FR2801203A1 - HAIR COSMETIC COMPOSITION PROVIDING GOOD HOLD PROPERTIES AND COMPRISING POLYURETHANES - Google Patents
HAIR COSMETIC COMPOSITION PROVIDING GOOD HOLD PROPERTIES AND COMPRISING POLYURETHANES Download PDFInfo
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- FR2801203A1 FR2801203A1 FR9914590A FR9914590A FR2801203A1 FR 2801203 A1 FR2801203 A1 FR 2801203A1 FR 9914590 A FR9914590 A FR 9914590A FR 9914590 A FR9914590 A FR 9914590A FR 2801203 A1 FR2801203 A1 FR 2801203A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- Cosmetics (AREA)
Abstract
L'invention a pour objet une composition cosmétique comprenant, dans un milieu cosmétiquement acceptable, au moins un polyuréthanne filmogène (A) choisi de telle sorte que le matériau obtenu par séchage de ce polymère en milieu aqueux ou alcoolique, à température ambiante et à un taux d'humidité relative de 50 %, présente un profil mécanique défini par au moins :(a) un taux d'allongement à la rupture (epsilonr ) supérieur ou égal à 500 %,(b) une recouvrance instantanée (R i ) comprise entre 30 et 85 %,(c) une recouvrance (R300 ) à 300 secondes comprise entre 50 et 100 %,(d) une température de transition vitreuse inférieure à 40 degreC.The subject of the invention is a cosmetic composition comprising, in a cosmetically acceptable medium, at least one film-forming polyurethane (A) chosen such that the material obtained by drying this polymer in an aqueous or alcoholic medium, at ambient temperature and at a relative humidity rate of 50%, has a mechanical profile defined by at least: (a) a rate of elongation at break (epsilonr) greater than or equal to 500%, (b) an instant recovery (R i) included between 30 and 85%, (c) a recovery (R300) at 300 seconds between 50 and 100%, (d) a glass transition temperature below 40 degreC.
Description
COMPOSITION COSMETIQUE CAPILLAIRE PROCURANT DE BONNESHAIR COSMETIC COMPOSITION PROVIDING GOOD
PROPRIETES DE TENUE ET COMPRENANT DES POLYURETHANNES HOLD PROPERTIES AND COMPRISING POLYURETHANES
L'invention a pour objet une composition cosmétique comprenant, dans un milieu cosmétiquement acceptable, au moins un polyuréthanne (A) aux caractéristiques particulières. Elle vise également un procédé de mise en forme ou de maintien des cheveux à l'aide de cette composition, ainsi que son utilisation pour la formulation de produits cosmétique capillaire, comme des produits de coiffage tels que les laques, les The subject of the invention is a cosmetic composition comprising, in a cosmetically acceptable medium, at least one polyurethane (A) with particular characteristics. It also relates to a process for shaping or maintaining hair using this composition, as well as its use for the formulation of hair cosmetic products, such as styling products such as hairsprays,
sprays ou les mousses, en vue d'obtenir le maintien ou la mise en forme de la coiffure. sprays or foams, in order to obtain the maintenance or the shaping of the hairstyle.
Parmi les produits capillaires pour la fixation des cheveux les plus répandus sur le marché de la cosmétique, on peut citer les compositions à pulvériser en aérosol ou en flacon pompe tels que les laques, les sprays ou les mousses, essentiellement constituées d'une solution le plus souvent alcoolique ou hydroalcoolique et d'un polymère filmogène Among the hair products for fixing hair that are most widespread on the cosmetic market, there may be mentioned compositions for spraying in an aerosol or in a pump bottle, such as lacquers, sprays or foams, essentially consisting of a more often alcoholic or hydroalcoholic and of a film-forming polymer
soluble dans l'eau ou dans l'alcool, en mélange avec divers adjuvants cosmétiques. soluble in water or alcohol, mixed with various cosmetic adjuvants.
Toutefois, ces formulations capillaires telles que les mousses, gels et surtout les sprays et les laques aérosols destinées à maintenir la forme de la coiffure ne permettent encore pas à la coiffure de résister de manière satisfaisante aux différents mouvements However, these hair formulations such as foams, gels and especially sprays and aerosol lacquers intended to maintain the shape of the hairstyle do not yet allow the hairstyle to resist satisfactorily the various movements.
naturels de la vie comme la marche, les mouvements de tête ou les coups de vent. natural elements of life such as walking, head movements or gusts of wind.
Les polymères utilisés pour la formulation de ces produits capillaires sont des polymères filmogènes anioniques, amphotères ou non ioniques, qui conduisent à la The polymers used for the formulation of these hair products are anionic, amphoteric or nonionic film-forming polymers, which lead to the
formation de films possédant un caractère plus ou moins dur et cassant. formation of films having a more or less hard and brittle character.
Lorsque le polymère est trop cassant, le pourcentage d'allongement à la rupture mesuré sur le film est faible, c'est-à-dire en général inférieur à 2 % et la tenue de la When the polymer is too brittle, the percentage of elongation at break measured on the film is low, that is to say generally less than 2% and the resistance of the
coiffure n'est pas assurée dans le temps. hairstyle is not guaranteed over time.
Pour remédier à ce problème, on a déjà mélangé ces polymères avec des plastifiants et obtenu des revêtements plus souples et non friables. Toutefois, ces films sont déformables et plastiques, c'est-à-dire qu'après déformation, ils ne récupèrent que très peu de leur forme initiale. Si la tenue de la coiffure est améliorée, elle n'est pas encore satisfaisante puisque la forme de la coiffure évolue dans le temps. Des résultats plus satisfaisants en terme de tenue ont été obtenus avec des compositions comprenant une association de polymères filmogènes, tels que par exemple un polymère polyvinylcaprolactame et un polymère acrylique. Toutefois, ces compositions ne donnent encore pas entièrement satisfaction, dans la mesure o les cheveux perdent certaines de leurs propriétés cosmétiques naturelles. En outre, il serait To remedy this problem, these polymers have already been mixed with plasticizers and obtained more flexible and non-friable coatings. However, these films are deformable and plastic, that is to say that after deformation, they recover very little of their initial shape. If the holding of the hairstyle is improved, it is not yet satisfactory since the shape of the hairstyle changes over time. More satisfactory results in terms of resistance have been obtained with compositions comprising a combination of film-forming polymers, such as for example a polyvinylcaprolactam polymer and an acrylic polymer. However, these compositions are not yet entirely satisfactory, insofar as the hair loses some of its natural cosmetic properties. Furthermore, it would
souhaitable d'augmenter encore le pouvoir fixant. desirable to further increase the fixing power.
On recherche donc des compositions cosmétiques, en particulier pour le maintien et/ou la fixation de la coiffure qui procurent à la chevelure, outre une fixation durable, de bonnes propriétés cosmétiques, notamment un bon démêlage, de la douceur et un aspect agréable. De manière surprenante et inattendue, la Demanderesse a découvert qu'il était possible de remédier aux problèmes techniques évoqués ci-dessus, en utilisant des Cosmetic compositions are therefore sought, in particular for maintaining and / or fixing the hairstyle which provides the hair, in addition to lasting fixation, with good cosmetic properties, in particular good disentangling, softness and a pleasant appearance. Surprisingly and unexpectedly, the Applicant has discovered that it is possible to remedy the technical problems mentioned above, by using
polymères particuliers.special polymers.
L'invention a pour objet une composition cosmétique comprenant, dans un milieu cosmétiquement acceptable, au moins un polyuréthanne filmogène (A) choisi de telle sorte que le matériau obtenu par séchage de ce polymère en milieu aqueux ou alcoolique, à température ambiante et à un taux d'humidité relative de 50 %, présente un profil mécanique défini par au moins: (a) un taux d'allongement à la rupture (Sr) supérieur ou égal à 500 %; (b) une recouvrance instantanée (Ri) comprise entre 30 et 85 %, (c) une recouvrance (R300) à 300 secondes comprise entre 50 et 100 %, The subject of the invention is a cosmetic composition comprising, in a cosmetically acceptable medium, at least one film-forming polyurethane (A) chosen such that the material obtained by drying this polymer in an aqueous or alcoholic medium, at ambient temperature and at a relative humidity rate of 50%, has a mechanical profile defined by at least: (a) a rate of elongation at break (Sr) greater than or equal to 500%; (b) an instant recovery (Ri) of between 30 and 85%, (c) a recovery (R300) at 300 seconds of between 50 and 100%,
(d) une température de transition vitreuse inférieure à 40 OC. (d) a glass transition temperature below 40 OC.
Un autre objet de la présente invention concerne un procédé de mise en forme ou Another object of the present invention relates to a method of shaping or
de maintien de la coiffure comprenant la mise en oeuvre de cette composition. for maintaining the hairstyle comprising the use of this composition.
Encore un autre objet de la présente invention concerne l'utilisation de cette composition pour la fabrication de compositions cosmétiques capillaires, en vue d'obtenir Yet another object of the present invention relates to the use of this composition for the manufacture of hair cosmetic compositions, with a view to obtaining
un maintien ou une mise en forme de la coiffure. maintaining or shaping the hairstyle.
Les polyuréthannes (A) particulièrement visés par la présente invention sont ceux distribués par Sanyo sous l'appellation PA Marin UA3 10 et PA Marin UA200, ainsi que The polyurethanes (A) particularly targeted by the present invention are those distributed by Sanyo under the name PA Marin UA3 10 and PA Marin UA200, as well as
le polyuréthanne commercialisé par Zeneca sous l'appellation Neorez R987. the polyurethane marketed by Zeneca under the name Neorez R987.
Les polyuréthannes PA Marin UA200 et Neroez R987 sont des polyuréthannes The polyurethanes PA Marin UA200 and Neroez R987 are polyurethanes
polyéthers, et le polyuréthanne PA Marin UA3 10 est un polyuréthanne carbonate. polyethers, and the polyurethane PA Marin UA3 10 is a carbonate polyurethane.
Au sens de la présente invention, on entend par film obtenu par séchage à température ambiante (22 + 2 C) et à un taux d'humidité relative de 50 % + 5%, le film obtenu dans ces conditions à partir d'un mélange à 6 % de matière active (ma.) de polymère A avec de l'éthanol ou de l'eau, la quantité de mélange étant adaptée pour obtenir dans une matrice en téflon, un film d'épaisseur de 500 5 50 lam. Le séchage est poursuivi jusqu'à ce que le poids du film n'évolue plus, ce qui représente environ 12 jours. Les polymères A solubles ou partiellement solubles dans l'éthanol sont testés dans For the purposes of the present invention, the term film obtained by drying at room temperature (22 + 2 ° C.) and at a relative humidity level of 50% + 5% means the film obtained under these conditions from a mixture at 6% of active material (ai) of polymer A with ethanol or water, the amount of mixture being adapted to obtain, in a Teflon matrix, a film with a thickness of 500 5 50 lam. Drying is continued until the weight of the film no longer changes, which represents approximately 12 days. Polymers A soluble or partially soluble in ethanol are tested in
l'éthanol. Les autres polymères sont testés dans l'eau sous forme soluble ou dispersée. ethanol. The other polymers are tested in water in soluble or dispersed form.
Au sens de la présente invention, le taux d'élongation à la rupture et le taux de Within the meaning of the present invention, the rate of elongation at break and the rate of
recouvrance sont évalués aux moyens des essais décrits ci-après. recovery are evaluated by means of the tests described below.
Pour effectuer les essais de traction, le film est découpé en éprouvettes de forme To carry out the tensile tests, the film is cut into shape test pieces
rectangulaire, de longueur 80 mm et de largeur 15 mm. rectangular, 80 mm long and 15 mm wide.
Les essais sont réalisés sur un appareil commercialisé sous l'appellation Lloyd ou commercialisé sous l'appellation Zwick dans les mêmes conditions de températures et d'humidité que pour le séchage, c'est-à-dire une température de 22 + 2 C et un taux The tests are carried out on a device marketed under the name Lloyd or marketed under the name Zwick under the same temperature and humidity conditions as for drying, that is to say a temperature of 22 + 2 C and a rate
d'humidité relative de 50 + 5 %.relative humidity of 50 + 5%.
Les éprouvettes sont étirées à la vitesse de 20mm/mn et la distance entre les mors estde50 + 1 mm. Pour déterminer la recouvrance instantanée (Ri), on procède comme suit: - on étire l'éprouvette de 150 % (amax) c'est-àdire 1,5 fois sa longueur initiale (Io) - on relâche la contrainte en imposant une vitesse de retour égale à la vitesse de traction, soit 20mm/mn et on mesure l'allongement de l'éprouvette en pourcentage, après The test pieces are drawn at a speed of 20mm / min and the distance between the jaws is 50 + 1 mm. To determine the instantaneous recovery (Ri), we proceed as follows: - we stretch the test piece by 150% (amax) i.e. 1.5 times its initial length (Io) - we release the constraint by imposing a speed return equal to the traction speed, i.e. 20mm / min and the elongation of the test piece is measured in percentage, after
retour à charge nulle (Ei).return to zero charge (Ei).
La recouvrance instantanée en % (Ri) est donnée par la formule ci-après: Ri = ((max- Ei)/ max) X 100 Pour déterminer la recouvrance à 300 secondes, on maintient à contrainte nulle pendant 300 secondes supplémentaires, l'éprouvette ayant subi les opérations The instantaneous recovery in% (Ri) is given by the following formula: Ri = ((max- Ei) / max) X 100 To determine the recovery at 300 seconds, we maintain at zero stress for an additional 300 seconds, the test tube having undergone the operations
précédentes, et on mesure son taux d'allongement en pourcentage (ú300). previous, and we measure its elongation rate in percentage (ú300).
La recouvrance à 300 secondes en % (R30oo) est donnée par la formule ciaprès: R300 = ((max - 8300)/ max) X 100 La température de transition vitreuse est évaluée à l'aide de l'appareil MDSC 299 commercialisé par TA Instrument, en mode standard. De préférence, la température de The recovery at 300 seconds in% (R30oo) is given by the following formula: R300 = ((max - 8300) / max) X 100 The glass transition temperature is evaluated using the MDSC 299 device marketed by TA Instrument, in standard mode. Preferably, the temperature of
transition vitreuse est inférieure à 10 C. glass transition is less than 10 C.
Dans les compositions conformes à l'invention, le ou les polyuréthannes filmogènes (A) sont, de préférence, présents à des concentrations comprises entre 0,05 et % en poids, plus préférentiellement comprises entre 0,1 et 15 % en poids, et plus préférentiellement entre 0,25 et 10 % en poids par rapport au poids total de la composition. De manière avantageuse, le polyuréthanne filmogène (A) est choisi dans le groupe comprenant les polyuréthannes les polyuréthannes polyéthers, les polyuréthannes carbonates. Le milieu cosmétiquement acceptable est, de préférence, constitué par de l'eau ou un ou plusieurs solvants cosmétiquement acceptables tels que des alcools ou des In the compositions in accordance with the invention, the film-forming polyurethane (s) (A) are preferably present at concentrations of between 0.05 and% by weight, more preferably between 0.1 and 15% by weight, and more preferably between 0.25 and 10% by weight relative to the total weight of the composition. Advantageously, the film-forming polyurethane (A) is chosen from the group comprising polyurethanes, polyether polyurethanes, polyurethane carbonates. The cosmetically acceptable medium is preferably constituted by water or one or more cosmetically acceptable solvents such as alcohols or
mélanges eau-solvant(s), ces solvants étant de préférence des alcools en CI-C4. water-solvent (s) mixtures, these solvents preferably being CI-C4 alcohols.
Parmi ces alcools, on peut citer l'éthanol, l'isopropanol. L'éthanol est Among these alcohols, mention may be made of ethanol and isopropanol. Ethanol is
particulièrement préféré.particularly preferred.
La composition de l'invention peut également contenir au moins un additif choisi parmi les silicones, les épaississants, les tensioactifs anioniques, non ioniques, cationiques ou amphotères, les parfums, les conservateurs, les filtres solaires, les protéines, les vitamines, les provitamines, les polymères non fixants anioniques, non ioniques, cationiques ou amphotères, les huiles minérales, végétales ou synthétiques, les céramides, pseudocéramides, les silicones volatiles ou non, linéaires ou cycliques, modifiées ou non, et tout autre additif classiquement utilisé dans les compositions cosmétiques destinées à The composition of the invention can also contain at least one additive chosen from silicones, thickeners, anionic, nonionic, cationic or amphoteric surfactants, perfumes, preservatives, sun filters, proteins, vitamins, provitamins , anionic, nonionic, cationic or amphoteric non-fixing polymers, mineral, vegetable or synthetic oils, ceramides, pseudoceramides, volatile or non-volatile, linear or cyclic silicones, modified or not, and any other additive conventionally used in the compositions cosmetics intended for
être appliquées sur les cheveux.be applied to the hair.
Bien entendu, l'homme de l'art veillera à choisir le ou les éventuels composés à ajouter à la composition selon l'invention de manière telle que les propriétés avantageuses attachées intrinsèquement à la composition conforme à l'invention ne soient Of course, those skilled in the art will take care to choose the optional compound (s) to be added to the composition according to the invention in such a way that the advantageous properties intrinsically attached to the composition according to the invention are not
pas ou substantiellement pas, altérées par l'addition envisagée. not or not substantially, altered by the proposed addition.
Ces compositions peuvent être conditionnées sous diverses formes, notamment dans des flacons pompes ou dans des dispositifs aérosols, afin d'assurer une application de la composition sous forme vaporisée ou sous forme de mousse. De telles formes de conditionnement sont indiquées, par exemple, lorsqu'on souhaite obtenir un spray, une laque ou une mousse pour la fixation ou le traitement des cheveux. Les compositions conformes à l'invention peuvent aussi se présenter sous la forme de crèmes, de gels, These compositions can be packaged in various forms, in particular in pump dispensers or in aerosol devices, in order to ensure application of the composition in vaporized form or in the form of foam. Such forms of packaging are indicated, for example, when it is desired to obtain a spray, a lacquer or a foam for fixing or treating the hair. The compositions in accordance with the invention can also be in the form of creams, gels,
d'émulsions, de lotions ou de cires. emulsions, lotions or waxes.
Lorsque la composition selon l'invention est conditionnée sous forme d'aérosol en vue d'obtenir une laque ou une mousse, elle comprend au moins un agent propulseur qui peut être choisi parmi les hydrocarbures volatils tels que le n-butane, le propane, l'isobutane, le pentane, un hydrocarbure chloré et/ou fluoré et leurs mélanges. On peut également utiliser en tant qu'agent propulseur le gaz carbonique, le protoxyde d'azote, le diméthyléther (DME), l'azote, l'air comprimé. On peut aussi utiliser des mélanges de When the composition according to the invention is packaged in the form of an aerosol in order to obtain a lacquer or a foam, it comprises at least one propellant which can be chosen from volatile hydrocarbons such as n-butane, propane, isobutane, pentane, a chlorinated and / or fluorinated hydrocarbon and their mixtures. Carbon dioxide, nitrous oxide, dimethyl ether (DME), nitrogen, compressed air can also be used as a propellant. It is also possible to use mixtures of
propulseurs. De préférence, on utilise le diméthyl éther. propellants. Preferably, dimethyl ether is used.
Avantageusement, l'agent propulseur est présent à une concentration comprise entre 5 et 90 % en poids par rapport au poids total de la composition dans le dispositif Advantageously, the propellant is present at a concentration of between 5 and 90% by weight relative to the total weight of the composition in the device
aérosol et, plus particulièrement, à une concentration comprise entre 10 et 60 %. aerosol and, more particularly, at a concentration of between 10 and 60%.
Les compositions conformes à l'invention peuvent être appliquées sur des The compositions according to the invention can be applied to
cheveux secs ou humides.dry or damp hair.
L'invention va être plus complètement illustrée à l'aide de l'exemple non limitatif suivant. Tous les pourcentages sont des pourcentages relatifs en poids par rapport au The invention will be more fully illustrated with the aid of the following nonlimiting example. All percentages are relative percentages by weight relative to
poids total de la composition et m.a. signifie matière active. total weight of the composition and m.a. means active ingredient.
EXEMPLE:EXAMPLE:
On réalise les compositions suivantes conformes à l'invention. The following compositions are produced in accordance with the invention.
Composition 1: PA Marin UA 310 commercialisé par Sanyo 6 % m.a Ethanol qsp 100 g Composition 2: PA Marin UA 200 commercialisé par Sanyo 6 % Ethanol qsp 100 g Composition 3 Neorez R987 commercialisé par Zeneca 6 % Ethanol qsp 100 g Les paramètres définissant le profil mécanique des compositions sont rassemblés Composition 1: PA Marin UA 310 marketed by Sanyo 6% ma Ethanol qs 100 g Composition 2: PA Marin UA 200 marketed by Sanyo 6% Ethanol qs 100 g Composition 3 Neorez R987 marketed by Zeneca 6% Ethanol qs 100 g The parameters defining the mechanical profile of the compositions are collected
dans le tableau I ci-après.in Table I below.
Tableau ITable I
Composition Allongement s (en Recouvrance Recouvrance à 300 Tg ( C) %) instantannée Ri (en secondes, R300 (en Composition Elongation s (in Recovery Recovery at 300 Tg (C)%) instantaneous Ri (in seconds, R300 (in
1 571 59 66 -391,571 59 66 -39
2 711 74 89 -432,711 74 89 -43
3 905 82 92 493,905 82 92 49
On utilise des compositions 1' à 3' conformes à l'invention et identiques aux compositions 1 à 3, si ce n'est qu'elles contiennent 1,5 % de m.a. au lieu de 6 %. Après conditionnement de ces solutions dans des flacons pompes et applications de 10 pressions sur des mèches de cheveux naturels de 5 grammes préalablement lavés et séchés, on constate que ces compositions fixent bien la coiffure et donnent aux cheveux Compositions 1 ′ to 3 ′ are used in accordance with the invention and identical to compositions 1 to 3, except that they contain 1.5% of m.a. instead of 6%. After packaging of these solutions in pump bottles and applications of 10 pressures on locks of natural hair of 5 grams previously washed and dried, it is found that these compositions fix the hairstyle well and give the hair
un toucher gainé agréable.a pleasant sheathed touch.
Claims (8)
Priority Applications (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9914590A FR2801203B1 (en) | 1999-11-19 | 1999-11-19 | HAIR COSMETIC COMPOSITION PROVIDING GOOD HOLD PROPERTIES AND COMPRISING POLYURETHANES |
PL00356209A PL356209A1 (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
RU2002116369/15A RU2002116369A (en) | 1999-11-19 | 2000-11-10 | COSMETIC HAIR COMPOSITION GIVING GOOD SAFETY CHARACTERISTICS AND CONTAINING POLYURETHANES |
JP2001537708A JP2003527339A (en) | 1999-11-19 | 2000-11-10 | Hair cosmetic composition providing excellent retention properties and comprising polyurethane |
EP00979714A EP1233741A1 (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
PCT/FR2000/003149 WO2001035915A1 (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
KR1020027006283A KR20020050285A (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
CNB008159343A CN1167404C (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
MXPA02004996A MXPA02004996A (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes. |
CA002391640A CA2391640A1 (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
AU17113/01A AU1711301A (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
BR0015762-7A BR0015762A (en) | 1999-11-19 | 2000-11-10 | Cosmetic composition comprising polyurethanes, aerosol device, styling or styling process and use of a composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9914590A FR2801203B1 (en) | 1999-11-19 | 1999-11-19 | HAIR COSMETIC COMPOSITION PROVIDING GOOD HOLD PROPERTIES AND COMPRISING POLYURETHANES |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2801203A1 true FR2801203A1 (en) | 2001-05-25 |
FR2801203B1 FR2801203B1 (en) | 2002-12-27 |
Family
ID=9552320
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR9914590A Expired - Fee Related FR2801203B1 (en) | 1999-11-19 | 1999-11-19 | HAIR COSMETIC COMPOSITION PROVIDING GOOD HOLD PROPERTIES AND COMPRISING POLYURETHANES |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP1233741A1 (en) |
JP (1) | JP2003527339A (en) |
KR (1) | KR20020050285A (en) |
CN (1) | CN1167404C (en) |
AU (1) | AU1711301A (en) |
BR (1) | BR0015762A (en) |
CA (1) | CA2391640A1 (en) |
FR (1) | FR2801203B1 (en) |
MX (1) | MXPA02004996A (en) |
PL (1) | PL356209A1 (en) |
RU (1) | RU2002116369A (en) |
WO (1) | WO2001035915A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2872424A1 (en) * | 2004-07-01 | 2006-01-06 | Oreal | Leave-in cosmetic composition for conditioning human keratin materials or for maintaining and/or setting hairstyle comprises elastomeric polymer forming film having predetermined elongation at break and instantaneous recovery |
FR2872425A1 (en) * | 2004-07-01 | 2006-01-06 | Oreal | Rinsing cosmetic composition, useful for treatment of keratinous fibers e.g. skin and hair, comprises elastomeric film forming polymer in a medium |
FR2872410A1 (en) * | 2004-07-01 | 2006-01-06 | Oreal | Topical cosmetic composition, useful to treat wrinkles, comprises a tensor agent and an elastomeric film-forming polymer in a medium |
FR2872428A1 (en) * | 2004-07-01 | 2006-01-06 | Oreal | Capillary composition conditioned in an aerosol device, useful in hair styling composition (hairsprays), comprises elastomeric filmforming polymer with fluoride groups and propelling agent in a medium |
WO2006003027A1 (en) * | 2004-07-01 | 2006-01-12 | L'oreal | Cosmetic composition comprising a tensioning agent and an elastomeric film-forming polymer |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2831437B1 (en) * | 2001-10-26 | 2004-02-06 | Oreal | COSMETIC HAIR TREATMENT COMPOSITION COMPRISING A NON-ASSOCIATIVE FIXING POLYURETHANE AND ANIONIC OR NON-IONIC ASSOCIATIVE POLYURETHANE, AND COSMETIC TREATMENT METHOD |
US20050209428A1 (en) * | 2002-06-19 | 2005-09-22 | Krishnan Tamareselvy | Breathable polyurethanes, blends, and articles |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3822238A (en) * | 1972-08-02 | 1974-07-02 | Princeton Polymer Lab | Hydrophilic polyurethane polymers |
US3975350A (en) * | 1972-08-02 | 1976-08-17 | Princeton Polymer Laboratories, Incorporated | Hydrophilic or hydrogel carrier systems such as coatings, body implants and other articles |
US4789720A (en) * | 1988-03-09 | 1988-12-06 | Tyndale Plains-Hunter, Ltd. | Hydrophilic polyurethanes prepared from mixed oxyalkylene glycols |
WO1994013724A1 (en) * | 1992-12-07 | 1994-06-23 | Basf Aktiengesellschaft | Use of cationic polyurethanes and polycarbamides as auxiliary substances in cosmetic and pharmaceutical compositions |
EP0779310A2 (en) * | 1992-07-29 | 1997-06-18 | Basf Aktiengesellschaft | Use of water-soluble or water-dispersible polyurethanes as auxiliary agents in cosmetic and pharmaceutical preparations and polyurethanes containing polylactic acid polyols incorporated by polymerization |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0441416A (en) * | 1990-06-07 | 1992-02-12 | Noevir Co Ltd | Cosmetic for hair |
JPH0627053B2 (en) * | 1990-09-28 | 1994-04-13 | 第一工業製薬株式会社 | Hair fixative |
EP0619111B2 (en) * | 1993-04-06 | 2005-09-14 | National Starch and Chemical Investment Holding Corporation | Use of polyurethanes with carboxylate functionality for hair fixative applications |
FR2740330B1 (en) * | 1995-10-27 | 1997-12-05 | Oreal | COMPOSITION CONSISTING OF A POLYMERIC SYSTEM AND USE OF THE SAID SYSTEM |
FR2751543B1 (en) * | 1996-07-24 | 1998-09-11 | Oreal | COMPOSITION COMPRISING A POLYMERIC SYSTEM AND USE OF SAID SYSTEM IN PARTICULAR IN COSMETICS |
FR2758084B1 (en) * | 1997-01-03 | 1999-02-05 | Oreal | COSMETIC AND / OR DERMATOLOGICAL COMPOSITION CONTAINING A DISPERSION OF A POLYMERIC SYSTEM AND USE OF THE SYSTEM AS A TENSIONER |
JP3667518B2 (en) * | 1997-01-14 | 2005-07-06 | 三洋化成工業株式会社 | Hair treatment agent |
JP3667480B2 (en) * | 1997-01-23 | 2005-07-06 | 三洋化成工業株式会社 | Hair treatment |
FR2771927B1 (en) * | 1997-12-05 | 2001-12-07 | Oreal | COSMETIC OR DERMATOLOGICAL COMPOSITION COMPRISING A FILM-FORMING POLYMER AND AN AQUEOUS SILICONE EMULSION |
FR2775593B1 (en) * | 1998-03-09 | 2002-06-14 | Oreal | FILM-FORMING COMPOSITION COMPRISING AN AQUEOUSLY DISPERSION POLYURETHANE AND A PLASTICIZING AGENT |
FR2788972B1 (en) * | 1999-02-03 | 2001-04-13 | Oreal | HAIR COMPOSITION COMPRISING A WASHING BASE, A CATIONIC POLYMER AND AN ANIONIC POLYURETHANE AND USE THEREOF |
JP4104791B2 (en) * | 1999-08-10 | 2008-06-18 | 日本エヌエスシー株式会社 | Cosmetics |
WO2001013884A2 (en) * | 1999-08-26 | 2001-03-01 | Basf Aktiengesellschaft | Cosmetic and/or pharmaceutical preparations with polymers containing polysiloxanes and the uses thereof |
DE19941365A1 (en) * | 1999-08-31 | 2001-03-01 | Basf Ag | Cosmetic agent based on urethane and / or urea group-containing oligomers |
-
1999
- 1999-11-19 FR FR9914590A patent/FR2801203B1/en not_active Expired - Fee Related
-
2000
- 2000-11-10 KR KR1020027006283A patent/KR20020050285A/en not_active Application Discontinuation
- 2000-11-10 MX MXPA02004996A patent/MXPA02004996A/en unknown
- 2000-11-10 CN CNB008159343A patent/CN1167404C/en not_active Expired - Fee Related
- 2000-11-10 PL PL00356209A patent/PL356209A1/en unknown
- 2000-11-10 CA CA002391640A patent/CA2391640A1/en not_active Abandoned
- 2000-11-10 JP JP2001537708A patent/JP2003527339A/en active Pending
- 2000-11-10 BR BR0015762-7A patent/BR0015762A/en not_active IP Right Cessation
- 2000-11-10 EP EP00979714A patent/EP1233741A1/en not_active Withdrawn
- 2000-11-10 WO PCT/FR2000/003149 patent/WO2001035915A1/en not_active Application Discontinuation
- 2000-11-10 RU RU2002116369/15A patent/RU2002116369A/en unknown
- 2000-11-10 AU AU17113/01A patent/AU1711301A/en not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3822238A (en) * | 1972-08-02 | 1974-07-02 | Princeton Polymer Lab | Hydrophilic polyurethane polymers |
US3975350A (en) * | 1972-08-02 | 1976-08-17 | Princeton Polymer Laboratories, Incorporated | Hydrophilic or hydrogel carrier systems such as coatings, body implants and other articles |
US4789720A (en) * | 1988-03-09 | 1988-12-06 | Tyndale Plains-Hunter, Ltd. | Hydrophilic polyurethanes prepared from mixed oxyalkylene glycols |
EP0779310A2 (en) * | 1992-07-29 | 1997-06-18 | Basf Aktiengesellschaft | Use of water-soluble or water-dispersible polyurethanes as auxiliary agents in cosmetic and pharmaceutical preparations and polyurethanes containing polylactic acid polyols incorporated by polymerization |
WO1994013724A1 (en) * | 1992-12-07 | 1994-06-23 | Basf Aktiengesellschaft | Use of cationic polyurethanes and polycarbamides as auxiliary substances in cosmetic and pharmaceutical compositions |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2872424A1 (en) * | 2004-07-01 | 2006-01-06 | Oreal | Leave-in cosmetic composition for conditioning human keratin materials or for maintaining and/or setting hairstyle comprises elastomeric polymer forming film having predetermined elongation at break and instantaneous recovery |
FR2872425A1 (en) * | 2004-07-01 | 2006-01-06 | Oreal | Rinsing cosmetic composition, useful for treatment of keratinous fibers e.g. skin and hair, comprises elastomeric film forming polymer in a medium |
FR2872410A1 (en) * | 2004-07-01 | 2006-01-06 | Oreal | Topical cosmetic composition, useful to treat wrinkles, comprises a tensor agent and an elastomeric film-forming polymer in a medium |
FR2872428A1 (en) * | 2004-07-01 | 2006-01-06 | Oreal | Capillary composition conditioned in an aerosol device, useful in hair styling composition (hairsprays), comprises elastomeric filmforming polymer with fluoride groups and propelling agent in a medium |
WO2006003027A1 (en) * | 2004-07-01 | 2006-01-12 | L'oreal | Cosmetic composition comprising a tensioning agent and an elastomeric film-forming polymer |
EP1623702A1 (en) * | 2004-07-01 | 2006-02-08 | L'oreal | Cosmetic composition comprising elastomeric film-forming polymers for conditioning the keratinic fibres |
EP1627628A1 (en) * | 2004-07-01 | 2006-02-22 | L'oreal | Pressurised hair composition comprising at least one film-forming elastomeric polymer |
EP1632221A1 (en) * | 2004-07-01 | 2006-03-08 | L'oreal | Cosmetic composition comprising elastomeric film-forming polymers and use thereof for conditioning keratinic fibres |
EP2243467A3 (en) * | 2004-07-01 | 2011-06-22 | L'Oréal | Rinse-out cosmetic composition comprising elastomeric film-forming polymers, use thereof for conditioning keratin materials |
EP2243466A3 (en) * | 2004-07-01 | 2011-06-22 | L'Oréal | Cosmetic composition comprising elastomeric film-forming polymers and use thereof for conditioning keratinic fibres |
Also Published As
Publication number | Publication date |
---|---|
KR20020050285A (en) | 2002-06-26 |
WO2001035915A1 (en) | 2001-05-25 |
FR2801203B1 (en) | 2002-12-27 |
PL356209A1 (en) | 2004-06-14 |
CN1391462A (en) | 2003-01-15 |
MXPA02004996A (en) | 2002-09-18 |
JP2003527339A (en) | 2003-09-16 |
AU1711301A (en) | 2001-05-30 |
CA2391640A1 (en) | 2001-05-25 |
RU2002116369A (en) | 2004-01-20 |
CN1167404C (en) | 2004-09-22 |
EP1233741A1 (en) | 2002-08-28 |
BR0015762A (en) | 2002-08-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |
Effective date: 20130731 |