CN87107306A - The softening detergent compositions of cellulase - Google Patents
The softening detergent compositions of cellulase Download PDFInfo
- Publication number
- CN87107306A CN87107306A CN198787107306A CN87107306A CN87107306A CN 87107306 A CN87107306 A CN 87107306A CN 198787107306 A CN198787107306 A CN 198787107306A CN 87107306 A CN87107306 A CN 87107306A CN 87107306 A CN87107306 A CN 87107306A
- Authority
- CN
- China
- Prior art keywords
- composition
- cellulase
- detergent compositions
- softening
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
Abstract
Composition disclosed herein has good cleaning function, can play the effect of textile softener simultaneously.These compositions contain cellulase, and can be formulated into weakly alkaline pH scope.
Description
The present invention relates to have good cleaning function, can be used as the detergent compositions of textile softener simultaneously again.
People have passed through various effort, attempt to prepare the laundry detergent compositions that not only has good cleaning function of institute's phase but also softening textiles effect is arranged.Therefore, the someone attempts to mix positively charged ion fabric tenderizer in the detergent compositions that with the anion surfactant is base, and its purpose is to use various means to overcome natural antagonism between the yin, yang ionic surface active agent.For example, british patent specification 1,518,529 detergent compositions of introducing, said composition contains: organic surface active agent, auxiliary agent and a kind of particle shape with poorly water-soluble scattered inhibitor blended quaternary ammonium type tenderizer (said here scattered inhibitor can suppress positively charged ion and disperse too early in washings).Even in these compositions, also have to adopt some compromise proposal between decontamination and softening effect.Provide another existing method of the combination detergent compositions with softening power to be to use nonionogenic tenside (rather than anionic) and cationic softening agent, for example, in british patent specification 1,079,388, German patent specification 12,20, this based composition is described in 956 United States Patent (USP)s 3,607,763.But find; If the nonionogenic tenside that provides good cleaning effect to use capacity is provided, will destroy the bating effect of cationic softening agent, so must accept dealing carefully with between cleaning and softening effect once more.
Recently, in british patent specification 1,514, disclose following content in 276: some has the tertiary amine of two chain alkyls or an alkenyl and a short-chain alkyl, can become effective fabric tenderizer in detergent compositions.
As british patent specification 1,400,898 is described, in order to obtain making textiles remollescent detergent compositions, once used the montmorillonite type clay.
European patent application book 0026528 has been introduced to unite in alkaline detergent compositions and has been used water-insoluble long chain tertiary amine and water-soluble cationic quaternary ammonium compound and/or water-soluble fatty amine when (can randomly add clay), and the performance of softening fabric can be provided.
Other method is as English Patent 1,368, and 599 is described, uses fiber hydrolase in the fabric softening compositio, i.e. cellulase is as falling hard agent.
British patent specification 2,075,028; 2,095,275; 2,094,826 and Japanese Patent 57108-199 further introduced the application of cellulase in detergent compositions.
European patent specification 0120528 has been introduced by water-insoluble C
10-C
26The softening detergent compositions of the alkalescence that tertiary amine and cellulase synergistic mixture are formed.
European patent specification 0177165 discloses and has contained the softening detergent compositions of the alkalescence that purifies terre verte and cellulase mixture.
But, up to the present, also do not find in washing agent industry, especially in the softening washing product, to accept the de-sludging cellulase widely.One of reason is that people also do not understand the interaction between cellulase and other washing agent components more commonly used.Another reason is not to be to use cellulase in the best pH scope of cellulase by the synthetic composition of prior art.
And, up to now,, when modulation softening washing detergent compositions, trend towards improving the pH(of composition far and away greater than 10 in order to strengthen clean effect), to cotton goods more so.Like this, because the deposition of softening component can reduce its clean effect again conversely.
Yet, in the pH of above-mentioned alkalescence scope, run into the problem of protection fabric, such as, can make fabric coarse, fabric damages or problem such as fade; Therefore, a kind of pH of necessary modulation is lower than 10 composition, and said composition should show good fabric provide protection and good ramollescence when having good soil-removing action.
The present invention has satisfied above-mentioned requirements, and provides effective weak base to soften detergent compositions, and said composition presents good fabric provide protection and ramollescence, has good clean effect simultaneously, and is especially true to cotton goods.
The present invention has also set forth the medium-term and long-term problem that exists of prior art;
A. in which kind of pH scope, use cellulase can make it present best effect?
B. the present invention proposes a wonderful discovery, as european patent application book 0026528 or 0120528 described water-insoluble long-chain alkanamine class, when under weak basic condition of the present invention, being used for washing in heaps, in the presence of cellulase, can cause and softening opposite effect.
Also find: in order to obtain the benefit of this paper composition, a large amount of anion surfactant of essential adding.
Therefore, one of task of the present invention provides at the abundant cellulose enzyme bating detergent compositions of the negatively charged ion of weakly alkaline pH＜10 modulated.
Another task of the present invention provides the cellulose enzyme bating detergent compositions that is substantially devoid of water-soluble long-chain alkanamine tenderizer or derivatives thereof.
The 3rd task of the present invention provide have good softening, decontamination, the softening detergent compositions of fabric provide protection.
The present invention relates to be used for cleaning, the detergent compositions of softening fibre product, said composition comprises the surfactivity anion surfactant of (wherein containing 50%(weight at least)) and cellulase.
The present composition is 1% the distilled water solution of pH6.5-9.5, and is substantially devoid of water-fast chain alkyl amine tenderizer or derivatives thereof.
Preferred compositions comprises the other composition that adds the clay softening thing.
Tensio-active agent
The tensio-active agent that is used for this paper contains 50%(weight at least), 60-100%(weight preferably) anion surfactant (salt form).Anion surfactant does not comprise the soap agent herein.Can be used for the anion surfactant wide range in the present composition.
Suitable anion surfactant is water-soluble alkylbenzene sulfonate, alkyl-sulphate, alkyl polyethoxy vitriol, paraffin sulfonate, alpha-olefins base sulfonate, alpha-sulfo carboxylate salt and their ester, alkyl glyceryl ether sulfonate, the vitriol of glycerine monofatty ester and sulfonate, alkylphenol polyethoxye ether sulfate, 2-acyloxy alkane-1-sulfonate, and β-alkoxyl group alkyl sulfonate.
Particularly preferred alkylbenzene sulfonate contains 9-15 on its straight or branched alkyl, particularly 11-13 carbon atom.Suitable alkyl-sulphate contains 10-22 on alkyl chain, particularly 12-18 carbon atom.The poly-ethoxy ether sulfate of suitable alkyl contains 10-18 carbon atom on its alkyl chain, and each molecule contain mean number be 1-12 individual-CH
2CH
2The O-group contains 10-16 carbon atom on the alkyl chain, each molecule on average contains 1-6-CH
2CH
2O-person is better.
Suitable paraffin sulfonate is a straight chain shape substantially, and contains 8-24, especially 14-18 carbon atom.Suitable alpha-olefins base sulfonate contains 10-24, especially 14-16 carbon atom; The preparation method of alpha-olefins sulfonate is: any sultones is hydrolyzed into corresponding hydroxyl alkyl sulphonic acid ester, and react promptly with sulphur trioxide the back that neutralizes under this condition.Suitable alpha-sulfo carboxylate salt contains 6-20 carbon atom; What this paper was included is not only α-alpha-sulfonated fatty hydrochlorate, also comprises the ester of the above-mentioned acid that is made by carbon containing 1-14 alcohol.
Suitable alkyl glycerol ether sulfate is the ether of carbon atoms 10-18 alcohol, especially from cocounut oil and Tallow, beef derive and alcohol ether.Suitable alkylphenol polyethoxye ether sulfate contains 8-12 carbon atom on its alkyl chain, each molecule on average contains 1-6-CH
2CH
2The O-group.Suitable 2-acyl-oxygen alkane-1-sulfonate contains 2-9 carbon atom and contains 9-23 carbon atom at moieties on its acyl group.Suitable β-alkoxyl group alkyl sulfonate contains 1-3 carbon atom and contains 8-20 carbon atom at paraffin section on alkyl.
The alkyl chain of aforementioned anion surfactant can obtain from natural resource such as cocounut oil or Tallow, beef, or obtains with artificial synthesis, for example adopts Ziegler process or oxo process (Oxo) method to obtain.Use basic metal, ammonium, or alkanol-ammonium cation; Preferably sodium can improve water-soluble degree.The present invention has thought better of the mixture of anion surfactant; Gratifying mixture contains at the alkylbenzene sulfonate that contains 11-13 carbon atom on the alkyl and contain the alkyl-sulphate of 12-18 carbon atom on alkyl.
Can mix the nonionogenic tenside of limit the quantity of (＜50%) in this paper composition.Suitable nonionogenic tenside is that hydrophile-lipophile balance value (HLB) is the water-soluble ethoxylate of 11.5-17.0, and includes, but is not limited to C
10-C
20Primary alcohol ethoxylate, secondary alcohol ethoxyl compound and C
6-C
10Alkyl phenol ethoxylate.Preferred person is C
14-C
18The product that straight chain primary alcohol and 7-30 moles of ethylene oxide/every mol of alcohol condensation forms, for example: C
14-C
15(EO)
7, C
16-C
18(EO)
25, C particularly
16-C
18(EO)
11
The tensio-active agent of other types also can mix use in finite quantity ground with anion surfactant.They comprise zwitter-ion, both sexes and cats product.
The adoptable positively charged ion cosurfactant of this paper comprises: chemical formula is R
4R
5R
6R
7N
+X
-Water-soluble quaternary ammonium compound, in the formula: R
4For containing 10-20, the alkyl of 12-18 carbon atom particularly, R
5, R
6, R
7C respectively does for oneself
1-C
7Alkyl, preferably methyl; X
-Be negatively charged ion, as chlorion.This class TMA (TriMethylAmine) examples for compounds comprises: chlorination C
12-C
14Alkyl trimethyl ammonium and coconut palm alkyl trimethyl ammonium methyl sulfate.
Cellulase
Can be used for cellulase of the present invention can be bacterium or the fungal cellulase of any best pH between 5 and 9.5.
GB-A-2,075,028; 2,095,275 and DE-OS 2,247,832 in introduced suitable cellulase.
The example of the plain enzyme of this fibrid has: by Humicola insolens(Humicola griseavar thermoidea) bacterial strain, especially the cellulase that produces of Humicola strain DSM 1800, with by Bacillus N fungi or belong to the mycetogenetic cellulase of the generation cellulase 212 of Aeromonas class, and from ocean mullosc(Dolabella Auricula Solander) cellulase that extracts of liver pancreas.
Add cellulase in the present composition and can be non-pulverizing particle (as " marumes " or particle (prills) "); or liquid; as cellulase is suspended in the nonionogenic tenside, or be dissolved in the water medium, make the cellulase concentrated solution thus.
With the foundation that is hydrolyzed to of carboxymethyl cellulose, carry out cellulase activity of the present invention and measure.According to the described yellow prussiate reaction of W.S.Hoffman (" J.BioI-Chem. " 120,51(1973)), by the low molecule reduced carbohydrate that colorimetric method for determining generated.
Crucial culture condition is: pH:7.0, and temperature is 40 ℃, incubation time is: 20 minutes.
A CMCase unit, it is defined as: under these conditions, the amount of the reduced carbohydrate that per minute forms is equivalent to 10
-6The mole enzyme amount that glucose consumed.
The best preferable range of cellulase activity is herein: 5-100CMCase activity unit/gram composition.
This paper composition does not contain water-insoluble long-chain alkanamine class tenderizer and derivative thereof substantially, and reason is to find surprisingly: this compounds produces under pH condition of the present invention and the cellulase opposite effect.Amine tenderizer derivative comprises the corresponding amide compound.EP.A 0,026, and 528; 0,120,528 have introduced such amine tenderizer, comprise that specifically structure is R
1R
2R
3The amine of N, wherein R
1And R
2Be C
6-C
20Alkyl chain, R
3Be C
1-C
10Alkyl chain or hydrogen.
This paper composition should be modulated into pH between 6.5-9.5, and concentration is 1% distilled water solution.In this pH scope, the cellulase that this paper adopted presents best effect.
Annexing ingredient
Except that basal component, this paper composition can contain optional annexing ingredient, and these components can be described as and very need.
For example, preferably contain the clay softening agent that mixes with cellulase in this paper composition.Such clay softening agent is widely known by the people in the washing agent patent documentation, and is extensive use of as commodity in the Europe and the U.S..Comprise heat treated kaolin of various processes and various multilayer terre verte in this class clay softening agent.Preferred clay softening agent is Germany Patent document 2334899 and English Patent 1,400, the terre verte tenderizer described in 898, and relevant details sees also above-mentioned two pieces of documents.
The clay softening material of most preferred fabric comprises unprocessed wilkinite material, promptly contains the wilkinite that is essentially polynite type clay of various impurity.The consumption of this clay and character depend on the source of clay material.In preferred compositions, the consumption of tenderizer clay is at least 1%, is generally 1-20%, preferably 2-10%.
Whole also advantageously washing contained detergent auxiliary and/or metal ion sequestering agent in the detergent compositions.The compound of the ranged detergent auxiliary that this area is known has: nitrilotriacetic acid(NTA) salt, polycarboxylate, Citrate trianion, water-soluble phosphate as: tri-polyphosphate and just-and Jiao-sodium phosphate, with and composition thereof.The metal ion sequestering agent comprises that all preambles are described, also has the picture edta salt in addition, and this class material of aminopolyphosphonic acid salt and other a large amount of various multi-functional organic acids and salt are too many in view of kind, do not give unnecessary details for this reason at this.The representative instance of relevant this application of class material in various cleansing compositions sees also United States Patent (USP) 3,579,454.Preferred polyfunctional group organic acid used herein has: citric acid, ethylenediamine tetramethylene phosphonic acid and diethylidene triamino pentamethylene phosphoric acid.
Being used for another kind of detergent auxiliary of the present invention is insoluble sodium silicoaluminate.German Patent 24,22, effect was excellent when 655 zeolite (as: zeolite A) auxiliary agents of having introduced 1-10 micron size were used for low phosphorus hydrochlorate or nonphosphate composition.Auxiliary agent/the sequestering agent that should comprise in a word, 0.5-45% in the composition.
Also can contain saturated in this paper composition or unsaturated fatty acids and corresponding soap agent.Suitable lipid acid (saturated or unsaturated) has 10-18 carbon atom on its alkyl chain.Preferred person is for having the unsaturated acid of 14-18 carbon atom, preferably oleic acid on the alkyl chain.Also can use corresponding soap agent.Additional fat acid/soap the agent concentration that is adopted can be up to 20%.
It is R-CH(COOH that this paper composition also can contain general formula) CH
2(COOH) compound, i.e. succinic acid derivative, R is C in the formula
10-C
20Alkyl or alkenyl, C
12-C
16The person is better, or the R in the formula can use hydroxyl, sulfo group, the replacement of substituting groups such as sulfoxylic acid base or sulfone.
Preferably use the succinate auxiliary agent, comprise their sodium, potassium, ammonium and alkanol ammonium salts with the form of water-soluble salt.
The specific examples of succinate auxiliary agent comprises: dodecyl succinate salt, tetradecyl succinate, hexadecyl succinate, 2-dodecenyl succinic succinate (preferably), 2-15 carbene base succinates or the like.
What also can be used as auxiliary agent in this article is United States Patent (USP) 4,663,071 described compound, it is the mixture of monosuccinic acid tartrate (tartrate monosuccinic acid) and two succsinic acid tartrates, monosuccinic acid is 97: 3 to 20: 80 with the weight ratio of two succsinic acids, preferably 95: 5 to 40: 60.
Another annexing ingredient is a SYNTHETIC OPTICAL WHITNER.Peroxide bleaching agent is a preferred compound, as: Sodium peroxoborate (marketing is monohydrate and tetrahydrate), yellow soda ash peroxyhydrate, burnt Alendronate peroxyhydrate, urea peroxyhydrate.
Bleach-activating agent can mix use with above-mentioned peroxide bleaching agent.The kind of bleach-activating agent comprises: ester, imines, imidazoles, oxime and carbonate.Wherein preferred material comprises: O-acetoxy group methyl benzoate; P-acetoxy group benzene sulfonic acid sodium salt, as: the hot acyloxy benzene sulfonic acid sodium salt of 4-; With 4-acyloxy in last of the ten Heavenly stems benzene sulfonic acid sodium salt: biological phenol diacetate esters (biophenol diacetate); Tetra acetyl ethylene diamine; Tetra-acetylated hexamethylene-diamine; Tetra-acetylated methylene diamine.
United States Patent (USP) 4,483, other better peroxide bleaching activators of introducing in 778 and 4,539,130 have alpha-substitution alkyl or alkenyl ester, as: the benzene sulfonic acid sodium salt hot acyloxy of 4-(2-chlorine), 4-(3,5,5-trimethyl acetyl oxygen base) benzene sulfonic acid sodium salt.Suitable peroxy acid also is the peroxide bleaching activator, for example, and described in the disclosed european patent application book 0166571; General formula is the compound of RXAOOH and RXAL, and R is hydrocarbon (hydroxcarbyl) base in the formula, and X is a heteroatoms, and A is a carbonyl abutment group, and L is a leavings group, particularly the oxo benzene sulfonic acid sodium salt.
The enzyme different with cellulase, as proteolytic ferment, amylolytic enzyme, or lipolytic enzyme also can mix use with cellulase as herein described.The general equal liquid embodiment that can be used for the present composition of all known enzyme stabilization systems according to the concentration that technical requirements is formulated.The example of suitable stable system comprises: short (C
1-4) combination of chain carboxylic acid, especially formic acid and low levels calcium; Boric acid and water-soluble salt thereof also can make up with polyvalent alcohol.
In addition, this paper composition also can add in other industrial goods habitual except that containing the component of above having mentioned, for attractive in appearance or increase the various additional composition of product performance benefit.Habitual composition comprises: pH regulator agent, spices, dyestuff, fluorescent bleaches, soil-suspending agent, hydrotropic agent, impregnation agent (gel-control agents), freeze-thaw stabilizer, sterilant, sanitas, foaming regulator and bleaching stibilizer.
The form of composition and preparation
Detergent compositions of the present invention can be comprising particle, liquid, and paste or scraps of paper shape exist at interior any proper physical state.These formulations can make with any method according to the requirement of its physical form; be about to component and mix, make their copolymerization caking, they microencapsulations; they are scattered in the liquid vehicle, they are adsorbed in or cover (as: on the non-textile or the scraps of paper) on the non-particulate matrix.
Following example detailed ground explain the present invention, but and do not mean that its scope that limits.
The example I
With following component and the ratio indicated, made the particulate state detergent compositions:
Weight percentages
C linear alkylbenzene sulphonic acid 11.0
Tallow, beef sodium alkyl sulfate 5.0
Tallow, beef alcohol ethoxy (E011) is changed thing 0.3
Tripoly phosphate sodium STPP 24.0
Wilkinite 8.5
Cellulase 3.0*
Proteolytic ferment 0.9
Sodium sulfate 40.0
Less important composition and water add to 100
PH(concentration is 1% distilled water solution) 8.7
* representing every gram composition is 40 CMCase units
Above-mentioned composition presents good soil-removing action and good ramollescence when presenting good fabric provide protection (do not find that fabric damages, fade, or fabric roughening).
Also made following particulate composition:
Weight percentages
Example II example III
C
12Linear alkylbenzene sulphonic acid 7.0 6.5
C
13-C
15Fatty Alcohol(C12-C14 and C12-C18)/11 ethylene oxide condensates 1.0 0.5
Sodium sulfate 15.0 15.0
Tripoly phosphate sodium STPP 24-
Zeolite A-26.0
Sodium nitrilo triacetate-5.0
Wilkinite 6.5 6.5
Cellulase 3.5** 3.5**
Proteolytic ferment 0.5 0.5
Sodium perborate tetrahydrate 20.0 20.0
TAED＊ 1.2 3.0
Boric acid 4.0 4.0
Fluorescent bleaches 0.3 0.5
Less important composition and water-add to 100-
PH(concentration is 1% distilled water solution) 9.0 9.0
* tetra acetyl ethylene diamine
It is 47 CMCase units that * represents every gram composition
Example II and III composition present good decontamination, softening and fabric provide protection.
The form of composition and preparation
Detergent compositions of the present invention can be comprising particle, liquid, and paste or scraps of paper shape exist at interior any proper physical state.These formulations can make with any method according to the requirement of its physical form; be about to component and mix, make their copolymerization caking, they microencapsulations; they are scattered in the liquid vehicle, they are adsorbed in or cover (as: on the non-textile or the scraps of paper) on the non-particulate matrix.
Following example detailed ground explain the present invention, but and do not mean that its scope that limits.
The example I
With following component and the ratio indicated, made the particulate state detergent compositions:
Weight percentages
C linear alkylbenzene sulphonic acid 11.0
Tallow, beef sodium alkyl sulfate 5.0
Tallow, beef alcohol ethoxy (E011) is changed thing 0.3
Tripoly phosphate sodium STPP 24.0
Wilkinite 8.5
Cellulase 3.0*
Proteolytic ferment 0.9
Sodium sulfate 40.0
Less important composition and water add to 100
PH(concentration is 1% distilled water solution) 8.7
* representing every gram composition is 40 CMCase units
Above-mentioned composition presents good soil-removing action and good ramollescence when presenting good fabric provide protection (do not find that fabric damages, fade, or fabric roughening).
Also made following particulate composition:
Weight percentages
Example II example III
C
12Linear alkylbenzene sulphonic acid 7.0 6.5
C
13-C
15Fatty Alcohol(C12-C14 and C12-C18)/11 ethylene oxide condensates 1.0 0.5
Sodium sulfate 15.0 15.0
Tripoly phosphate sodium STPP 24-
Zeolite A-26.0
Sodium nitrilo triacetate-5.0
Wilkinite 6.5 6.5
Cellulase 3.5** 3.5**
Proteolytic ferment 0.5 0.5
Sodium perborate tetrahydrate 20.0 20.0
TAED＊ 1.2 3.0
Boric acid 4.0 4.0
Fluorescent bleaches 0.3 0.5
Less important composition and water-add to 100-
PH(concentration is 1% distilled water solution) 9.0 9.0
* tetra acetyl ethylene diamine
* represents every gram composition 47 CMCase units
Example II and III composition present good decontamination, softening and fabric provide protection.
The example IV
Also made following liquid detergent compositions:
Weight percentages
C
12Linear alkyl benzene sulphonic acid 11.0
Coconut palm alkyl-sulphate (trolamine (TEA) salt) 4.0
C
12-15Tallow, beef alcohol ethoxylate (EO7) 10.0
Cocoanut fatty acid 10.0
Oleic acid 5.0
Citric acid 1.0
Trolamine 4.0
Ethanol 6.0
Propylene glycol 1.5
Sodium hydroxide 3.0
Sodium formiate 1.0
Cellulase 2.5*
Proteolytic ferment 0.6
Less important composition, water adds to 100
PH(concentration is 1% distilled water solution) 7.5
* representing every gram composition is 34 CMCase units
Claims (7)
1, be used to clean and the detergent compositions of softening textiles, said composition contains,
-contain the tensio-active agent of at least 50% (weight) anion surfactant,
-de-sludging cellulase,
-said composition does not contain water-insoluble long-chain alkanamine tenderizer substantially, or derivatives thereof, and the pH of 1% distilled water solution of this detergent compositions is 6.5-9.5.
2, according to the composition of claim 1, wherein, cellulase is that best pH is bacterium or the fungal cellulase between 5 and 11.5.
3, according to the composition of claim 1, wherein, cellulase is that best pH is the alkali cellulose enzyme of 6.5-9.5.
4, according to the composition of claim 1, wherein the cellulase activity of said composition is 5-100CMCase activity unit/gram composition.
5, according to the composition of claim 1, wherein, tensio-active agent contains 60-100%(weight) anion surfactant.
6,, wherein also contain the clay material of softening fabric according to the composition of claim 1.
7, according to the composition of claim 6, wherein the clay material of softening fabric is a wilkinite.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB868627914A GB8627914D0 (en) | 1986-11-21 | 1986-11-21 | Softening detergent compositions |
| GB8627914 | 1986-11-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN87107306A true CN87107306A (en) | 1988-06-01 |
Family
ID=10607738
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN198787107306A Pending CN87107306A (en) | 1986-11-21 | 1987-11-21 | The softening detergent compositions of cellulase |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0269168B1 (en) |
| JP (1) | JPS63199297A (en) |
| KR (1) | KR880006354A (en) |
| CN (1) | CN87107306A (en) |
| AT (1) | ATE122713T1 (en) |
| AU (1) | AU595401B2 (en) |
| DE (1) | DE3751304T2 (en) |
| DK (1) | DK611487A (en) |
| EG (1) | EG18380A (en) |
| FI (1) | FI91276C (en) |
| GB (1) | GB8627914D0 (en) |
| PH (1) | PH25615A (en) |
| TR (1) | TR24080A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1324128C (en) * | 2002-04-25 | 2007-07-04 | 花王株式会社 | Mutated alkaline cellulase |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5120463A (en) * | 1989-10-19 | 1992-06-09 | Genencor International, Inc. | Degradation resistant detergent compositions based on cellulase enzymes |
| EP0495257B1 (en) * | 1991-01-16 | 2002-06-12 | The Procter & Gamble Company | Compact detergent compositions with high activity cellulase |
| US5443750A (en) * | 1991-01-16 | 1995-08-22 | The Procter & Gamble Company | Detergent compositions with high activity cellulase and softening clays |
| US5668073A (en) * | 1991-11-06 | 1997-09-16 | The Procter & Gamble Company | Detergent compounds with high activity cellulase and quaternary ammonium compounds |
| AU3151293A (en) * | 1991-12-04 | 1993-06-28 | Procter & Gamble Company, The | Liquid laundry detergents with citric acid, cellulase, and boric-diol complex to inhibit proteolytic enzyme |
| WO1993016158A1 (en) * | 1992-02-18 | 1993-08-19 | The Procter & Gamble Company | Detergent compositions with high activity cellulase and quaternary ammonium compounds |
| CA2134446A1 (en) * | 1992-05-01 | 1993-11-11 | Kathleen A. Clarkson | Methods for treating cotton-containing fabrics with cbh i enriched cellulase |
| US5599786A (en) * | 1993-08-12 | 1997-02-04 | The Procter & Gamble Company | Cellulase fabric-conditioning compositions |
| US5616553A (en) * | 1993-08-12 | 1997-04-01 | The Procter & Gamble Company | Fabric conditioning compositions |
| CN1151176A (en) * | 1994-04-29 | 1997-06-04 | 普罗格特-甘布尔公司 | Cellulase fabric-conditioning compositions |
| US5445747A (en) * | 1994-08-05 | 1995-08-29 | The Procter & Gamble Company | Cellulase fabric-conditioning compositions |
| DE19515072A1 (en) * | 1995-04-28 | 1996-10-31 | Cognis Bio Umwelt | Detergent containing cellulase |
| US6187740B1 (en) | 1997-07-11 | 2001-02-13 | The Procter & Gamble Company | Alkaline detergent compositions comprising a specific cellulase |
| EP1012220A1 (en) * | 1997-07-11 | 2000-06-28 | The Procter & Gamble Company | Alkaline detergent compositions comprising a specific cellulase |
| CN103897840A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Fabric flexible washing agent |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK187280A (en) * | 1980-04-30 | 1981-10-31 | Novo Industri As | RUIT REDUCING AGENT FOR A COMPLETE LAUNDRY |
| GB2095275B (en) * | 1981-03-05 | 1985-08-07 | Kao Corp | Enzyme detergent composition |
| JPS591598A (en) * | 1982-06-25 | 1984-01-06 | 花王株式会社 | Detergent composition |
| JPS59221396A (en) * | 1983-05-31 | 1984-12-12 | ライオン株式会社 | Enzyme-containing detergent composition |
| GB8421802D0 (en) * | 1984-08-29 | 1984-10-03 | Unilever Plc | Detergent composition |
| JPS6262898A (en) * | 1985-09-13 | 1987-03-19 | 花王株式会社 | Detergent composition |
| GB8627915D0 (en) * | 1986-11-21 | 1986-12-31 | Procter & Gamble | Detergent compositions |
-
1986
- 1986-11-21 GB GB868627914A patent/GB8627914D0/en active Pending
-
1987
- 1987-11-11 DE DE3751304T patent/DE3751304T2/en not_active Revoked
- 1987-11-11 EP EP87202189A patent/EP0269168B1/en not_active Revoked
- 1987-11-11 AT AT87202189T patent/ATE122713T1/en not_active IP Right Cessation
- 1987-11-19 EG EG672/87A patent/EG18380A/en active
- 1987-11-20 DK DK611487A patent/DK611487A/en not_active Application Discontinuation
- 1987-11-20 PH PH36097A patent/PH25615A/en unknown
- 1987-11-20 TR TR87/0814A patent/TR24080A/en unknown
- 1987-11-20 FI FI875137A patent/FI91276C/en not_active IP Right Cessation
- 1987-11-20 AU AU81433/87A patent/AU595401B2/en not_active Ceased
- 1987-11-21 KR KR870013126A patent/KR880006354A/en not_active Application Discontinuation
- 1987-11-21 CN CN198787107306A patent/CN87107306A/en active Pending
- 1987-11-21 JP JP62295002A patent/JPS63199297A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1324128C (en) * | 2002-04-25 | 2007-07-04 | 花王株式会社 | Mutated alkaline cellulase |
Also Published As
| Publication number | Publication date |
|---|---|
| DK611487D0 (en) | 1987-11-20 |
| TR24080A (en) | 1991-03-04 |
| AU8143387A (en) | 1988-05-26 |
| ATE122713T1 (en) | 1995-06-15 |
| FI875137A (en) | 1988-05-22 |
| FI91276B (en) | 1994-02-28 |
| DE3751304T2 (en) | 1995-11-09 |
| DK611487A (en) | 1988-05-22 |
| PH25615A (en) | 1991-08-08 |
| AU595401B2 (en) | 1990-03-29 |
| DE3751304D1 (en) | 1995-06-22 |
| EP0269168A2 (en) | 1988-06-01 |
| GB8627914D0 (en) | 1986-12-31 |
| KR880006354A (en) | 1988-07-22 |
| EG18380A (en) | 1993-07-30 |
| FI91276C (en) | 1994-06-10 |
| FI875137A0 (en) | 1987-11-20 |
| EP0269168B1 (en) | 1995-05-17 |
| EP0269168A3 (en) | 1989-05-31 |
| JPS63199297A (en) | 1988-08-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN87107307A (en) | The detergent compositions of cellulase | |
| CN1289649C (en) | Laundry detergent compositions with cyclic amine polymers to provide appearance and integrity benefits to fabrics laundered therewith | |
| CN1211476C (en) | Fabric softening compositions | |
| CN1097090C (en) | Preparation of high Di (alkyl fatty ester) quaternary ammonium salt compound from triethanolamine | |
| CN87107306A (en) | The softening detergent compositions of cellulase | |
| CN1210390C (en) | Laundry detergent compositions with linea amine based polymer to provide appearance and integrity benefits to fabrics laundered therewith | |
| CN1082995C (en) | Fabric softening composition containing chlorine scavengers | |
| CN1031589C (en) | Liquid detergents with aryl boric acid for inhibition of proteolytic enzyme | |
| CN1297643C (en) | Structural fabric nursing composition | |
| JP6504710B2 (en) | Liquid cleaner | |
| CN100343376C (en) | Mdea ester quats with high content of monoester in blends with TEA ester quats | |
| CN1035065C (en) | Detergent compositions containing calcium and polyhydroxy fatty acid amide | |
| CN101076583A (en) | Solid laundry detergents with polyanionic ammonium surfactant | |
| CN1073714A (en) | Detergent bleach compositions | |
| CN1090879A (en) | Low sudsing polyhydroxy fatty acid amide detergents | |
| CN1046957C (en) | Cellulase fabric-conditioning compositions | |
| CN1918116A (en) | Novel alkyl ether sulfates | |
| CN100350031C (en) | Liquid detergent | |
| CN1168691A (en) | Detergent compositions containing amines and steatolysis enzyme | |
| CN1090886A (en) | Calcium ions and polyhydroxy fatty acid amide nonionic/selected anionic/soap surfactant mixture detergent composition | |
| CN1130400A (en) | Detergent composition for inhibiting dye transfer | |
| CN1130399A (en) | Detergent composition for inhibiting dye transfer | |
| CN1026124C (en) | Detergent compositions containing cellulase granulates | |
| CN1649989A (en) | Fabric conditioning composition comprising agent for enhancing the appearance of the rinse solution | |
| CN1262703A (en) | Light-duty liquid or gel dishwashing detergent compositions having controlled pH and desivable food soil removal and sudsing characteristics |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |