CN116965409A - Pesticide composition containing menthone - Google Patents
Pesticide composition containing menthone Download PDFInfo
- Publication number
- CN116965409A CN116965409A CN202311019794.1A CN202311019794A CN116965409A CN 116965409 A CN116965409 A CN 116965409A CN 202311019794 A CN202311019794 A CN 202311019794A CN 116965409 A CN116965409 A CN 116965409A
- Authority
- CN
- China
- Prior art keywords
- menthone
- osthole
- eugenol
- peanut
- wheat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 title claims abstract description 181
- 229930007503 menthone Natural products 0.000 title claims abstract description 181
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 title claims abstract description 168
- 239000000203 mixture Substances 0.000 title claims abstract description 18
- 239000000575 pesticide Substances 0.000 title abstract description 12
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims abstract description 171
- HPUXDMUGCAWDFW-UHFFFAOYSA-N Osthole Natural products COc1ccc2CCC(=O)Oc2c1C=CC(=O)C HPUXDMUGCAWDFW-UHFFFAOYSA-N 0.000 claims abstract description 95
- MBRLOUHOWLUMFF-UHFFFAOYSA-N osthole Chemical compound C1=CC(=O)OC2=C(CC=C(C)C)C(OC)=CC=C21 MBRLOUHOWLUMFF-UHFFFAOYSA-N 0.000 claims abstract description 89
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims abstract description 88
- 239000005770 Eugenol Substances 0.000 claims abstract description 88
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims abstract description 88
- 229960002217 eugenol Drugs 0.000 claims abstract description 88
- 235000017060 Arachis glabrata Nutrition 0.000 claims abstract description 21
- 244000105624 Arachis hypogaea Species 0.000 claims abstract description 21
- 235000010777 Arachis hypogaea Nutrition 0.000 claims abstract description 21
- 235000018262 Arachis monticola Nutrition 0.000 claims abstract description 21
- 241000209140 Triticum Species 0.000 claims abstract description 21
- 235000021307 Triticum Nutrition 0.000 claims abstract description 21
- 235000020232 peanut Nutrition 0.000 claims abstract description 21
- 206010039509 Scab Diseases 0.000 claims abstract description 16
- 240000008042 Zea mays Species 0.000 claims abstract description 13
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 13
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 13
- 235000005822 corn Nutrition 0.000 claims abstract description 13
- 230000000844 anti-bacterial effect Effects 0.000 claims description 28
- 208000031888 Mycoses Diseases 0.000 claims description 8
- 230000001954 sterilising effect Effects 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 abstract description 21
- 230000002195 synergetic effect Effects 0.000 abstract description 20
- 201000010099 disease Diseases 0.000 abstract description 11
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 8
- -1 menthone compound Chemical class 0.000 abstract description 3
- 239000003674 animal food additive Substances 0.000 abstract description 2
- 244000000004 fungal plant pathogen Species 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 19
- 239000003814 drug Substances 0.000 description 19
- 230000004071 biological effect Effects 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 13
- 241001451172 Fusarium pseudograminearum Species 0.000 description 12
- 241000223218 Fusarium Species 0.000 description 9
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 8
- 239000003899 bactericide agent Substances 0.000 description 8
- 238000013329 compounding Methods 0.000 description 8
- 238000011160 research Methods 0.000 description 8
- MJPMPMZXJIZPRE-UHFFFAOYSA-N 3-butyl-5,6,7,7a-tetrahydro-3h-2-benzofuran-1-one Chemical compound C1CCC=C2C(CCCC)OC(=O)C21 MJPMPMZXJIZPRE-UHFFFAOYSA-N 0.000 description 6
- 241000879295 Fusarium equiseti Species 0.000 description 6
- 241000223221 Fusarium oxysporum Species 0.000 description 6
- 241000813090 Rhizoctonia solani Species 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 241001530056 Athelia rolfsii Species 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- 244000246386 Mentha pulegium Species 0.000 description 3
- 235000016257 Mentha pulegium Nutrition 0.000 description 3
- 235000004357 Mentha x piperita Nutrition 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 244000052616 bacterial pathogen Species 0.000 description 3
- 230000003385 bacteriostatic effect Effects 0.000 description 3
- MYSWGUAQZAJSOK-UHFFFAOYSA-N ciprofloxacin Chemical compound C12=CC(N3CCNCC3)=C(F)C=C2C(=O)C(C(=O)O)=CN1C1CC1 MYSWGUAQZAJSOK-UHFFFAOYSA-N 0.000 description 3
- 238000010668 complexation reaction Methods 0.000 description 3
- 235000001050 hortel pimenta Nutrition 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- OICGFSUWXCJLCO-UHFFFAOYSA-N 1-ethylsulfonylsulfanylethane Chemical compound CCSS(=O)(=O)CC OICGFSUWXCJLCO-UHFFFAOYSA-N 0.000 description 2
- 241001290235 Ceratobasidium cereale Species 0.000 description 2
- 241000221779 Fusarium sambucinum Species 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 235000007746 carvacrol Nutrition 0.000 description 2
- HHTWOMMSBMNRKP-UHFFFAOYSA-N carvacrol Natural products CC(=C)C1=CC=C(C)C(O)=C1 HHTWOMMSBMNRKP-UHFFFAOYSA-N 0.000 description 2
- RECUKUPTGUEGMW-UHFFFAOYSA-N carvacrol Chemical compound CC(C)C1=CC=C(C)C(O)=C1 RECUKUPTGUEGMW-UHFFFAOYSA-N 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 230000006806 disease prevention Effects 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- WYXXLXHHWYNKJF-UHFFFAOYSA-N isocarvacrol Natural products CC(C)C1=CC=C(O)C(C)=C1 WYXXLXHHWYNKJF-UHFFFAOYSA-N 0.000 description 2
- PVTHJAPFENJVNC-MHRBZPPQSA-N kasugamycin Chemical compound N[C@H]1C[C@H](NC(=N)C(O)=O)[C@@H](C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H]1O PVTHJAPFENJVNC-MHRBZPPQSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VVOAZFWZEDHOOU-UHFFFAOYSA-N magnolol Chemical compound OC1=CC=C(CC=C)C=C1C1=CC(CC=C)=CC=C1O VVOAZFWZEDHOOU-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000010413 mother solution Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- AMNAZJFEONUVTD-KEWDHRJRSA-N (2s,3s,4s,5r,6r)-6-(4-amino-2-oxopyrimidin-1-yl)-4,5-dihydroxy-3-[[(2s)-3-hydroxy-2-[[2-(methylamino)acetyl]amino]propanoyl]amino]oxane-2-carboxamide Chemical compound O1[C@H](C(N)=O)[C@@H](NC(=O)[C@H](CO)NC(=O)CNC)[C@H](O)[C@@H](O)[C@@H]1N1C(=O)N=C(N)C=C1 AMNAZJFEONUVTD-KEWDHRJRSA-N 0.000 description 1
- 240000004510 Agastache rugosa Species 0.000 description 1
- JDLKFOPOAOFWQN-VIFPVBQESA-N Allicin Natural products C=CCS[S@](=O)CC=C JDLKFOPOAOFWQN-VIFPVBQESA-N 0.000 description 1
- 241000050051 Chelone glabra Species 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 101100136092 Drosophila melanogaster peng gene Proteins 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 241001149959 Fusarium sp. Species 0.000 description 1
- FEACDOXQOYCHKU-UHFFFAOYSA-N Gougerotin Natural products CNCC(=O)NC1=NC(=O)N(C=C1)C2OC(C(O)C(NC(=O)C(N)CO)C2O)C(=O)N FEACDOXQOYCHKU-UHFFFAOYSA-N 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- QNVSXXGDAPORNA-UHFFFAOYSA-N Resveratrol Natural products OC1=CC=CC(C=CC=2C=C(O)C(O)=CC=2)=C1 QNVSXXGDAPORNA-UHFFFAOYSA-N 0.000 description 1
- 241000951473 Schizonepeta Species 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- LUKBXSAWLPMMSZ-OWOJBTEDSA-N Trans-resveratrol Chemical compound C1=CC(O)=CC=C1\C=C\C1=CC(O)=CC(O)=C1 LUKBXSAWLPMMSZ-OWOJBTEDSA-N 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- VMFXMTJCTSYHCF-HHQUSWFZSA-N [(2r,3r,4s,5r)-5-(hexylamino)-4-hydroxy-2-(hydroxymethyl)-6-[(7-hydroxy-4-oxo-1,3a,5,6,7,7a-hexahydroimidazo[4,5-c]pyridin-2-yl)amino]oxan-3-yl] carbamate Chemical compound CCCCCCN[C@@H]1[C@H](O)[C@@H](OC(N)=O)[C@@H](CO)OC1\N=C\1NC(C(=O)NCC2O)C2N/1 VMFXMTJCTSYHCF-HHQUSWFZSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- JDLKFOPOAOFWQN-UHFFFAOYSA-N allicin Chemical compound C=CCSS(=O)CC=C JDLKFOPOAOFWQN-UHFFFAOYSA-N 0.000 description 1
- 235000010081 allicin Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000941 bile Anatomy 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000003589 local anesthetic agent Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229930003658 monoterpene Natural products 0.000 description 1
- 235000002577 monoterpenes Nutrition 0.000 description 1
- 239000010661 oregano oil Substances 0.000 description 1
- 229940111617 oregano oil Drugs 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 229940016667 resveratrol Drugs 0.000 description 1
- 235000021283 resveratrol Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of pesticides, and particularly relates to a pesticide composition containing menthone. A pesticide composition containing menthone contains osthole or eugenol and menthone as effective components. The osthole or eugenol and menthone are compounded according to a certain quality, a synergistic effect is shown on various plant pathogenic fungi, the control effect on plant diseases can be improved, data support is provided for effective control of wheat stem rot, wheat scab, peanut root rot, peanut southern blight and corn scab, and the osthole or eugenol and menthone compound feed additive has important significance on high quality and high yield of crops such as wheat, peanut and corn.
Description
Technical Field
The invention belongs to the technical field of pesticides, and particularly relates to a pesticide composition containing menthone.
Background
The occurrence of diseases causes great threat to agricultural production, and the use of chemical pesticides plays an important role in preventing, controlling crop diseases, ensuring stable yield and high yield of agricultural and forestry crops and the like. However, long-term application of chemical pesticides is easy to cause poisoning of people and livestock, high residue, environmental pollution and other consequences, and hidden danger is brought to ecological environment and human health.
The plant source bactericide is one medicine prepared with some parts of plant with bactericidal and bacteriostatic activity and extracted effective components and separated and purified monomer matter and through processing. The botanical fungicide gradually becomes a hot spot for controlling plant diseases due to the unique advantages of high efficiency, low toxicity, low residue, high selectivity, small influence on environment and the like. At present, scholars at home and abroad have conducted a great deal of research on the aspect of controlling fungal diseases by using a plant source bactericide, and find a plurality of plant resources with bactericidal action, which provides important basis for disease control research by using the plant source bactericide.
Currently, a plurality of plant source bactericides including ethylicin, kasugamycin, eugenol, carvacrol, osthole and the like exist in the market, are popularized and applied to the prevention and treatment of various crop diseases, and achieve remarkable prevention and treatment effects. For example Wang Zhifeng, eugenol has a strong antifungal effect and has a control effect of 78% on tomato late blight; peng Zhiguo and the like report that the control effect of the 1% osthole on powdery mildew of cucumber in a greenhouse reaches 79.33%; sun Xuemei the control effect of the ethylicin, kasugamycin, ningnanmycin and Zhongshengmycin on strawberry leaf spot disease can reach more than 80% through root dipping treatment; meanwhile, the latest researches of Zheng Anke and the like show that 9 plant source bactericides such as eugenol, allicin and osthole to be tested have an inhibiting effect on sunflower rust bacteria, 0.3% eugenol has the strongest toxicity, and the inhibiting effect is as high as more than 85%, and further show that the plant source bactericides have stronger potential for preventing and controlling plant diseases.
Menthone belongs to monoterpene compounds, widely exists in volatile oils of various plants such as peppermint, schizonepeta, baical skullcap root, wrinkled giant hyssop and the like, and researches show that the menthone has the effects of resisting viruses, resisting inflammation, promoting bile flow, promoting permeation and the like. At present, menthone and derivatives thereof are relatively widely applied in medicine and mainly used as local anesthetic, protective agent and the like, but are reported in the research process of plant diseases.
The prior researches of the inventor find that the menthone has better antibacterial effects on wheat stem basal rot, wheat scab, peanut root rot, peanut southern blight, corn scab and the like, and has better disease prevention and control potential. In order to further use menthone to develop plant disease prevention and control, the inventor develops compound researches on menthone, magnolol, carvacrol, oregano oil, osthole, eugenol, resveratrol, garlicin and other plant source bactericides, and partial compound combinations of the plant source bactericides show a strong synergistic effect, and the research results provide data support for effective prevention and control of wheat stem rot, wheat scab, peanut root rot, peanut southern blight and corn scab and have important significance for high quality and high yield of crops such as wheat, peanut and corn.
The information disclosed in this background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person of ordinary skill in the art.
Disclosure of Invention
The invention aims to provide a menthone-containing pesticide composition which can effectively inhibit the growth of pathogenic bacteria such as wheat stem rot, wheat scab, peanut root rot, peanut southern blight, corn scab and the like, effectively prevent and control various plant fungal diseases, and has important significance for the high quality and high yield of crops such as wheat, peanut, corn and the like.
In order to achieve the above purpose, the present invention provides the following technical solutions:
a pesticide composition containing menthone contains osthole or eugenol and menthone as effective components.
Preferably, the mass ratio of osthole to menthone is 1-9:9-1.
Preferably, the mass ratio of eugenol to menthone is 1-9:9-1.
The invention also provides application of the menthone-containing pesticide composition in preventing and controlling fungal diseases of crops.
Preferably, the crop fungal diseases include wheat stem rot, wheat scab, peanut root rot, peanut southern blight and corn scab.
Compared with the prior art, the invention has the following beneficial effects:
the osthole or eugenol and menthone are compounded according to a certain quality, a synergistic effect is shown on pathogenic bacteria of various plant fungal diseases, the control effect on plant diseases can be improved, data support is provided for effective control of wheat stem rot, wheat scab, peanut root rot, peanut southern blight and corn scab, and the osthole or eugenol and menthone compound feed additive has important significance on high quality and high yield of crops such as wheat, peanut and corn.
Detailed Description
The following is a clear and complete description of the technical solutions of the present patent.
Examples
1. Test strain
TABLE 1 test strains
2. Test agent
98% osthole (Shanghai Yuan Ye Biotechnology Limited), 98.5% eugenol (Shanghai Yuan Ye Biotechnology Limited), 99% menthone (Wuhan Rong Bright Biotechnology Co., ltd.).
After the test agent is dissolved, diluting the test agent into a single-agent mother solution by using 0.1% Tween-80 aqueous solution, setting a plurality of groups of proportions, and setting 5 mass concentration gradients of each single-agent mother solution and each proportion mixture according to an equal proportion method.
3. Test method
Adding 9mL of pre-melted PDA culture medium into a sterile conical flask, sequentially quantitatively sucking 1mL of liquid medicine from low concentration to high concentration, respectively adding into the conical flask, fully shaking uniformly, pouring into 1 culture dishes with the diameter of 9cm, preparing medicine-containing flat plates with corresponding concentrations, simultaneously setting treatment without medicines as blank control, and treating 10 flat plates with each liquid medicine with the mass concentration. Cutting bacterial cake at the colony edge of the tested bacterial strain by using a puncher with the diameter of 5mm, inoculating the bacterial cake to the centers of a medicine-containing flat plate and a blank control flat plate, covering a dish cover, and placing the dish cover in a constant temperature oven at 25 ℃ for cultivation. When the diameter of the blank control colony grows to about 2/3 of the diameter of the culture dish, measuring the colony diameter by a crisscross method, and calculating the inhibition rate of different treatments on hypha growth.
4. Data analysis
Data statistics analysis is carried out by adopting DPS software to obtain a virulence regression equation and virulence EC of the medicament on target bacteria 50 Values and co-toxicity coefficients (CTCs) were calculated according to the grand cloud Pei method.
In the above formula: the toxicity index measured by the ATI-mixed agent; EC of S-standard agent 50 The unit is mg/L; EC of M-mixture 50 The unit is mg/L.
TTI＝TI A ×P A +TI B ×P B
In the above formula: theoretical toxicological index of TTI-blends; TI (TI) A -a toxicity index of the agent; p (P) A -a percentage of agent in the mix in percent (%); TI (TI) B -a toxicity index of the B agent; p (P) B The percentage of agent B in the mixture is expressed as a percentage (%).
In the above formula: CTC-co-toxicity coefficient; the ATI-mixed agent actually measures the toxicity index; TTI-blend theoretical virulence index.
5. Measurement results
The synergy of the agents was evaluated based on the calculated co-toxicity coefficient (CTC), CTC.ltoreq.80 being antagonism, CTC.ltoreq.120 being additive, CTC.ltoreq.120 being synergy, the results are shown in tables 2-17.
TABLE 2 determination of indoor biological Activity of cnidium lactone and menthone Complex to Rhizoctonia cerealis
| Medicament name and ratio | EC 50 (mg/L) | ATI | TTI | CTC |
| Osthole | 24.8923 | 100.0000 | -- | -- |
| Menthone | 59.6386 | 41.7386 | -- | -- |
| Osthole 9: menthone 1 | 20.1431 | 123.5773 | 94.1739 | 131.2225 |
| Osthole 8: menthone 2 | 21.8283 | 114.0368 | 88.3477 | 129.0773 |
| Osthole 7: menthone 3 | 22.2765 | 111.7424 | 82.5216 | 135.4100 |
| Osthole 6: menthone 4 | 21.7146 | 114.6339 | 76.6954 | 149.4664 |
| Osthole 5: menthone 5 | 23.3722 | 106.5039 | 70.8693 | 150.2821 |
| Osthole 4: menthone 6 | 38.7564 | 64.2276 | 65.0431 | 98.7461 |
| Osthole 3: peppermint (peppermint)Ketone 7 | 34.4018 | 72.3576 | 59.2170 | 122.1905 |
| Osthole 2: menthone 8 | 44.3738 | 56.0968 | 53.3909 | 105.0683 |
| Osthole 1: menthone 9 | 57.7690 | 43.0894 | 47.5647 | 90.5910 |
From Table 2, it can be seen that the aligned micronucleus bacteria show excellent antibacterial activity after the osthole and the menthone are compounded. When the compounding ratio of osthole to menthone is 4: 6. 2:8 and 1:9, the compound combination and alignment sclerotium rolfsii show additive effect; the co-toxicity coefficients of the other compound combinations and the aligned sclerotium rolfsii are all larger than 120, and the synergistic effect is shown.
Table 3 determination of indoor biological Activity of osthole and menthone Complex against Fusarium pseudograminearum
From Table 3, it can be seen that osthole and menthone show excellent antibacterial activity against Fusarium pseudograminearum after being compounded. When the compounding ratio of osthole to menthone is 9: 1. 8: 2. 2:8 and 1: at 9, the addition is performed; the co-toxicity coefficient of the other compound combinations on the fusarium pseudograminearum is more than 120, and the synergistic effect is shown.
TABLE 4 determination of indoor biological Activity of cnidium lactone and menthone compounded Rhizoctonia solani
| Medicament name and ratio | EC 50 (mg/L) | ATI | TTI | CTC |
| Osthole | 37.6274 | 100.0000 | -- | -- |
| Menthone | 30.6867 | 122.6179 | -- | -- |
| Osthole 9: menthone 1 | 30.3438 | 124.0036 | 102.2618 | 121.2609 |
| Osthole 8: menthone 2 | 26.2394 | 143.4004 | 104.5236 | 137.1943 |
| Osthole 7: menthone 3 | 26.4953 | 142.0154 | 106.7854 | 132.9914 |
| Osthole 6: menthone 4 | 27.2942 | 137.8586 | 109.0472 | 126.4211 |
| Osthole 5: menthone 5 | 26.8867 | 139.9480 | 111.3090 | 125.7293 |
| Osthole 4: menthone 6 | 30.5143 | 123.3107 | 113.5708 | 108.5761 |
| Osthole 3: menthone 7 | 33.1192 | 113.6120 | 115.8326 | 98.0830 |
| Osthole 2: menthone 8 | 36.2103 | 103.9135 | 118.0944 | 87.9920 |
| Osthole 1: menthone 9 | 48.0668 | 78.2815 | 120.3561 | 65.0415 |
From table 4, it can be seen that osthole and menthone show excellent antibacterial activity against rhizoctonia solani after being compounded. When the compounding ratio of osthole to menthone is 9-5:1-5, the co-toxicity coefficients of the compound combination against rhizoctonia solani are all larger than 120, and the synergistic effect is shown.
TABLE 5 determination of indoor biological Activity of osthole and menthone Complex Fusarium pseudograminearum
| Medicament name and ratio | EC 50 (mg/L) | ATI | TTI | CTC |
| Osthole | 15.1544 | 100.0000 | -- | -- |
| Menthone | 58.2502 | 26.0160 | -- | -- |
| Osthole 9: menthone 1 | 13.3715 | 113.3336 | 92.6016 | 122.3884 |
| Osthole 8: menthone 2 | 13.7767 | 110.0002 | 85.2032 | 129.1034 |
| Osthole 7: menthone 3 | 15.1544 | 100.0000 | 77.8048 | 128.5268 |
| Osthole 6: menthone 4 | 14.4328 | 104.9997 | 70.4064 | 149.1337 |
| Osthole 5: menthone 5 | 13.7757 | 110.0082 | 63.0080 | 174.5940 |
| Osthole 4: menthone 6 | 13.9887 | 108.3332 | 55.6096 | 194.8101 |
| Osthole 3: menthone 7 | 17.1559 | 88.3335 | 48.2112 | 183.2217 |
| Osthole 2: menthone 8 | 16.8382 | 90.0001 | 40.8128 | 220.5191 |
| Osthole 1: menthone 9 | 19.7666 | 76.6667 | 33.4144 | 229.4418 |
From table 5, it can be seen that osthole and menthone show excellent antibacterial activity against fusarium pseudograminearum after being compounded. The co-toxicity coefficient of all tested compound combinations to the fusarium pseudograminearum is more than 120, and the synergistic effect is shown.
Table 6 determination of indoor biological Activity of Fusarium roseum by cnidium lactone and menthone Complex
| Medicament name and ratio | EC 50 (mg/L) | ATI | TTI | CTC |
| Osthole | 10.8644 | 100.0000 | -- | -- |
| Menthone | 110.2090 | 9.8580 | -- | -- |
| Osthole 9: menthone 1 | 10.6534 | 101.9806 | 90.9858 | 112.0841 |
| Osthole 8: menthone 2 | 8.3764 | 129.7025 | 81.9716 | 158.2286 |
| Osthole 7: menthone 3 | 8.5062 | 127.7233 | 72.9574 | 175.0656 |
| Osthole 6: menthone 4 | 8.9212 | 121.7818 | 63.9432 | 190.4531 |
| Osthole 5: menthone 5 | 9.2992 | 116.8316 | 54.9290 | 212.6956 |
| Osthole 4: menthone 6 | 10.9730 | 99.0103 | 45.9148 | 215.6392 |
| Osthole 3: menthone 7 | 12.4693 | 87.1292 | 36.9006 | 236.1186 |
| Osthole 2: menthone 8 | 15.4550 | 70.2970 | 27.8864 | 252.0834 |
Table 6 shows that osthole and menthone show excellent antibacterial activity against Fusarium rubrum after being compounded. When the compounding ratio of osthole to menthone is 8-1:2-9, the co-toxicity coefficient of the compound combination on Fusarium rubrum is more than 120, and the synergistic effect is shown.
TABLE 7 indoor biological Activity determination of osthole and menthone Complex Fusarium equisetum
| Medicament name and ratio | EC 50 (mg/L) | ATI | TTI | CTC |
| Osthole | 26.1725 | 100.0000 | -- | -- |
| Menthone | 145.5956 | 17.9762 | -- | -- |
| Osthole 9: menthone 1 | 22.2745 | 117.4998 | 91.7976 | 127.9988 |
| Osthole 8: menthone 2 | 20.5275 | 127.4997 | 83.5952 | 152.5203 |
| Osthole 7: menthone 3 | 26.1725 | 100.0000 | 75.3928 | 132.6386 |
| Osthole 6: menthone 4 | 33.7710 | 77.4999 | 67.1905 | 115.3436 |
| Osthole 5: menthone 5 | 45.5174 | 57.5000 | 58.9881 | 97.4773 |
| Osthole 4: menthone 6 | 55.1000 | 47.5000 | 50.7857 | 93.5303 |
| Osthole 3: menthone 7 | 95.1727 | 27.5000 | 42.5833 | 64.5793 |
| Osthole 2: menthone 8 | 116.3222 | 22.5000 | 34.3809 | 65.4433 |
| Osthole 1: menthone 9 | 174.4833 | 15.0000 | 26.1785 | 57.2988 |
From Table 7, it is clear that osthole and menthone show excellent antibacterial activity against Fusarium equisetum after being compounded. When the compounding ratio of osthole to menthone is 9-7:1-3, the co-toxicity coefficient of the compound combination on the fusarium equiseti is more than 120, and the synergistic effect is shown.
Table 8 determination of indoor biological Activity of Fusarium on the layer compounded with osthole and menthone
From table 8, it can be seen that osthole and menthone show excellent antibacterial activity against fusarium. When the compounding ratio of osthole to menthone is 8: 2. 6:4 and 5:5, the compound combination shows a synergistic effect on fusarium.
Table 9 determination of indoor biological Activity of Fusarium oxysporum compounded with osthole
| Medicament name and ratio | EC 50 (mg/L) | ATI | TTI | CTC |
| Osthole | 25.7242 | 100.0000 | -- | -- |
| Menthone | 144.7977 | 17.7656 | -- | -- |
| Osthole 9: menthone 1 | 25.0968 | 102.4999 | 91.7766 | 111.6842 |
| Osthole 8: menthone 2 | 21.8929 | 117.5002 | 83.5531 | 140.6293 |
| Osthole 7: menthone 3 | 27.8099 | 92.5002 | 75.3297 | 122.7938 |
| Osthole 6: menthone 4 | 25.0968 | 102.4999 | 67.1062 | 152.7427 |
| Osthole 5: menthone 5 | 36.7488 | 70.0001 | 58.8828 | 118.8804 |
| Osthole 4: menthone 6 | 44.7377 | 57.5001 | 50.6594 | 113.5033 |
| Osthole 3: menthone 7 | 57.1648 | 45.0001 | 42.4359 | 106.0424 |
| Osthole 2: menthone 8 | 79.1513 | 32.5000 | 34.2125 | 94.9946 |
| Osthole 1: menthone 9 | 85.7473 | 30.0000 | 25.9891 | 115.4333 |
From Table 9, it is clear that osthole and menthone show excellent antibacterial activity against Fusarium oxysporum after being compounded. When the compounding ratio of osthole to menthone is 8-6:2-4, the compound combination shows a synergistic effect on fusarium oxysporum.
TABLE 10 determination of indoor biological Activity of eugenol and menthone Complex to Rhizoctonia cerealis
From table 10, it can be seen that the aligned micronucleus exhibits excellent antibacterial activity after the eugenol and menthone are compounded. When the compounding ratio of eugenol and menthone is 2: at 8, the addition is exhibited; the co-toxicity coefficients of the other compound combinations and the aligned sclerotium rolfsii are all larger than 120, and the synergistic effect is shown.
TABLE 11 determination of indoor biological Activity of Fusarium pseudograminearum by eugenol and menthone complexation
| Medicament name and ratio | EC 50 (mg/L) | ATI | TTI | CTC |
| Eugenol | 37.4238 | 100.0000 | -- | -- |
| Menthone | 80.5613 | 46.4538 | -- | -- |
| Eugenol 9: menthone 1 | 48.1114 | 77.7857 | 94.6454 | 82.1865 |
| Eugenol 8: menthone 2 | 28.0650 | 133.3469 | 89.2908 | 149.3401 |
| Eugenol 7: menthone 3 | 33.6780 | 111.1224 | 83.9361 | 132.3892 |
| Eugenol 6: menthone 4 | 31.5731 | 118.5306 | 78.5815 | 150.8378 |
| Eugenol 5: menthone 5 | 26.5879 | 140.7550 | 73.2269 | 192.2176 |
| Eugenol 4: menthone 6 | 30.6164 | 122.2345 | 67.8723 | 180.0948 |
| Eugenol 3: menthone 7 | 91.4891 | 40.9052 | 62.5177 | 65.4298 |
| Eugenol 2: menthone 8 | 101.0340 | 37.0408 | 57.1631 | 64.7985 |
| Eugenol 1: menthone 9 | 53.1758 | 70.3775 | 51.8084 | 135.8418 |
As can be seen from table 11, eugenol and menthone show excellent antibacterial activity against fusarium pseudograminearum after being compounded. When the mixing ratio of eugenol and menthone is 3:7 and 2:8, exhibit antagonism; when the mixing ratio of eugenol and menthone is 9: at 1, the addition is shown; the co-toxicity coefficient of the other compound combinations on the fusarium pseudograminearum is more than 120, and the synergistic effect is shown.
Table 12 determination of indoor biological Activity of eugenol and menthone compounded against Rhizoctonia solani
| Medicament name and ratio | EC 50 (mg/L) | ATI | TTI | CTC |
| Eugenol | 11.0604 | 100.0000 | -- | -- |
| Menthone | 30.6867 | 36.0430 | -- | -- |
| Eugenol 9: menthone 1 | 10.8629 | 101.8181 | 93.6043 | 108.7750 |
| Eugenol 8: menthone 2 | 6.6122 | 167.2726 | 87.2086 | 191.8075 |
| Eugenol 7: menthone 3 | 8.0043 | 138.1807 | 80.8129 | 170.9885 |
| Eugenol 6: menthone 4 | 7.6040 | 145.4550 | 74.4172 | 195.4589 |
| Eugenol 5: menthone 5 | 9.3588 | 118.1818 | 68.0215 | 173.7419 |
| Eugenol 4: menthone 6 | 6.4034 | 172.7270 | 61.6258 | 280.2836 |
| Eugenol 3: menthone 7 | 15.2081 | 72.7270 | 55.2301 | 131.6801 |
| Eugenol 2: menthone 8 | 14.2505 | 77.6141 | 48.8344 | 158.9334 |
| Eugenol 1: menthone 9 | 11.9848 | 92.2869 | 42.4387 | 217.4594 |
From table 12, it can be seen that eugenol and menthone show excellent antibacterial activity against rhizoctonia solani after being compounded. When the mixing ratio of eugenol and menthone is 9:1, which exhibits additive action; the co-toxicity coefficient of the other compound combinations to the rhizoctonia solani is more than 120, and the synergistic effect is shown.
TABLE 13 determination of indoor biological Activity of Fusarium pseudograminearum by eugenol and menthone complexation
From table 13, it can be seen that eugenol and menthone show excellent antibacterial activity against fusarium pseudograminearum after being compounded. The co-toxicity coefficient of all tested compound combinations to the fusarium pseudograminearum is more than 120, and the synergistic effect is shown.
TABLE 14 determination of indoor biological Activity of Fusarium roseum by eugenol and menthone complexation
| Medicament name and ratio | EC 50 (mg/L) | ATI | TTI | CTC |
| Eugenol | 40.5637 | 100.0000 | -- | -- |
| Menthone | 110.2090 | 36.8062 | -- | -- |
| Eugenol 9: menthone 1 | 13.8510 | 292.8576 | 93.6806 | 312.6128 |
| Eugenol 8: menthone 2 | 14.5613 | 278.5720 | 87.3612 | 318.8737 |
| Eugenol 7: menthone 3 | 11.1351 | 364.2868 | 81.0418 | 449.5046 |
| Eugenol 6: menthone 4 | 17.7466 | 228.5717 | 74.7225 | 305.8942 |
| Eugenol 5: menthone 5 | 9.3097 | 435.7144 | 68.4031 | 636.9806 |
| Eugenol 4: menthone 6 | 12.9066 | 314.2865 | 62.0837 | 506.2303 |
| Eugenol 3: menthone 7 | 13.2068 | 307.1425 | 55.7643 | 550.7869 |
| Eugenol 2: menthone 8 | 19.5825 | 207.1426 | 49.4449 | 418.9360 |
| Eugenol 1: menthone 9 | 63.0991 | 64.2857 | 43.1255 | 149.0664 |
As can be seen from table 14, eugenol and menthone showed excellent bacteriostatic activity against fusarium erythropolis after being compounded. The co-toxicity coefficient of all tested compound combinations on Fusarium rubrum is more than 120, and the synergistic effect is shown.
Table 15 determination of indoor biological Activity of Fusarium equisetum by complexing eugenol with menthone
From table 15, it can be seen that eugenol and menthone show excellent antibacterial activity against fusarium equiseti after being compounded. The co-toxicity coefficient of all tested compound combinations to the fusarium equiseti is more than 120, and the synergistic effect is shown.
TABLE 16 determination of indoor biological Activity of Fusarium species by complexing eugenol with menthone
| Medicament name and ratio | EC 50 (mg/L) | ATI | TTI | CTC |
| Eugenol | 255.7452 | 100.0000 | -- | -- |
| Menthone | 114.0774 | 177.5054 | -- | -- |
| Eugenol 9: menthone 1 | 45.6310 | 560.4637 | 107.7505 | 520.1493 |
| Eugenol 8: menthone 2 | 8.7752 | 2914.4088 | 115.5011 | 2523.2740 |
| Eugenol 7: menthone 3 | 9.5065 | 2690.2141 | 123.2516 | 2182.7006 |
| Eugenol 6: menthone 4 | 11.4077 | 2241.8647 | 131.0022 | 1711.3188 |
| Eugenol 5: menthone 5 | 9.9198 | 2578.1286 | 138.7527 | 1858.0744 |
| Eugenol 4: menthone 6 | 7.1298 | 3586.9898 | 146.5033 | 2448.4028 |
| Eugenol 3: menthone 7 | 114.0774 | 224.1857 | 154.2538 | 145.3356 |
| Eugenol 2: menthone 8 | 38.0258 | 672.5571 | 162.0043 | 415.1476 |
| Eugenol 1: menthone 9 | 12.0081 | 2129.7724 | 169.7549 | 1254.6163 |
As can be seen from table 16, eugenol and menthone showed excellent bacteriostatic activity against fusarium sp. The co-toxicity coefficient of the fusarium on the opposite layer of all tested compound combinations is more than 120, and the synergistic effect is shown, especially when the mass ratio is 8:2, the co-toxicity coefficient reaches 2523.2740, and the synergy is most remarkable.
Table 17 determination of indoor biological Activity of Fusarium oxysporum compounded with eugenol and menthone
| Medicament name and ratio | EC 50 (mg/L) | ATI | TTI | CTC |
| Eugenol | 117.3203 | 100.0000 | -- | -- |
| Menthone | 144.7977 | 81.0236 | -- | -- |
| Eugenol 9: menthone 1 | 93.0471 | 126.0870 | 98.1024 | 128.5260 |
| Eugenol 8: menthone 2 | 41.5133 | 282.6089 | 96.2047 | 293.7579 |
| Eugenol 7: menthone 3 | 84.3240 | 139.1304 | 94.3071 | 147.5291 |
| Eugenol 6: menthone 4 | 87.0441 | 134.7826 | 92.4094 | 145.8537 |
| Eugenol 5: menthone 5 | 67.4592 | 173.9130 | 90.5118 | 192.1440 |
| Eugenol 4: menthone 6 | 56.2160 | 208.6956 | 88.6142 | 235.5104 |
| Eugenol 3: menthone 7 | 93.0471 | 126.0870 | 86.7165 | 145.4014 |
| Eugenol 2: menthone 8 | 91.5469 | 128.1532 | 84.8189 | 151.0905 |
| Eugenol 1: menthone 9 | 112.4320 | 104.3478 | 82.9212 | 125.8396 |
From Table 17, it is clear that eugenol and menthone show excellent antibacterial activity against Fusarium oxysporum after being compounded. The co-toxicity coefficient of all tested compound combinations to fusarium oxysporum is more than 120, and the synergistic effect is shown.
In conclusion, the osthole or eugenol and the menthone are compounded according to a certain mass, so that a synergistic effect is shown on pathogenic bacteria of various plant fungal diseases, the control effect on plant diseases can be improved, data support is provided for effective control of wheat stem rot, wheat scab, peanut root rot, peanut southern blight and corn scab, and the osthole or eugenol and eugenol are of great significance to high quality and high yield of crops such as wheat, peanut and corn.
The foregoing descriptions of specific exemplary embodiments of the present invention are presented for purposes of illustration and description. It is not intended to limit the invention to the precise form disclosed, and obviously many modifications and variations are possible in light of the above teaching. The exemplary embodiments were chosen and described in order to explain the specific principles of the invention and its practical application to thereby enable one skilled in the art to make and utilize the invention in various exemplary embodiments and with various modifications as are suited to the particular use contemplated. It is intended that the scope of the invention be defined by the claims and their equivalents.
Claims (5)
1. The sterilizing composition containing menthone is characterized in that the effective component is compounded by osthole or eugenol and menthone.
2. The menthone-containing bactericidal composition according to claim 1, wherein the mass ratio of osthole to menthone is 1-9:9-1.
3. The menthone-containing bactericidal composition according to claim 1, wherein the mass ratio of eugenol to menthone is 1-9:9-1.
4. Use of a bactericidal composition containing menthone according to any of claims 1-3 for controlling fungal diseases of crops.
5. The use according to claim 4, wherein the crop fungal diseases include wheat stem rot, wheat scab, peanut root rot, peanut southern blight and corn scab.
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