CN1167404C - Cosmetic hair composition providing good resistance properties and comprising polyurethanes - Google Patents

Cosmetic hair composition providing good resistance properties and comprising polyurethanes Download PDF

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Publication number
CN1167404C
CN1167404C CNB008159343A CN00815934A CN1167404C CN 1167404 C CN1167404 C CN 1167404C CN B008159343 A CNB008159343 A CN B008159343A CN 00815934 A CN00815934 A CN 00815934A CN 1167404 C CN1167404 C CN 1167404C
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CN
China
Prior art keywords
compositions
polyurethane
film forming
hair
hair style
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB008159343A
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Chinese (zh)
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CN1391462A (en
Inventor
H・萨曼
H·萨曼
ひ
C·迪皮伊
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LOreal SA
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LOreal SA
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Publication of CN1167404C publication Critical patent/CN1167404C/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87—Polyurethanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00—Drugs for dermatological disorders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Organic Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Dispersion Chemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The invention concerns a cosmetic composition comprising, in a cosmetically acceptable medium, at least a film-forming polyurethane (A) selected such that the material resulting from drying said polymer in an aqueous or alcoholic medium, at room temperature and at a relative humidity rate of 50 %, has a profile defined by at least: (a) an ultimate elongation ( epsilon r) not less than 500 %; (b) an instantaneous recovery (Ri) ranging between 30 and 85 %; (c) a recovery (R300) at 300 seconds ranging between 50 and 100 %; (d) a glass transition temperature less than 45 DEG C.

Description

Good maintenance performance and the hair dressing composition that comprises polyurethane are provided
The objective of the invention is a kind of cosmetic composition, be included in the cosmetics acceptable medium, at least a polyurethane (A) with concrete property.Target of the present invention also is to use said composition to form or keeps the method and the purposes in following hair caring product preparation of hair style: approved product for example as lacquer (lacquer), spray or mousse, is used to obtain the maintenance of hair style or forms hair style.
On cosmetics market in the modal hair caring product that is used for fixing hair, what can mention is with aerosol or with the compositions of pump-effect aerosol spray, as lacquer, spray or mousse, basic solution by film forming polymer, generally be that alcohols or moisture/alcohol solution are formed, film forming polymer is water-soluble or be dissolved in the alcohol, is the mixture with various cosmetic additives.
Yet, these hair preparatons, as be used to keep hair style mousse, gel and, particularly aerosol and spray and lacquer, still can not allow hair style to stand all natural motioies of life every day with satisfactory way, as walking, head movement or fitful wind.
The polymer that is used for the preparation of these hair caring products is anion, both sexes or nonionic film forming polymer, and it causes the formation of film, and film has more or less rigid and fragility essence.
When polymer was too crisp, the extension at break percentage ratio of measuring for film was lower, promptly is generally less than 2%, and can not guarantees that hair style keeps for a long time.
Be head it off, with these polymer and plasticizer blend with obtained more flexible and non-friable coating.Yet these polymer are deformable and plasticity, and promptly after distortion, they only can return to their original form on very little degree.Although improved the maintenance of hair style, because the time variation subsequently of the form of hair style is not so still be gratifying.
Employing comprises film forming polymer, and for example combination of Vinylcaprolactam homopolymer polymer and acrylic polymer obtains more gratifying result aspect maintenance.Yet these compositionss still are not entirely satisfactory, at present some its natural cosmetic resistances of hair loss.In addition, need further to increase crystallized ability.
Therefore carry out cosmetic composition, especially for the maintenance of hair style form and/or the fixed research of hair style, it provides removes prolonged the fixing good cosmetics performance, the particularly good property untied, pliability and beautiful outward appearance.
With unexpected ground, applicant's company finds can address the above problem by using concrete polymer astoundingly.
The objective of the invention is a kind of cosmetic composition, be included in the cosmetics acceptable medium, the film forming polyurethane (A) of at least a selection makes in moisture or alcoholic medium, the material that obtains by dry this polymer at ambient temperature and under 50% relative humidity shows the mechanical performance by following at least a definition:
(a) more than or equal to 500% extension at break (ε b);
(b) instantaneous recovery (R of 30-85% i);
(c) recovery (R in the time of 300 seconds of 50-100% 300);
(d) less than 40 ℃ glass transition temperature.
Another object of the present invention relates to the method that forms or keep hair style, comprises the use of said composition.
Still another one purpose of the present invention relates to this compositions and is used for the purposes that hair dressing composition is made, and is used to keep hair style or hair style is shaped.
Especially by the present invention as the polyurethane (A) of target be by Sanyo with title PA MarinUA 310 and PA Marin UA200 distribution those and sell with title Neorez R987 by Zeneca those.
Polyurethane PA Marin UA200 and Neorez R987 are polyether-polyurethanes, and polyurethane PA Marin UA310 is a carbonic ester polyurethane.
Within meaning of the present invention, term " ambient temperature (22 ± 2 ℃) down and the film by the drying acquisition down of the relative humidity 50% ± 5% " be interpreted as polymer A and alcohol or the water of expression from comprising 6% active material (a.m.), the film of Huo Deing under these conditions, the quantity of regulating mixture is with in the polytetrafluoroethylene matrix, and obtaining thickness is the film of 500 ± 50 μ m.Continue dry weight up to film and no longer change, it is approximately 12 days.In ethanol, test is dissolved in or is partially soluble in alcoholic acid polymer A.In water,, test other polymer with dissolving or dispersive form.
Within meaning of the present invention, by the degree of following test evaluation extension at break and the degree of recovery.
For carrying out extension test, film is cut into orthogonal test sample, length is that 80mm and width are 15mm.
Be used for exsiccant uniform temp and damp condition, promptly under 22 ± 2 ℃ temperature and 50% ± 5% the relative humidity,, testing on the equipment of selling with title Lloyd or on the equipment of selling with title Zwick.
With the speed extension test print of 20mm/min and the distance between jaw is 50 ± 1mm.
Be used for instantaneous recovery (R i) testing procedure as follows:
-with test sample stretching 150% (ε Max), i.e. its initial length (I 0) 1.5 times,
-discharge stress to make simultaneously and return speed and equal rate of extension, promptly 20mm/min after turning back to zero load, measures (ε with the elongation of test sample with percentage ratio i).
Provide instantaneous recovery (R by following formula with % i):
R i＝((ε max-ε i)/ε max)×100
Be to measure the recovery of locating at 300 seconds, the test sample that carried out aforesaid operations was remained on 300 seconds other under the zero stress and its elongation degree is measured as percentage ratio (R 300).
Be given in the recovery of locating in 300 seconds by following formula:
R 300＝((ε max-ε 300)/ε max)×100
MDSC 299 equipment that use is sold by TA Instrument with mode standard, are estimated glass transition temperature.Glass transition temperature is preferably less than 10 ℃.
In compositions of the present invention, the concentration that exists of film forming polyurethane or polyurethane (A) is preferably 0.05-20wt%, and more preferably 0.1-15wt% and more preferably 0.25-10wt% are with respect to the gross weight of compositions.
Film forming polyurethane (A) advantageously is selected from polyurethane, polyether-polyurethane and carbonic ester polyurethane.
The cosmetics acceptable medium preferably is made up of following material: water or one or more are the solvent of cosmetics acceptance more, as alcohol, or the mixture of water and solvent, these solvents are C preferably 1-C 4Alcohol.
In these alcohol, what can mention is ethanol or isopropyl alcohol.Ethanol especially preferably.
Compositions of the present invention also can comprise at least a following additive that is selected from: siloxanes, thickening agent, anion, nonionic, cation or amphoteric surfactant, flavouring agent, antiseptic, opacifier, protein, vitamin, provitamin, anion, nonionic, cation or both sexes on-fixed polymer, mineral, vegetable oil or artificial oil, ceramide, false vitalility be through amide, volatility or non-volatile, linearity or ring-type and modification or unmodified siloxanes and be generally used for being coated to any other additive of the cosmetic composition on the hair.
In fact, those skilled in the art understand careful selection will join inessential chemical compound in the present composition, make the advantageous property that interrelates with present composition inherence not can, or the adverse effect of the adding that can not be imagined substantially.
These compositionss can be packaged into various forms, particularly with pump-effect spray or in aerosol device, for providing with vaporous form or with the coating of the compositions of mousse form.For example obtain spray, lacquer or mousse is used for fixing or during hair conditioning, indicate such packaged form when needs.Compositions of the present invention also can emulsifiable paste, the form of gel, emulsion, washing liquid or wax provides.
When compositions of the present invention is being used to obtain to coat with lacquer or during the aerosol form packing of mousse, it comprises at least a propellant, propellant can be selected from volatile hydrocarbon, as normal butane, propane, iso-butane or pentane, chlorination and/or fluorinated hydrocarbons, and composition thereof.Also can use following material as propellant: carbon dioxide, nitrous oxide, dimethyl ether (DME), nitrogen or compressed air.Also can use the mixture of propellant.The preferred dimethyl ether that uses.
It is 5-90wt% that preferably there is concentration in propellant, with respect to the device in compositions gross weight and more particularly concentration be 10-60%.
Compositions of the present invention can be coated on drying or the wet hair.
By means of following non-limiting example, the present invention is described more completely.
All percentage ratio is percentage by weight, represents active material with respect to the gross weight and the a.m. of compositions.
Embodiment:
The present composition that is prepared as follows.
Compositions 1:
PA Marin UA310 sells 6%a.m. by Sanyo
Ethanol q.s. reaches 100g
Compositions 2:
PA Marin UA200 sells 6% by Sanyo
Ethanol q.s. reaches 100g
Compositions 3:
Neorez sells 6% by Zeneca
Ethanol q.s. reaches 100g
The parameter of the definitions section compound mechanical performance I that sees the following form.
Table I
Compositions Elongation epsilon (with %) Instantaneous recovery R i(with %) Recovery in the time of 300 seconds, R 300(with %) Tg(℃)
1 571 59 66 -39
2 711 74 89 -43
3 905 82 92 -49
Compositions 1 '-3 ' of the present invention is identical with compositions 1-3, and difference is that they comprise 1.5% a.m., rather than uses 6% a.m..
After following operation: these solution are packaged into pump-effect spray and adopt 10 extrusion devices coatings to lock heavy 5 grams washing and exsiccant hair in advance, find these compositionss veritably fixedly hair style with provide hair good coating sense of touch.

Claims (10)

1. cosmetic composition, be included in the cosmetics acceptable medium, the film forming polyurethane A of at least a selection makes in moisture or alcoholic medium, the material that obtains by dry this polymer at ambient temperature and under 50% relative humidity shows the mechanical performance by following at least a definition:
(a) more than or equal to 500% extension at break ε b
(b) the instantaneous recovery R of 30-85% i
(c) the recovery R in the time of 300 seconds of 50-100% 300
(d) less than 40 ℃ glass transition temperature.
2. claim 1 compositions is characterized in that glass transition temperature is less than 10 ℃.
3. each compositions in the aforementioned claim is characterized in that the concentration that exists of film forming or polyurethane A is 0.05-20wt%, with respect to the gross weight of compositions.
4. the compositions of claim 3 is characterized in that the concentration that exists of film forming or polyurethane A is 0.1-15wt%, with respect to the gross weight of compositions.
5. the compositions of claim 4 is characterized in that the concentration that exists of film forming or polyurethane A is 0.25-10wt%, with respect to the gross weight of compositions.
6. aforementioned claim 1 or 2 compositions is characterized in that film forming polyurethane A is selected from polyether-polyurethane and carbonic ester polyurethane.
7. aforementioned claim 1 or 2 compositions, it is characterized in that comprising in addition the conventional cosmetics additive of selection: siloxanes, thickening agent, anion, nonionic, cation or amphoteric surfactant, flavouring agent, antiseptic, opacifier, protein, vitamin, provitamin, anion, nonionic, cation or both sexes on-fixed polymer, mineral, vegetable oil or artificial oil, ceramide, the false vitalility is through amide, volatility or non-volatile, linearity or ring-type and modification or unmodified siloxanes, with any other additive that is generally used for to be coated to the cosmetic composition on the hair.
8. aerosol device comprises the compositions among any one of the aforementioned claim 1-7.
9. a method that keeps hair style or hair style is shaped is characterized in that it comprises the use of any compositions of claim 1-7.
10. any compositions of claim 1-7 is used for the purposes of hair caring product, and this product is used to keep hair style or hair style is shaped.
CNB008159343A 1999-11-19 2000-11-10 Cosmetic hair composition providing good resistance properties and comprising polyurethanes Expired - Fee Related CN1167404C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR99/14590 1999-11-19
FR9914590A FR2801203B1 (en) 1999-11-19 1999-11-19 HAIR COSMETIC COMPOSITION PROVIDING GOOD HOLD PROPERTIES AND COMPRISING POLYURETHANES

Publications (2)

Publication Number Publication Date
CN1391462A CN1391462A (en) 2003-01-15
CN1167404C true CN1167404C (en) 2004-09-22

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CNB008159343A Expired - Fee Related CN1167404C (en) 1999-11-19 2000-11-10 Cosmetic hair composition providing good resistance properties and comprising polyurethanes

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EP (1) EP1233741A1 (en)
JP (1) JP2003527339A (en)
KR (1) KR20020050285A (en)
CN (1) CN1167404C (en)
AU (1) AU1711301A (en)
BR (1) BR0015762A (en)
CA (1) CA2391640A1 (en)
FR (1) FR2801203B1 (en)
MX (1) MXPA02004996A (en)
PL (1) PL356209A1 (en)
RU (1) RU2002116369A (en)
WO (1) WO2001035915A1 (en)

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Publication number Priority date Publication date Assignee Title
FR2831437B1 (en) * 2001-10-26 2004-02-06 Oreal COSMETIC HAIR TREATMENT COMPOSITION COMPRISING A NON-ASSOCIATIVE FIXING POLYURETHANE AND ANIONIC OR NON-IONIC ASSOCIATIVE POLYURETHANE, AND COSMETIC TREATMENT METHOD
US20050209428A1 (en) * 2002-06-19 2005-09-22 Krishnan Tamareselvy Breathable polyurethanes, blends, and articles
FR2872424B1 (en) * 2004-07-01 2006-12-29 Oreal NON-RINSE COSMETIC COMPOSITION COMPRISING ELASTOMERIC FILMOGENIC POLYMERS, ITS USE FOR PACKAGING KERATINIC MATERIALS
FR2872410B1 (en) * 2004-07-01 2006-12-15 Oreal COSMETIC COMPOSITION COMPRISING A TENSOR AND ELASTOMERIC FILMOGENIC POLYMER
FR2872428B1 (en) * 2004-07-01 2006-09-15 Oreal PRESSURIZED CAPILLARY COMPOSITION COMPRISING AT LEAST ONE ELASTOMERIC FILMOGENIC POLYMER
FR2872425B1 (en) * 2004-07-01 2006-12-22 Oreal RINSE COSMETIC COMPOSITION COMPRISING ELASTOMERIC FILMOGENIC POLYMERS, USE THEREOF FOR CONDITIONING KERATINIC MATERIALS
WO2006003027A1 (en) * 2004-07-01 2006-01-12 L'oreal Cosmetic composition comprising a tensioning agent and an elastomeric film-forming polymer

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JPH0441416A (en) * 1990-06-07 1992-02-12 Noevir Co Ltd Cosmetic for hair
JPH0627053B2 (en) * 1990-09-28 1994-04-13 第一工業製薬株式会社 Hair fixative
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FR2751543B1 (en) * 1996-07-24 1998-09-11 Oreal COMPOSITION COMPRISING A POLYMERIC SYSTEM AND USE OF SAID SYSTEM IN PARTICULAR IN COSMETICS
FR2758084B1 (en) * 1997-01-03 1999-02-05 Oreal COSMETIC AND / OR DERMATOLOGICAL COMPOSITION CONTAINING A DISPERSION OF A POLYMERIC SYSTEM AND USE OF THE SYSTEM AS A TENSIONER
JP3667518B2 (en) * 1997-01-14 2005-07-06 三洋化成工業株式会社 Hair treatment agent
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Also Published As

Publication number Publication date
KR20020050285A (en) 2002-06-26
WO2001035915A1 (en) 2001-05-25
FR2801203B1 (en) 2002-12-27
PL356209A1 (en) 2004-06-14
CN1391462A (en) 2003-01-15
MXPA02004996A (en) 2002-09-18
JP2003527339A (en) 2003-09-16
AU1711301A (en) 2001-05-30
CA2391640A1 (en) 2001-05-25
RU2002116369A (en) 2004-01-20
FR2801203A1 (en) 2001-05-25
EP1233741A1 (en) 2002-08-28
BR0015762A (en) 2002-08-06

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