry then, pulverize, obtain calcium of organic acid powder or xln.
4, method of producing full-soluble calcium of organic acid with the birds, beasts and eggs shell according to claim 2, it is characterized in that: comprise during the operation step is poly-: the calcium of organic acid solution that closes of will satisfying is further heated, discard suspended substance and make it purifying, be condensed into cream, dry then, pulverize, obtain calcium of organic acid powder or xln.
5, according to claim 1,2,3 or 4 described methods of producing full-soluble calcium of organic acid with the birds, beasts and eggs shell, it is characterized in that: edible organic acid is glacial acetic acid or acetate in the raw material, and the finished product that makes is complete molten lime acetate.
6, according to claim 1,2,3 or 4 described methods of producing full-soluble calcium of organic acid with the birds, beasts and eggs shell, it is characterized in that: edible organic acid is a citric acid in the raw material, and the finished product that makes is complete molten citrate of lime.
7, a kind of method with the complete molten high-calsium vinegar of birds, beasts and eggs shell production is characterized in that: adopt following raw material and operation steps to produce.
Raw material: the complete molten lime acetate that makes vinegar and make by aforesaid right requirement 5 methods.
Operation steps: the i) calcium content of the complete molten lime acetate of mensuration; Ii) making vinegar by every liter contains the proportion requirement of 1000 to 5000mg calcium, during a considerable amount of complete molten lime acetates addings are made vinegar.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97110498 CN1172100A (en) | 1997-05-30 | 1997-05-30 | Method for producing full-soluble calcium of organic acid using bird's egg shell |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97110498 CN1172100A (en) | 1997-05-30 | 1997-05-30 | Method for producing full-soluble calcium of organic acid using bird's egg shell |
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| Publication Number | Publication Date |
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| CN1172100A true CN1172100A (en) | 1998-02-04 |
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| CN 97110498 Pending CN1172100A (en) | 1997-05-30 | 1997-05-30 | Method for producing full-soluble calcium of organic acid using bird's egg shell |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103202492A (en) * | 2013-01-09 | 2013-07-17 | 湖南农业大学 | Preparation method for high-calcium flavor spiced duck egg |
| CN103961688A (en) * | 2014-04-30 | 2014-08-06 | 湖北神地农业科贸有限公司 | Eggshell source compound calcium citrate chewable tablet and preparation method thereof |
| CN104387256A (en) * | 2014-11-12 | 2015-03-04 | 天津渤化永利化工股份有限公司 | Method for utilizing mixed waste acids in acetic acid production device |
| CN104387256B (en) * | 2014-11-12 | 2017-01-04 | 天津渤化永利化工股份有限公司 | A kind of production of acetic acid device mixes the Application way of spent acid |
| CN108497334A (en) * | 2018-04-25 | 2018-09-07 | 河南科技大学 | It is a kind of to ferment mutton sausage and preparation method using industrial egg shell as the high calcium of calcium source |
| CN109744492A (en) * | 2019-01-10 | 2019-05-14 | 蕴彤本草(北京)生物科技有限公司 | Production method of high bioactivity shell egg body fermentation material and products thereof and application |
-
1997
- 1997-05-30 CN CN 97110498 patent/CN1172100A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103202492A (en) * | 2013-01-09 | 2013-07-17 | 湖南农业大学 | Preparation method for high-calcium flavor spiced duck egg |
| CN103961688A (en) * | 2014-04-30 | 2014-08-06 | 湖北神地农业科贸有限公司 | Eggshell source compound calcium citrate chewable tablet and preparation method thereof |
| CN104387256A (en) * | 2014-11-12 | 2015-03-04 | 天津渤化永利化工股份有限公司 | Method for utilizing mixed waste acids in acetic acid production device |
| CN104387256B (en) * | 2014-11-12 | 2017-01-04 | 天津渤化永利化工股份有限公司 | A kind of production of acetic acid device mixes the Application way of spent acid |
| CN108497334A (en) * | 2018-04-25 | 2018-09-07 | 河南科技大学 | It is a kind of to ferment mutton sausage and preparation method using industrial egg shell as the high calcium of calcium source |
| CN109744492A (en) * | 2019-01-10 | 2019-05-14 | 蕴彤本草(北京)生物科技有限公司 | Production method of high bioactivity shell egg body fermentation material and products thereof and application |
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