CN116354746A - Ceramic clay cosmetic soil for ceramic glaze surface decoration and use method thereof - Google Patents
Ceramic clay cosmetic soil for ceramic glaze surface decoration and use method thereof Download PDFInfo
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- CN116354746A CN116354746A CN202310342035.2A CN202310342035A CN116354746A CN 116354746 A CN116354746 A CN 116354746A CN 202310342035 A CN202310342035 A CN 202310342035A CN 116354746 A CN116354746 A CN 116354746A
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- clay
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- cosmetic soil
- oxide
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- 239000004927 clay Substances 0.000 title claims abstract description 94
- 239000002689 soil Substances 0.000 title claims abstract description 73
- 239000000919 ceramic Substances 0.000 title claims abstract description 70
- 239000002537 cosmetic Substances 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000005034 decoration Methods 0.000 title claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 210000000988 bone and bone Anatomy 0.000 claims abstract description 43
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 36
- 230000005484 gravity Effects 0.000 claims abstract description 19
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 17
- 238000005507 spraying Methods 0.000 claims abstract description 14
- 238000001035 drying Methods 0.000 claims abstract description 7
- 238000005245 sintering Methods 0.000 claims abstract description 7
- 238000000227 grinding Methods 0.000 claims abstract description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 21
- 235000012211 aluminium silicate Nutrition 0.000 claims description 21
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 12
- 238000000498 ball milling Methods 0.000 claims description 12
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 12
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 12
- 229910000702 sendust Inorganic materials 0.000 claims description 12
- 238000007873 sieving Methods 0.000 claims description 12
- 235000012239 silicon dioxide Nutrition 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 6
- 229910052656 albite Inorganic materials 0.000 claims description 6
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000292 calcium oxide Substances 0.000 claims description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 6
- 230000002950 deficient Effects 0.000 claims description 6
- 239000010459 dolomite Substances 0.000 claims description 6
- 229910000514 dolomite Inorganic materials 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 6
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 6
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 6
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 6
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 6
- 239000010453 quartz Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 6
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 235000012222 talc Nutrition 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 3
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 claims description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 5
- 238000005524 ceramic coating Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to a ceramic clay cosmetic soil for ceramic glaze surface decoration and a use method thereof, wherein the ceramic clay cosmetic soil comprises ceramic clay and low-temperature bone enamel according to the weight ratio of 4:1, spraying the ceramic clay cosmetic soil on the outer surface of the finished porcelain, spraying the low-temperature bone porcelain glaze on the outer surface of the ceramic clay cosmetic soil, drying and sintering to obtain the product. The ceramic clay is one of red clay, black clay, purple clay and daily white clay, and the low-temperature bone porcelain glaze is prepared from bone porcelain frit and Suzhou soil according to the weight ratio of 100: 2-5, adding water, ball grinding into water glaze with specific gravity of 1.40 g/ml. The preparation method is simple, the raw materials are abundant in sources and low in cost, and the ceramic can be applied to the surface of finished porcelain, and can be quickly burned by using an electric furnace, so that the ceramic has a wide market prospect.
Description
Technical Field
The invention relates to the technical field of traditional ceramics, in particular to clay cosmetic soil for ceramic glaze surface decoration and a use method thereof.
Background
The cosmetic soil is white or pasty soil with other colors, which is prepared for covering the original rough surface of the green body and the color of the green body in the ceramic production, is also called cover paste or ceramic coating, and the traditional cosmetic soil is mainly applied to the clay body, has a single covering effect and has no related report on the application of the cosmetic soil to the surface of the ceramic glaze for decoration.
Disclosure of Invention
The invention aims to solve the technical problem of providing the ceramic clay cosmetic soil for ceramic glaze surface decoration and the use method thereof, wherein the ceramic clay cosmetic soil has the advantages of simple process, low cost and unique effect.
The technical scheme of the invention is as follows: the clay cosmetic soil for ceramic glaze surface decoration is characterized in that: the ceramic clay and the low-temperature bone enamel are mixed according to the weight ratio of 4:1, mixing to obtain;
the ceramic mud is one of red ceramic mud, black ceramic mud, purple clay mud and daily white mud;
the low-temperature bone porcelain glaze is prepared from bone porcelain frit and Suzhou soil according to the weight ratio of 100: 2-5, adding water, ball grinding into water glaze with specific gravity of 1.40 g/ml.
The red clay comprises the following components in percentage by weight: mixing 25-28% of Longyan kaolin, 28-30% of Jingdezhen wujinning clay, 5-8% of potassium feldspar, 5% of baking soda, 6-9% of alumina, 5-8% of dolomite, 4-6% of quartz, 3-5% of star kaolin and 5-6% of iron black, and mixing: ball: water 1:1.5: ball milling for 24 hours in proportion of 0.6, sieving with a 200-mesh sieve, wherein the screen residue is less than 1%, and adding water and sendust to enable the specific gravity of slurry to be 1.55-1.60 g/ml;
the black clay comprises the following components in percentage by weight: 21-25% of Longyan kaolin, 9-11% of calcined talcum, 6-10% of potassium feldspar, 8% of albite, 12% of iron oxide red, 6% of iron oxide black, 10-14% of bentonite and 15-18% of calcined kaolin, and mixing the materials: ball: water 1:1.5: ball milling for 24 hours in proportion of 0.6, sieving with a 200-mesh sieve, wherein the screen residue is less than 1%, and adding water and sendust to enable the specific gravity of slurry to be 1.55-1.60 g/ml;
the purple clay mud comprises the following components in percentage by weight: 60-65% of Jingdezhen purple clay raw ore, 18-20% of Longyan kaolin, 10-15% of potassium feldspar and 6-8% of calcined talcum, and mixing the materials: ball: water 1:1.5: ball milling for 24 hours in proportion of 0.6, sieving with a 200-mesh sieve, wherein the screen residue is less than 1%, and adding water and sendust to enable the specific gravity of slurry to be 1.55-1.60 g/ml;
the daily white mud comprises the following components in percentage by weight: 50-55% of Longyan kaolin, 3-5% of bentonite, 10-13% of potassium feldspar, 6% of albite, 10-13% of dolomite, 6% of quartz and 8-10% of calcined kaolin, and mixing the materials: ball: water 1:1.5: ball milling for 24 hours in proportion of 0.6, sieving with a 200-mesh sieve, wherein the screen residue is less than 1%, and adding water and sendust to enable the specific gravity of slurry to be 1.55-1.60 g/ml;
the bone china frit comprises the following components in percentage by weight: 45-50% of silicon dioxide, 9-10% of aluminum oxide, 9-10% of calcium oxide, 2.3-3.2% of magnesium oxide, 6.3-7.6% of potassium oxide, 1.2-1.9% of sodium oxide, 13.3-16.2% of zinc oxide, 2-3.4% of barium oxide, 3-3.4% of diboron trioxide and 1.1-1.7% of lithium oxide are mixed, and the mixture is placed in a frit furnace to be melted at 1280-1330 ℃ and then rapidly cooled by water to prepare the frit.
The application method of the ceramic clay cosmetic soil is characterized by comprising the following steps of: spraying the clay cosmetic soil onto the outer surface of the ceramic, spraying the low-temperature bone porcelain glaze onto the outer surface of the clay cosmetic soil, drying and sintering to obtain the product.
The ceramic is a product after being fired at a high temperature of 1260-1330 ℃.
The surface of the product is provided with transparent glaze or single-color glaze.
The product can be a defective product with slight deformation, color dirt, frightened glaze and color loss of the color glaze.
The thickness of the ceramic clay cosmetic soil on the outer surface of the finished ceramic is 0.1-0.3 mm, and the thickness of the low-temperature bone enamel on the outer surface of the ceramic clay cosmetic soil is 0.05-0.1 mm.
And after the ceramic clay cosmetic soil is sprayed on the outer surface of the finished porcelain, continuously heating the ceramic clay cosmetic soil by using a hot air gun at 100 ℃.
The continuous heating time of the hot air gun is 3-5 min.
The firing schedule is as follows: from room temperature to 300 ℃ in kiln for 1 hour, from 300 to 1000 ℃ in kiln for 3 hours, and from 1000 to 1150 ℃ in kiln for 1 hour.
The invention utilizes the continuous heating of the low-temperature bone porcelain glaze and the hot air gun in the ceramic clay cosmetic soil to ensure that the original glaze on the ceramic clay cosmetic soil is preliminarily fixed, and the low-temperature bone porcelain glaze outside the ceramic clay cosmetic soil is melted at high temperature and then mutually fused with the original glaze on the ceramic clay cosmetic soil and the low-temperature bone porcelain glaze in the ceramic clay cosmetic soil, thereby firmly fixing the ceramic clay cosmetic soil on the ceramic clay surface and simultaneously obtaining a smooth, flat and high-brightness glaze on the ceramic clay cosmetic soil surface.
The invention provides clay cosmetic soil capable of being arranged on the surface of a finished porcelain for decoration, which not only can realize a distinctive artistic decoration effect on the surface of the finished porcelain, but also can repair the surface of the porcelain with flaws. The preparation method is simple, the sources of raw materials are rich, the price is low, and the preparation method can be used for the surface of finished porcelain, and can use an electric furnace to burn quickly, so that the preparation method has a wide market prospect.
Detailed Description
In order to further describe the technical means and effects adopted by the invention to achieve the preset aim, the following is a detailed description of specific implementation, method, steps, characteristics and effects of the clay cosmetic soil for ceramic glaze surface decoration and the use method thereof according to the invention, which are described in the following by combining with the preferred embodiment:
example 1
The clay cosmetic soil for ceramic glaze surface decoration is prepared from red clay and low-temperature bone enamel according to the weight ratio of 4:1, mixing to obtain clay cosmetic soil, spraying the clay cosmetic soil onto the outer surface of the finished porcelain, continuously heating the clay cosmetic soil for 3min at 100 ℃ by using a hot air gun, spraying low-temperature bone enamel onto the outer surface of the clay cosmetic soil, and drying and sintering to obtain the product.
The low-temperature bone porcelain glaze is prepared from bone porcelain frit and Suzhou soil according to the weight ratio of 100:2, adding water, ball grinding into water glaze with specific gravity of 1.40 g/ml.
The red clay comprises the following components in percentage by weight: 28% of Longyan kaolin, 29% of Jingdezhen gold clay, 7% of potassium feldspar, 5% of baking soda, 9% of alumina, 7% of dolomite, 5% of quartz, 4% of star kaolin and 6% of iron black, and mixing the materials: ball: water 1:1.5: ball milling for 24 hours according to the proportion of 0.6, sieving with a 200-mesh sieve, wherein the screen residue is less than 1%, and adding water and sendust to enable the specific gravity of slurry to be 1.55g/ml;
the bone china frit comprises the following components in percentage by weight: 46.7% of silicon dioxide, 9% of aluminum oxide, 10% of calcium oxide, 2.3% of magnesium oxide, 7.6% of potassium oxide, 1.2% of sodium oxide, 16% of zinc oxide, 3% of barium oxide, 3% of diboron trioxide and 1.2% of lithium oxide are mixed, and the mixture is placed in a frit furnace to be melted at 1280 ℃ and then rapidly cooled by water to prepare the frit.
The finished porcelain is a product which is fired at the high temperature of 1260 ℃, the surface of the product is provided with transparent glaze, and the product is a slightly deformed defective product.
The thickness of the ceramic clay cosmetic soil on the outer surface of the finished ceramic is 0.1mm, and the thickness of the low-temperature bone enamel on the outer surface of the ceramic clay cosmetic soil is 0.05mm.
The firing schedule is as follows: from room temperature to 300 ℃ in kiln for 1 hour, from 300 to 1000 ℃ in kiln for 3 hours, and from 1000 to 1150 ℃ in kiln for 1 hour.
Example 2
The clay cosmetic soil for ceramic glaze surface decoration uses black clay and low-temperature bone enamel according to the weight ratio of 4:1, mixing to obtain clay cosmetic soil, spraying the clay cosmetic soil onto the outer surface of the finished porcelain, continuously heating the clay cosmetic soil for 4min at 100 ℃ by using a hot air gun, spraying low-temperature bone enamel onto the outer surface of the clay cosmetic soil, and drying and sintering to obtain the product.
The low-temperature bone porcelain glaze is prepared from bone porcelain frit and Suzhou soil according to the weight ratio of 100:3, adding water to ball mill into water glaze with specific gravity of 1.40 g/ml.
The black clay comprises the following components in percentage by weight: 24% of Longyan kaolin, 10% of calcined talcum, 8% of potassium feldspar, 8% of albite, 12% of iron oxide red, 6% of iron oxide black, 14% of bentonite and 18% of calcined kaolin, and mixing the materials: ball: water 1:1.5: ball milling for 24 hours according to the proportion of 0.6, sieving with a 200-mesh sieve, wherein the screen residue is less than 1%, and adding water and sendust to enable the specific gravity of slurry to be 1.55g/ml;
the bone china frit comprises the following components in percentage by weight: 47.3% of silicon dioxide, 10% of aluminum oxide, 10% of calcium oxide, 3% of magnesium oxide, 7% of potassium oxide, 1.5% of sodium oxide, 14% of zinc oxide, 3% of barium oxide, 3% of diboron trioxide and 1.2% of lithium oxide are mixed, and the mixture is placed in a frit furnace to be melted at 1290 ℃ and then rapidly cooled by water to prepare the frit.
The finished porcelain is a product which is baked at a high temperature of 1280 ℃, the surface of the product is provided with a single-color glaze, and the product is a dirty defective product.
The thickness of the ceramic clay cosmetic soil on the outer surface of the finished ceramic is 0.15mm, and the thickness of the low-temperature bone enamel on the outer surface of the ceramic clay cosmetic soil is 0.07mm.
The firing schedule is as follows: from room temperature to 300 ℃ in kiln for 1 hour, from 300 to 1000 ℃ in kiln for 3 hours, and from 1000 to 1150 ℃ in kiln for 1 hour.
Example 3
The clay cosmetic soil for decorating the surface of the ceramic glaze uses purple clay and low-temperature bone enamel according to the weight ratio of 4:1, mixing to obtain clay cosmetic soil, spraying the clay cosmetic soil onto the outer surface of the finished porcelain, continuously heating the clay cosmetic soil for 5min at 100 ℃ by using a hot air gun, spraying low-temperature bone enamel onto the outer surface of the clay cosmetic soil, and drying and sintering to obtain the product.
The low-temperature bone porcelain glaze is prepared from bone porcelain frit and Suzhou soil according to the weight ratio of 100:4, adding water, ball grinding into water glaze with specific gravity of 1.40 g/ml.
The purple clay mud comprises the following components in percentage by weight: 62% of Jingdezhen purple clay raw ore, 20% of Longyan kaolin, 11% of potassium feldspar and 7% of calcined talcum, and mixing the ingredients, and then: ball: water 1:1.5: ball milling for 24 hours according to the proportion of 0.6, sieving with a 200-mesh sieve, wherein the screen residue is less than 1%, and adding water and sendust to enable the specific gravity of slurry to be 1.60g/ml;
the bone china frit comprises the following components in percentage by weight: 49.4% of silicon dioxide, 9% of aluminum oxide, 9% of calcium oxide, 2.3% of magnesium oxide, 7.6% of potassium oxide, 1.6% of sodium oxide, 15% of zinc oxide, 2% of barium oxide, 3% of diboron trioxide and 1.1% of lithium oxide are mixed, and the mixture is placed in a frit furnace to be melted at 1310 ℃ and then rapidly cooled by water to prepare the frit.
The finished porcelain is a product which is fired at a high temperature of 1300 ℃, transparent glaze is arranged on the surface of the product, and the product is a defective product of the surprise glaze.
The thickness of the ceramic clay cosmetic soil on the outer surface of the finished ceramic is 0.2mm, and the thickness of the low-temperature bone enamel on the outer surface of the ceramic clay cosmetic soil is 0.1mm.
The firing schedule is as follows: from room temperature to 300 ℃ in kiln for 1 hour, from 300 to 1000 ℃ in kiln for 3 hours, and from 1000 to 1150 ℃ in kiln for 1 hour.
Example 4
The clay cosmetic soil for ceramic glaze surface decoration uses daily white clay and low-temperature bone enamel according to the weight ratio of 4:1, mixing to obtain clay cosmetic soil, spraying the clay cosmetic soil onto the outer surface of the finished porcelain, continuously heating the clay cosmetic soil for 3.5min at 100 ℃ by using a hot air gun, spraying low-temperature bone enamel onto the outer surface of the clay cosmetic soil, and drying and sintering to obtain the product.
The low-temperature bone porcelain glaze is prepared from bone porcelain frit and Suzhou soil according to the weight ratio of 100:5, adding water, and ball grinding into water glaze with specific gravity of 1.40 g/ml.
The daily white mud comprises the following components in percentage by weight: 53% of Longyan kaolin, 4% of bentonite, 13% of potassium feldspar, 6% of albite, 10% of dolomite, 6% of quartz and 8% of calcined kaolin are mixed in a proportioning mode, and then: ball: water 1:1.5: ball milling for 24 hr in proportion of 0.6, sieving with 200 mesh sieve with screen residue below 1%, and adding water and sendust to make mud specific gravity 1.60g/ml.
The bone china frit comprises the following components in percentage by weight: 48% of silicon dioxide, 9.5% of aluminum oxide, 9.5% of calcium oxide, 3% of magnesium oxide, 7% of potassium oxide, 1.5% of sodium oxide, 13.9% of zinc oxide, 3% of barium oxide, 3% of diboron trioxide and 1.6% of lithium oxide are mixed, and the mixture is placed in a frit furnace to be melted at 1330 ℃ and then rapidly cooled by water to prepare the frit.
The finished porcelain is a product which is fired at a high temperature of 1320 ℃, the surface of the product is provided with a single-color glaze, and the product is a defective product with the color lost by the color glaze.
The thickness of the ceramic clay cosmetic soil on the outer surface of the finished ceramic is 0.3mm, and the thickness of the low-temperature bone enamel on the outer surface of the ceramic clay cosmetic soil is 0.1mm.
The firing schedule is as follows: from room temperature to 300 ℃ in kiln for 1 hour, from 300 to 1000 ℃ in kiln for 3 hours, and from 1000 to 1150 ℃ in kiln for 1 hour.
Claims (10)
1. The clay cosmetic soil for ceramic glaze surface decoration is characterized in that: the ceramic clay and the low-temperature bone enamel are mixed according to the weight ratio of 4:1, mixing to obtain;
the ceramic mud is one of red ceramic mud, black ceramic mud, purple clay mud and daily white mud;
the low-temperature bone porcelain glaze is prepared from bone porcelain frit and Suzhou soil according to the weight ratio of 100: 2-5, adding water, ball grinding into water glaze with specific gravity of 1.40 g/ml.
2. The clay cosmetic soil according to claim 1, wherein: the red clay comprises the following components in percentage by weight: mixing 25-28% of Longyan kaolin, 28-30% of Jingdezhen wujinning clay, 5-8% of potassium feldspar, 5% of baking soda, 6-9% of alumina, 5-8% of dolomite, 4-6% of quartz, 3-5% of star kaolin and 5-6% of iron black, and mixing: ball: water 1:1.5: ball milling for 24 hours in proportion of 0.6, sieving with a 200-mesh sieve, wherein the screen residue is less than 1%, and adding water and sendust to enable the specific gravity of slurry to be 1.55-1.60 g/ml;
the black clay comprises the following components in percentage by weight: 21-25% of Longyan kaolin, 9-11% of calcined talcum, 6-10% of potassium feldspar, 8% of albite, 12% of iron oxide red, 6% of iron oxide black, 10-14% of bentonite and 15-18% of calcined kaolin, and mixing the materials: ball: water 1:1.5: ball milling for 24 hours in proportion of 0.6, sieving with a 200-mesh sieve, wherein the screen residue is less than 1%, and adding water and sendust to enable the specific gravity of slurry to be 1.55-1.60 g/ml;
the purple clay mud comprises the following components in percentage by weight: 60-65% of Jingdezhen purple clay raw ore, 18-20% of Longyan kaolin, 10-15% of potassium feldspar and 6-8% of calcined talcum, and mixing the materials: ball: water 1:1.5: ball milling for 24 hours in proportion of 0.6, sieving with a 200-mesh sieve, wherein the screen residue is less than 1%, and adding water and sendust to enable the specific gravity of slurry to be 1.55-1.60 g/ml;
the daily white mud comprises the following components in percentage by weight: 50-55% of Longyan kaolin, 3-5% of bentonite, 10-13% of potassium feldspar, 6% of albite, 10-13% of dolomite, 6% of quartz and 8-10% of calcined kaolin, and mixing the materials: ball: water 1:1.5: ball milling for 24 hours in proportion of 0.6, sieving with a 200-mesh sieve, wherein the screen residue is less than 1%, and adding water and sendust to enable the specific gravity of slurry to be 1.55-1.60 g/ml;
the bone china frit comprises the following components in percentage by weight: 45-50% of silicon dioxide, 9-10% of aluminum oxide, 9-10% of calcium oxide, 2.3-3.2% of magnesium oxide, 6.3-7.6% of potassium oxide, 1.2-1.9% of sodium oxide, 13.3-16.2% of zinc oxide, 2-3.4% of barium oxide, 3-3.4% of diboron trioxide and 1.1-1.7% of lithium oxide are mixed, and the mixture is placed in a frit furnace to be melted at 1280-1330 ℃ and then rapidly cooled by water to prepare the frit.
3. The method for using the clay cosmetic according to claim 1, wherein: spraying the clay cosmetic soil onto the outer surface of the ceramic, spraying the low-temperature bone porcelain glaze onto the outer surface of the clay cosmetic soil, drying and sintering to obtain the product.
4. A method of use according to claim 3, wherein: the ceramic is a product after being fired at a high temperature of 1260-1330 ℃.
5. The method of use according to claim 4, wherein: the surface of the product is provided with transparent glaze or single-color glaze.
6. The method of use according to claim 4, wherein: the product can be a defective product with slight deformation, color dirt, frightened glaze and color loss of the color glaze.
7. A method of use according to claim 3, wherein: the thickness of the ceramic clay cosmetic soil on the outer surface of the finished ceramic is 0.1-0.3 mm, and the thickness of the low-temperature bone enamel on the outer surface of the ceramic clay cosmetic soil is 0.05-0.1 mm.
8. A method of use according to claim 3, wherein: and after the ceramic clay cosmetic soil is sprayed on the outer surface of the finished porcelain, continuously heating the ceramic clay cosmetic soil by using a hot air gun at 100 ℃.
9. The method of use according to claim 8, wherein: the continuous heating time of the hot air gun is 3-5 min.
10. A method of use according to claim 3, wherein: the firing schedule is as follows: from room temperature to 300 ℃ in kiln for 1 hour, from 300 to 1000 ℃ in kiln for 3 hours, and from 1000 to 1150 ℃ in kiln for 1 hour.
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