CN116349681A - 一种杀真菌组合物及其应用 - Google Patents
一种杀真菌组合物及其应用 Download PDFInfo
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- CN116349681A CN116349681A CN202111612842.9A CN202111612842A CN116349681A CN 116349681 A CN116349681 A CN 116349681A CN 202111612842 A CN202111612842 A CN 202111612842A CN 116349681 A CN116349681 A CN 116349681A
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- Prior art keywords
- alkyl
- methyl
- acid
- general formula
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- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 230000000855 fungicidal effect Effects 0.000 title claims abstract description 20
- 150000001875 compounds Chemical class 0.000 claims abstract description 33
- 150000003839 salts Chemical class 0.000 claims abstract description 28
- 201000010099 disease Diseases 0.000 claims abstract description 18
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 18
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 13
- 239000003899 bactericide agent Substances 0.000 claims abstract description 13
- 239000003112 inhibitor Substances 0.000 claims abstract description 11
- 241000233679 Peronosporaceae Species 0.000 claims abstract description 9
- 206010039509 Scab Diseases 0.000 claims abstract description 8
- 241000221785 Erysiphales Species 0.000 claims abstract description 6
- 208000031888 Mycoses Diseases 0.000 claims abstract description 6
- 240000007594 Oryza sativa Species 0.000 claims abstract description 6
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 6
- 235000009566 rice Nutrition 0.000 claims abstract description 6
- 241000233647 Phytophthora nicotianae var. parasitica Species 0.000 claims abstract description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 241001530056 Athelia rolfsii Species 0.000 claims abstract description 3
- 241000395107 Cladosporium cucumerinum Species 0.000 claims abstract description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 43
- 229910052739 hydrogen Inorganic materials 0.000 claims description 29
- 239000001257 hydrogen Substances 0.000 claims description 29
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 28
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 20
- 239000000460 chlorine Substances 0.000 claims description 20
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 16
- 229910052736 halogen Inorganic materials 0.000 claims description 16
- 150000002367 halogens Chemical class 0.000 claims description 16
- 150000002431 hydrogen Chemical class 0.000 claims description 16
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 claims description 15
- 239000005745 Captan Substances 0.000 claims description 15
- 229940117949 captan Drugs 0.000 claims description 15
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 14
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 14
- 229910052801 chlorine Inorganic materials 0.000 claims description 14
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 14
- 229910052731 fluorine Inorganic materials 0.000 claims description 14
- 239000011737 fluorine Substances 0.000 claims description 14
- 239000005747 Chlorothalonil Substances 0.000 claims description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 13
- 239000005802 Mancozeb Substances 0.000 claims description 13
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 claims description 13
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 12
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 12
- 229910052794 bromium Inorganic materials 0.000 claims description 12
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 12
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 12
- -1 nitro, hydroxy Chemical group 0.000 claims description 11
- 125000006274 (C1-C3)alkoxy group Chemical group 0.000 claims description 10
- 241000196324 Embryophyta Species 0.000 claims description 10
- 239000005823 Propineb Substances 0.000 claims description 10
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 claims description 10
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims description 8
- 239000005789 Folpet Substances 0.000 claims description 8
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 8
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- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 8
- HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 claims description 8
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 8
- 239000005809 Metiram Substances 0.000 claims description 7
- 229920000257 metiram Polymers 0.000 claims description 7
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 6
- KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 6
- 235000019253 formic acid Nutrition 0.000 claims description 6
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 claims description 6
- 229920000940 maneb Polymers 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 5
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 4
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 claims description 4
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 claims description 4
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims description 4
- 239000005711 Benzoic acid Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 claims description 4
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 4
- 235000010233 benzoic acid Nutrition 0.000 claims description 4
- JJKSAEHNIHMQKQ-UHFFFAOYSA-N copper;quinoline Chemical compound [Cu].N1=CC=CC2=CC=CC=C21 JJKSAEHNIHMQKQ-UHFFFAOYSA-N 0.000 claims description 4
- 229940098779 methanesulfonic acid Drugs 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 235000006408 oxalic acid Nutrition 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims description 3
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- 125000004455 (C1-C3) alkylthio group Chemical group 0.000 claims description 2
- FXVNBZGTAWLLNE-UHFFFAOYSA-N 1,3-thiazole;zinc Chemical compound [Zn].C1=CSC=N1 FXVNBZGTAWLLNE-UHFFFAOYSA-N 0.000 claims description 2
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- 239000005821 Propamocarb Substances 0.000 claims description 2
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- 229910052802 copper Inorganic materials 0.000 claims description 2
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- IPENDKRRWFURRE-UHFFFAOYSA-N fluoroimide Chemical compound C1=CC(F)=CC=C1N1C(=O)C(Cl)=C(Cl)C1=O IPENDKRRWFURRE-UHFFFAOYSA-N 0.000 claims description 2
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- 125000002541 furyl group Chemical group 0.000 claims description 2
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- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 2
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/32—Cyclic imides of polybasic carboxylic acids or thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/34—Nitriles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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Abstract
本发明属于农用杀菌剂领域,具体的说是一种杀真菌组合物及其应用。组合物为A、B两种活性组分,活性组分A和活性组分B之间的重量比为1:99‑99:1;活性组分A选自如下通式I所示的化合物及其盐,活性组分B选自多位点抑制剂类杀菌剂。本发明杀真菌组合物特别适合防治多种植物病原性真菌病害,如白粉病、锈病、黑星病、轮纹病、缩叶病、流胶病、黑胫病、稻瘟病、叶霉病、灰霉病、赤霉病、霜霉病、疫病、炭疽病、疮痂病、褐腐病、叶斑病、纹枯病或立枯病。
Description
技术领域
本发明属于农用杀菌剂领域,具体涉及一种含取代三唑啉酮醚类化合物与多位点抑制剂类杀菌剂的杀真菌组合物及其应用。
背景技术
专利CN102336744B公开了一种含取代三唑啉酮醚类化合物及其用途,其中报道了如下通式I所示的化合物对多种真菌病害具有良好的活性。
多位点抑制剂类杀菌剂是一类保护性杀菌剂,可以与真菌细胞中的多种酶发生作用,从而破坏酶的活性,使真菌细胞的新陈代谢受破坏而失去生命力。该类杀菌剂杀菌范围广、不易产生抗性,但活性低,用量大。
发明内容
本发明目的在于提供一种含取代三唑啉酮醚类化合物与多位点抑制剂类杀菌剂的杀真菌增效组合物及其应用。
为实现上述目的,本发明采用技术方案如下:
一种杀真菌组合物,组合物为A、B两种活性组分,活性组分A和活性组分B之间的重量比为1:99-99:1;
活性组分A为通式I所示的化合物或其盐。
式中:
Q选自如下所示的Q1或Q2:
W选自O;
R1选自甲基;
当Q选自Q1时:R2选自氢、卤素、氰基、硝基、CH2CN、C1-C6烷基、卤代C1-C6烷基或C3-C6环烷基,R3选自氢、C1-C6烷基或卤代C1-C6烷基;
当Q选自Q2时:R2选自卤素、C1-C6烷基、卤代C1-C6烷基或C3-C6环烷基,R3选自C1-C6烷基或卤代C1-C6烷基;
R4选自卤素、氰基、硝基、羟基、C1-C4烷基、卤代C1-C3烷基、C1-C3烷氧基、卤代C1-C3烷氧基、C1-C3烷硫基、C1-C3烷基磺酰基,未取代的或被1-5个独立选自以下基团取代的苯基或苯氧基;以下基团为氯、溴、氟、硝基、氰基、三氟甲基、C1-C3烷基、C1-C3烷氧基或卤代C1-C3烷氧基;n=0-5;
R5、R6可相同或不同,分别选自氢、卤素、硝基、氰基、C1-C6烷基、卤代C1-C6烷基、C1-C6烷氧基、卤代C1-C6烷氧基、C1-C6烷硫基、C1-C6烷磺酰基,未取代的或被1-5个独立选自以下基团取代的苯基、吡啶基、呋喃基、噻吩基或噻唑基,以下基团为卤素、氰基、硝基、CO2(C1-C4烷基)、C1-C6烷基、卤代C1-C6烷基、C1-C6烷氧基、卤代C1-C6烷氧基、C1-C6烷硫基或C1-C6烷基磺酰基;
Y选自卤素、OR7、SR7、SOR7、SO2R7或NHR7;其中,R7选自氢或C1-C4烷基;
活性组分B选自多位点抑制剂类杀菌剂的代森锰锌B1、克菌丹B2、百菌清B3、代森联B4、丙森锌B5、硫黄B6、苯氟磺胺B7、甲苯氟磺胺B8、氟酰亚胺B9、磺菌威B10、敌菌丹B11、灭菌丹B12、喹啉铜B13、噻唑锌B14、噻菌铜B15中的一种或几种。
优选,所述活性组分A选自通式I所示的化合物或其盐。
通式中:
Q选自如下所示的Q1或Q2:
W选自O;
R1选自甲基;
当Q选自Q1时:R2选自氢、氟、氯、溴或C1-C4烷基,R3选自氢或C1-C6烷基;
当Q选自Q2时:R2选自C1-C4烷基,R3选自C1-C6烷基;
R4选自卤素、氰基、硝基、C1-C4烷基、卤代C1-C3烷基、C1-C3烷氧基、卤代C1-C3烷氧基或C1-C3烷基磺酰基;
n=0-3;
R5、R6可相同或不同,分别选自氢、氯、溴、氟、硝基、氰基、C1-C4烷基、卤代C1-C4烷基、C1-C4烷氧基或卤代C1-C4烷氧基;
Y选自Cl、OR7或SR7;其中,R7选自C1-C4烷基;
所述通式I所示的化合物的盐为通式化合物与盐酸、硫酸、磷酸、甲酸、乙酸、三氟乙酸、草酸、甲磺酸、对甲苯磺酸、苯甲酸、邻苯二甲酸、马来酸、富马酸形成的盐;
活性组分B选自多位点抑制剂类杀菌剂的代森锰锌B1、克菌丹B2、百菌清B3、代森联B4、丙森锌B5、硫黄B6、苯氟磺胺B7、磺菌威B10、灭菌丹B12、喹啉铜B13中的一种或几种;
A、B两种活性组分之间的重量比为1:50-50:1。
进一步优选,所述活性组分A选自通式I所示的化合物或其盐。
通式中:
Q选自Q1或Q2;
W选自O;
R1选自甲基;
当Q选自Q1时:R2选自氢或甲基,R3选自氢、甲基或乙基;
当Q选自Q2时:R2选自甲基,R3选自甲基;
R4选自卤素、氰基、硝基、甲基、乙基、异丙基、叔丁基、CF3、CH3O或CF3O;
n=0-3;
R5、R6可相同或不同,分别选自氢、氯、溴、氟或C1-C4烷基;
Y选自Cl、CH3O或CH3S;
所述通式I所示的化合物的盐为通式化合物与盐酸、硫酸、磷酸、甲酸、乙酸、三氟乙酸、草酸、甲磺酸、对甲苯磺酸、苯甲酸形成的盐;
活性组分B选自多位点抑制剂类杀菌剂的代森锰锌B1、克菌丹B2、百菌清B3、代森联B4、丙森锌B5、硫黄B6、灭菌丹B12、喹啉铜B13中的一种或几种;
所述A、B两种活性组分之间的重量比为1:20-20:1。
再进一步的优选,所述活性组分A选自通式I所示的化合物或其盐。
通式中:
Q选自Q2;
W选自O;
R1选自甲基;
R2选自甲基,R3选自甲基;
R4选自氟、氯、溴、氰基、硝基、甲基、乙基、异丙基、叔丁基、CF3、CH3O或CF3O;
n=0、1、2或3;
R5、R6可相同或不同,分别选自氢、氯、溴、氟、甲基、乙基或异丙基;
Y选自Cl或CH3O;
所述通式I所示的化合物的盐为通式化合物与盐酸、硫酸、磷酸、甲酸、乙酸形成的盐;
活性组分B选自多位点抑制剂类杀菌剂的代森锰锌B1、克菌丹B2、百菌清B3、代森联B4、丙森锌B5、灭菌丹B12、喹啉铜B13中的一种或几种;
所述A、B两种活性组分之间的重量比为1:10-10:1。
更进一步的优选,所述活性组分A选自通式I所示的化合物或其盐。
通式中:
Q选自Q2;W选自O;R1选自甲基;R2选自甲基,R3选自甲基;n=0;R5、R6均选自氢;Y选自CH3O);
或Q选自Q2;W选自O;R1选自甲基;R2选自甲基,R3选自甲基;R4选自氟;n=1;R5、R6均选自氢;Y选自CH3O);
或Q选自Q2;W选自O;R1选自甲基;R2选自甲基,R3选自甲基;R4选自氯;n=1;R5、R6均选自氢;Y选自CH3O);
所述通式I所示的化合物的盐为通式化合物与盐酸、硫酸形成的盐;
活性组分B选自多位点抑制剂类杀菌剂的代森锰锌B1、克菌丹B2、百菌清B3、代森联B4、丙森锌B5中的一种或几种;
所述A、B两种活性组分之间的重量比为1:4-4:1。
一种杀真菌组合物的应用,所述杀真菌组合物用于制备防治植物病原性真菌病害的药物。
所述植物病原性真菌病害为植物白粉病、锈病、黑星病、轮纹病、缩叶病、流胶病、黑胫病、稻瘟病、叶霉病、灰霉病、赤霉病、霜霉病、疫病、炭疽病、疮痂病、褐腐病、叶斑病、纹枯病或立枯病。
根据农作物病害的发生程度,在农作物种植区域内,本发明组合物的使用浓度为5-500mg/L(有效成分含量,下同),优选50-200mg/L。
本发明组合物中活性组分A和至少一种活性组分B按照本发明提供的合适配比,预先配制好或在使用现场配制或将两组分单独依次使用。
本发明组合物适合用于树木(苹果、橡胶、梨、柑橘、桃、山楂、板栗、花椒、枸杞、芒果、木瓜等)、藤蔓植物(葡萄)、瓜菜类(番茄、茄子、辣椒、黄瓜、甜瓜、冬瓜、西瓜、南瓜、苦瓜、丝瓜、佛手瓜、葫芦、西葫芦、胡萝卜、莴苣、甘蓝、马铃薯)、豆类(大豆、豌豆、芸豆、豇豆)、禾谷类(小麦、大麦、燕麦、水稻、玉米)、葱蒜类(葱、蒜、洋葱)、棉花、烟草、花生、花卉、植物和草坪的真菌病害防治,以及种子处理、水果保鲜等应用。
本发明杀真菌组合物特别适合防治下列植物病害:番茄早疫病、番茄晚疫病、番茄叶霉病、马铃薯晚疫病、瓜类霜霉病、蔬菜霜霉病、葡萄霜霉病、蔬菜灰霉病、蔬菜炭疽病、果树炭疽病、花生叶斑病、水稻纹枯病、桃褐腐病、桃缩叶病、桃流胶病、果树疮痂病、麦类赤霉病、麦类白粉病、瓜类白粉病、果树白粉病、梨黑星病、苹果轮纹病、烟草黑胫病、大田作物锈病、大田作物叶斑病、水稻纹枯病、小麦纹枯病、蔬菜立枯病。
本发明所具有优点
本发明按不同比例将活性组分A和活性组分B组合,有效的提高病害防治效果。采用专业公式科学计算后,组合物试验配比的观察效力值均远高于计算效力值,协同增效作用十分明显,同时采用特定组分特定比例下的组合能够延缓病原菌抗药性的产生,降低用量,延长药剂的使用寿命。
具体实施方式
本发明组合物对有害真菌的协同增效作用可通过下列实施例作进一步说明,但本发明绝非仅限于此。其中所述的活性组分即为本发明的杀真菌组合物中的活性组份A与多位点抑制剂类杀菌剂B;且活性组份A的制备参见专利CN102336744B中的记载。
测试方法及评价方法如下:
待测活性样品分别为活性组分A、活性组分B、活性组分A与活性组分B的组合物。
活性组分A为活性组分A1或活性组分A2;其中,A2为化合物A1与硫酸形成的盐。
活性组分A为通式I所示的化合物A1(以此化合物为例):
通式中:
Q选自如下所示的Q2:
W选自O;R1选自甲基;R2选自甲基,R3选自甲基;n=0;R5、R6均选自氢;Y选自CH3O;即为化合物A1。
活性组分B为代森锰锌B1、克菌丹B2、百菌清B3、代森联B4。
待测组合物为活性组分A1分别与代森锰锌B1、克菌丹B2、百菌清B3、代森联B4组成的组合物;或活性组分A2与代森锰锌B1、克菌丹B2、百菌清B3、代森联B4组成的组合物。
具体方式:
将上述各活性组分或组合物用丙酮或水溶解(丙酮量与喷液量的体积比等于或小于0.05),用含有0.1%吐温80的水稀释,配制成所需浓度待测液,另按设定比例配制组合物的待测液。在作物喷雾机上,将待测液喷施于病害寄主植物上,24小时后进行病害接种。依据病害特点,将需要控温保湿培养的病害植物接种后放在气候室中培养,待病害完成侵染后,移入温室培养。待对照充分发病后,测定病原物侵染作物叶面积百分数,使用Abbot公式计算,即得到观察效力(W):
W=(1-α/β)×100
式中:
α:处理作物的真菌侵染百分数;
β:未处理(空白对照)作物的真菌侵染百分数;
效力为“0”表示处理作物的侵染水平与未处理对照作物的侵染水平相同;效力为“100”表示处理作物未受侵染。
组合物的预期效力(计算效力)使用Colby公式(见R.S.Colby,杂草(Weeds),1967,15,20-22)确定,并与观察效力比较。
E=X+Y–XY/100
式中:
E:使用浓度为a和b的活性组分A和B的组合物时的预期效力(以下各表中的计算效力),以未处理对照的%表示;
X:使用浓度为a时的活性组分A的效力,以未处理对照的%表示;
Y:使用浓度为b时的活性组分B的效力,以未处理对照的%表示。
当观察效力值大于计算效力值时,表示组合物具有增效作用;当观察效力值等于计算效力值时,表示组合物为加合作用;当观察效力值小于计算效力值时,表示组合物为拮抗作用。
实施例1防治黄瓜霜霉病试验
将品种为“新泰密刺”的盆栽两叶期黄瓜苗用各活性组分或组合物的水溶液(有效成分浓度如下表所述)喷雾处理,24小时后接种黄瓜霜霉病孢子囊悬浮液,并在气候室中培养,待病害完成侵染后,移入温室培养,7天后测定叶片上病菌侵染的发展程度。
各单独活性组分及本发明组合物防治黄瓜霜霉病的活性数据见表1和表2。
结果显示,组合物的观察效力值均大于计算效力值,组合物在试验配比范围内表现为增效作用。
表1单独活性组分的活性
表2本发明组合物的活性
实施例2防治番茄晚疫病试验
将品种为“L-402”的盆栽番茄幼苗用各活性组分或组合物的水溶液(有效成分浓度如下表所述)喷雾处理,24小时后,接种晚疫病孢子囊悬浮液,并在气候室中培养,待病害完成侵染后,移入温室培养,5天后测定叶片上病菌侵染的发展程度。
各单独活性组分及本发明组合物防治番茄晚疫病的活性数据见表3和表4。
结果显示,组合物的观察效力值均大于计算效力值,组合物在试验配比范围内表现为增效作用。
表3单独活性组分的活性
表4本发明组合物的活性
实施例3防治黄瓜炭疽病试验
将品种为“新泰密刺”的盆栽两叶期黄瓜苗用各活性组分或组合物的水溶液(浓度如下表所述)喷雾处理,24小时后,将黄瓜炭疽病孢子悬浮液接种在黄瓜叶片上,并在气候室中培养,待病害完成侵染后,移入温室培养,6天后测定叶片上病菌侵染的发展程度。
各单独的活性组分及本发明组合物防治黄瓜炭疽病的活性数据见表5和表6。
结果显示,组合物的观察效力值均大于计算效力值,组合物在试验配比范围内表现为增效作用。
表5单独活性组分的活性
表6本发明组合物的活性
实施例4防治花生叶斑病试验
将品种为“白沙1016”的盆栽两叶期花生幼苗用各活性组分或组合物的水溶液(浓度如下表所述)喷雾处理,24小时后,将叶斑病孢子悬浮液接种在花生叶片上,并在气候室中培养,待病害完成侵染后,移入温室培养,5天后测定叶片上病菌侵染的发展程度。
各单独的活性组分及本发明组合物花生叶斑病的活性数据见表7和表8。
结果显示,组合物的观察效力值均大于计算效力值,组合物在试验配比范围内表现为增效作用。
表7单独活性组分的活性
表8本发明组合物的活性
Claims (7)
1.一种杀真菌组合物,其特征在于:组合物为A、B两种活性组分,活性组分A和活性组分B之间的重量比为1:99-99:1;
活性组分A为通式I所示的化合物或其盐;
通式中:
Q选自如下所示的Q1或Q2:
W选自O;
R1选自甲基;
当Q选自Q1时:R2选自氢、卤素、氰基、硝基、CH2CN、C1-C6烷基、卤代C1-C6烷基或C3-C6环烷基,R3选自氢、C1-C6烷基或卤代C1-C6烷基;
当Q选自Q2时:R2选自卤素、C1-C6烷基、卤代C1-C6烷基或C3-C6环烷基,R3选自C1-C6烷基或卤代C1-C6烷基;
R4选自卤素、氰基、硝基、羟基、C1-C4烷基、卤代C1-C3烷基、C1-C3烷氧基、卤代C1-C3烷氧基、C1-C3烷硫基、C1-C3烷基磺酰基,未取代的或被1-5个独立选自以下基团取代的苯基或苯氧基;以下基团为氯、溴、氟、硝基、氰基、三氟甲基、C1-C3烷基、C1-C3烷氧基或卤代C1-C3烷氧基;n=0-5;
R5、R6可相同或不同,分别选自氢、卤素、硝基、氰基、C1-C6烷基、卤代C1-C6烷基、C1-C6烷氧基、卤代C1-C6烷氧基、C1-C6烷硫基、C1-C6烷磺酰基,未取代的或被1-5个独立选自以下基团取代的苯基、吡啶基、呋喃基、噻吩基或噻唑基,以下基团为卤素、氰基、硝基、CO2(C1-C4烷基)、C1-C6烷基、卤代C1-C6烷基、C1-C6烷氧基、卤代C1-C6烷氧基、C1-C6烷硫基或C1-C6烷基磺酰基;
Y选自卤素、OR7、SR7、SOR7、SO2R7或NHR7;其中,R7选自氢或C1-C4烷基;
活性组分B选自多位点抑制剂类杀菌剂的代森锰锌B1、克菌丹B2、百菌清B3、代森联B4、丙森锌B5、硫黄B6、苯氟磺胺B7、甲苯氟磺胺B8、氟酰亚胺B9、磺菌威B10、敌菌丹B11、灭菌丹B12、喹啉铜B13、噻唑锌B14、噻菌铜B15中的一种或几种。
2.根据权利要求1所述的杀真菌组合物,其特征在于:所述活性组分A选自通式I所示的化合物或其盐;
通式中:
Q选自如下所示的Q1或Q2:
W选自O;
R1选自甲基;
当Q选自Q1时:R2选自氢、氟、氯、溴或C1-C4烷基,R3选自氢或C1-C6烷基;
当Q选自Q2时:R2选自C1-C4烷基,R3选自C1-C6烷基;
R4选自卤素、氰基、硝基、C1-C4烷基、卤代C1-C3烷基、C1-C3烷氧基、卤代C1-C3烷氧基或C1-C3烷基磺酰基;
n=0-3;
R5、R6可相同或不同,分别选自氢、氯、溴、氟、硝基、氰基、C1-C4烷基、卤代C1-C4烷基、C1-C4烷氧基或卤代C1-C4烷氧基;
Y选自Cl、OR7或SR7;其中,R7选自C1-C4烷基;
所述通式I所示的化合物的盐为通式化合物与盐酸、硫酸、磷酸、甲酸、乙酸、三氟乙酸、草酸、甲磺酸、对甲苯磺酸、苯甲酸、邻苯二甲酸、马来酸、富马酸形成的盐;
活性组分B选自多位点抑制剂类杀菌剂的代森锰锌B1、克菌丹B2、百菌清B3、代森联B4、丙森锌B5、硫黄B6、苯氟磺胺B7、磺菌威B10、灭菌丹B12、喹啉铜B13中的一种或几种;
A、B两种活性组分之间的重量比为1:50-50:1。
3.根据权利要求2所述的杀真菌组合物,其特征在于:所述活性组分A选自通式I所示的化合物或其盐;
通式中:
Q选自Q1或Q2;
W选自O;
R1选自甲基;
当Q选自Q1时:R2选自氢或甲基,R3选自氢、甲基或乙基;
当Q选自Q2时:R2选自甲基,R3选自甲基;
R4选自卤素、氰基、硝基、甲基、乙基、异丙基、叔丁基、CF3、CH3O或CF3O;
n=0-3;
R5、R6可相同或不同,分别选自氢、氯、溴、氟或C1-C4烷基;
Y选自Cl、CH3O或CH3S;
所述通式I所示的化合物的盐为通式化合物与盐酸、硫酸、磷酸、甲酸、乙酸、三氟乙酸、草酸、甲磺酸、对甲苯磺酸、苯甲酸形成的盐;
活性组分B选自多位点抑制剂类杀菌剂的代森锰锌B1、克菌丹B2、百菌清B3、代森联B4、丙森锌B5、硫黄B6、灭菌丹B12、喹啉铜B13中的一种或几种;
所述A、B两种活性组分之间的重量比为1:20-20:1。
4.根据权利要求2所述的杀真菌组合物,其特征在于:所述活性组分A选自通式I所示的化合物或其盐;
通式中:
Q选自Q2;
W选自O;
R1选自甲基;
R2选自甲基,R3选自甲基;
R4选自氟、氯、溴、氰基、硝基、甲基、乙基、异丙基、叔丁基、CF3、CH3O或CF3O;
n=0、1、2或3;
R5、R6可相同或不同,分别选自氢、氯、溴、氟、甲基、乙基或异丙基;
Y选自Cl或CH3O;
所述通式I所示的化合物的盐为通式化合物与盐酸、硫酸、磷酸、甲酸、乙酸形成的盐;
活性组分B选自多位点抑制剂类杀菌剂的代森锰锌B1、克菌丹B2、百菌清B3、代森联B4、丙森锌B5、灭菌丹B12、喹啉铜B13中的一种或几种;
所述A、B两种活性组分之间的重量比为1:10-10:1。
5.根据权利要求4所述的杀真菌组合物,其特征在于:所述活性组分A选自通式I所示的化合物或其盐;
通式中:
Q选自Q2;W选自O;R1选自甲基;R2选自甲基,R3选自甲基;n=0;R5、R6均选自氢;Y选自CH3O);
或Q选自Q2;W选自O;R1选自甲基;R2选自甲基,R3选自甲基;R4选自氟;n=1;R5、R6均选自氢;Y选自CH3O);
或Q选自Q2;W选自O;R1选自甲基;R2选自甲基,R3选自甲基;R4选自氯;n=1;R5、R6均选自氢;Y选自CH3O);
所述通式I所示的化合物的盐为通式化合物与盐酸、硫酸形成的盐;
活性组分B选自多位点抑制剂类杀菌剂的代森锰锌B1、克菌丹B2、百菌清B3、代森联B4、丙森锌B5中的一种或几种;
所述A、B两种活性组分之间的重量比为1:4-4:1。
6.一种杀真菌组合物的应用,其特征在于:所述杀真菌组合物用于制备防治植物病原性真菌病害的药物。
7.根据权利要求6所述的杀真菌组合物的应用,其特征在于:所述植物病原性真菌病害为植物白粉病、锈病、黑星病、轮纹病、缩叶病、流胶病、黑胫病、稻瘟病、叶霉病、灰霉病、赤霉病、霜霉病、疫病、炭疽病、疮痂病、褐腐病、叶斑病、纹枯病或立枯病。
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2773155A1 (fr) * | 1997-12-29 | 1999-07-02 | Rhone Poulenc Agrochimie | Nouveaux composes fongicides |
CN102336742A (zh) * | 2010-07-20 | 2012-02-01 | 中国中化股份有限公司 | 一种取代三唑啉酮醚类化合物及其应用 |
CN102336743A (zh) * | 2010-07-20 | 2012-02-01 | 中国中化股份有限公司 | 取代三唑啉酮醚类化合物及其应用 |
CN102336744A (zh) * | 2010-07-20 | 2012-02-01 | 中国中化股份有限公司 | 取代三唑啉酮醚类化合物及其作为杀菌、杀虫、杀螨剂的用途 |
CN111316987A (zh) * | 2018-12-14 | 2020-06-23 | 沈阳中化农药化工研发有限公司 | 一种杀真菌组合物及其应用 |
CN112868660A (zh) * | 2019-11-29 | 2021-06-01 | 沈阳中化农药化工研发有限公司 | 一种杀真菌组合物及其应用 |
-
2021
- 2021-12-27 CN CN202111612842.9A patent/CN116349681A/zh active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2773155A1 (fr) * | 1997-12-29 | 1999-07-02 | Rhone Poulenc Agrochimie | Nouveaux composes fongicides |
CN102336742A (zh) * | 2010-07-20 | 2012-02-01 | 中国中化股份有限公司 | 一种取代三唑啉酮醚类化合物及其应用 |
CN102336743A (zh) * | 2010-07-20 | 2012-02-01 | 中国中化股份有限公司 | 取代三唑啉酮醚类化合物及其应用 |
CN102336744A (zh) * | 2010-07-20 | 2012-02-01 | 中国中化股份有限公司 | 取代三唑啉酮醚类化合物及其作为杀菌、杀虫、杀螨剂的用途 |
CN111316987A (zh) * | 2018-12-14 | 2020-06-23 | 沈阳中化农药化工研发有限公司 | 一种杀真菌组合物及其应用 |
CN112868660A (zh) * | 2019-11-29 | 2021-06-01 | 沈阳中化农药化工研发有限公司 | 一种杀真菌组合物及其应用 |
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