CN116590362A - High fructose syrup production process - Google Patents

High fructose syrup production process Download PDF

Info

Publication number
CN116590362A
CN116590362A CN202310204433.8A CN202310204433A CN116590362A CN 116590362 A CN116590362 A CN 116590362A CN 202310204433 A CN202310204433 A CN 202310204433A CN 116590362 A CN116590362 A CN 116590362A
Authority
CN
China
Prior art keywords
sugar
production process
temperature
saccharifying
starch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN202310204433.8A
Other languages
Chinese (zh)
Inventor
王宝华
梁年生
何玲
谢良葵
刘仁满
曾令龙
陈曙亮
梁志翔
刘小兵
谢高平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Jindai Technology Development Co ltd
Original Assignee
Hunan Jindai Technology Development Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan Jindai Technology Development Co ltd filed Critical Hunan Jindai Technology Development Co ltd
Priority to CN202310204433.8A priority Critical patent/CN116590362A/en
Publication of CN116590362A publication Critical patent/CN116590362A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C13SUGAR INDUSTRY
    • C13KSACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
    • C13K1/00Glucose; Glucose-containing syrups
    • C13K1/06Glucose; Glucose-containing syrups obtained by saccharification of starch or raw materials containing starch
    • C13K1/08Purifying
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P19/00Preparation of compounds containing saccharide radicals
    • C12P19/02Monosaccharides
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P19/00Preparation of compounds containing saccharide radicals
    • C12P19/14Preparation of compounds containing saccharide radicals produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase, e.g. by cellulase, hemicellulase
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P19/00Preparation of compounds containing saccharide radicals
    • C12P19/24Preparation of compounds containing saccharide radicals produced by the action of an isomerase, e.g. fructose
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • Genetics & Genomics (AREA)
  • Emergency Medicine (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

The application provides a high-temperature liquefying and saccharifying process for the high-temperature liquefying and saccharifying the starch slurry, wherein the temperature of the high-temperature liquefying and saccharifying starch slurry is reduced to 52-65 ℃, and then the saccharified liquid is conveyed to a saccharifying tank, so that light residues and heavy residues in the sugar liquid can be separated independently, and the sugar residues are saccharified again, thereby fully utilizing the sugar residues, avoiding the direct waste of the sugar residues, reducing the discharge amount of the sugar residues, and in addition, the high-pH liquid is neutralized in a decoloration filtering and sodium carbonate solution, thereby controlling the production of colored substances in the production process, ensuring the colorless and transparent requirements of the high-temperature liquefying and saccharifying liquid, and ensuring the quality of the high-temperature liquefying and saccharifying syrup.

Description

High fructose syrup production process
Technical Field
The application relates to the technical field of high fructose syrup, in particular to a high fructose syrup production process.
Background
The fructose syrup is a starch sugar crystal prepared by hydrolysis and isomerization of plant starch, is an important sweetener and mainly consists of fructose and glucose, so the fructose syrup is called as fructose syrup, the sweetness of the fructose syrup is close to that of sucrose with the same concentration, the fructose syrup is one of important food additives in the modern food industry, the fructose syrup is a product which can completely replace the sucrose, and can be widely applied to the food and beverage industry like the sucrose, particularly the application in the beverage industry, the flavor and the taste of the fructose syrup are superior to those of the sucrose, but sugar residues are generated in the production process and are usually discharged directly and are not used, so that the sugar residues cannot be fully utilized, and when the pH value of the feed liquid is low, the color of the feed liquid is deepened, so that the colorless and transparent requirement cannot be accurately ensured.
Disclosure of Invention
The application aims to solve the defects in the prior art and provides a high fructose syrup production process.
In order to achieve the above purpose, the present application adopts the following technical scheme: a high fructose syrup production process comprises the following steps:
s1: mixing starch, namely adding part of water into a mixing barrel and stirring, adding starch in the stirring process, continuously adding water to fully stir the starch into starch slurry, adjusting the pH value of the starch slurry to 3.0-5.2, and liquefying the starch slurry at high temperature;
s2: saccharifying, namely reducing the temperature of the starch slurry after high-temperature liquefaction to 52-65 ℃, then conveying the starch slurry into a saccharifying tank, and adding glucose into the saccharifying tank for saccharification after the feeding is finished, wherein the saccharification time is 16-28 h;
s3: filtering the saccharified liquid, separating light slag and heavy slag in the saccharified liquid by using a filter, and saccharifying the separated sugar slag again by the step II;
s4: treating the sugar solution, putting the sugar solution into a decoloring barrel after cooling all the sugar solution, adding quantitative activated carbon for decoloring and filtering, then conveying the sugar solution into an ion exchanger for ion exchange to remove impurity ions in the sugar solution, and adding isomerase into the saccharified solution after impurity removal to convert part of glucose into fructose through isomerism;
s5: and (3) evaporating and concentrating, namely adding active carbon into the sugar solution obtained in the step (III) to carry out secondary decoloring and filtering, evaporating and concentrating the sugar solution after the secondary decoloring and filtering to obtain the fructose-glucose syrup, and transferring the fructose-glucose syrup into a storage tank for storage.
In order to ensure the correct proportion of starch and water, the application is improved in the S1, wherein the mass ratio of the starch to the water is 1:1 to 1.5, liquefying enzyme or hydrochloric acid can be added to adjust the pH value of the starch slurry.
In order to raise the temperature of the starch slurry, the improvement of the application is that in the step S1, the starch slurry is conveyed into a high-temperature tank, the temperature is controlled to be 100-120 ℃, the time is controlled to be 5-12 minutes, and the liquefied product is filtered.
In order to check the color of the saccharification liquid, the application is improved in the step S2, a saccharification liquid sample is extracted, an iodine solution is used for checking the saccharification end point, and the saccharification liquid is in a reddish brown color and can be added into a sodium carbonate solution for neutralization.
In order to separate the saccharified liquid and the solid residue, the application improves that in the S3, the glucose content in the saccharified liquid obtained by the sugar residue is not lower than 95 percent, and the saccharified liquid and the solid residue are separated by adopting a three-phase centrifuge.
In order to activate the isomerase, the improvement of the application is that in the S4, magnesium sulfate can be added into each liter of sugar solution as an activator of the isomerase in the process of the isomerization conversion.
In order to perform ion exchange for multiple times, the application improves that in the S4, secondary ion exchange impurity removal is performed, and the dry fructose content of the sugar solution is less than 5% after the secondary ion exchange impurity removal.
In order to determine the storage temperature of the fructose-glucose syrup, the application is improved in the step S5, wherein the storage temperature of the fructose-glucose syrup is 25-32 ℃.
Compared with the prior art, the application has the advantages and positive effects that,
in the application, the saccharified feed liquid is filtered, so that light residues and heavy residues in the sugar liquid can be separated independently, and the sugar residues are saccharified again, thereby fully utilizing the sugar residues, avoiding the sugar residues from being directly wasted, reducing the discharge amount of the sugar residues, in addition, the color-changing filtration and the neutralization of the sodium carbonate solution with higher pH value feed liquid control the generation of colored substances in the production process, ensuring the colorless and transparent requirements of the fructose syrup, improving the quality of the fructose syrup and ensuring the product property to be more stable.
Drawings
Fig. 1 is a flow chart of a high fructose syrup production process according to the present application.
Detailed Description
In order that the above objects, features and advantages of the application will be more clearly understood, a further description of the application will be rendered by reference to the appended drawings and examples. It should be noted that, without conflict, the embodiments of the present application and features in the embodiments may be combined with each other.
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present application, however, the present application may be practiced otherwise than as described herein, and therefore the present application is not limited to the specific embodiments of the disclosure that follow.
Example 1
Referring to fig. 1, the present application provides a technical solution: a high fructose syrup production process comprises the following steps:
s1: mixing starch, namely adding part of water into a mixing barrel and stirring, adding starch in the stirring process, continuously adding water to fully stir the starch into starch slurry, adjusting the pH value of the starch slurry to 3.0-5.2, and liquefying the starch slurry at high temperature;
s2: saccharifying, namely reducing the temperature of the starch slurry after high-temperature liquefaction to 52-65 ℃, then conveying the starch slurry into a saccharifying tank, and adding glucose into the saccharifying tank for saccharification after the feeding is finished, wherein the saccharification time is 16-28 h;
s3: filtering the saccharified liquid, separating light slag and heavy slag in the saccharified liquid by using a filter, and saccharifying the separated sugar slag again by the step II;
s4: treating the sugar solution, putting the sugar solution into a decoloring barrel after cooling all the sugar solution, adding quantitative activated carbon for decoloring and filtering, then conveying the sugar solution into an ion exchanger for ion exchange to remove impurity ions in the sugar solution, and adding isomerase into the saccharified solution after impurity removal to convert part of glucose into fructose through isomerism;
s5: and (3) evaporating and concentrating, namely adding active carbon into the sugar solution obtained in the step (III) to carry out secondary decoloring and filtering, evaporating and concentrating the sugar solution after the secondary decoloring and filtering to obtain the fructose-glucose syrup, and transferring the fructose-glucose syrup into a storage tank for storage.
Starch and water according to the mass ratio of 1: 1-1.5, regulating pH value of starch slurry, adding liquefying enzyme or hydrochloric acid, conveying the starch slurry into high-temperature tank, controlling temperature at 100 deg.C and time at 12 min, filtering liquefied product, extracting saccharified liquid sample, checking saccharifying end point with iodine solution, and adding sodium carbonate solution for neutralization.
The glucose content in the saccharified liquid obtained by the sugar residue is not lower than 95%, a three-phase centrifuge is adopted to separate the saccharified liquid and the solid residue, magnesium sulfate can be added into each liter of sugar liquid as an activating agent of isomerase in the process of isomerization conversion, secondary ion exchange impurity removal is carried out, after the secondary ion exchange impurity removal, the dry fructose content of the sugar liquid is lower than 5%, and the storage temperature of the fructose syrup is 25-32 ℃.
Example two
Referring to fig. 1, a high fructose syrup production process includes the following steps:
s1: mixing starch, namely adding part of water into a mixing barrel and stirring, adding starch in the stirring process, continuously adding water to fully stir the starch into starch slurry, adjusting the pH value of the starch slurry to 3.0-5.2, and liquefying the starch slurry at high temperature;
s2: saccharifying, namely reducing the temperature of the starch slurry after high-temperature liquefaction to 52-65 ℃, then conveying the starch slurry into a saccharifying tank, and adding glucose into the saccharifying tank for saccharification after the feeding is finished, wherein the saccharification time is 16-28 h;
s3: filtering the saccharified liquid, separating light slag and heavy slag in the saccharified liquid by using a filter, and saccharifying the separated sugar slag again by the step II;
s4: treating the sugar solution, putting the sugar solution into a decoloring barrel after cooling all the sugar solution, adding quantitative activated carbon for decoloring and filtering, then conveying the sugar solution into an ion exchanger for ion exchange to remove impurity ions in the sugar solution, and adding isomerase into the saccharified solution after impurity removal to convert part of glucose into fructose through isomerism;
s5: and (3) evaporating and concentrating, namely adding active carbon into the sugar solution obtained in the step (III) to carry out secondary decoloring and filtering, evaporating and concentrating the sugar solution after the secondary decoloring and filtering to obtain the fructose-glucose syrup, and transferring the fructose-glucose syrup into a storage tank for storage.
Starch and water according to the mass ratio of 1: 1-1.5, regulating pH value of starch slurry, adding liquefying enzyme or hydrochloric acid, conveying the starch slurry into high-temperature tank, controlling temperature at 120 deg.C, controlling time at 5 min, filtering liquefied product, extracting saccharified liquid sample, checking saccharifying end point with iodine solution, and adding sodium carbonate solution for neutralization.
The glucose content in the saccharified liquid obtained by the sugar residue is not lower than 95%, a three-phase centrifuge is adopted to separate the saccharified liquid and the solid residue, magnesium sulfate can be added into each liter of sugar liquid as an activating agent of isomerase in the process of isomerization conversion, secondary ion exchange impurity removal is carried out, after the secondary ion exchange impurity removal, the dry fructose content of the sugar liquid is lower than 5%, and the storage temperature of the fructose syrup is 25-32 ℃.
In the application, the saccharified feed liquid is filtered, so that light residues and heavy residues in the sugar liquid can be separated independently, and the sugar residues are saccharified again, thereby fully utilizing the sugar residues, avoiding the sugar residues from being directly wasted, reducing the discharge amount of the sugar residues, in addition, the color-changing filtration and the neutralization of the sodium carbonate solution with higher pH value feed liquid control the generation of colored substances in the production process, ensuring the colorless and transparent requirements of the fructose syrup, improving the quality of the fructose syrup and ensuring the product property to be more stable.
The present application is not limited to the above-mentioned embodiments, and any equivalent embodiments which can be changed or modified by the technical content disclosed above can be applied to other fields, but any simple modification, equivalent changes and modification made to the above-mentioned embodiments according to the technical substance of the present application without departing from the technical content of the present application still belong to the protection scope of the technical solution of the present application.

Claims (8)

1. The high fructose syrup production process is characterized by comprising the following steps of:
s1: mixing starch, namely adding part of water into a mixing barrel and stirring, adding starch in the stirring process, continuously adding water to fully stir the starch into starch slurry, adjusting the pH value of the starch slurry to 3.0-5.2, and liquefying the starch slurry at high temperature;
s2: saccharifying, namely reducing the temperature of the starch slurry after high-temperature liquefaction to 52-65 ℃, then conveying the starch slurry into a saccharifying tank, and adding glucose into the saccharifying tank for saccharification after the feeding is finished, wherein the saccharification time is 16-28 h;
s3: filtering the saccharified liquid, separating light slag and heavy slag in the saccharified liquid by using a filter, and saccharifying the separated sugar slag again by the step II;
s4: treating the sugar solution, putting the sugar solution into a decoloring barrel after cooling all the sugar solution, adding quantitative activated carbon for decoloring and filtering, then conveying the sugar solution into an ion exchanger for ion exchange to remove impurity ions in the sugar solution, and adding isomerase into the saccharified solution after impurity removal to convert part of glucose into fructose through isomerism;
s5: and (3) evaporating and concentrating, namely adding active carbon into the sugar solution obtained in the step (III) to carry out secondary decoloring and filtering, evaporating and concentrating the sugar solution after the secondary decoloring and filtering to obtain the fructose-glucose syrup, and transferring the fructose-glucose syrup into a storage tank for storage.
2. The high fructose corn syrup production process of claim 1, wherein: in the S1, the mass ratio of the starch to the water is 1:1 to 1.5, liquefying enzyme or hydrochloric acid can be added to adjust the pH value of the starch slurry.
3. The high fructose corn syrup production process of claim 1, wherein: in the step S1, the starch slurry is conveyed into a high-temperature tank, the temperature is controlled to be 100-120 ℃, the time is controlled to be 5-12 minutes, and the liquefied product is filtered.
4. The high fructose corn syrup production process of claim 1, wherein: in the step S2, a saccharification liquid sample is extracted, the saccharification end point is checked by using iodine solution, and the saccharification liquid is in a reddish brown color and can be added into sodium carbonate solution for neutralization.
5. The high fructose corn syrup production process of claim 1, wherein: in the step S3, the glucose content in the saccharified liquid obtained by the sugar residue is not less than 95%, and a three-phase centrifuge is adopted to separate the saccharified liquid from the solid residue.
6. The high fructose corn syrup production process of claim 1, wherein: in the S4, magnesium sulfate can be added into each liter of sugar solution as an activator of the isomerase in the process of the isomerization conversion.
7. The high fructose corn syrup production process of claim 1, wherein: in the step S4, secondary ion exchange impurity removal is carried out, and after the secondary ion exchange impurity removal, the dry fructose content of the sugar solution is less than 5%.
8. The high fructose corn syrup production process of claim 1, wherein: in the step S5, the storage temperature of the high fructose corn syrup is 25-32 ℃.
CN202310204433.8A 2023-03-02 2023-03-02 High fructose syrup production process Withdrawn CN116590362A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310204433.8A CN116590362A (en) 2023-03-02 2023-03-02 High fructose syrup production process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310204433.8A CN116590362A (en) 2023-03-02 2023-03-02 High fructose syrup production process

Publications (1)

Publication Number Publication Date
CN116590362A true CN116590362A (en) 2023-08-15

Family

ID=87610505

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310204433.8A Withdrawn CN116590362A (en) 2023-03-02 2023-03-02 High fructose syrup production process

Country Status (1)

Country Link
CN (1) CN116590362A (en)

Similar Documents

Publication Publication Date Title
CN107130007A (en) A kind of starch syrup production technology
CN103060402A (en) Production method of starch syrup
CN109371078B (en) Preparation process of high-purity maltose
CN111100892A (en) High fructose corn syrup production process
CN109321553A (en) A kind of industrial complex enzyme detersive of high temperature resistant cane sugar manufacture and its preparation and application
CN103146782B (en) Method for preparing glucose syrup by using rice bran as raw material
CN114410725A (en) Enzymolysis and decoloration method for protein in potato starch wastewater
CN105316374A (en) Sugar making method
CN102676605A (en) Method for producing xylose and L-arabinose using xylose mother liquor
CN112094956A (en) Method for removing glucose by continuous fermentation of xylose mother liquor
CN111850069B (en) Production and preparation process of trehalose
CN100507006C (en) Compound enzyme preparation for sucrose industry
CN106543236A (en) A kind of method of utilization xylose mother liquid crystalline xylose and arabinose
CN101693907A (en) Method for using dried potato flour to prepare potassium citrate
CN113801905A (en) Preparation method of high-temperature-resistant high fructose corn syrup
CN110819671B (en) Maltodextrin and its production process and application
CN109517860A (en) A method of crystal xylose is prepared using xylose mother liquid
CN116590362A (en) High fructose syrup production process
US20120225455A1 (en) Method for Producing Sugar
CN112048496B (en) Complex enzyme preparation special for sugar production and preparation method and application thereof
CN112322680A (en) Maltose preparation process
ZA200210223B (en) Process for preheating colored aqueous sugar solutions to produce a low colored crystallized sugar.
CN107287263A (en) A kind of preparation method of high-purity malt sugar coproduction β limit dextrins
CN112410387A (en) Production method of low-iodine value and ultrahigh malt syrup
CN111118086A (en) Method for preparing starch syrup, phytic acid and protein by co-production of bran and starch syrup

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20230815