CN117121913A - 含28-高芸苔素内酯和氨基寡糖素的组合物、制剂及其应用 - Google Patents
含28-高芸苔素内酯和氨基寡糖素的组合物、制剂及其应用 Download PDFInfo
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Classifications
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01P21/00—Plant growth regulators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Botany (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明涉及生物农药技术领域，特别是涉及一种含28‑高芸苔素内酯和氨基寡糖素的组合物、制剂及其应用。所述组合物活性成分包含28‑高芸苔素内酯和氨基寡糖素，所述28‑高芸苔素内酯和氨基寡糖素的质量比为1：(0.05～20)。本发明的目的是提供一种含28‑高芸苔素内酯和氨基寡糖素的组合物、制剂及其应用，用于调节番茄生长，以解决上述现有技术存在的问题。
Description
技术领域
本发明涉及生物农药技术领域，特别是涉及一种含28-高芸苔素内酯和氨基寡糖素的组合物、制剂及其应用。
背景技术
番茄生长过程中不可避免的会遇到病害问题，如早疫病、晚疫病、立枯病、炭疽病等。要及时发现和防治病害，可以采取化学药剂或生物制剂的方式进行防治。早疫病是由革兰氏阴性菌引起的病害，症状表现为叶片上出现深绿色水渍，随之出现大量黄色或褐色小斑点；防治方法包括早期发现和使用化学药剂进行防治。晚疫病是由革兰氏阴性菌引起的病害，症状表现为叶片上出现小黑点，并迅速扩散，在潮湿天气下会有黏液细胞形成；防治方法包括早期发现和使用化学药剂进行防治。立枯病是由离属芽孢杆菌引起的病害，症状表现为整株植株矮化，叶片逐渐变黄；防治方法包括优质播种，控制灌溉和施肥以及定期喷洒杀菌剂。炭疽病是由炭疽杆菌引起的病害，症状表现为叶片和果实上出现灰黑色圆形或不规则病斑；防治方法包括早期发现和采取化学药剂和生物制剂等防治措施。
28-高芸苔素内酯是一种植物生长素，也被称为GA3。它在植物的生长和发育中发挥着重要作用，包括促进幼嫩组织生长、增加叶片面积和改善果实品质。它也被广泛应用于农业和园艺领域，用于控制果树的开花和结实、提高葡萄和西瓜等水果的产量和品质，以及延长鲜切花的保存时间等。
氨基寡糖素是流行于大自然中的一种活性分子，它广泛存在于植物、动物、微生物等生物体内。在农业方面，氨基寡糖素可以发挥以下作用：促进植物生长：氨基寡糖素可被植物吸收，促进根系的发育和吸收水分、养分的能力，提高植株对自然环境的适应能力；改善土壤质量：氨基寡糖素能够刺激相关菌群的生长，催化菌与土壤介质之间的物质代谢，这使得土壤更加丰富、有机质更多、通气更好、排水更畅通，从而增加表层土壤所包容的水和营养质量，达到促进作物生长和提高产量的效果；增强耐盐碱、抗病虫害能力：通过增强植物的自然屏障作用，氨基寡糖素可以使作物提高对不良环境和病虫害的抵御能力，从而增大抗旱、抗盐碱、抗病虫害等方面的表现；促进果蔬品质：氨基寡糖素在果蔬生产过程中广泛应用，有助于提高水果、香料、辣椒等作物的品质和营养成分，如口感、色泽、风味、芳香、维生素含量等。
发明内容
本发明的目的是提供一种含28-高芸苔素内酯和氨基寡糖素的组合物、制剂及其应用，用于调节番茄生长，以解决上述现有技术存在的问题。
本发明所述的辅料或载体，如乳化剂、润湿分散剂、增稠剂、防冻剂、稳定剂、防腐剂、崩解剂、粘结剂等，均是农药制剂中常规的成分。例如，所述乳化剂可以选自非离子表面活性剂蓖麻油环氧乙烷加成物(EL40或者EL90)、壬基酚聚氧乙烯醚、脂肪醇聚氧乙烯醚、苯乙基酚聚氧乙烯聚氧丙烯醚、烷基酚聚氧乙烯醚甲醛缩合物中的一种或几种；所述润湿分散剂可以选自十二烷基硫酸钠、拉开粉BX、烷基酚聚氧乙烯基醚、萘磺酸甲醛缩合物的盐或聚氧乙烯基聚氧丙烯醚嵌段共聚物中的一种或两种以上按照任意比例组成的混合物；所述增稠剂可以选自黄原胶、羧甲基纤维素、聚丙烯酸钠、硅酸铝镁、气态二氧化硅或凹凸棒土中的任何一种或多种；所述防冻剂可以选自乙二醇、丙二醇、甘油、甘油-乙醚双甘醇或甲基亚丙基双甘醇中的任意一种或一种以上按照任意比例组成的混合物；所述的稳定剂可以选自2,6-二叔丁基-4-甲基苯酚(BHT)、柠檬酸或丁基羟基茴香醚(BHA)中的任意一种或多种；所述崩解剂可以选自尿素、膨润土、蒙脱土或海藻酸钠中的任意一种或多种组成的混合物；所述的粘结剂可以选自明胶、阿拉伯胶、黄原胶、三聚磷酸钠、酚醛树脂或聚乙烯吡咯烷酮中的一种或多种组成的混合物；所述的填料可以是高岭土、陶土、膨润土中的一种或多种。
本发明提供了一种含28-高芸苔素内酯和氨基寡糖素的组合物，所述组合物活性成分包含28-高芸苔素内酯和氨基寡糖素，所述28-高芸苔素内酯和氨基寡糖素的质量比为1：(0.05～20)。
在上述含28-高芸苔素内酯和氨基寡糖素的组合物中，作为优选方案，按照重量份数计，所述组合物包括28-高芸苔素内酯10～20份和氨基寡糖素1～10份。
在上述含28-高芸苔素内酯和氨基寡糖素的组合物中，作为优选方案，按照重量份数计，所述组合物包括28-高芸苔素内酯15份和氨基寡糖素6份。
在上述含28-高芸苔素内酯和氨基寡糖素的组合物中，作为优选方案，按照重量份数计，所述组合物包括28-高芸苔素内酯1～10份和氨基寡糖素10～20份。
在上述含28-高芸苔素内酯和氨基寡糖素的组合物中，作为优选方案，按照重量份数计，所述组合物包括28-高芸苔素内酯6份和氨基寡糖素15份，占剂型总重量的0.1％—50％。
本发明还提供一种可溶粉剂制剂，按照重量份数计，所述制剂包括如上述的组合物50份，还包括有湿润剂、分散剂、白炭黑和/或填料20份，助剂包括十二烷基苯磺酸钠2-10份，填料包括硅藻土。
本发明还提供一种可溶液剂制剂，所述制剂包括如上述的组合物50份，还包括有乙二醇和/或环己酮25-50份，余量为水。
本发明还提供一种悬浮剂制剂，所述制剂包括如上述的组合物50份，还包括有乙二醇和/或环己酮2-5份，甘露醇和/或山梨醇2-5份，硫酸镁1-2份，余量为水。
本发明还提供一种颗粒剂制剂，所述制剂包括如上述的组合物50份，还包括有萘磺酸甲醛缩聚物10-15份，十二烷基硫酸钠2-5份，硫酸铵2-10份，余量为硅藻土。
本发明还提供将上述的组合物或上述的可溶粉剂或上述的可溶液剂或上述的悬浮剂或上述的颗粒剂用于调节番茄生长的应用。
本发明与现有技术相比，具有以下技术效果：
1.本发明提供了一种含28-高芸苔素内酯和氨基寡糖素的组合物，应用到番茄的生长过程中，促进幼嫩组织生长、增加叶片面积和改善番茄果实品质的同时，在生长过程中增强番茄幼苗对细菌的抵抗能力，且不易产生抗性；
2.本发明提供了一种含28-高芸苔素内酯和氨基寡糖素的组合物，能够延缓病毒病对药剂抗药性的产生，可以延长农药活性成分的使用寿命。
本发明还提供了一种含上述组合物的制剂和应用，其有益效果与组合物相似，不再赘述。
具体实施方式
现详细说明本发明的多种示例性实施方式，该详细说明不应认为是对本发明的限制，而应理解为是对本发明的某些方面、特性和实施方案的更详细的描述。
应理解本发明中所述的术语仅仅是为描述特别的实施方式，并非用于限制本发明。另外，对于本发明中的数值范围，应理解为还具体公开了该范围的上限和下限之间的每个中间值。在任何陈述值或陈述范围内的中间值以及任何其他陈述值或在所述范围内的中间值之间的每个较小的范围也包括在本发明内。这些较小范围的上限和下限可独立地包括或排除在范围内。
除非另有说明，否则本文使用的所有技术和科学术语具有本发明所述领域的常规技术人员通常理解的相同含义。虽然本发明仅描述了优选的方法和材料，但是在本发明的实施或测试中也可以使用与本文所述相似或等同的任何方法和材料。本说明书中提到的所有文献通过引用并入，用以公开和描述与所述文献相关的方法和/或材料。在与任何并入的文献冲突时，以本说明书的内容为准。
在不背离本发明的范围或精神的情况下，可对本发明说明书的具体实施方式做多种改进和变化，这对本领域技术人员而言是显而易见的。由本发明的说明书得到的其他实施方式对技术人员而言是显而易见的。本申请说明书和实施例仅是示例性的。
关于本文中所使用的“包含”、“包括”、“具有”、“含有”等等，均为开放性的用语，即意指包含但不限于。
在没有特别解释的情况下，本发明中出现的与中医、中药相关的词的含义是本领域技术人员所公知的含义，例如闷润、润透等。
本发明中所述的“份”如无特别说明，均按质量份计。
本发明所述重量份主要包括公开的数值范围，公开范围内的任一数值(包括整数和小数)或任两数值的区间，或不连续的多个区间，还包括接近数值范围端值可以预期其效果近似的数值或数值范围，比如，5-10份，不仅仅包括5份，6份，7份，8份，9份，10份以及任两个份数的区间，对于其他数值范围，不一一举例，均包含在本发明当中。因此，本发明还包括已经直接公开的任意数值范围的子范围或其中任意具体数值。
本发明提供了一种含28-高芸苔素内酯和氨基寡糖素的组合物，所述组合物活性成分包含28-高芸苔素内酯和氨基寡糖素，所述28-高芸苔素内酯和氨基寡糖素的质量比为1：(0.05～20)。
在上述含28-高芸苔素内酯和氨基寡糖素的组合物中，作为优选方案，按照重量份数计，所述组合物包括28-高芸苔素内酯10～20份(例如10份、13份、15份、20份等，可取小数)和氨基寡糖素1～10份(例如1份、2份、3份、4份、5份、8份、10份等，可取小数)。
在上述含28-高芸苔素内酯和氨基寡糖素的组合物中，作为优选方案，按照重量份数计，所述组合物包括28-高芸苔素内酯15份(例如1份、2份、3份、4份、5份、8份、10份、13份、15份等，可取小数)和氨基寡糖素6份(例如1份、2份、3份、4份、5份、6份等，可取小数)。
在上述含28-高芸苔素内酯和氨基寡糖素的组合物中，作为优选方案，按照重量份数计，所述组合物包括28-高芸苔素内酯1～10份(例如1份、2份、3份、4份、5份、8份、10份等，可取小数)和氨基寡糖素10～20份(例如10份、13份、15份、20份等，可取小数)。
在上述含28-高芸苔素内酯和氨基寡糖素的组合物中，作为优选方案，按照重量份数计，所述组合物包括28-高芸苔素内酯6份(例如1份、2份、3份、4份、5份、6份等，可取小数)和氨基寡糖素15份(例如1份、2份、3份、4份、5份、8份、10份、13份、15份等，可取小数)，占剂型总重量的0.1％—50％。
本发明还提供一种可溶粉剂制剂，按照重量份数计，所述制剂包括如上述的组合物50份，还包括有湿润剂、分散剂、白炭黑和/或填料20份，助剂包括十二烷基苯磺酸钠2-10份，填料包括硅藻土。
本发明还提供一种可溶液剂制剂，所述制剂包括如上述的组合物50份，还包括有乙二醇和/或环己酮25-50份，余量为水。
本发明还提供一种悬浮剂制剂，所述制剂包括如上述的组合物50份，还包括有乙二醇和/或环己酮2-5份，甘露醇和/或山梨醇2-5份，硫酸镁1-2份，余量为水。
本发明还提供一种颗粒剂制剂，所述制剂包括如上述的组合物50份，还包括有萘磺酸甲醛缩聚物10-15份，十二烷基硫酸钠2-5份，硫酸铵2-10份，余量为硅藻土。
本发明还提供将上述的组合物或上述的可溶粉剂或上述的可溶液剂或上述的悬浮剂或上述的颗粒剂用于调节番茄生长的应用。
以上所述的实施例仅是对本发明的优选方式进行描述，并非对本发明的范围进行限定，在不脱离本发明设计精神的前提下，本领域普通技术人员对本发明的技术方案做出的各种变形和改进，均应落入本发明权利要求书确定的保护范围内。
Claims (10)
1.一种含28-高芸苔素内酯和氨基寡糖素的组合物，其特征在于，所述组合物活性成分包含28-高芸苔素内酯和氨基寡糖素，所述28-高芸苔素内酯和氨基寡糖素的质量比为1：(0.05～20)。
2.根据权利要求1所述含28-高芸苔素内酯和氨基寡糖素的组合物，其特征在于，按照重量份数计，所述组合物包括28-高芸苔素内酯10～20份和氨基寡糖素1～10份。
3.根据权利要求2所述含28-高芸苔素内酯和氨基寡糖素的组合物，其特征在于，按照重量份数计，所述组合物包括28-高芸苔素内酯15份和氨基寡糖素6份。
4.根据权利要求1所述含28-高芸苔素内酯和氨基寡糖素的组合物，其特征在于，按照重量份数计，所述组合物包括28-高芸苔素内酯1～10份和氨基寡糖素10～20份。
5.根据权利要求4所述含28-高芸苔素内酯和氨基寡糖素的组合物，其特征在于，按照重量份数计，所述组合物包括28-高芸苔素内酯6份和氨基寡糖素15份，占剂型总重量的0.1％—50％。
6.一种可溶粉剂制剂，其特征在于，按照重量份数计，所述制剂包括如权利要求1～5任一所述的组合物50份，还包括有湿润剂、分散剂、白炭黑和/或填料20份，助剂包括十二烷基苯磺酸钠2-10份，填料包括硅藻土。
7.一种可溶液剂制剂，其特征在于，所述制剂包括如权利要求1～5任一所述的组合物50份，还包括有乙二醇和/或环己酮25-50份，余量为水。
8.一种悬浮剂制剂，其特征在于，所述制剂包括如权利要求1～5任一所述的组合物50份，还包括有乙二醇和/或环己酮2-5份，甘露醇和/或山梨醇2-5份，硫酸镁1-2份，余量为水。
9.一种颗粒剂制剂，其特征在于，所述制剂包括如权利要求1～5任一所述的组合物50份，还包括有萘磺酸甲醛缩聚物10-15份，十二烷基硫酸钠2-5份，硫酸铵2-10份，余量为硅藻土。
10.如权利要求1～5任一所述的组合物或如权利要求6所述的可溶粉剂或如权利要求7所述的可溶液剂或如权利要求8所述的悬浮剂或如权利要求9所述的颗粒剂用于调节番茄生长的应用。
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