CN117121259A - 锂二次电池用液体电解质 - Google Patents

锂二次电池用液体电解质 Download PDF

Info

Publication number
CN117121259A
CN117121259A CN202280026896.3A CN202280026896A CN117121259A CN 117121259 A CN117121259 A CN 117121259A CN 202280026896 A CN202280026896 A CN 202280026896A CN 117121259 A CN117121259 A CN 117121259A
Authority
CN
China
Prior art keywords
lithium
chf
carbonate
liquid electrolyte
carrying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202280026896.3A
Other languages
English (en)
Chinese (zh)
Inventor
J-A·蔡
E-J·文
J-H·李
J-H·元
H-K·黄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siensco
Original Assignee
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay SA filed Critical Solvay SA
Publication of CN117121259A publication Critical patent/CN117121259A/zh
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • H01M10/0569Liquid materials characterised by the solvents
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • H01M10/0567Liquid materials characterised by the additives
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • H01M10/0568Liquid materials characterised by the solutes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027Negative electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0025Organic electrolyte
    • H01M2300/0028Organic electrolyte characterised by the solvent
    • H01M2300/0034Fluorinated solvents
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0025Organic electrolyte
    • H01M2300/0028Organic electrolyte characterised by the solvent
    • H01M2300/0037Mixture of solvents
    • H01M2300/004Three solvents
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/364Composites as mixtures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386Silicon or alloys based on silicon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
CN202280026896.3A 2021-04-08 2022-04-05 锂二次电池用液体电解质 Pending CN117121259A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP21167334.8 2021-04-08
EP21167334.8A EP4071872A1 (en) 2021-04-08 2021-04-08 Liquid electrolyte for lithium secondary batteries
PCT/EP2022/059024 WO2022214493A1 (en) 2021-04-08 2022-04-05 Liquid electrolyte for lithium secondary batteries

Publications (1)

Publication Number Publication Date
CN117121259A true CN117121259A (zh) 2023-11-24

Family

ID=75438594

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202280026896.3A Pending CN117121259A (zh) 2021-04-08 2022-04-05 锂二次电池用液体电解质

Country Status (6)

Country Link
US (1) US20240243364A1 (https=)
EP (2) EP4071872A1 (https=)
JP (1) JP2024513101A (https=)
KR (1) KR20230167366A (https=)
CN (1) CN117121259A (https=)
WO (1) WO2022214493A1 (https=)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20230238570A1 (en) * 2022-01-27 2023-07-27 GM Global Technology Operations LLC Electrolyte composition for batteries
EP4386925A4 (en) * 2022-11-04 2025-10-01 The School Corporation Kansai Univ ELECTROLYTIC SOLUTION, RECHARGEABLE LITHIUM-SULFUR BATTERY AND MODULE
WO2024144170A1 (ko) * 2022-12-28 2024-07-04 주식회사 엘지에너지솔루션 전해질을 포함하는 리튬 이차 전지
WO2025093455A1 (en) * 2023-11-02 2025-05-08 Specialty Operations France Lithium secondary battery with enhanced energy density
WO2025131951A1 (en) * 2023-12-21 2025-06-26 Solvay Specialty Polymers Italy S.P.A. Lithium secondary battery with high energy density and safety
JP2026035532A (ja) * 2024-08-19 2026-03-04 ダイキン工業株式会社 電解液用組成物、電気化学デバイス、二次電池及びリチウムイオン二次電池
WO2026048484A1 (ja) * 2024-08-26 2026-03-05 株式会社Gsユアサ 非水電解質蓄電素子、非水電解質及び非水電解質蓄電素子の製造方法
CN119627209A (zh) * 2024-11-22 2025-03-14 江苏大学 一种适配于高致密聚苯硫醚固态隔膜的高倍率耐低温电解液、制备方法及锂电池
CN119674219B (zh) * 2024-12-16 2025-10-31 惠州亿纬锂能股份有限公司 一种基于碳酸丙烯酯的电解液及应用其的二次电池

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19619233A1 (de) * 1996-05-13 1997-11-20 Hoechst Ag Fluorhaltige Lösungsmittel für Lithiumbatterien mit erhöhter Sicherheit
US6203944B1 (en) 1998-03-26 2001-03-20 3M Innovative Properties Company Electrode for a lithium battery
US6255017B1 (en) 1998-07-10 2001-07-03 3M Innovative Properties Co. Electrode material and compositions including same
JP4431941B2 (ja) * 2003-06-06 2010-03-17 株式会社ジーエス・ユアサコーポレーション 非水電解質二次電池
JP2006216361A (ja) * 2005-02-03 2006-08-17 Three M Innovative Properties Co リチウム電池用電解液
JP5343665B2 (ja) * 2009-03-31 2013-11-13 ダイキン工業株式会社 リチウム二次電池の非水電解液用溶媒
JP5678539B2 (ja) * 2009-09-29 2015-03-04 三菱化学株式会社 非水系電解液電池
CN103384656B (zh) 2010-12-21 2016-11-09 索尔维特殊聚合物意大利有限公司 用于生产氟化的有机化合物的方法
CN103959544A (zh) 2011-09-02 2014-07-30 纳幕尔杜邦公司 氟化电解质组合物
JP2016519400A (ja) * 2013-04-04 2016-06-30 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company 非水性電解質組成物
EP2800197B1 (en) * 2013-05-02 2017-03-22 Westfälische Wilhelms-Universität Münster Fluorinated carbonates as solvent for lithium sulfonimide-based electrolytes
WO2015078791A1 (en) 2013-11-28 2015-06-04 Solvay Specialty Polymers Italy S.P.A. Electrolyte compositions for lithium batteries
WO2016152425A1 (ja) * 2015-03-25 2016-09-29 日本電気株式会社 ハイドロフルオロエーテル化合物、非水電解液およびリチウムイオン二次電池
KR102810661B1 (ko) * 2015-10-26 2025-05-22 사이언스코 플루오린화 용매 및 2-푸라논을 포함하는 비수성 전해질 조성물
JP2017120765A (ja) * 2015-12-25 2017-07-06 パナソニック株式会社 非水電解質二次電池
JP6696590B2 (ja) * 2016-12-20 2020-05-20 ダイキン工業株式会社 電解液、電気化学デバイス、リチウムイオン二次電池及びモジュール
FR3100384B1 (fr) * 2019-08-29 2021-08-06 Accumulateurs Fixes Composition d’electrolyte fluore pour element electrochimique lithium-ion
CN112186190A (zh) * 2020-10-09 2021-01-05 西安科技大学 一种高电压锂离子电池
PL4264709T3 (pl) * 2020-12-16 2025-08-04 Syensqo Sa Kompozycja elektrolitu do baterii z metalicznym litem

Also Published As

Publication number Publication date
KR20230167366A (ko) 2023-12-08
WO2022214493A1 (en) 2022-10-13
JP2024513101A (ja) 2024-03-21
EP4320669A1 (en) 2024-02-14
US20240243364A1 (en) 2024-07-18
EP4071872A1 (en) 2022-10-12

Similar Documents

Publication Publication Date Title
JP7830476B2 (ja) リチウム金属電池用電解質組成物
JP6996070B2 (ja) 非水電解液電池用電解液、及びこれを用いた非水電解液電池
US12555818B2 (en) Anode-less lithium ion battery
CN117121259A (zh) 锂二次电池用液体电解质
JP2020109760A (ja) 非水電解液電池用電解液、及びこれを用いた非水電解液電池
KR20130122364A (ko) 전해액 첨가제, 상기 첨가제를 포함하는 비수성 전해액 및 리튬 이차 전지
JP6991471B2 (ja) 高電圧電池用の電解質成分としてのピリジン三酸化硫黄錯体
KR20240123315A (ko) 리튬 2차 배터리
US20250070247A1 (en) Lithium secondary batteries
KR102794805B1 (ko) 전해질 성분으로서의 메틸포스포노일옥시메탄
US20250201928A1 (en) Liquid electrolyte for lithium metal batteries

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20240613

Address after: Brussels

Applicant after: SIENSCO

Country or region after: Belgium

Address before: Brussels

Applicant before: SOLVAY S.A.

Country or region before: Belgium

TA01 Transfer of patent application right