CN116254707A - Production process of fireproof yarn material for zipper strips - Google Patents
Production process of fireproof yarn material for zipper strips Download PDFInfo
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- CN116254707A CN116254707A CN202310283304.2A CN202310283304A CN116254707A CN 116254707 A CN116254707 A CN 116254707A CN 202310283304 A CN202310283304 A CN 202310283304A CN 116254707 A CN116254707 A CN 116254707A
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- Prior art keywords
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- fireproof
- yarn material
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- 239000000463 material Substances 0.000 title claims abstract description 45
- 238000004519 manufacturing process Methods 0.000 title abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 239000002994 raw material Substances 0.000 claims abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000853 adhesive Substances 0.000 claims abstract description 14
- 230000001070 adhesive effect Effects 0.000 claims abstract description 14
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 13
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 13
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 13
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 239000004744 fabric Substances 0.000 claims abstract description 13
- 239000011248 coating agent Substances 0.000 claims abstract description 12
- 238000000576 coating method Methods 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims abstract description 11
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 9
- 229920002334 Spandex Polymers 0.000 claims abstract description 9
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 9
- 239000011324 bead Substances 0.000 claims abstract description 9
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 9
- 229920003086 cellulose ether Polymers 0.000 claims abstract description 9
- 239000003822 epoxy resin Substances 0.000 claims abstract description 9
- 239000011521 glass Substances 0.000 claims abstract description 9
- 239000010439 graphite Substances 0.000 claims abstract description 9
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 9
- 239000004816 latex Substances 0.000 claims abstract description 9
- 229920000126 latex Polymers 0.000 claims abstract description 9
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 9
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 9
- 239000003607 modifier Substances 0.000 claims abstract description 9
- 239000012188 paraffin wax Substances 0.000 claims abstract description 9
- 239000000049 pigment Substances 0.000 claims abstract description 9
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 9
- 239000004759 spandex Substances 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- 239000010455 vermiculite Substances 0.000 claims abstract description 9
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 9
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000013530 defoamer Substances 0.000 claims abstract description 5
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010408 film Substances 0.000 claims abstract description 5
- 229920000728 polyester Polymers 0.000 claims abstract description 5
- 229940083037 simethicone Drugs 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 20
- 229920002472 Starch Polymers 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 16
- 239000008107 starch Substances 0.000 claims description 16
- 235000019698 starch Nutrition 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 14
- 238000009987 spinning Methods 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 12
- 239000004088 foaming agent Substances 0.000 claims description 12
- 238000000227 grinding Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 238000004132 cross linking Methods 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 238000009941 weaving Methods 0.000 claims description 5
- 239000005714 Chitosan hydrochloride Substances 0.000 claims description 4
- 229920000742 Cotton Polymers 0.000 claims description 4
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920004933 Terylene® Polymers 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000002518 antifoaming agent Substances 0.000 claims description 4
- 238000000498 ball milling Methods 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- 239000003431 cross linking reagent Substances 0.000 claims description 4
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 230000002708 enhancing effect Effects 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 229920005610 lignin Polymers 0.000 claims description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical group OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004014 plasticizer Substances 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 238000004321 preservation Methods 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 4
- 230000001105 regulatory effect Effects 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 4
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 claims description 4
- 239000011345 viscous material Substances 0.000 claims description 4
- 238000005491 wire drawing Methods 0.000 claims description 4
- 210000002268 wool Anatomy 0.000 claims description 4
- 239000004753 textile Substances 0.000 abstract description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003063 flame retardant Substances 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000010292 electrical insulation Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 description 8
- 239000002585 base Substances 0.000 description 6
- 238000009940 knitting Methods 0.000 description 3
- 238000007639 printing Methods 0.000 description 2
- 239000011165 3D composite Substances 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000009984 hand spinning Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0018—Collagen fibres or collagen on fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0034—Polyamide fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/04—Vegetal fibres
- D06N2201/042—Cellulose fibres, e.g. cotton
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/10—Conjugate fibres, e.g. core-sheath, side-by-side
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/10—Particulate form, e.g. powder, granule
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/143—Inert, i.e. inert to chemical degradation, corrosion resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1642—Hardnes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1664—Releasability
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a production process of a fireproof yarn material for zipper strips, and relates to the technical field of textile production. The fireproof yarn material for the zipper cloth strip is prepared from the following raw materials: polyester, spandex, dispersing agent, modifier, glass beads, pigment, ammonium polyphosphate, curing agent, expanded graphite, epoxy resin, cellulose ether, expanded vermiculite, magnesium hydroxide, sodium silicate, simethicone, isobutyl ketone, chlorinated paraffin, butyl latex, thickener, defoamer, antibacterial agent, water, film former and acid donor. The production process of the fireproof yarn material for the zipper strips has the advantages of good environmental protection performance, high flame retardant efficiency and the like, can continuously play a fireproof protection role, increases the flame retardant effect of the coating, prolongs the effective fireproof time of the coating, has strong adhesive force, and the cured product has excellent chemical corrosion resistance, heat resistance, acid and alkali resistance and good electrical insulation, and improves the fireproof capability of yarn raw materials.
Description
Technical Field
The invention relates to the technical field of textile production, in particular to a production process of a fireproof yarn material for zipper strips.
Background
The textile is a generic term of spinning and weaving, but with the continuous development and perfection of a textile knowledge system and a subject system, especially after the production of technologies such as non-woven textile materials and three-dimensional composite weaving, not only traditional hand spinning and weaving, but also non-woven textile technologies, modern three-dimensional weaving technologies, modern electrostatic nanoweb technologies and other clothing, industrial and decorative textiles are adopted, so that modern textile refers to a multi-scale structure processing technology of fibers or fiber assemblies, ancient textile and printing and dyeing technologies in China have very long history, old people have already been in the original society period to adapt to the change of climate, have already been informed of local materials, use natural resources as raw materials for spinning and printing, and manufacture simple hand textile tools, but in the existing technology, the raw materials of yarns have poor fireproof capability due to the problems of materials and production technologies.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a production process of a fireproof yarn material for zipper strips, which solves the problems in the prior art. In order to achieve the above purpose, the invention is realized by the following technical scheme: the fireproof yarn material for the zipper strips is prepared from the following raw materials:
polyester, spandex, dispersing agent, modifier, glass beads, pigment, ammonium polyphosphate, curing agent, expanded graphite, epoxy resin, cellulose ether, expanded vermiculite, magnesium hydroxide, sodium silicate, simethicone, isobutyl ketone, chlorinated paraffin, butyl latex, thickener, defoamer, antibacterial agent, water, film former, acid donor, carbon donor, foaming agent, synergist, catalyst and charring agent, and the preparation method comprises the following steps:
step one, preparing a solution for enhancing the strength of spinning wires, placing the spinning wires in the solution for soaking for 15-20 minutes, then fishing out, airing in a room with the temperature of 30-40 ℃ for 4-8 hours, and carrying out standby after airing;
step two, uniformly mixing terylene, spandex, a dispersing agent and a modifying agent, and carrying out wiredrawing extrusion by a screw machine at the temperature of 250-300 ℃ to prepare the fabric;
step three, mixing glass beads, pigment, ammonium polyphosphate, curing agent, expanded graphite and solvent, uniformly stirring, and grinding at a high speed until the fineness is 15-20 mu m to obtain fine powder; mixing epoxy resin, cellulose ether, expanded vermiculite, magnesium hydroxide, sodium silicate, dimethyl silicone oil, isobutyl ketone, chlorinated paraffin, butyl latex, a thickening agent, a defoaming agent, an antibacterial agent and water, uniformly stirring, adding the prepared fine powder, and dispersing at a high speed for 15-20 minutes to obtain color paste;
fourthly, putting the film forming agent, the acid donor and the carbon donor into the mixture, uniformly stirring the mixture, adding the inorganic hollow filler into the mixture, and adjusting the pH value to be 4.3-5.5; after the preparation is finished, heating the mixture until the temperature is raised to 50-80 ℃, adding a foaming agent, a synergist and a solvent in the raw materials, carrying out reflux reaction, and then raising the temperature to 78-85 ℃ again, and carrying out constant-temperature reaction for 1.5-3 hours; after the reaction is finished, adding an adhesive in the raw materials to adjust the pH value of the solution to 7-9, cooling to be less than or equal to 70 ℃, vacuum dehydrating, cooling, and discharging to obtain a viscous substance which is a base material for later use;
step five, adding the catalyst, the charring agent and the color paste prepared in the step three into a stirring kettle, and uniformly stirring to obtain a mixed stirring material for later use; adding all the prepared mixed stirring materials into the base material, then adding additives in the raw materials, fully and uniformly stirring, and grinding again to remove impurities;
and step six, uniformly coating the coating in the step five on the fabric manufactured in the step two to obtain the fireproof yarn material for the zipper cloth strip.
Preferably, the modifier is obtained by ball milling and dispersing diatomite, bentonite, montmorillonite and alumina after mixing for 1-3 hours.
Preferably, the dispersing agent is prepared by mixing chitosan hydrochloride, polyvinylpyrrolidone, polymethyl acryloyloxyethyl trimethyl ammonium chloride and lignin, heating at 200-300 ℃ for 30min, cooling and grinding into powder.
Preferably, the spun yarn in the first step is formed by knitting cotton fibers, wool fibers and polyamide fibers, and then placing the knitted yarn in a dryer at 110-120 ℃ for 3-5 minutes.
Preferably, the catalyst is ammonium polyphosphate and the foaming agent is melamine.
Preferably, the charring agent is pentaerythritol.
Preferably, the preparation method of the adhesive comprises the steps of preparing starch slurry, and adjusting the pH value of the starch slurry to 8-10; adding a cross-linking agent into the starch slurry to carry out a cross-linking reaction; regulating the pH value of the starch slurry after the crosslinking reaction to 6-8 to obtain a mixed solution; and adding a plasticizer into the mixed solution, and preparing the adhesive through a heating and heat preservation process.
Preferably, the temperature stored in the fifth step is room temperature.
The invention provides a production process of a fireproof yarn material for zipper strips. The beneficial effects are as follows:
(1) The production process of the fireproof yarn material for the zipper strips has the advantages of good environmental protection performance, high flame retardant efficiency and the like, can continuously play a fireproof protection role, increases the flame retardant effect of the coating, prolongs the effective fireproof time of the coating, has strong adhesive force, and the cured product has excellent chemical corrosion resistance, heat resistance, acid and alkali resistance and good electrical insulation, and improves the fireproof capability of yarn raw materials.
(2) According to the production process of the fireproof yarn material for the zipper strips, the yarns are soaked in the solution, so that the strength and the softness of the yarns are increased, the yarns are convenient to weave, and the flexibility of the molded yarn material is increased.
Description of the embodiments
The technical solutions of the embodiments of the present invention will be clearly and completely described in the following in conjunction with the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, but not all embodiments.
Examples
The fireproof yarn material for the zipper strips is prepared from the following raw materials:
polyester, spandex, dispersing agent, modifier, glass beads, pigment, ammonium polyphosphate, curing agent, expanded graphite, epoxy resin, cellulose ether, expanded vermiculite, magnesium hydroxide, sodium silicate, simethicone, isobutyl ketone, chlorinated paraffin, butyl latex, thickener, defoamer, antibacterial agent, water, film former, acid donor, carbon donor, foaming agent, synergist, catalyst and charring agent, and the preparation method comprises the following steps:
step one, preparing a solution for enhancing the strength of spinning wires, placing the spinning wires in the solution for soaking for 15-20 minutes, then fishing out, airing in a room with the temperature of 30-40 ℃ for 4-8 hours, and carrying out standby after airing;
step two, uniformly mixing terylene, spandex, a dispersing agent and a modifying agent, and carrying out wiredrawing extrusion by a screw machine at the temperature of 250-300 ℃ to prepare the fabric;
step three, mixing glass beads, pigment, ammonium polyphosphate, curing agent, expanded graphite and solvent, uniformly stirring, and grinding at a high speed until the fineness is 15-20 mu m to obtain fine powder; mixing epoxy resin, cellulose ether, expanded vermiculite, magnesium hydroxide, sodium silicate, dimethyl silicone oil, isobutyl ketone, chlorinated paraffin, butyl latex, a thickening agent, a defoaming agent, an antibacterial agent and water, uniformly stirring, adding the prepared fine powder, and dispersing at a high speed for 15-20 minutes to obtain color paste;
fourthly, putting the film forming agent, the acid donor and the carbon donor into the mixture, uniformly stirring the mixture, adding the inorganic hollow filler into the mixture, and adjusting the pH value to be 4.3-5.5; after the preparation is finished, heating the mixture until the temperature is raised to 50-80 ℃, adding a foaming agent, a synergist and a solvent in the raw materials, carrying out reflux reaction, and then raising the temperature to 78-85 ℃ again, and carrying out constant-temperature reaction for 1.5-3 hours; after the reaction is finished, adding an adhesive in the raw materials to adjust the pH value of the solution to 7-9, cooling to be less than or equal to 70 ℃, vacuum dehydrating, cooling, and discharging to obtain a viscous substance which is a base material for later use;
step five, adding the catalyst, the charring agent and the color paste prepared in the step three into a stirring kettle, and uniformly stirring to obtain a mixed stirring material for later use; adding all the prepared mixed stirring materials into the base material, then adding additives in the raw materials, fully and uniformly stirring, and grinding again to remove impurities;
and step six, uniformly coating the coating in the step five on the fabric manufactured in the step two to obtain the fireproof yarn material for the zipper cloth strip.
The modifier is prepared by mixing diatomite, bentonite, montmorillonite and alumina, and then ball milling and dispersing for 1-3 hours.
The dispersing agent is prepared by mixing chitosan hydrochloride, polyvinylpyrrolidone, polymethyl acryloyloxyethyl trimethyl ammonium chloride and lignin, heating at 200-300 deg.C for 30min, cooling, and grinding into powder.
The spinning yarn in the first step is formed by knitting cotton fibers, wool fibers and polyamide fibers, and then placing the knitted yarn in a dryer at 110-120 ℃ for 3-5 minutes.
The catalyst is ammonium polyphosphate, and the foaming agent is melamine.
The charring agent is pentaerythritol.
The preparation method of the adhesive comprises the steps of preparing starch slurry, and adjusting the pH value of the starch slurry to 8-10; adding a cross-linking agent into the starch slurry to carry out a cross-linking reaction; regulating the pH value of the starch slurry after the crosslinking reaction to 6-8 to obtain a mixed solution; and adding a plasticizer into the mixed solution, and preparing the adhesive through a heating and heat preservation process.
The temperature stored in the fifth step is room temperature.
Examples
The fireproof yarn material for the zipper strips is prepared from the following raw materials:
polyester, spandex, dispersing agent, modifier, glass beads, pigment, ammonium polyphosphate, curing agent, expanded graphite, epoxy resin, cellulose ether, expanded vermiculite, magnesium hydroxide, sodium silicate, simethicone, isobutyl ketone, chlorinated paraffin, butyl latex, thickener, defoamer, antibacterial agent, water, film former, acid donor, carbon donor, foaming agent, synergist, catalyst and charring agent, and the preparation method comprises the following steps:
step one, preparing a solution for enhancing the strength of spinning wires, placing the spinning wires in the solution for soaking for 15 minutes, then fishing out, placing the spinning wires in a room with the temperature of 30 ℃ for airing for 4 hours, and carrying out standby after the airing is finished;
step two, uniformly mixing terylene, spandex, a dispersing agent and a modifying agent, and carrying out wiredrawing extrusion by a screw machine at the temperature of 250 ℃ to prepare a fabric;
step three, mixing glass beads, pigment, ammonium polyphosphate, curing agent, expanded graphite and solvent, uniformly stirring, and grinding at a high speed until the fineness is 15 mu m to obtain fine powder; mixing epoxy resin, cellulose ether, expanded vermiculite, magnesium hydroxide, sodium silicate, dimethyl silicone oil, isobutyl ketone, chlorinated paraffin, butyl latex, a thickening agent, a defoaming agent, an antibacterial agent and water, uniformly stirring, adding the prepared fine powder, and dispersing at a high speed for 15 minutes to obtain color paste;
fourthly, putting the film forming agent, the acid donor and the carbon donor into the mixture, uniformly stirring the mixture, adding the inorganic hollow filler into the mixture, and adjusting the pH value to be 4.3; after the preparation is finished, heating the mixture until the temperature is raised to 50 ℃, adding a foaming agent, a synergist and a solvent in the raw materials, carrying out reflux reaction, and then raising the temperature to 78 ℃ again, and carrying out constant-temperature reaction for 1.5h; after the reaction is finished, adding an adhesive in the raw materials to adjust the pH value of the solution to 7, cooling to be less than or equal to 70 ℃, vacuum dehydrating, cooling, and discharging to obtain a viscous substance which is a base material for later use;
step five, adding the catalyst, the charring agent and the color paste prepared in the step three into a stirring kettle, and uniformly stirring to obtain a mixed stirring material for later use; adding all the prepared mixed stirring materials into the base material, then adding additives in the raw materials, fully and uniformly stirring, and grinding again to remove impurities;
and step six, uniformly coating the coating in the step five on the fabric manufactured in the step two to obtain the fireproof yarn material for the zipper cloth strip.
The modifier is prepared by mixing diatomite, bentonite, montmorillonite and alumina, and then ball milling and dispersing for 1-3 hours.
The dispersing agent is prepared by mixing chitosan hydrochloride, polyvinylpyrrolidone, polymethyl acryloyloxyethyl trimethyl ammonium chloride and lignin, heating at 200-300 deg.C for 30min, cooling, and grinding into powder.
The spinning yarn in the first step is formed by knitting cotton fibers, wool fibers and polyamide fibers, and then placing the knitted yarn in a dryer at 110-120 ℃ for 3-5 minutes.
The catalyst is ammonium polyphosphate, and the foaming agent is melamine.
The charring agent is pentaerythritol.
The preparation method of the adhesive comprises the steps of preparing starch slurry, and adjusting the pH value of the starch slurry to 8-10; adding a cross-linking agent into the starch slurry to carry out a cross-linking reaction; regulating the pH value of the starch slurry after the crosslinking reaction to 6-8 to obtain a mixed solution; and adding a plasticizer into the mixed solution, and preparing the adhesive through a heating and heat preservation process.
The temperature stored in the fifth step is room temperature.
The foregoing is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art, who is within the scope of the present invention, should make equivalent substitutions or modifications according to the technical scheme of the present invention and the inventive concept thereof, and should be covered by the scope of the present invention.
Claims (8)
1. The fireproof yarn material for the zipper strips is prepared from the following raw materials:
polyester, spandex, dispersing agent, modifier, glass beads, pigment, ammonium polyphosphate, curing agent, expanded graphite, epoxy resin, cellulose ether, expanded vermiculite, magnesium hydroxide, sodium silicate, simethicone, isobutyl ketone, chlorinated paraffin, butyl latex, thickener, defoamer, antibacterial agent, water, film former, acid donor, carbon donor, foaming agent, synergist, catalyst and charring agent, and the preparation method comprises the following steps:
step one, preparing a solution for enhancing the strength of spinning wires, placing the spinning wires in the solution for soaking for 15-20 minutes, then fishing out, airing in a room with the temperature of 30-40 ℃ for 4-8 hours, and carrying out standby after airing;
step two, uniformly mixing terylene, spandex, a dispersing agent and a modifying agent, and carrying out wiredrawing extrusion by a screw machine at the temperature of 250-300 ℃ to prepare the fabric;
step three, mixing glass beads, pigment, ammonium polyphosphate, curing agent, expanded graphite and solvent, uniformly stirring, and grinding at a high speed until the fineness is 15-20 mu m to obtain fine powder; mixing epoxy resin, cellulose ether, expanded vermiculite, magnesium hydroxide, sodium silicate, dimethyl silicone oil, isobutyl ketone, chlorinated paraffin, butyl latex, a thickening agent, a defoaming agent, an antibacterial agent and water, uniformly stirring, adding the prepared fine powder, and dispersing at a high speed for 15-20 minutes to obtain color paste;
fourthly, putting the film forming agent, the acid donor and the carbon donor into the mixture, uniformly stirring the mixture, adding the inorganic hollow filler into the mixture, and adjusting the pH value to be 4.3-5.5; after the preparation is finished, heating the mixture until the temperature is raised to 50-80 ℃, adding a foaming agent, a synergist and a solvent in the raw materials, carrying out reflux reaction, and then raising the temperature to 78-85 ℃ again, and carrying out constant-temperature reaction for 1.5-3 hours; after the reaction is finished, adding an adhesive in the raw materials to adjust the pH value of the solution to 7-9, cooling to be less than or equal to 70 ℃, vacuum dehydrating, cooling, and discharging to obtain a viscous substance which is a base material for later use;
step five, adding the catalyst, the charring agent and the color paste prepared in the step three into a stirring kettle, and uniformly stirring to obtain a mixed stirring material for later use; adding all the prepared mixed stirring materials into the base material, then adding additives in the raw materials, fully and uniformly stirring, and grinding again to remove impurities;
and step six, uniformly coating the coating in the step five on the fabric manufactured in the step two to obtain the fireproof yarn material for the zipper cloth strip.
2. The process for producing a fireproof yarn material for a slide fastener tape according to claim 1, wherein: the modifier is prepared by mixing diatomite, bentonite, montmorillonite and alumina, and then performing ball milling and dispersing for 1-3 hours.
3. The process for producing a fireproof yarn material for a slide fastener tape according to claim 1, wherein: the dispersing agent is prepared by mixing chitosan hydrochloride, polyvinylpyrrolidone, polymethyl acryloyloxyethyl trimethyl ammonium chloride and lignin, heating at 200-300 ℃ for 30min, cooling and grinding into powder.
4. The process for producing a fireproof yarn material for a slide fastener tape according to claim 1, wherein: the spinning yarn in the first step is formed by weaving cotton fibers, wool fibers and polyamide fibers, and then is placed in a dryer at 110-120 ℃ for 3-5 minutes.
5. The process for producing a fireproof yarn material for a slide fastener tape according to claim 1, wherein: the catalyst is ammonium polyphosphate, and the foaming agent is melamine.
6. The process for producing a fireproof yarn material for a slide fastener tape according to claim 1, wherein: the charring agent is pentaerythritol.
7. The process for producing a fireproof yarn material for a slide fastener tape according to claim 1, wherein: the preparation method of the adhesive comprises the steps of preparing starch slurry, and adjusting the pH value of the starch slurry to 8-10; adding a cross-linking agent into the starch slurry to carry out a cross-linking reaction; regulating the pH value of the starch slurry after the crosslinking reaction to 6-8 to obtain a mixed solution; and adding a plasticizer into the mixed solution, and preparing the adhesive through a heating and heat preservation process.
8. The process for producing a fireproof yarn material for a slide fastener tape according to claim 1, wherein: the temperature stored in the fifth step is room temperature.
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| CN202310283304.2A CN116254707A (en) | 2023-03-22 | 2023-03-22 | Production process of fireproof yarn material for zipper strips |
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