CN1170426A - Low sudsing liquid detergent compositions - Google Patents
Low sudsing liquid detergent compositions Download PDFInfo
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- CN1170426A CN1170426A CN 95196961 CN95196961A CN1170426A CN 1170426 A CN1170426 A CN 1170426A CN 95196961 CN95196961 CN 95196961 CN 95196961 A CN95196961 A CN 95196961A CN 1170426 A CN1170426 A CN 1170426A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
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- Detergent Compositions (AREA)
Abstract
The present invention relates to liquid detergent compositions containing a nonionic surfactant system, said surfactant system comprising one or more surfactants selected from the group of Guerbet nonionic surfactants having formula (I) wherein R1 and R2 are independently C3-C22 alkyl groups, m is 2 to 4, n is greater than 0 and R3 is a hydrogen or a C1-C22 alkyl group.
Description
Invention field
The present invention relates to have the detergent composition of in check foaming profile.Particularly the invention relates to and contain the detergent composition that one or both are selected from the Guerbet nonionogenic tenside.
Background of invention
Be used to wash the various nonionogenic tensides of the common use of detergent composition of purpose such as laundering of textile fabrics.But described tensio-active agent is high foaminess often.
People have advised that mixing foam inhibition system in the nonionic detergent blending ingredients of this routine overcomes this problem in the prior art.Foam inhibition system comprises for example suds suppressor such as siloxanes.But foam inhibition system is difficult to remain in the liquid composition as dispersion and is difficult to be handled.Siloxanes kilfoam costliness in addition.
Therefore, the purpose of this invention is to provide the detergent composition that contains nonionogenic tenside, described composition has in check foaming profile.
Have been found that now this purpose can contain the detergent composition realization of Guerbet nonionogenic tenside by preparation.
Advantage of the present invention is that composition provides enhanced to remove the ability of hydrophobicity grease stain.
Another advantage of the present invention is owing to increased the solvability of tensio-active agent, the easier preparation of tensio-active agent.And owing to reduced conventional suds suppressor significantly, described composition is mixed with so-called ' concentrating ' composition easily.In addition, the preparation present composition is more cheap.
Another advantage of the present composition is that this liquid detergent composition is mutually stable.
Term used herein " Guerbet " tensio-active agent refers to by 2-alkyl-alkanol deutero-branched chain surfactant.
The Guerbet tensio-active agent is known in the prior art.EP254208 has disclosed a kind of low-foam surfactant mixtures that contains straight chain and/or side chain nonionogenic tenside.But, wherein do not mention the Guerbet nonionogenic tenside especially.
DE4021265 has disclosed the purposes of Guerbet alcohol as suds suppressor.Wherein do not mention the Guerbet nonionogenic tenside.
WO92/20768 has disclosed as the dialkyl ether of foam inhibition system and Guerbet nonionogenic tenside (C
16-C
20EO
1-5) binding substances.
Summary of the invention
The present invention relates to contain the detergent composition of non-ionic surfactant system, described surfactant system contains one or more tensio-active agents that is selected from the Guerbet nonionogenic tenside with following formula:
R wherein
1And R
2Be respectively C
3-22Alkyl, m are 2-4, and n is number and the R greater than 0
3Be hydrogen or C
1-22Alkyl.N is 1-14 preferably, and more preferably 1-10 most preferably is 3-7.
Detailed Description Of The Invention
The present invention relates to contain the detergent composition of non-ionic surfactant system, described surfactant system contains one or more tensio-active agents that is selected from the Guerbet nonionogenic tenside with following formula:
R wherein
1And R
2Be respectively C
3-22Alkyl, m are 2-4, and n is number and the R greater than 0
3Be hydrogen or C
1-22Alkyl.N is 1-14 preferably, and more preferably 1-10 most preferably is 3-7.
Except as otherwise noted, all quantity, ratio and percentage are by the weight percentage of total composition.
Detergent composition preferably contains at least 1%, more preferably 1%-70%, the most preferably non-ionic surfactant system of describing herein of 25%-40% (weight).
Preferably, the Guerbet nonionogenic tenside to be accounting for the 1%-100% of non-ionic surfactant system weight, preferred 10%-90%, and more preferably the content of 30%-70% is present in the non-ionic surfactant system.
The suitable non-Guerbet ionic surfactant pack that is used for non-ionic surfactant system draw together by with oxyethane with have active hydrogen atom, for example, hydroxyl, carboxyl, or the hydrocarbon of amido, those nonionogenic tensides of condensation prepared and comprise having general formula R A (CH in the presence of acid or alkaline catalysts
2CH
2O)
nThe compound of H, wherein R represents hydrophobic part, A represents to have the group of active hydrogen atom and the average number that n represents ethylene oxide moiety.R generally contains 8-22 the carbon atom of having an appointment.They also can be by propylene oxide and low-molecular weight compound condensation prepared.N changes between about 2 to about 24 usually.
A preferred class nonionic ethoxylate by having 12-15 carbon atom Fatty Alcohol(C12-C14 and C12-C18) and the condensation product of every mole of about 4-10 moles of ethylene oxide of Fatty Alcohol(C12-C14 and C12-C18) represent.Such suitable ethoxylate comprises: C
12-15The condensation product of oxo-pure and mild every mol of alcohol 3-9 moles of ethylene oxide; Narrow fraction C
14-15The condensation product of oxo-pure 3-9 moles of ethylene oxide of pure and mild every mole of fat (oxo); Narrow fraction C
12-13The condensation product of fat (oxo) pure and mild every mole of Fatty Alcohol(C12-C14 and C12-C18) 6,5 moles of ethylene oxide; And degree of ethoxylation (every mole of Fatty Alcohol(C12-C14 and C12-C18) EO mole number) is at the C of 4-8 scope
10-14The condensation product of coconut Fatty Alcohol(C12-C14 and C12-C18).
Other suitable non-Guerbet nonionogenic tensides are semi-polar nonionic surfactants, comprise that containing one has about 8 and be selected to the alkyl of about 28 carbon atoms or hydroxyalkyl part and two and contain 1 alkyl or hydroxyalkyl water-soluble amine oxide compound partly to about 3 carbon atoms, said two parts in the back formation ring structure that can optionally connect together.
What be suitable as nonionogenic tenside equally is the polyhydroxy fatty acid amide surfactant of following formula:
R
2-C (O)-N (R
1)-Z is R wherein
1Be H, or R
1Be C
1-4Alkyl, 2-hydroxyethyl, 2-hydroxypropyl or their mixture, R
2Be C
5-31Alkyl and Z have to contain at least 3 polyhydroxy alkyls that are directly connected in the straight-chain alkyl chain of the hydroxyl on the chain, or their alkoxy derivative.Preferred R
1Be methyl, R
2It is straight chain C
11-15Alkyl or alkenyl such as coconut alkyl or their mixture and Z are by reducing sugar such as glucose, and fructose, maltose, lactose are derived in reductive amination process and obtained.
Composition of the present invention provide improve remove the ability of hydrophobicity grease spot from dirt such as makeup, disc bar condiment, shoe polish and other similar dirts, have the foaminess that is controlled simultaneously.Detergent component
Another embodiment of the present invention provides and has contained the surfactant system of the present invention and the detergent composition of blended detergent component with it.Can use the tensio-active agent of wide region in the detergent composition of the present invention.
Typical negatively charged ion, nonionic, both sexes and zwitterionics, and the kind form of these tensio-active agents provides in licensing to the U.S. Pat 3664961 of Norris on May 23rd, 1972.Anion surfactant
Suitable anion surfactant comprises having formula RO (A)
mSO
3The alkyl alkoxylated sulfate surfactant of the water-soluble salt of M or acid, wherein R does not replace C
10-C
24Alkyl or have C
10-24The hydroxyalkyl of moieties, preferred C
12-20Alkyl or hydroxyalkyl, more preferably C
12-18Alkyl or hydroxyalkyl, A is oxyethyl group or propoxy-unit, m is greater than 0, generally between about 0.5 to about 6, more preferably about 0.5 to about 3 and M be H or positively charged ion, it can be, for example, and metallic cation (for example, sodium, potassium, lithium, calcium, magnesium, etc.), ammonium or replacement ammonium cation.The present invention is inclined to use alkyl ethoxylated sulfate and alkyl propoxylated sulphates.The specific examples of the ammonium cation that replaces comprise methyl-, dimethyl-, trimethylammonium-ammonium cation and quaternary ammonium cation such as tetramethyl--ammonium and lupetidine positively charged ion and from alkylamine such as ethamine, diethylamine, the replacement ammonium cation that triethylamine and their mixture etc. is derived and obtained.The example of tensio-active agent is C
12-18Alkyl polyethoxylated (1.0) vitriol (C
12-18E (1.0) M), C
12-18Alkyl polyethoxylated (2.25) vitriol (C
12-18E (2.25) M), C
12-18Alkyl polyethoxylated (3.0) vitriol (C
12-18And C E (3.0) M),
12-18Alkyl polyethoxylated (4.0) vitriol (C
12-18E (4.0) M), wherein M can be selected from sodium and potassium easily.
The suitable anion surfactant that the present invention uses is an alkyl sulfonate surfactants, comprises according to " (american petroleum chemistry meeting will) ", 52 (1975), the gas SO of the method in the 323-329 page or leaf
3Sulfonated C
8-20The linear ester of carboxylic acid (that is lipid acid).Suitable starting raw material should comprise as from tallow, the natural fat thing that the palm wet goods is derived and obtained.
Preferred alkyl sulfonate surfactants comprises the alkyl sulfonate surfactants of following structural formula in particular for such tensio-active agent of laundry:
R
3-CH (SO
3M)-C (O)-OR
4R wherein
3Be C
8-20Alkyl, preferred alkyl, or their binding substances, R
4Be C
1-6Alkyl, preferred alkyl, or their binding substances and M are the positively charged ions that forms water-soluble salt with alkyl ester sulfonate.Suitable salt-forming cation comprises metal ion such as sodium, potassium, and the ammonium cation of lithium and replacement or non-replacement, and as monoethanolamine, diethanolamine, and trolamine.Preferred R
3Be C
10-16Alkyl, and R
4Be methyl, ethyl or sec.-propyl.Especially preferred is R wherein
3Be C
10-16The methyl ester sulfonate of alkyl.
Other suitable anion surfactants comprise having formula ROSO
3The alkyl sulfate tensio-active agent of the water-soluble salt of M or acid, the wherein preferred C of R
10-24Alkyl preferably has C
10-20The alkyl or the hydroxyalkyl of alkyl-alkyl part, more preferably C
12-18Alkyl or hydroxyalkyl, with M be H or positively charged ion, for example, alkali metal cation is (for example, sodium, potassium, lithium), or ammonium or replace ammonium cation (for example methyl-, dimethyl-, and trimethylammonium-ammonium cation and quaternary ammonium cation such as tetramethyl--ammonium and lupetidine positively charged ion and from alkylamine such as ethamine, diethylamine, triethylamine and their the mixture quaternary ammonium cation that obtains etc. of deriving).Usually, C
12-16Alkyl chain is preferred for cold washing (for example being lower than about 50 ℃) and C
16-18Alkyl chain is preferred for comparatively high temps washing (for example being higher than about 50 ℃).
Other anion surfactants that are used for washing also can be included in laundry detergent composition of the present invention.They can comprise soap salt (comprise, for example, sodium, potassium, ammonium and substituted ammonium salt as single-, two-and triethanolamine salt), C
9-20Linear alkylbenzene sulfonate, C
8-22Uncle or secondary alkyl sulfonate, C
8-24Olefin sulfonate, by the sulfonation poly carboxylic acid of the sulfonation reaction preparation of the pyrolysis product of alkaline earth metal citrate, for example, those sulfonation poly carboxylic acids of in English Patent GB1082179, describing, C
8-24Alkyl polyglycol ether sulfate (contain and be up to 10 mole ethylene oxides); Alkyl glycerol sulfonate; the fatty acyl group glycerol sulfonate; fatty oil thiazolinyl glycerine vitriol; alkylphenol ethylene oxide ether sulfate, paraffin sulfonate, alkylphosphonic; isethionate such as acyl isethinate; N-acyl group cow-bezoar hydrochlorate, amber alkyl amide salts and sulfosuccinate, the monoesters of sulfosuccinate (especially saturated and unsaturated C
12-18Monoesters) and the diester of sulfo-succinic acid (especially saturated and unsaturated C
6-12Diester), acyl sarcosinate, the vitriol of alkyl polysaccharide class such as the vitriol of alkyl polyglucoside (compound of nonionic non-sulfuric acidization is described hereinafter), chain primary alkyl sulfate and alkyl polyethoxye carboxylate salt are suc as formula RO (CH
2CH
2O)
k-CH
2COO
-M
+Those carboxylate salts, wherein R is C
8-22Alkyl, k are that integer and the M of 0-10 is the solubility salt-forming cation.Resinous acid and hydrogenated resin acid also are suitable for, as rosin, and staybelite and the resinous acid and the hydrogenated resin acid of in Yatall MA or from Yatall MA, deriving and obtaining.Other case descriptions (1st and II volume, Schwartz, Perry and berch) in " tensio-active agent and washing composition ".Many such tensio-active agents also walk in the 29th hurdle the 23rd row on the 23rd hurdle the 58th that licensed to people's such as Laughlin U.S. Pat 3929678 on December 30th, 1975 usually and disclose (document is quoted as a reference by this paper).
When including this anion surfactant, laundry detergent composition of the present invention generally contains has an appointment 1% to about 40%, the preferred about 3% this anion surfactant to about 20% (weight).Nonionogenic tenside
The polyethylene oxide of alkylphenol, poly(propylene oxide) and polybutylene oxide condenses are applicable to the nonionogenic tenside as surfactant system of the present invention, and wherein polyethylene oxide condensation compound is preferred.These compounds comprise containing has an appointment 6 to about 14 carbon atoms, preferred about 8 straight chain or the alkylphenol of branched-chain alkyl and the condensation products of oxyalkylene to about 14 carbon atoms.In preferred embodiments, the amount of oxyethane is that every mole of alkylphenol correspondence exists about 5 to about 25 moles, and more preferably from about 3 to about 15 moles of ethylene oxide.Such can the commercial ionic surfactant pack of buying draw together the Igepal that is sold by GAF company
TMCO-630; With Triton by rom and Haars Co., Ltd's sale
TMX-45, X-114, X-100 and X-102.These tensio-active agents are commonly called alkylphenol alcoxylates (for example, alkyl phenol ethoxylate).
Primary and secondary Fatty Alcohol(C12-C14 and C12-C18) and about 1 condensation product to about 25 moles of ethylene oxide are suitable as the nonionogenic tenside of non-ionic surfactant system of the present invention.The alkyl chain of Fatty Alcohol(C12-C14 and C12-C18) can be straight or branched, primary alkyl or secondary alkyl, they contain usually has an appointment 8 to about 22 carbon atoms.Preferably every mole has and contains about 8 to about 20 carbon atoms, more preferably from about 10 alcohol and about 2 condensation products to about 10 moles of ethylene oxide to the alkyl of about 18 carbon atoms.Such can the commercial nonionogenic tenside of buying example comprise the Tergitol that sells by Union Carbide Corporation
TM15-S-9 (C
11-15The condensation product of straight chain alcohol and 9 moles of ethylene oxide), Tergitol
TM24-L-6NMW (the C of narrow molecular weight distributions
12-14The condensation product of primary alconol and 6 moles of ethylene oxide); Neodol by the sale of shell chemical company
TM45-9 (C
14-15The condensation product of straight chain alcohol and 9 moles of ethylene oxide), Neodol
TM23-6.5 (C
12-13The condensation product of straight chain alcohol and 6.5 moles of ethylene oxide), Neodol
TM45-7 (C
14-15The condensation product of straight chain alcohol and 7 moles of ethylene oxide), NeodolTM45-4 (C
14-15The condensation product of straight chain alcohol and 4 moles of ethylene oxide) with by P﹠amp; The Kyro that G company sells
TMEOB (C
13-15The condensation product of alcohol and 9 moles of ethylene oxide).
The alkyl polysaccharide that discloses in can the U.S. Pat 4565647 that also has the Llenado that authorizes on January 21st, 1986 as the nonionogenic tenside of surfactant system of the present invention, such glycan has to contain has an appointment 6 to about 30 carbon atoms, preferred about 10 hydrophobic groups to about 16 carbon atoms, with one contain and have an appointment 1.3 to about 10, preferred about 1.3 to about 3, more preferably from about 1.3 glycan to about saccharides unit of 2.7 (for example poly-glycosides) hydrophilic group.Can use any reduction saccharides that contains 5 or 6 carbon atoms, for example, glucose, semi-lactosi and galactosyl part can replace the glucosyl part, and (hydrophobic group optionally is connected 2-, 3-, 4-, Deng the position, therefore obtain glucose or semi-lactosi) on glucoside or galactoside opposite.Key between the saccharides can be, for example, unitary position of other saccharidess and the unitary 2-of aforementioned saccharides, 3-, 4-, and/or between the 6-position.
Optionally and not necessarily be that polyalkyleneimine chain can add hydrophobic part and glycan part.Preferred alkylene oxide is an oxyethane.Typical hydrophobic group comprises alkyl, and alkyl can be saturated or unsaturated, and is side chain or non-side chain and contain and have an appointment 8 to about 18 carbon atoms, and preferred about 10 to about 16 carbon atoms.Alkyl is the saturated alkyl of straight chain preferably.Alkyl can contain and be up to about 3 hydroxyls and/or polyalkyleneimine chain and can contain and be up to about 10, preferably less than 5 alkylene oxide parts.Suitable alkyl polysaccharide is an octyl group, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, and octadecyl, two-, three-, four-, five-and six glucosides, galactoside, lactoside, glucose, fructoside, fructose and/or semi-lactosi.Suitable mixture comprises the coconut alkyl, two-, three-, four-and five glucosides and tallow alkyl four-, five-and six glucosides.
Preferred alkyl polyglucoside has following formula:
R
2O (C
nH
2nO)
t(glycosyl)
xR wherein
2Be selected from alkyl, alkyl phenyl, hydroxyalkyl, hydroxyalkyl phenyl and their mixture, wherein alkyl contains and has an appointment 10 to about 18, and preferred about 12 to about 14 carbon atoms; N is 2 or 3, preferred 2; T is 0-10, preferred 0; With x be about 1.3 to about 10, preferred about 1.3 to about 3, most preferably from about 1.3 to about 2.7.Glycosyl is preferably derived by glucose and is obtained.In order to prepare these compounds, at first form alcohol or alkyl polyethoxye alcohol, then with glucose, or the source of glucose reaction, form glucoside (connecting) in the 1-position.Then can be with the 2-of the glycosyl units of the 1-position of other glycosyl units and front, 3-, 4-and/or 6-position connect, preferably mainly in the 2-position.
Although be not preferred, the condensation product of oxyethane and the hydrophobic group of condensation formation by propylene oxide and propylene glycol also is suitable as other nonionogenic tenside of non-ionic surfactant system of the present invention.The hydrophobic part of these compounds preferably has about 1500 to about 1800 molecular weight and has water-insoluble.The polyoxyethylene part that adds to this hydrophobic part often increases the water-soluble of whole molecule, and the content that the fluid characteristics of product remains to polyoxyethylene is the about 50% of condensation product gross weight, this corresponding to up to about 40 moles ethylene oxide condensation.Such examples for compounds comprise some by BASF AG sell can the commercial Pluronic that buys
TMTensio-active agent.
Be suitable as the condensation product that also has oxyethane and the product that obtains from propylene oxide and reacting ethylenediamine of the nonionogenic tenside of non-ionic surfactant system of the present invention.The hydrophobic part of these products is made up of the reaction product of quadrol and excessive propylene oxide, and they have about 2500 to about 3000 molecular weight usually.This hydrophobic part and ethylene oxide condensation have an appointment 40% to the polyoxyethylene of about 80% (weight) with have about 5000 to about 11000 molecular weight to a kind of like this degree so that condensation product contains.The example of such nonionogenic tenside comprise some by BASF AG sell can the commercial Tetronic that buys
TMTensio-active agent.
The nonionogenic tenside that is preferably used as surfactant system of the present invention is the polyethylene oxide condensation compound of alkylphenol, primary and secondary Fatty Alcohol(C12-C14 and C12-C18) and about 1 condensation product to about 25 moles of ethylene oxide, alkyl polysaccharide thing and their mixture.The C that most preferably has 3-15 oxyethyl group
8-14Alkylphenol ethoxylate and C with 2-10 oxyethyl group
8-18Alcohol ethoxylate (preferred average C
10) and their mixture.
Nonionogenic tenside very preferably is a polyhydroxy fatty acid amide surfactant.
Be suitable as the polyhydroxy fatty acid amide surfactant that also has following formula of nonionogenic tenside:
R
2-C (O)-N (R
1)-Z, wherein R
1Be H, or R
1Be C
1-4Alkyl, 2-hydroxyethyl, 2-hydroxypropyl or their mixture, R
2Be C
5-31Alkyl and Z have straight-chain alkyl chain and at least 3 polyhydroxy alkyls that directly are connected the hydroxyl on the chain, or their alkoxy derivative.Preferably, R
1Be methyl, R
2It is straight chain C
11-15Alkyl or alkenyl chain such as coconut alkyl or their mixture and Z be by reducing sugar such as glucose, fructose, and maltose, lactose, deriving in reductive amination process obtains.
When ionic surfactant pack was drawn together in this laundry detergent composition, non-ionic surfactant system of the present invention was used to improve the characteristic of removing greasy/oily spot of this laundry detergent composition under the laundry situation of wide region.
Laundry detergent composition agent of the present invention also can contain positively charged ion, both sexes, zwitter-ion and half-polar surfactant, and the nonionogenic tenside outside those tensio-active agents of having described of this paper.
The preferred cationic surfactants system comprises nonionic and amphoterics.Be applicable to that the cationic detersive tensio-active agent in the laundry detergent composition of the present invention is those cats products with a long chain hydrocarbon groups.The example of this cats product comprises ammonium surfactant such as alkyl dimethyl ammonium halogenide and has the tensio-active agent of following formula:
[R
2(OR
3)
Y] [R
4(OR
3)
Y]
2R
5N
+X
-R wherein
2Be in alkyl chain, to have about 8 to about 18 carbon atom alkyls or alkyl phenyl, each R
3Be selected from-CH
2CH
2-,-CH
2CH (CH
3)-,-CH
2CH (CH
2OH)-,-CH
2CH
2CH
2-and their mixture; Each R
4Be selected from C
1-4Alkyl, C
1-4Hydroxyalkyl is by two R
4Group is in conjunction with the benzyl rings structure that forms ,-CH
2CHOH-CHOHCOR
6CHOHCH
2OH, wherein R
6Be to have less than any hexose or the hexose polymkeric substance of about 1000 molecular weight or when y is not 0, can be hydrogen; R
5With R
4Identical or R wherein
2And R
5The total number of carbon atoms be no more than about 18 alkyl chain; Each y is 0 to about 10, and y value sum is 0 to about 15; With X be any compatible negatively charged ion.
Preferred cationic surfactants is the soluble quaternary ammonium with following formula that can be used in the present composition:
R
1R
2R
3R
4N
+X
-(i) R wherein
1Be C
8-16Alkyl, each R
2, R
3And R
4Be respectively C
1-4Alkyl, C
1-4Hydroxyalkyl, benzyl and-(C
2H
40)
xH, wherein x is that 2-5 and X are negatively charged ion.R
2, R
3And R
4In have only one to be benzyl at most.R
1Preferred alkyl chain length be C
12-15, especially wherein alkyl is the long-chain mixture of being derived and being obtained by coconut or palm-kernel fat, or like this during pure synthetic the obtaining of synthetic or OXO by alkene.Preferred R
2, R
3And R
4Be methyl and hydroxyethyl, negatively charged ion X can be selected from halogen, Methylsulfate, acetate and phosphate ion.
Being used for suitable formula of the present invention (i) quarternary ammonium salt compound example is:
Chlorination or bromination coco group trimethyl ammonium;
Chlorination or bromination coco group methyl dihydroxy ethyl ammonium;
Chlorination decyl triethyl ammonium;
Chlorination or bromination decyl dimethyl hydroxyethyl ammonium;
Chlorination or bromination C
12-15The dimethyl hydroxyethyl ammonium;
Chlorination or bromination coco group dimethyl hydroxyethyl ammonium;
Myristyl trimethyl ammonium methyl sulfate salt;
Chlorination or bromination lauryl dimethyl hexadecyldimethyl benzyl ammonium;
Chlorination or bromination lauryl dimethyl (oxyethylene group) 4 ammoniums;
Cholinesterase (R wherein
1Be-CH
2-O-C (O)-C
12-14Alkyl and R
2, R
3, R
4
Be formula (i) compound of methyl).
Can be used for the U.S. Pat 4228044 that other cats products of the present invention also are described in the Cambre that authorized on October 14th, 1980.
When including this cats product, laundry detergent composition of the present invention generally contains 0% to about 25%, the preferred about 3% this cats product to about 15% (weight).
Amphoterics also is applicable in the laundry detergent composition of the present invention.These tensio-active agents can briefly be described as the aliphatic derivatives of the second month in a season or tertiary amine, or the aliphatic derivatives of the heterocycle second month in a season or tertiary amine, and wherein aliphatic group can be a straight or branched.One of aliphatic series substituting group contains at least about 8 carbon atoms, is typically about 8 to about 18 carbon atoms, and at least one contains anionic water-solubilizing group, for example, and carboxyl, sulfonate, vitriol.Referring to the capable amphoterics example of the 19th hurdle 18-35 in the people's such as Laughlin that authorized on December 30th, 1975 the U.S. Pat 3929678.
When including this amphoterics, laundry detergent composition of the present invention generally contains 0% to about 15%, the preferred about 1% this amphoterics to about 10% (weight).
Zwitterionics also is applicable in the laundry detergent composition of the present invention.These tensio-active agents can briefly be described as the derivative of the second month in a season or tertiary amine, or the derivative of the heterocycle second month in a season or tertiary amine, the derivative of quaternary ammonium, quaternary phosphonium or uncle's sulfonium compound.Zwitterionics example referring to the 38th to the 22nd hurdle, the 19th hurdle the 48th row in the people's such as Laughlin that authorized on December 30th, 1975 the U.S. Pat 3929678.
When including this zwitterionics, laundry detergent composition of the present invention generally contains 0% to about 15%, the preferred about 1% this zwitterionics to about 10% (weight).
Semi-polar nonionic surfactants is the special nonionogenic tenside of a class, and it comprises containing one about 10 to the moieties of about 18 carbon atoms and two and being selected from and contains the 1 water-soluble amine oxide compound to the part of the alkyl of about 3 carbon atoms and hydroxyalkyl of having an appointment; Contain one about 10 to the moieties of about 18 carbon atoms and two and be selected from and contain 1 the water-soluble phosphine oxide compound of having an appointment to the part of the alkyl of about 3 carbon atoms and hydroxyalkyl; Contain one about 10 to the moieties of about 18 carbon atoms and a part and be selected to contain and have an appointment 1 to the alkyl of about 3 carbon atoms and the water-soluble oxysulfide of hydroxyalkyl.
Semi-polarity nonionic detergent surfactant comprises the amine oxide tensio-active agent with following formula:
R
3(OR
4)
xN (O) (R
5)
2R wherein
3Be to contain 8 the alkyl of having an appointment to about 22 carbon atoms, hydroxyalkyl, or alkyl phenyl or their mixture; R
4Be to contain 2 alkylidene group or hydroxy alkylidene or their mixtures of having an appointment to about 3 carbon atoms; X is 0 to about 3; With each R
5Be to contain to have an appointment 1 to the alkyl or the hydroxyalkyl of about 3 carbon atoms or contain 1 the polyethylene oxide base of having an appointment to about 3 Oxyranyles.Radicals R
5Can interconnect, for example, be connected to form ring structure by oxygen or nitrogen-atoms.
These amine oxide tensio-active agents preferably include C
10-18Alkyl dimethyl amine oxide and C
8-12Alkoxyethyl dihydroxy ethyl amine oxide.
When including this semi-polar nonionic surfactants, laundry detergent composition of the present invention generally contains 0% to about 15%, the preferred about 1% this semi-polar nonionic surfactants to about 10% (weight).
The present invention also provides and has contained at least about 1%, and preferred about 3% to about 65%, more preferably from about 10% laundry detergent composition to the total surfactant of about 25% (weight).
Composition of the present invention can also contain builder system.The builder system of any routine all is applicable to the present invention, they comprise alumino-silicate materials, silicate, multi-carboxylation thing and lipid acid, as the edetate material, metal ion sequestering agent such as amino polyphosphonate, especially ethylenediamine tetramethylene phosphonic acid and diethylenetriamine pentamethylenophosphonic acid(DTPP).Though because tangible environmental factors, phosphate builders is not preferred, phosphate builders also can also be used for the present invention.
Can be used for suitable multi-carboxylation thing washing assistant of the present invention and comprise citric acid, it is preferably with the water-soluble salt form, formula R-CH (COOH) CH
2(COOH) succinic acid derivative, wherein R is C
10-20Alkyl or alkenyl, preferred C
12-16, or wherein R can use hydroxyl, sulfo group, and sulfo group sulfonyloxy or sulfone substituting group replace.Specific examples comprises the lauryl succinate, myristyl succinate, palmityl succinate, 2-dodecenyl succinic succinate, 2-tetradecene base succinate.The succinate washing assistant preferably with their water-soluble salt form, comprises sodium, potassium, and ammonium and alkanol ammonium salt form use.
Other suitable multi-carboxylation things are mixtures that oxygen connects disuccinate and tartrate monosuccinic acid and tartrate disuccinic acid, those as describing in U.S. Pat 4663071.
Especially in order to make as liquid, use therein suitable lipid acid washing assistant is saturated or unsaturated C in the present invention
10-18Lipid acid, and their corresponding soaps.Preferred saturated fatty acid has the alkyl chain of 12-16 carbon atom.Preferred unsaturated fatty acids is an oleic acid.
Other preferred liquid composition builder systems are based on the builder system of dodecenyl succinic succsinic acid and citric acid.
Washing auxiliary detergent salt is usually with the 3%-50% of composition weight, preferred 5%-30%, and most preferably the quantity of 5%-25% is included in the composition.
Detergent composition of the present invention can optionally contain SYNTHETIC OPTICAL WHITNER or contain SYNTHETIC OPTICAL WHITNER and the bleaching composition of one or more bleach activators.When containing SYNTHETIC OPTICAL WHITNER, SYNTHETIC OPTICAL WHITNER is generally detergent composition, in particular for about 1% to about 30%, more preferably about 5% to about 20% of the detergent composition of laundering of textile fabrics.If contain bleach activator, its content is generally about 0.1% to about 60%, more preferably about 0.5% to about 40% of the bleaching composition that contains SYNTHETIC OPTICAL WHITNER and bleach activator.
SYNTHETIC OPTICAL WHITNER used herein can be to detergent composition at cleaning fabric or other known now or with known cleaning use in useful any SYNTHETIC OPTICAL WHITNER.
Being suitable for SYNTHETIC OPTICAL WHITNER of the present invention can be activatory or inactive SYNTHETIC OPTICAL WHITNER.
Be suitable for SYNTHETIC OPTICAL WHITNER of the present invention and comprise peroxygen bleach.The example of suitable water-soluble solid peroxygen bleach comprises hydrogen peroxide releasing agent such as hydrogen peroxide, perborate, perborate monohydrate for example, perborate tetrahydrate, persulphate, percarbonate, peroxydisulfate, superphosphate and peroxyhydrate.Preferred SYNTHETIC OPTICAL WHITNER is percarbonate and perborate.
Hydrogen peroxide also can occur by the mode that adds enzyme system (being enzyme and its matrix), and this enzyme system is beginning washing or can produce hydrogen peroxide in washing and/or rinse cycle.This enzyme system discloses in the european patent application of submitting on October 9th, 1,991 91202655.6.
Other are suitable for peroxygen bleach of the present invention and comprise organic peroxide acid such as percarboxylic acids.
The suitable example of this class SYNTHETIC OPTICAL WHITNER comprises monoperphthalic acid magnesium hexahydrate, metachloroperbenzoic acid magnesium salts, 4-nonyl amino-4-oxo Perbutyric Acid magnesium and diperoxy dodecanedioic acid magnesium.These SYNTHETIC OPTICAL WHITNER are disclosed in the U.S. Pat 4483781 of the Hartman that authorized on November 20th, 1984, the people's such as Burns of application on June 3rd, 1985 U.S. Patent application 740446, February in 1985 people such as disclosed Banks on the 20th european patent application 0133354 and the people's such as Chung that authorize November 1 nineteen eighty-three U.S. Pat 4412934 in.Most preferred SYNTHETIC OPTICAL WHITNER also comprises 6-nonyl amino-6-oxo-mistake oxy hexanoic acid of describing as in the U.S. Pat 4634551 that licenses to people such as Burns on January 6th, 1987.
Preferred percarbonate bleach contains scope at about 500 dried particles to about 1000 microns average particle size, and described particle is less than about 200 microns about 10% (weight) that is no more than, greater than about 1250 microns about 10% (weight) that is no more than.Percarbonate can optionally use silicate, borate or water soluble surfactant active to apply.Percarbonate can be from various commercial source such as FMC, and Solvay and Tokai Denka obtain.
The present invention also can use the mixture of SYNTHETIC OPTICAL WHITNER.
Peroxygen bleach, perborate, percarbonate etc. preferably are used in combination with bleach activator, and this causes producing on the spot the peroxy acid corresponding to bleach activator in the aqueous solution (promptly at washing process).The various non-limiting examples of activator are disclosed in and license in people's such as Mao the U.S. Pat 4915854 and U.S. Pat 4412934 April 10 nineteen ninety.Nonanoly acyloxy benzene sulfonate (NOBS) and tetra acetyl ethylene diamine (TAED) activator are typical activators, also can use their mixture.Typical SYNTHETIC OPTICAL WHITNER of useful herein other and activator are in addition referring to U.S. Pat 4634551.
Amido very preferably-deutero-bleach activator has formula:
R
1N (R
5) C (O) R
2C (O) L or R
1C (O) N (R
5) R
2C (O) L is R wherein
1Be to contain 6 the alkyl of having an appointment, R to about 12 carbon atoms
2Be to contain 1 alkylidene group, R to about 6 carbon atoms
5Be that H or alkyl, aryl or the alkylaryl that contains 1 to 10 carbon atom of having an appointment and L are any suitable leavings groups.The leavings group substituted any leavings group that is bleach activator owing to cross the result of hydrolysis negatively charged ion nucleophilic attack on bleach activator.Preferred leavings group is a phenylbenzimidazole sulfonic acid salt.
The preferred embodiment of following formula bleach activator comprises (6-decoyl amino-caproyl) oxygen base benzene sulfonate of describing as in U.S. Pat 4634551 (document is quoted as a reference by this paper); (the amino caproyl of 6-nonanoyl) oxygen base benzene sulfonate; (6-caprinoyl amino-caproyl) oxygen base benzene sulfonate and their mixture.
Another kind of bleach activator comprises disclosed benzo oxazinyl promoting agent in the people's such as Hodge that authorize October 30 nineteen ninety the U.S. Pat 4966723 (document is quoted as a reference by this paper).The promoting agent very preferably of benzo oxazinyl is:
Another kind of preferred bleach activator comprises the acyl lactam promoting agent, especially the acyl caprolactam of following formula and acyl group Valerolactim:
R wherein
6Be H or have 1 alkyl, aryl, alkoxy aryl, or alkylaryl to about 12 carbon atoms.Lactan promoting agent very preferably comprises benzoyl caprolactam, capryloyl hexanolactam, 3; 5,5-trimethyl acetyl base hexanolactam, nonanoyl hexanolactam; the decanoyl hexanolactam, undecylene acyl caprolactam, benzoyl Valerolactim; the capryloyl Valerolactim, decanoyl Valerolactim, undecylene acyl group Valerolactim; the nonanoyl Valerolactim; 3,5,5-trimethyl acetyl base Valerolactim and their mixture.Also referring to the U.S. Pat 4545784 (document is quoted as a reference by this paper) of the Sanderson that authorized on October 8th, 1985, wherein disclose acyl caprolactam, comprised benzoyl caprolactam, they are inhaled in the Sodium peroxoborate.
Those SYNTHETIC OPTICAL WHITNER that are not oxygen bleaching agent also are well known in the art, and can be used for the present invention.The non-oxygen bleaching agent that one class is good especially comprises photoactivation SYNTHETIC OPTICAL WHITNER such as sulfonated Phthalocyanine Zinc and/or aluminium.Also license to people's such as Holcombe U.S. Pat 4033718 referring on July 5th, 1977.If necessary, detergent composition generally contains have an appointment 0.025% such SYNTHETIC OPTICAL WHITNER to about 1.25% (weight), especially Phthalocyanine Zinc sulfonate.
If necessary, bleaching compounds can be by using manganic compound catalysis.This compounds is a compound well known in the art, comprises, for example, at U.S. Pat 5246621, US5244594, US5194416, US5114606 and European patent EP 549271A1, EP549272A1, disclosed manganese among EP544440A2 and the EP544490A1-catalyst based; The preferred embodiment of such catalyzer comprises Mn
IV 2(u-O)
3(1,4,7-trimethylammonium-1,4,7-7-triazacyclononane)
2(PF6)
2, Mn
III 2(u-O)
1(u-OAc)
2(1,4,7-trimethylammonium-1,4,7-7-triazacyclononane)
2(ClO
4)
2, Mn
IV 4(u-O)
6(1,4, the 7-7-triazacyclononane)
4(ClO
4)
4, Mn
IIIMn
IV 4(u-O)
1(u-OAc)
2(1,4,7-trimethylammonium-1,4,7-7-triazacyclononane)
2(ClO
4)
3, Mn
IV(1,4,7-trimethylammonium-1,4,7-7-triazacyclononane) (OCH
3)
3(PF
6) and their mixture.Other metal matrix-bleaching catalysts are included in those disclosed among U.S. Pat 4430243 and the US5114611.The purposes that has the manganese of various complex ligands also is in the news in following United States Patent (USP): US4728455, US5284944, US5246612, US5256779, US5280117, US5274147, US5153161, US5227084.
The present composition and method can be conditioned so that per at least active bleaching catalyst of 1/10000000th is provided in wash water solution, preferably provide about 0.1ppm to about 700ppm in washing liq, and more preferably from about 1ppm is to such catalyzer of about 500ppm.When only doing actual application, this selects for use, as restriction invention scope.
Detergent composition of the present invention can contain amine.Such amine is usually corresponding to following formula:
R wherein
1Be C
6-22Alkyl, alkenyl, cyclic aliphatic base or many cyclic groups, they can replace with extremely reaching three hydroxyls or phenyl, and can be optionally by extremely nearly 12 ethylene oxide moieties insertion;
R wherein
2And R
3Respectively be H or C
1-18Straight or branched alkyl or alkenyl, they can be with replacing to reaching 12 ethylene oxide moieties; With
R wherein
1And R
2Be joined together to form the tetrahydroglyoxaline of following formula structure:
R wherein
4Be C
8-18Alkyl.
In following formula, preferred R
1Be C
6-18Alkyl; R
2And R
3Be respectively C
1-4Alkyl, they are optionally inserted by 1 or 2 ethylene oxide moiety; And R
4Be C
10-16Alkyl.
As indicated such, the normally known amine of the amine of following formula as tensio-active agent.As at Kirk-Othmer; " encyclopedia of chemical technology) ", the 4th edition, the 2nd volume, those materials of describing in detail in " aliphatic amide ", 405-425 (1992).The document is quoted as a reference by this paper.
Suitable primary amine, that is, and R in those superincumbent formulas
2And R
3The amine that all is hydrogen comprises the 1-hexyl amine, 1-octyl amine, lauryl amine, palmityl amine, stearylamide, oleylamide, coconut alkylamine, tallow alkyl amine, 6-amino-1-hexanol; 3-isopropoxide propyl amine, 3-(2-methoxy ethoxy) propyl group amine, 2-(2-amino ethoxy) ethanol and cyclo-hexylamine.
Suitable secondary amine, that is, and R in those superincumbent formulas
2And R
3In have only one to be that the amine of hydrogen comprises two coconut alkylamines, two positive 12 carbon alkylamines, two hexadecane base amine, two octodecane base amine and two tallow alkyl amine.
Suitable tertiary amine, that is, and R in those superincumbent formulas
2And R
3The amine that is not hydrogen comprises coconut alkyl dimethyl amine; dimethyl oil base amine; two positive decyl methylamine; two coconut alkyl methyl amine, three n-octylamine, three positive 12 carbon alkylamines; hexadecane base three (inferior ethoxyl) dimethyl amine; tallow alkyl two (2-hydroxyethyl) amine, stearyl-two (2-hydroxyethyl) amine and oleoyl two (2-hydroxyethyl) amine.
Can be used for suitable tetrahydroglyoxaline of the present invention is following formula: compound:
R wherein
4Be C
9-13Alkyl.This material is sold on market with trade(brand)name VARINE.
Suitable polycyclic amines comprises those polycyclic amines based on sylvic acid.The example of this amine is a following formula: compound:
Wherein x and y are 1-3.Such amine is sold with trade(brand)name POLYRAD.
In all aforementioned amine, the trialkylamine of selling with trade(brand)name ADOGEN preferably, long chain alkyl dimethyl amine of selling with trade(brand)name ARMEEN and the ethoxylated amine of selling with trade(brand)name ETHOMEEN.The most preferred amine that uses in the present composition is the 1-hexyl amine, 1-octyl amine, positive 12 carbon alkyl dimethyl amine (ARMEEN DM12D) and two-hydroxyethyl coconut alkylamine (ETHOMEEN C/12).
Do not wish to be bound by theory, the amine that it is believed that aforementioned type under the pH condition of using detergent composition of the present invention by protonated.The positively charged ion protonated amines that obtains then with oleoylsarcosine and or other anion surfactants interact, it is right to form lipophilic tensio-active agent.Cause bigger surperficial receptivity so again and better remove the greasy dirt ability of fats/oils.Being used for the alkylamine that has the 9-11pKa value usually of the present invention provides surge capability also can for their detergent composition of use.
The present invention also can use other components that are used for detergent composition, as enzyme and enzyme stabilizers, and soil-suspending agent, soil release polymer, abrasive, sterilant, tarnish inhibitor, tinting material, Foam Control, corrosion inhibitor and spices.
Detergent composition of the present invention can be with liquid, lotion, gelinite, stick or particle form.Particulate composition of the present invention also can be with " closely knit form ", that is, they can have high relatively density than the granulated detergent of routine, that is, its density is higher than about 600 grams per liters; In this case, compare with the granulated detergent of routine, granular detergent composition of the present invention should contain more a spot of " mineral filler salt "; Typical filling salt is alkaline earth metal sulphate and alkaline earth metal chloride, is typically sodium sulfate; " closely knit " washing composition typically contains and is no more than 10% filling salt.
Liquid composition of the present invention is preferably with " conc forms "; In this case, compare with the liquid washing agent of routine, liquid detergent composition of the present invention should contain more a spot of water.Its water-content is lower than 50% of detergent composition weight, preferably is lower than 30%, more preferably less than 20%.
Described concentrated product provides benefit for human consumer and manufacturer, and the human consumer has had can be with the product of a small amount of use, and manufacturer's transportation cost reduces.
When liquid composition directly was applied to dirt and color spot in pre-treatment step, liquid composition was effective especially.Detergent composition of the present invention also can be used as the washing composition addition product and uses.This addition product is the performance that is used for replenishing or improving conventional detergent composition.
Detergent composition of the present invention comprises and is used to wash matrix, as fabric, and fiber, the composition of skin etc., for example laundry detergent composition and automatically and non--automatic tableware cleaning composition.
The following examples are to be used to illustrate composition of the present invention, but they and do not mean that and limit the scope of the present invention.Embodiment 1
Preparation has the aqueous liquid detergent compositions of the present invention of following composition:
The weight percentage of total detergent composition
Embodiment 2
| ??A | ?B | ??C | ??D | ??E | ??F | ??G | ??H | ??I | |
| Guerbet C 12-15Alkylethoxylate (7EO) | ??4 | ?8 | ??15 | ??10 | ??20 | ??10 | ??8 | ??3 | ??10 |
| Straight chain C 12-14Alkylethoxylate (7EO) | ??4 | ?- | ??- | ??3 | ??- | ??- | ??- | ??7 | ??- |
| Straight chain C 12-14Alkyl-sulphate .No salt | ??10 | ?- | ??- | ??5 | ??8 | ??- | ??- | ??- | ??- |
| Guerbet C 12-15Alkyl-sulphate .No salt. | ??- | ?15 | ??- | ??10 | ??- | ??- | ??17 | ??- | ??10 |
| Linear alkylbenzene sulfonate | ??- | ?- | ??15 | ??- | ??- | ??- | ??- | ??10 | ??- |
| Straight chain C 12-16Sulfated alkyl ether (EO3) | ??- | ?3 | ??- | ??- | ??5 | ??10 | ??3 | ??- | ??2 |
| C 12-14The N-methyl glucose amide | ??- | ?2 | ??- | ??- | ??- | ??5 | ??3 | ??- | ??3 |
| C 12-14Lipid acid | ??10 | ?10 | ??10 | ??10 | ??10 | ??10 | ??10 | ??10 | ??10 |
| Citric acid | ??1 | ?1 | ??1 | ??1 | ??1 | ??1 | ??1 | ??1 | ??1 |
| Diethylenetriamine five ethylidene phosphonic acids | ??1.5 | ?1.5 | ??1.5 | ??1.5 | ??1.5 | ??1.5 | ??1.5 | ??1.5 | ??1.5 |
| MEA | ??3 | ?3 | ??3 | ??3 | ??3 | ??3 | ??3 | ??3 | ??3 |
| Sodium hydroxide | Be up to pH7.8 | ||||||||
| 1, the 2-propylene glycol | ??3 | ?3 | ??3 | ??3 | ??3 | ??3 | ??3 | ??3 | ??3 |
| Ethanol | ??10 | ?10 | ??10 | ??10 | ??10 | ??10 | ??10 | ??10 | ??10 |
| The ethoxylation tetracthylene pentamine | ??0.7 | ?0.7 | ??0.7 | ??0.7 | ??0.7 | ??0.7 | ??0.7 | ??0.7 | ??0.7 |
| Thermanyl R300KNU/g | ??0.13 | ?0.13 | ??0.13 | ??0.13 | ??0.13 | ??0.13 | ??0.13 | ??0.13 | ??0.13 |
| Carezyme R500CEVU/g | ?0.01 ?4 | ?0.01 ?4 | ?0.01 ?4 | ?0.01 ?4 | ?0.01 ?4 | ?0.014 | ?0.01 ?4 | ?0.01 ?4 | ?0.01 ?4 |
| 40 milligrams/gram of proteolytic enzyme | ?1.8 | ?1.8 | ?1.8 | ?1.8 | ?1.8 | ?1.8 | ?1.8 | ?1.8 | ?1.8 |
| Lipolase R100KLU/g | ?0.14 | ?0.14 | ?0.14 | ?0.14 | ?0.14 | ?0.14 | ?0.14 | ?0.14 | ?0.14 |
| Endog?lucanase A5000?CEVU/g | ?0.53 | ?0.53 | ?0.53 | ?0.53 | ?0.53 | ?0.53 | ?0.53 | ?0.53 | ?0.53 |
| (Isofol 12 for water and remainder R/ siloxanes) | To 100 | ||||||||
Preparation has the non-aqueous liquid detergent compositions of the present invention of following composition:
The weight percentage of total detergent composition
| ????A | ????B | ????C | ????D | ????E | ????F | |
| Macrogol 200 | ????35 | ????35 | ????35 | ????35 | ????30 | ????0 |
| C 12-14EO3 | ????15 | ????15 | ????15 | ????15 | ????15 | ????15 |
| C 12-14EO7 | ????15 | ????15 | ????15 | ????15 | ????15 | ????15 |
| Propylene glycol | ????0.6 | ????0.6 | ????1.1 | ????1.1 | ????0 | ????35 |
| Guerbet C 12-15Alkylethoxylate (5EO) | ????5 | ????5 | ????10 | ????10 | ????6 | ????10 |
| Boric acid | ????0.82 | ????1.67 | ????1.67 | ?????3.28 | ????1.7 | ????1.2 |
| Total umber | ||||||
| Solid ingredient and remainder to 100 |
Claims (8)
1. detergent composition that contains non-ionic surfactant system, described non-ionic surfactant system contains one or more and is selected from the Guerbet nonionogenic tenside with following formula:
R wherein
1And R
2Be respectively C
3-22Alkyl, m are 2-4, and n is greater than 0 and R
3Be hydrogen or C
1-22Alkyl.
2. according to the detergent composition of claim 1, wherein n is 1-14, more preferably 1-10, most preferably 3-7.
3. according to the detergent composition of claim 1-2, wherein the Guerbet nonionogenic tenside is with the 1-100% of non-ionic surfactant system weight, preferred 10-90%, and more preferably 30-70% is present in the non-ionic surfactant system.
4. according to the detergent composition of claim 1-3, it also contains the nonionogenic tenside that is selected from polyhydroxy fatty acid amide.
5. according to the detergent composition of claim 1-4, wherein nonionogenic tenside is C
12-14The N-methyl glucose amide.
6. according to the detergent composition of claim 1-5, wherein anion surfactant is selected from alkyl ethoxylated sulfate and/or alkyl-sulphate.
7. according to the detergent composition of claim 1, it also contains tensio-active agent, washing assistant, enzyme and other conventional detergent components.
8. according to the purposes of detergent composition in the fabric pre-treatment of claim 1-7.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP94307794A EP0709450A1 (en) | 1994-10-24 | 1994-10-24 | Low sudsing liquid detergent compositions |
| EP94307794.1 | 1994-10-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1170426A true CN1170426A (en) | 1998-01-14 |
Family
ID=8217888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 95196961 Pending CN1170426A (en) | 1994-10-24 | 1995-10-12 | Low sudsing liquid detergent compositions |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0709450A1 (en) |
| JP (1) | JPH10507788A (en) |
| CN (1) | CN1170426A (en) |
| CA (1) | CA2203268A1 (en) |
| MX (1) | MX9702982A (en) |
| WO (1) | WO1996012782A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100434500C (en) * | 2005-07-04 | 2008-11-19 | 中国科学院理化技术研究所 | Guerbet anion surfactant, and its preparing method and use |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2222475T3 (en) * | 1996-06-10 | 2005-02-01 | THE PROCTER & GAMBLE COMPANY | CLEANING COMPOSITIONS. |
| DE69732773T2 (en) | 1997-10-08 | 2006-04-06 | The Procter & Gamble Co., Cincinnati | Multi-purpose liquid cleaning compositions with effective foam control |
| JP2002537482A (en) * | 1999-02-22 | 2002-11-05 | ザ、プロクター、エンド、ギャンブル、カンパニー | Cleaning composition containing selected nonionic surfactant |
| CA2619644C (en) | 2005-11-30 | 2015-07-21 | Ecolab Inc. | Detergent composition containing branched alcohol alkoxylate and compatibilizing surfactant, and method for using |
| JP2011040475A (en) * | 2009-08-07 | 2011-02-24 | Dai Ichi Kogyo Seiyaku Co Ltd | Detergent composition for cutting objects |
| JP5727610B2 (en) | 2010-08-17 | 2015-06-03 | ザ プロクター アンド ギャンブルカンパニー | Method for hand-washing dishes with persistent foam |
| JP2012248738A (en) * | 2011-05-30 | 2012-12-13 | Dai Ichi Kogyo Seiyaku Co Ltd | Surface treatment agent composition for silicon wafer |
| US9029309B2 (en) | 2012-02-17 | 2015-05-12 | Ecolab Usa Inc. | Neutral floor cleaner |
| US8901063B2 (en) | 2012-11-30 | 2014-12-02 | Ecolab Usa Inc. | APE-free laundry emulsifier |
| ES2647090T3 (en) * | 2012-12-21 | 2017-12-19 | The Procter & Gamble Company | Dishwashing composition |
| JP6192231B2 (en) * | 2014-07-02 | 2017-09-06 | ライオン株式会社 | Liquid detergent for dishwashing |
| DE102014226293A1 (en) * | 2014-12-17 | 2016-06-23 | Henkel Ag & Co. Kgaa | Detergent with improved stain removal |
| WO2017173590A1 (en) * | 2016-04-06 | 2017-10-12 | The Procter & Gamble Company | A stable liquid detergent composition containing a self-structuring surfactant system |
| AU2017267127B2 (en) * | 2016-05-17 | 2020-04-02 | Unilever Global Ip Limited | Liquid laundry detergent compositions |
| US10947480B2 (en) | 2016-05-17 | 2021-03-16 | Conopeo, Inc. | Liquid laundry detergent compositions |
| CN109923198A (en) | 2016-10-31 | 2019-06-21 | 沙特基础工业全球技术有限公司 | Formula for excellent spatter property and antiredeposition benefit |
| AR118833A1 (en) * | 2019-05-03 | 2021-11-03 | Sasol Performance Chemicals Gmbh | NON-AQUEOUS DEFOAMING COMPOSITIONS AND THEIR USE IN FOAM CONTROL OF NON-AQUEOUS FOAMS |
| WO2021100691A1 (en) * | 2019-11-21 | 2021-05-27 | 花王株式会社 | Detergent composition |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2243307C2 (en) * | 1972-09-02 | 1982-04-15 | Henkel KGaA, 4000 Düsseldorf | Solid detergents and washing auxiliaries with a content of anti-graying additives |
| DE2301728C2 (en) * | 1973-01-13 | 1982-09-02 | Henkel KGaA, 4000 Düsseldorf | Liquid laundry detergent and auxiliary agent with a content of anti-graying additives |
| DE3018173A1 (en) * | 1980-05-12 | 1981-11-19 | Henkel KGaA, 4000 Düsseldorf | Solid, alkaline low-foaming cleansing compsn. e.g. for bottle-washing - contg. propylene oxide adduct on aliphatic branched alcohol as foam-inhibitor |
| JPS6160794A (en) * | 1984-08-31 | 1986-03-28 | ライオン株式会社 | Animal wool treating agent |
| WO1988005809A1 (en) * | 1987-02-06 | 1988-08-11 | Gaf Corporation | Propoxylated guerbet alcohols and esters thereof |
| DE3928601A1 (en) * | 1989-08-30 | 1991-03-07 | Henkel Kgaa | USE OF SELECTED MIXTURES OF POLYALKYLENE DIOLETHERS AS FOAM-PRESSING ADDITIVES FOR LOW-FOAM CLEANING AGENTS |
| DE3928602A1 (en) * | 1989-08-30 | 1991-03-07 | Henkel Kgaa | ALKALISTABLE AND STRONG ALKALINE-MOLDABLE ANTI-FOAM AGENTS FOR COMMERCIAL CLEANING, ESPECIALLY FOR BOTTLE AND CIP CLEANING |
| DE4116406A1 (en) * | 1991-05-18 | 1992-11-19 | Henkel Kgaa | USE OF DIALKYL ETHERS AS FOAM REGULATORS |
| GB9113139D0 (en) * | 1991-06-18 | 1991-08-07 | Procter & Gamble | Detergent compositions |
| EP0593406A1 (en) * | 1992-10-13 | 1994-04-20 | The Procter & Gamble Company | Non-aqueous liquid detergent compositions |
-
1994
- 1994-10-24 EP EP94307794A patent/EP0709450A1/en not_active Withdrawn
-
1995
- 1995-10-12 MX MX9702982A patent/MX9702982A/en unknown
- 1995-10-12 JP JP8514069A patent/JPH10507788A/en active Pending
- 1995-10-12 CN CN 95196961 patent/CN1170426A/en active Pending
- 1995-10-12 WO PCT/US1995/013576 patent/WO1996012782A1/en active Search and Examination
- 1995-10-12 CA CA 2203268 patent/CA2203268A1/en not_active Abandoned
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100434500C (en) * | 2005-07-04 | 2008-11-19 | 中国科学院理化技术研究所 | Guerbet anion surfactant, and its preparing method and use |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2203268A1 (en) | 1996-05-02 |
| MX9702982A (en) | 1997-06-28 |
| WO1996012782A1 (en) | 1996-05-02 |
| EP0709450A1 (en) | 1996-05-01 |
| JPH10507788A (en) | 1998-07-28 |
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